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1. 发明授权

US6008502A Diamond electron emitting device having an insulative electron supply layer 失效
标题翻译：具有绝缘电子供应层的金刚石电子发射器件
公开(公告)号：US6008502A
公开(公告)日：1999-12-28
申请号：US945877
申请日：1997-11-03
申请人： Masahiro Deguchi , Akio Hiraki , Toshimichi Ito , Akimitsu Hatta , Nobuhiro Eimori , Makoto Kitabatake
发明人： Masahiro Deguchi , Akio Hiraki , Toshimichi Ito , Akimitsu Hatta , Nobuhiro Eimori , Makoto Kitabatake
IPC分类号： H01J1/312 , H01L29/06 , H01L29/12
CPC分类号： B82Y10/00 , H01J1/312 , H01J2201/30457
摘要： The present invention provides an electron emitting device for efficiently emitting electron beams by applying a forward bias to an MIS, pn, and a pin structure using a diamond layer so as to supply electrons from an electron supply layer to a p-type diamond layer. Furthermore, the present invention provides a method for easily and efficiently performing important production processes for producing a highly efficient electron emitting device having a diamond layer and controlling a surface state of the diamond layer. A multi-layer structure including an electrode layer, an electron supply layer and a diamond layer is used as the structure thereof. Alternatively, the electron affinity state of the surface of the diamond layer is arbitrarily controlled by a method such as ultraviolet ray irradiation.
摘要翻译： PCT No.PCT / JP97 / 01031 Sec。 371日期：1997年11月3日 102（e）日期1997年11月3日PCT 1997年3月26日PCT公布。公开号WO97 / 36309 日期1997年10月2日本发明提供了一种电子发射器件，用于通过使用金刚石层向MIS，pn和引脚结构施加正向偏压来有效地发射电子束，以便将电子从电子供给层提供给p 型金刚石层。此外，本发明提供了一种方法，用于容易且有效地执行用于制造具有金刚石层并控制金刚石层的表面状态的高效电子发射器件的重要生产方法。使用包括电极层，电子供给层和金刚石层的多层结构作为其结构。或者，通过紫外线照射等方法任意地控制金刚石层的表面的电子亲合性。

2. 发明授权

US06337060B1 Hydrophilic diamond particles and method of producing the same 失效
标题翻译：亲水性金刚石颗粒及其制备方法
公开(公告)号：US06337060B1
公开(公告)日：2002-01-08
申请号：US08662022
申请日：1996-06-12
申请人： Akio Hiraki , Toshimichi Ito , Akimitsu Hatta , Hiroshi Makita , Kazuhito Nishimura , Hiroshi Ishizuka , Satoru Hosomi
发明人： Akio Hiraki , Toshimichi Ito , Akimitsu Hatta , Hiroshi Makita , Kazuhito Nishimura , Hiroshi Ishizuka , Satoru Hosomi
IPC分类号： C01B3106
CPC分类号： C01B32/28
摘要： The principal objects of the invention is to provide diamond fine particles with a surface nature so improved as to form a stable, uniform suspension or dispersion in a common medium such as water and alcohol. Another object is to provide an effective technique for producing hydrophilic diamond fine particles by chemically modifying the particle surface nature, while removing at the same time contaminants and foreign materials which coexist with the diamond. In the invention, diamond particles are treated by boiling in the treatment fluid of sulfuric acid solution, which is in particular of concentrated or fuming nature, at a temperature more than 200° C., which is preferably 250° C. or more.
摘要翻译：本发明的主要目的是提供具有如此改进的表面性质的金刚石细颗粒，以在普通介质如水和醇中形成稳定的均匀悬浮液或分散体。另一个目的是提供通过化学改性颗粒表面性质同时同时除去与金刚石共存的污染物和异物来生产亲水性金刚石细颗粒的有效技术。在本发明中，金属颗粒在温度超过200℃，优选为250℃以上的温度下，在特别浓缩或发烟性质的硫酸溶液的处理液中沸腾处理。

3. 发明授权

US4078017A Process for production of modified polypropylene 失效
标题翻译：生产改性聚丙烯的方法
公开(公告)号：US4078017A
公开(公告)日：1978-03-07
申请号：US774202
申请日：1977-03-03
申请人： Kikuo Nagatoshi , Toshimichi Ito , Atsunobu Sakoda , Akio Inayoshi , Noriki Fujimoto , Hidehiko Kaji , Hirozo Sugahara
发明人： Kikuo Nagatoshi , Toshimichi Ito , Atsunobu Sakoda , Akio Inayoshi , Noriki Fujimoto , Hidehiko Kaji , Hirozo Sugahara
IPC分类号： C08F8/00 , C08F8/46 , C08F255/00 , C08F291/00 , C08F291/02 , C08L9/00 , C08L23/02 , C08L23/12 , C08L23/26 , C08L51/06 , C08F255/02
CPC分类号： C08F291/02 , C08F255/00 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/26 , C08L2312/00 , C08L2555/40 , C08L51/06 , C08L9/00
摘要： A process for producing modified polypropylene comprising reacting polypropylene with a liquid rubber and maleic anhydride in a solvent in the presence of a radical generator.
摘要翻译：一种生产改性聚丙烯的方法，包括在自由基发生剂存在下，使聚丙烯与液体橡胶和马来酸酐在溶剂中反应。

4. 发明授权

US5334453A Diamond-coated bodies and process for preparation thereof 失效
标题翻译：金刚石涂层体及其制备方法
公开(公告)号：US5334453A
公开(公告)日：1994-08-02
申请号：US905199
申请日：1992-06-26
申请人： Satoshi Iio , Masakazu Watanabe , Toshimichi Ito , Masaya Tsubokawa
发明人： Satoshi Iio , Masakazu Watanabe , Toshimichi Ito , Masaya Tsubokawa
IPC分类号： C04B41/50 , C04B41/85 , C23C16/02 , C23C16/27 , B23P15/28 , B23B27/20
CPC分类号： C23C16/27 , C04B41/5002 , C04B41/85 , C23C16/0209 , Y10T428/30
摘要： A diamond-coated body is prepared by coating a diamond film on the surface of a sintered body by means of vapor phase synthesis, the sintered body being so prepared by subjecting a sintered body prepared from ceramics based on silicon nitride to heat treatment at the temperature of 1,400.degree. C. to 1,700.degree. C. as to give a crystalline intergranular phase. The resulting diamond-coated body has excellent adhesion between the diamond film and the substrate and it is appropriately employed for cutting tools and so on because, when applied to the cutting tools, they can be used for cutting for a long period of time.
摘要翻译：通过气相合成在烧结体的表面上涂布金刚石膜来制备金刚石涂层体，该烧结体通过将由氮化硅制成的陶瓷制成的烧结体在温度下进行热处理 1400℃至1700℃，以产生结晶晶间相。所得到的金刚石涂层体在金刚石膜和基材之间具有优异的粘合性，并且适用于切削工具等，因为当应用于切削工具时，它们可以长时间地切割。

5. 发明授权

US4181689A Resin compositions containing modified polypropylene 失效
标题翻译：含有改性聚丙烯的树脂组合物
公开(公告)号：US4181689A
公开(公告)日：1980-01-01
申请号：US951364
申请日：1978-10-16
申请人： Kikuo Nagatoshi , Toshimichi Ito , Akio Inayoshi , Atsunobu Sakoda , Noriki Fujimoto , Hidehiko Kaji , Hirozo Sugahana
发明人： Kikuo Nagatoshi , Toshimichi Ito , Akio Inayoshi , Atsunobu Sakoda , Noriki Fujimoto , Hidehiko Kaji , Hirozo Sugahana
IPC分类号： C08F8/46 , C08F255/02 , C08F291/02 , C08L9/00 , C08L23/02 , C08L23/12 , C08L23/26 , C08L51/06
CPC分类号： C08F291/02 , C08F255/02 , C08L23/02 , C08L23/10 , C08L23/12 , C08L23/26 , C08L2555/40 , C08L51/06 , C08L9/00
摘要： A resin composition comprising a modified polypropylene obtained by reacting a polypropylene with a liquid rubber and maleic anhydride in a solvent in the presence of a radical generator, another polyolefin and, if desired, an inorganic and/or an organic filler.The resin composition has excellent coating, adhesion and plating properties.
摘要翻译：一种树脂组合物，其包含通过在自由基发生剂，另一种聚烯烃和如果需要的情况下使无机和/或有机填料存在下，使聚丙烯与液体橡胶和马来酸酐在溶剂中反应获得的改性聚丙烯。树脂组合物具有优异的涂层，粘合性和电镀性能。

6. 发明授权

US5318836A Diamond-coated body 失效
标题翻译：金刚石涂层体
公开(公告)号：US5318836A
公开(公告)日：1994-06-07
申请号：US911803
申请日：1992-07-10
申请人： Toshimichi Ito , Masaya Tsubokawa , Masakazu Watanabe , Satoshi Iio
发明人： Toshimichi Ito , Masaya Tsubokawa , Masakazu Watanabe , Satoshi Iio
IPC分类号： B23P15/28 , C04B41/50 , C04B41/85 , C09K3/14 , C04B41/87
CPC分类号： C04B41/009 , B23P15/28 , C04B35/593 , C04B41/5001 , C04B41/5002 , C04B41/52 , C04B41/85 , C09K3/1436 , C04B2235/3206 , C04B2235/3217 , C04B2235/3225 , C04B2235/3244 , C04B2235/3873 , C04B2235/5409 , C04B2235/5445 , C04B2235/656 , C04B2235/77 , C04B2235/785 , C04B2235/786 , C04B2235/788 , Y10T428/25 , Y10T428/265 , Y10T428/30
摘要： The present invention is directed to a diamond-coated body having a diamond coat film formed on the surface of a ceramic substrate containing acicular grains having a thickness of 0.2 .mu.m to 1 .mu.m and an aspect ratio of 2 or higher at the two-dimensional density of 30% or higher, and the diamond coat film has good adhesion to the ceramic substrate. Thus the diamond-coated body is superior in durability and can be appropriately utilized as cutting tools and so on.
摘要翻译： PCT No.PCT / JP90 / 00782 Sec。 371日期：1991年4月4日 102（e）日期1991年4月4日PCT Filed 1990年6月15日PCT公布。出版物WO90 / 15787 日本1990年12月27日。本发明涉及一种金刚石涂层体，其具有形成在陶瓷基板的表面上的金刚石涂膜，该陶瓷基板含有厚度为0.2μm〜1μm的针状晶粒，纵横比为 2以上，二维密度为30％以上，金刚石涂膜对陶瓷基板具有良好的粘附性。因此，金刚石涂层体的耐久性优异，可以适当地用作切削工具等。

7. 发明授权

US5258206A Method and apparatus for producing diamond thin films 失效
标题翻译：制造金刚石薄膜的方法和装置
公开(公告)号：US5258206A
公开(公告)日：1993-11-02
申请号：US813041
申请日：1991-12-23
申请人： Nariyuki Hayashi , Toshimichi Ito
发明人： Nariyuki Hayashi , Toshimichi Ito
IPC分类号： C23C16/27 , C23C16/458 , C30B25/12 , B05D3/06 , B01J3/06
CPC分类号： C23C16/27 , C23C16/274 , C23C16/277 , C23C16/458 , C30B25/12
摘要： The present invention concerns a method of producing a diamond thin film. A plasma-activated gas, obtained by exciting a starting material containing a carbon source gas, is brought into contact with a surface of a substrate, on which a diamond thin film is to be formed under the presence of an auxiliary member placed adjacent to a protruded portion present at the surface of the substrate. The diamond thin film is thereby formed on the substrate. An apparatus for producing a diamond thin film by means of a microwave plasma method has an auxiliary member placed adjacent to a protruded portion present at the surface of the substrate on which the diamond thin film is to be formed.
摘要翻译：本发明涉及一种制造金刚石薄膜的方法。通过激发含有碳源气体的原料而获得的等离子体活化气体与在与其邻接设置的辅助构件的存在下将要形成金刚石薄膜的基板的表面接触存在于基板表面的突出部分。由此，在基板上形成金刚石薄膜。通过微波等离子体法制造金刚石薄膜的装置具有与存在于其上将要形成金刚石薄膜的基板表面上的突出部分相邻放置的辅助部件。

8. 发明授权

US4990403A Diamond coated sintered body 失效
标题翻译：金刚石涂层烧结体
公开(公告)号：US4990403A
公开(公告)日：1991-02-05
申请号：US459626
申请日：1990-01-02
申请人： Toshimichi Ito
发明人： Toshimichi Ito
IPC分类号： B24D3/10 , C04B41/50 , C04B41/85 , C23C16/26
CPC分类号： C04B41/009 , B24D3/10 , C04B41/5002 , C04B41/85 , C23C16/26 , Y10S428/936 , Y10T428/30
摘要： The present invention provides a diamond coated sintered body characterized by having a diamond film formed by a gas phase synthesis method on the surface of a sintered body obtained from a mixture of tungsten carbide and at least one compound selected from the group consisting of carbide and nitride of silicon or boron and, if necessary, additionally at least one compound selected from the group consisting of carbide, oxide, nitride, carbonitride, carbonate, boride and organic compound of at least one element selected from the group consisting of metals and rare earth elements belonging to Groups Ia, IIa, IIIa, IVa, Va, IIIb and IVb of the Mendelejeff's periodic table.
摘要翻译：本发明提供一种金刚石涂层烧结体，其特征在于，在碳化物与选自碳化物和氮化物的至少一种化合物的混合物中，在烧结体的表面上具有通过气相合成法形成的金刚石膜的硅或硼，并且如果需要另外选自碳化物，氧化物，氮化物，碳氮化物，碳酸盐，硼化物和选自金属和稀土元素中的至少一种元素的有机化合物中的至少一种化合物属于Mendelejeff周期表的Ia，IIa，IIIa，IVa，Va，IIIb和IVb族组。

9. 发明授权

US6150427A Foaming propylene copolymer, and foamed particles and foams thereof 失效
标题翻译：发泡丙烯共聚物，发泡颗粒和泡沫
公开(公告)号：US6150427A
公开(公告)日：2000-11-21
申请号：US147735
申请日：1999-02-26
申请人： Toshimichi Ito , Yasushi Seta , Ryoichi Tsunori
发明人： Toshimichi Ito , Yasushi Seta , Ryoichi Tsunori
IPC分类号： C08J9/18 , C08F210/06 , C08F210/16 , C08J9/16 , C08J9/228 , C08J9/20 , C08J9/22
CPC分类号： C08J9/16 , C08F210/06 , C08F210/16 , C08J2323/16
摘要： Provided are a foaming propylene-ethylene random copolymer which is characterized in that (1) its ethylene unit content [x (wt. %)] falls between 0.2 and 10% by weight, (2) its MI falls between 1 and 16 g/10 min, (3) its boiling diethyl ether extraction [E (wt. %)] and x satisfy the relation of a formula (I):E.ltoreq.0.25x+1.1 (I),(4) its melting point [Tm (.degree. C.)] and x satisfy the relation of a formula (II):Tm.ltoreq.165-5x (II),(5) its isotactic triad fraction in the PPP chain moiety as measured through .sup.13 C.ltoreq.NMR is not smaller than 98 mol %, and preferably, (6) the relation between the time of relaxation .tau. (sec) of the copolymer and MI of the copolymer satisfies a formula (III):.tau..ltoreq.0.80-0.42.times.log MI (III),and also its foaming beads and cellular articles. The copolymer and its foaming beads have improved primary and secondary foamability, and the cellular articles of the copolymer have excellent mechanical properties including rigidity.
摘要翻译： PCT No.PCT / JP98 / 02926 Sec。 371日期1999年2月26日 102（e）日期1999年2月26日PCT提交1998年6月30日PCT公布。 WO99 / 01486 PCT公开号日期1999年1月14日提供发泡丙烯 - 乙烯无规共聚物，其特征在于（1）其乙烯单元含量[x（重量％）]为0.2-10重量％，（2）其MI为 1和16g / 10min，（3）其沸腾乙醚萃取[E（wt。％）]和x满足式（I）的关系：E <= 0.25x + 1.1（I），（4 ）其熔点[Tm（℃）]和x满足式（II）的关系：Tm 165-5x（II），（5）其PPP链部分中的全同立构三单元组分数通过 13 C NMR不小于98mol％，优选（6）共聚物的松弛时间τ（sec）与共聚物的MI之间的关系满足式（III）：τ<0.80 -0.42xlog MI（III），还有其发泡珠和细胞制品。共聚物及其发泡珠具有改善的初级和次级起泡性，并且共聚物的多孔物品具有优异的机械性能，包括刚性。

10. 发明授权

US5028451A Method of producing sintered hard metal with diamond film 失效
标题翻译：用金刚石膜制造烧结硬质金属的方法
公开(公告)号：US5028451A
公开(公告)日：1991-07-02
申请号：US488420
申请日：1990-03-02
申请人： Toshimichi Ito , Satoshi Katsumata , Masakazu Watanabe , Satoshi Iio
发明人： Toshimichi Ito , Satoshi Katsumata , Masakazu Watanabe , Satoshi Iio
IPC分类号： C23C16/02 , C23C16/27 , C30B25/02
CPC分类号： C23C16/274 , C23C16/0281 , C23C16/277 , C30B25/02 , C30B29/04
摘要： The present invention is directed to a method of producing a sintered hard metal having a diamond film wherein a gas that is obtained by activating a raw material gas containing 2 to 60 mol % of carbon monoxide and hydrogen gas is brought in contact with a sintered hard metal to form a diamond film, thereby a diamond film can be formed on said sintered hard metal with the adhesion of the diamond excellent.

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