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1. 发明授权

US5599870A Aqueous emulsion 失效
标题翻译：水乳液
公开(公告)号：US5599870A
公开(公告)日：1997-02-04
申请号：US407670
申请日：1995-03-21
申请人： Masato Nakamae , Naoki Fujiwara , Kazutoshi Terada , Daisuke Miyake , Ken Yuki , Toshiaki Sato , Hitoshi Maruyama
发明人： Masato Nakamae , Naoki Fujiwara , Kazutoshi Terada , Daisuke Miyake , Ken Yuki , Toshiaki Sato , Hitoshi Maruyama
IPC分类号： B01F17/52 , C08F2/30 , C08L29/00 , C09J133/04 , C08L29/04
CPC分类号： C08F2/30 , C09J133/04 , C08L29/00 , Y10S516/06 , Y10S526/911 , Y10S526/912
摘要： The present invention relates to an aqueous emulsion comprising a dispersant of a modified polyvinyl alcohol with an ethylene unit content of 2 to 9 mol % and a degree of hydrolysis of at least 95 mol %, a dispersoid of a polymer of an ethylenically unsaturated monomer, and a ratio (.eta.2 rpm/.eta.20 rpm) of Brookfield viscosity at 30.degree. C., 2 rpm (.eta.2 rpm) as against Brookfield viscosity at 30.degree. C., 20 rpm (.eta.20 rpm) being 1 to 1.8 when the latter viscosity (.eta.20 rpm) is adjusted to 5,000 to 10,000 mPa.multidot.S.The aqueous emulsion according to the present invention is excellent in structural viscosity (flowability, high speed application performance), provides coated layers with high water resistance and low-temperature stability, and can be suitably used extensively as an adhesive for paper, wood and plastics, as a binder for impregnated paper and non-woven products, as an additive for mortar, as a paint, and in paper and fiber processings.
摘要翻译：本发明涉及含有乙烯单元含量为2〜9mol％，水解度为95mol％以上的改性聚乙烯醇的分散剂，烯键式不饱和单体的聚合物的分散体，并且在30℃下，Brookfield粘度在30℃，2rpm（eta 2rpm）下的Brookfield粘度与20℃下的Brookfield粘度（20rpm）的比（η2rpm /η20rpm）为1至1.8当将后一粘度（η20rpm）调节至5,000至10,000mPaxS。本发明的水性乳液的结构粘度（流动性，高速涂布性）优异，可提供耐水性和低温稳定性的涂布层，可广泛适用于纸，木材，塑料的粘合剂作为浸渍纸和无纺布产品的粘合剂，作为砂浆添加剂，作为涂料，以及纸和纤维加工。

2. 发明授权

US5331055A Process for producing vinyl ester polymer and process for producing vinyl alcohol polymer 失效
标题翻译：制备乙烯基酯聚合物的方法和生产乙烯醇聚合物的方法
公开(公告)号：US5331055A
公开(公告)日：1994-07-19
申请号：US928774
申请日：1992-08-17
申请人： Naoki Fujiwara , Kazutoshi Terada , Hitoshi Maruyama
发明人： Naoki Fujiwara , Kazutoshi Terada , Hitoshi Maruyama
IPC分类号： C08F2/24 , C08F8/12 , C08F263/00 , C08F2/30
CPC分类号： C08F263/00 , C08F8/12 , C08J5/18
摘要： There are disclosed a process for producing a vinyl ester polymer having a high degree of polymerization at a high efficiency, which process comprises subjecting a vinyl ester monomer to seed polymerization by the use of a vinyl ester polymer emulsion as a seed emulsion under the conditions in which the charge of a water-soluble initiator per unit volume (1 liter) of reactant liquid charge is 1.times.10.sup.-8 to 2.times.10.sup.-4 mol, and the charge of the water-soluble initiator per one particle of the vinyl ester polymer particles in the seed emulsion is 1.times.10.sup.-28 to 1.times.10.sup.-20 mol, and a process for producing a vinyl alcohol polymer at a high efficiency from the vinyl ester polymer thus obtained.According to these processes of the present invention, both a vinyl ester polymer and vinyl alcohol polymer each having a higher degree of polymerization can be produced with ease on an industrial scale.
摘要翻译：公开了一种以高效率生产高聚合度的乙烯基酯聚合物的方法，该方法包括使乙烯基酯单体通过使用乙烯基酯聚合物乳液作为种子乳液进行种子聚合，其中每单位体积（1升）反应物液体电荷的水溶性引发剂的电荷为1×10 -8至2×10 -4摩尔，并且每1个乙烯基酯聚合物颗粒中的水溶性引发剂的电荷种子乳液为1×10-28至1×10-20mol，以及由此获得的乙烯基酯聚合物以高效率生产乙烯醇聚合物的方法。根据本发明的这些方法，可以容易地以工业规模生产各自具有较高聚合度的乙烯基酯聚合物和乙烯醇聚合物。

3. 发明授权

US5308911A Secondary suspending agent for suspension polymerization of vinyl compound 失效
标题翻译：乙烯基化合物悬浮聚合用二次悬浮剂
公开(公告)号：US5308911A
公开(公告)日：1994-05-03
申请号：US28181
申请日：1993-03-09
申请人： Shigeki Takada , Hitoshi Maruyama , Naoki Fujiwara , Kazutoshi Terada
发明人： Shigeki Takada , Hitoshi Maruyama , Naoki Fujiwara , Kazutoshi Terada
IPC分类号： C08F2/20 , C08F14/06 , C08L29/04 , C08F2/00
CPC分类号： C08F2/20 , C08F14/06
摘要： There are disclosed a secondary suspending agent for suspension polymerization of a vinyl compound (vinyl chloride, etc.) which comprises an aqueous dispersion comprising as the dispersoid, a polyvinyl ester having a degree of hydrolysis of 60 mol% or less, an average degree of polymerization of 4000 or more and an average particle diameter of 100 .mu.m or less; a suspension stabilizing agent comprising 5 to 70% by weight of the secondary suspending agent (PVA, etc.) and 30 to 95% by weight of a water-soluble high molecular compound having a degree of polymerization of 500 or more, the agent being used for suspension polymerization of a vinyl compound; and a process for producing a vinyl polymer (PVC, etc.) comprising suspension polymerizing a vinyl compound by the use of the above suspension stabilizing agent. Both the agents are well suited for producing vinyl polymer granules enhanced in absorption rate of plasticizer, bulk density, removality of residual monomer and porosity.
摘要翻译：公开了一种乙烯基化合物（氯乙烯等）的悬浮聚合用二次悬浮剂，其包含含有分散体的水分散体，水解度为60摩尔％以下的聚乙烯基酯，聚合4000以上，平均粒径为100μm以下; 包含5〜70重量％的二次悬浮剂（PVA等）和30〜95重量％的聚合度为500以上的水溶性高分子化合物的悬浮稳定剂，试剂为用于乙烯基化合物的悬浮聚合; 以及包含通过使用上述悬浮稳定剂使乙烯基化合物悬浮聚合的乙烯基聚合物（PVC等）的制造方法。这两种试剂都非常适合生产提高增塑剂吸收速率，堆积密度，残留单体去除率和孔隙率的乙烯基聚合物颗粒。

4. 发明授权

US07981958B1 Synthetic resin emulsion powder 有权
标题翻译：合成树脂乳液粉末
公开(公告)号：US07981958B1
公开(公告)日：2011-07-19
申请号：US10653056
申请日：2003-09-03
申请人： Seiji Tanimoto , Tetsuo Murakami , Masato Nakamae , Naoki Fujiwara
发明人： Seiji Tanimoto , Tetsuo Murakami , Masato Nakamae , Naoki Fujiwara
IPC分类号： C08J3/12
CPC分类号： C08J3/122 , C08L31/04 , C08L2205/02 , C08L2666/04
摘要： Disclosed is a synthetic resin emulsion powder obtained by spray-drying a composition that comprises an emulsion (A) where the dispersoid is a polymer that having one or more unsaturated monomer units selected from ethylenic unsaturated monomers and dienic monomers, and a polyvinyl alcohol (B) having, in the molecule, from 1 to 12 mol % of ethylene units. The emulsion powder has good redispersibility and good water resistance. Its redispersion well form good films and has good storage stability at low temperatures. The emulsion powder is favorable for additives to hydraulic substances, as it well disperses in hydraulic substances such as cement mortar and gives hardened articles of high mechanical strength. The emulsion powder is also favorable for joint materials for hydraulic substances, as its adhesiveness and durability are both good and gives jointed articles of high mechanical strength.
摘要翻译：公开了通过喷雾干燥包含乳液（A）的组合物获得的合成树脂乳液粉末，其中分散质是具有一个或多个选自烯属不饱和单体和二烯单体的不饱和单体单元的聚合物和聚乙烯醇（B ）在分子中具有1至12mol％的乙烯单元。乳液粉末具有良好的再分散性和良好的耐水性。其再分散形成良好的膜，并且在低温下具有良好的储存稳定性。乳液粉末有利于水硬性物质的添加剂，因为它很好地分散在诸如水泥砂浆的水硬物质中，并且产生具有高机械强度的硬化制品。乳液粉末对于水硬性物质的接合材料也是有利的，因为其粘合性和耐久性均良好，并且具有高机械强度的接合制品。

5. 发明申请

US20080293884A1 SYNTHETIC RESIN EMULSION POWDER 审中-公开
标题翻译：合成树脂乳化粉
公开(公告)号：US20080293884A1
公开(公告)日：2008-11-27
申请号：US12147530
申请日：2008-06-27
申请人： Seiji Tanimoto , Tetsuo Murakami , Masato Nakamae , Naoki Fujiwara
发明人： Seiji Tanimoto , Tetsuo Murakami , Masato Nakamae , Naoki Fujiwara
IPC分类号： C08L29/04
CPC分类号： C08J3/122 , C08L31/04 , C08L2205/02 , C08L2666/04
摘要： Disclosed is a synthetic resin emulsion powder obtained by spray-drying a composition that comprises an emulsion (A) where the dispersoid is a polymer that having one or more unsaturated monomer units selected from ethylenic unsaturated monomers and dienic monomers, and a polyvinyl alcohol (B) having, in the molecule, from 1 to 12 mol % of ethylene units. The emulsion powder has good redispersibility and good water resistance. Its redispersion well form good films and has good storage stability at low temperatures. The emulsion powder is favorable for additives to hydraulic substances, as it well disperses in hydraulic substances such as cement mortar and gives hardened articles of high mechanical strength. The emulsion powder is also favorable for joint materials for hydraulic substances, as its adhesiveness and durability are both good and gives jointed articles of high mechanical strength.
摘要翻译：公开了通过喷雾干燥包含乳液（A）的组合物获得的合成树脂乳液粉末，其中分散质是具有一个或多个选自烯属不饱和单体和二烯单体的不饱和单体单元的聚合物和聚乙烯醇（B ）在分子中具有1至12mol％的乙烯单元。乳液粉末具有良好的再分散性和良好的耐水性。其再分散形成良好的膜，并且在低温下具有良好的储存稳定性。乳液粉末有利于水硬性物质的添加剂，因为它很好地分散在诸如水泥砂浆的水硬物质中，并且产生高机械强度的硬化物品。乳液粉末对于水硬性物质的接合材料也是有利的，因为其粘合性和耐久性均良好，并且具有高机械强度的接合制品。

6. 发明授权

US6156840A Method for producing aqueous emulsion of polyurethane 有权
标题翻译：生产聚氨酯水乳液的方法
公开(公告)号：US6156840A
公开(公告)日：2000-12-05
申请号：US233047
申请日：1999-01-19
申请人： Masato Nakamae , Seiji Tanimoto , Mitsuru Kato , Naoki Fujiwara
发明人： Masato Nakamae , Seiji Tanimoto , Mitsuru Kato , Naoki Fujiwara
IPC分类号： C08G18/08 , C08G18/12 , C08G18/62 , C09D175/04 , C08J3/00 , C08G18/00 , C08K3/20 , C08L75/00
CPC分类号： C09D175/04 , C08G18/0823 , C08G18/12 , C08G18/6212 , C08G18/6283 , C08G2170/80
摘要： Provided is a method for producing a polyurethane (PU) emulsion having good solvent resistance and water resistance and having good compatibility with other aqueous emulsions to give stable mixtures with them. The method comprises reacting (A) a PU prepolymer having an isocyanate group in the molecule, (B) a modified PVA having at least one member selected from the group consisting of an amino group, a primary hydroxyl group and an acetoacetyl group and (C) a low-molecular compound having an amino group and/or a hydroxyl group, in an aqueous medium.
摘要翻译：本发明提供了具有良好的耐溶剂性和耐水性且与其它水性乳液具有良好相容性的聚氨酯（PU）乳液的制备方法，以与它们形成稳定的混合物。该方法包括使（A）在分子中具有异氰酸酯基的PU预聚物，（B）具有选自氨基，伯羟基和乙酰乙酰基中的至少一种的改性PVA，和（C ）具有氨基和/或羟基的低分子化合物。

7. 发明授权

US5866655A Vinyl alcohol polymer 失效
标题翻译：乙烯醇聚合物
公开(公告)号：US5866655A
公开(公告)日：1999-02-02
申请号：US864738
申请日：1997-05-28
申请人： Naoki Fujiwara , Takeshi Kusudou , Takaharu Kawahara , Toshiaki Sato
发明人： Naoki Fujiwara , Takeshi Kusudou , Takaharu Kawahara , Toshiaki Sato
IPC分类号： C08F8/12 , C08F16/06
CPC分类号： C08F16/06 , C08F8/12 , C08F2800/10
摘要： A vinyl alcohol polymer with a side chain being a hydroxyalkyl group having 2 to 20 carbon atoms is disclosed. Conventional water-soluble vinyl alcohol polymers gives, where they have a high interfacial activity, an aqueous solution with much-foaming and hence a problem when used for commercial purposes. On the other hand, the vinyl alcohol polymer of the present invention gives, where it is water-soluble, an aqueous solution with less-foaming in spite of its high interfacial activity, and hence an excellent industrial applicability. The vinyl alcohol polymer of the present invention is useful as thermoplastic resin and dispersion stabilizer. In addition, the vinyl alcohol polymer of the present invention is usable for various purposes, e.g. surfactants for various uses, paper coating agent, quality-improving agent for paper such as paper ingredients and pigment binders, adhesive for wood, paper, aluminum foil and inorganic materials, binder for nonwoven fabric, paint, warp sizing agent, fiber-processingagent, sizing agent for hydrophobic fibers such as polyester fiber, various films and sheets, bottles and fibers.
摘要翻译：公开了具有侧链为碳原子数2〜20的羟烷基的乙烯醇聚合物。常规的水溶性乙烯醇聚合物在其具有高界面活性的情况下，具有大量起泡的水溶液，因此在用于商业目的时产生问题。另一方面，本发明的乙烯醇聚合物尽管具有高的界面活性，但在水溶性的情况下给出了发泡少的水溶液，因此具有优异的工业实用性。本发明的乙烯醇聚合物可用作热塑性树脂和分散稳定剂。此外，本发明的乙烯醇聚合物可用于各种目的，例如，用于各种用途的表面活性剂，纸张涂布剂，纸成分和颜料粘合剂等纸张质量改进剂，木材用粘合剂，纸，铝箔和无机材料，无纺布用粘合剂，油漆，经纱上浆剂，纤维加工剂，疏水纤维如聚酯纤维，各种薄膜和片材，瓶子和纤维的上浆剂。

8. 发明授权

US06632878B1 Production process for polymers with hydroxyl groups and polymers obtained by the process 失效
标题翻译：通过该方法获得的具有羟基和聚合物的聚合物的制备方法
公开(公告)号：US06632878B1
公开(公告)日：2003-10-14
申请号：US09631287
申请日：2000-08-02
申请人： Yoichi Matsumoto , Naoki Fujiwara , Toshiaki Sato , Fumio Nakahara
发明人： Yoichi Matsumoto , Naoki Fujiwara , Toshiaki Sato , Fumio Nakahara
IPC分类号： C08F812
CPC分类号： C08F8/12 , C08F2800/10 , C08F118/08 , C08F218/08 , C08F210/02 , C08F116/18
摘要： A hydroxyl group containing polymer is prepared by a process, comprising: contacting the polymer having a substituent with high temperature, high pressure water, thereby converting the substituent to hydroxyl groups.
摘要翻译：通过一种方法制备含羟基的聚合物，其包括：使具有取代基的聚合物与高温高压水接触，从而将取代基转化为羟基。

9. 发明授权

US5885720A Paper coating agent 失效
标题翻译：纸张涂布剂
公开(公告)号：US5885720A
公开(公告)日：1999-03-23
申请号：US974978
申请日：1997-11-20
申请人： Naoki Fujiwara , Sadahiko Shiraga , Kazuhiko Ootake , Toshiaki Sato
发明人： Naoki Fujiwara , Sadahiko Shiraga , Kazuhiko Ootake , Toshiaki Sato
IPC分类号： D21H19/12 , B32B23/08
CPC分类号： D21H19/12 , Y10T428/31895
摘要： Disclosed herein is a paper coating agent which comprises a modified polyvinyl alcohol (A) containing 3 to 15 mol % of ethylene units and an alkali metal ion (B), with the ratio of component (A) to component (B) being 100:0.003 to 100:1 in parts by weight. Disclosed also herein is a heat-sensitive recording material which comprises a coating layer on a substrate, said coating layer comprising a modified polyvinyl alcohol containing 3 to 15 mol % of ethylene units.The paper coating agent of the present invention has such excellent solubility in boiling water that there is not a problem of insoluble matter in an aqueous solution of the coating agent. When applied for a paper surface coating agent, it gives coated paper without discoloration, superior, in surface strength, air barrier properties, and printability. When applied for a paper pigmented coating agent, it gives coated paper without discoloration, superior in water resistance and printability.The heat-sensitive recording material of the present invention is superior in color developing sensitivity, water resistance, oil resistance, plasticizer resistance, and PVC film resistance. Furthermore it is superior in high-speed printability and image resolution, and it can be used in the field, such as facsimile, where high-speed printing is required.
摘要翻译：本文公开了一种纸涂层剂，其包含含有3至15mol％的乙烯单元和碱金属离子（B）的改性聚乙烯醇（A），组分（A）与组分（B）的比例为100： 0.003〜100:1重量份。本文还公开了一种热敏记录材料，其包括在基材上的涂层，所述涂层包含含有3至15mol％乙烯单元的改性聚乙烯醇。本发明的纸张涂布剂在沸水中的溶解性优异，在涂布剂的水溶液中不存在不溶物质的问题。当涂布纸表面涂层剂时，它可以使涂布纸无变色，表面强度，空气阻隔性和可印刷性优异。当涂布纸颜料涂布剂时，其涂布纸不变色，耐水性和印刷性优异。本发明的热敏记录材料的显色灵敏度，耐水性，耐油性，耐增塑剂性和耐PVC膜性优异。此外，它在高速可打印性和图像分辨率方面是优越的，并且可以在诸如需要高速打印的传真机等领域中使用。

10. 发明授权

US5710211A Process for producing vinyl alcohol polymer 失效
标题翻译：制备乙烯醇聚合物的方法
公开(公告)号：US5710211A
公开(公告)日：1998-01-20
申请号：US684484
申请日：1996-07-19
申请人： Toshiaki Sato , Naoki Fujiwara , Atsushi Jikihara
发明人： Toshiaki Sato , Naoki Fujiwara , Atsushi Jikihara
IPC分类号： C08F8/12 , C08F8/34 , C08F8/00
CPC分类号： C08F8/34
摘要： According to the present invention, there are provided a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (A) having an epoxy group with a compound (B) having a thiol or thioester group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction; and a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (C) having a thiol or thioester group with a compound (D) having an epoxy group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction. According to the present invention, it is possible to efficiently introduce into PVA various functional groups having excellent reactivity, crosslinkability, ionic interactivity, water-solubility, interfacial physical properties, low-temperature flexibility, etc., under relatively mild reaction conditions. According to the present invention, in addition, it is possible to introduce into PVA such various functional groups, which could not be obtained by conventional methods.
摘要翻译：根据本发明，提供一种乙烯醇聚合物的制造方法，其包括具有环氧基的乙烯基酯聚合物（A）与具有硫醇或硫酯基的化合物（B）的反应及其水解反应，所述水解为在所述反应期间或之后进行; 以及包括具有硫醇或硫酯基的乙烯基酯聚合物（C）与具有环氧基的化合物（D）的水解反应的乙烯醇聚合物的方法，所述水解在所述反应期间或之后进行。根据本发明，在相对温和的反应条件下，可以有效地向PVA中引入具有优异的反应性，交联性，离子交互性，水溶性，界面物理性质，低温柔韧性等的各种官能团。根据本发明，另外，可以将常规方法不能得到的各种官能团引入到PVA中。

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