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1. 发明授权

US3953546A Thio(dithio)phosphorates 失效
标题翻译：硫（二硫）磷酸盐
公开(公告)号：US3953546A
公开(公告)日：1976-04-27
申请号：US487670
申请日：1974-07-11
申请人： Masachika Hirano , Kunio Mukai , Hisami Takeda
发明人： Masachika Hirano , Kunio Mukai , Hisami Takeda
IPC分类号： A01N57/14 , C07F9/18 , A01N9/36
CPC分类号： A01N57/14 , C07F9/18
摘要： Thio(dithio)-phosphorate of the formula, ##SPC1##Wherein A represents an alkyl having up to 6 carbon atoms; B represents lower alkyl having up to 4 carbon atoms; Y represents halogen, methoxy or ethoxy; X represents oxygen or sulfur; R.sub.1 represents alkyl having up to 6 carbon atoms, phenyl, phenyl substituted by halogen or phenyl substituted by lower alkyl having up to 4 carbon atoms; R.sub.2 represents hydrogen or alkyl having up to 6 carbon atoms; R.sub.3 represents hydrogen or alkyl having up to 6 carbon atoms; and n represents 0, 1 or 2, which is useful as a pesticide.
摘要翻译：硫代（二硫代） - 磷酸酯，其中A代表具有至多6个碳原子的烷基; B代表具有至多4个碳原子的低级烷基; Y表示卤素，甲氧基或乙氧基; X表示氧或硫; R 1表示具有至多6个碳原子的烷基，苯基，被卤素取代的苯基或被具有至多4个碳原子的低级烷基取代的苯基; R2代表氢或具有至多6个碳原子的烷基; R3表示氢或具有至多6个碳原子的烷基; n表示0,1或2，可用作农药。

2. 发明授权

US4263463A Acetylenic secondary alcohols 失效
标题翻译：乙酸仲醇
公开(公告)号：US4263463A
公开(公告)日：1981-04-21
申请号：US735733
申请日：1976-10-26
申请人： Shigeyoshi Kitamura , Norbushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
发明人： Shigeyoshi Kitamura , Norbushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
IPC分类号： C07C33/048 , C07D307/28 , C07D307/45 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16
CPC分类号： C07D307/42 , C07C403/12 , C07D307/28 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16 , C07C2101/02 , C07C2101/08 , C07C2101/16
摘要： Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub. 1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentylidenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are as defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropanecarboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.
摘要翻译：由式表示的新型炔基环丙烷羧酸酯，其中R 1表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，低至5个碳原子的低级炔基，C1-C4烷氧基 C 1 -C 4烷基，C 1 -C 4烷硫基C 1 -C 4烷基，芳基，芳基C 1 -C 4烷基，呋喃基，取代的呋喃基，噻吩基，取代的噻吩基，糠基，取代的糠基，噻吩基，取代的芳基，环C 3 -C 6烷基，取代的环 C 3 -C 6烷基，环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，具有至多5个碳原子的低级炔基，芳基，芳基C 1 -C 4烷基或可形成碳 - 碳键; 或者R 1和R 3在末端彼此键合形成含有或不含有氧原子或不含硫原子的多亚甲基链，或者R 1和R 2在末端彼此键合形成含有或不含有氧或硫原子; R4代表氢或甲基; 当R 4为氢时，R 5表示氢，甲基，乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲氧基甲基-1-丙烯基，2-甲氧基羰基-1-丙烯基，2,2-二氯乙烯基或环戊烯基甲基，R5 当R 4为甲基时为甲基; 并且R 6和R 7表示氢或甲基。这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与下式的环丙烷羧酸反应来制备：其中R1，R2，R3和R6如上所定义，A是羟基，卤素或芳基磺酰基，，其中R4，R5和R7如上定义，或其反应性衍生物。这些酯可用作对哺乳动物无害的杀虫剂。

3. 发明授权

US3973036A Cyclopropanecarboxylic acid esters 失效
标题翻译：环丙烷羧酸酯
公开(公告)号：US3973036A
公开(公告)日：1976-08-03
申请号：US620188
申请日：1975-10-06
申请人： Masachika Hirano , Takashi Matsuo , Hisami Takeda , Toshio Nishioka
发明人： Masachika Hirano , Takashi Matsuo , Hisami Takeda , Toshio Nishioka
IPC分类号： C07C69/743 , A01N53/00 , A01N53/08 , C07C67/00 , C07C69/747 , C07C253/00 , C07C255/39 , C07C255/53 , A01N9/20 , A01N9/24 , C07C69/74 , C07C121/75
CPC分类号： C07C255/53
摘要： A novel cyclopropanecarboxylic acid ester of the formula, ##SPC1##Wherein R.sub.1 is a hydrogen atom, a cyano or ethynyl group, and X is a chlorine, bromine or fluorine atom, which possesses various useful insecticidal and acaricidal activities and can be prepared by reacting a compound of the formula, ##SPC2##Wherein R.sub.1 is as defined above and R.sub.2 is hydroxyl, a halogen atom or an arylsulfoxy group, with a cyclopropanecarboxylic acid of the formula, ##EQU1## wherein X is as defined above, or its reactive derivative.
摘要翻译：一种下式的新型环丙烷羧酸酯，其中，R 1是氢原子，氰基或乙炔基，X是氯，溴或氟原子，其具有各种有用的杀虫和杀螨活性，并且可以通过使式中，R 1如上所定义，R 2是羟基，卤素原子或芳基磺酰基，与下式的环丙烷羧酸，其中X HO-C-CH-CH-CH = C角度平行角OCX角CH 3 CH 3，其中X 如上所定义，或其活性衍生物。

4. 发明授权

US3950374A Carbamate pesticide 失效
标题翻译：氨基甲酸酯农药
公开(公告)号：US3950374A
公开(公告)日：1976-04-13
申请号：US326101
申请日：1973-01-23
申请人： Minoru Ueda , Shigehiro Ooba , Masachika Hirano , Hisami Takeda
发明人： Minoru Ueda , Shigehiro Ooba , Masachika Hirano , Hisami Takeda
IPC分类号： A01N47/24 , C07C119/18
CPC分类号： A01N47/24
摘要： Compounds of the formula ##EQU1## wherein R is phenyl, .alpha.-naphthyl, substituted phenyl or a group of the formula ##EQU2## R.sub.1 is lower alkyl, R.sub.2 is alkyl, phenyl, aralkyl or substituted phenyl, and R.sub.3 and R.sub.4 are lower alkyl, which compounds are useful as insecticidal, nematocidal and acarididal agents.
摘要翻译：式R1的化合物其中R是苯基，α-萘基，取代的苯基或式R3的基团，其中R是氢，烷基，苯基，芳烷基或取代的苯基，R3和R4是低级烷基，该化合物可用作杀虫剂，杀线虫剂和螨类药剂。

5. 发明授权

US4003945A Novel cyclopropanecarboxylates 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4003945A
公开(公告)日：1977-01-18
申请号：US461029
申请日：1974-04-15
申请人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
发明人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
IPC分类号： C07C69/743 , A01N53/10 , C07C69/74 , C07D307/28 , C07D307/45 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16
CPC分类号： C07D307/42 , C07C403/12 , C07D307/28 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16 , Y10S514/937 , Y10S514/952 , Y10S514/953 , Y10S514/957
摘要： Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub.1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentyl-idenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropane-carboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.
摘要翻译：由式表示的新型炔基环丙烷羧酸酯，其中R 1表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，低至5个碳原子的低级炔基，C1-C4烷氧基 C 1 -C 4烷基，C 1 -C 4烷硫基C 1 -C 4烷基，芳基，芳基C 1 -C 4烷基，呋喃基，取代的呋喃基，噻吩基，取代的噻吩基，糠基，取代的糠基，噻吩基，取代的芳基，环C 3 -C 6烷基，取代的环 C 3 -C 6烷基，环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，具有至多5个碳原子的低级炔基，芳基，芳基C 1 -C 4烷基或可形成碳 - 碳键; 或者R 1和R 3在末端彼此键合以形成含有或不含有氧原子或硫原子的多亚甲基链，或者R 1和R 2在末端彼此结合形成含有或不含有氧或硫原子; R4代表氢或甲基; 当R4为氢时，R5代表氢，甲基，乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲氧基甲基-1-丙烯基，2-甲氧基羰基-1-丙烯基，2,2-二氯乙烯基或环戊基 - 当R 4为甲基时，R 5表示甲基; 并且R 6和R 7表示氢或甲基。这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与其中R1，R2，R3和R6定义如上，A是羟基，卤素或芳基磺酰基的醇或其卤化物或芳基磺酸酯与式，其中R 4，R 5和R 7如上所定义，或其反应性衍生物。这些酯可用作对哺乳动物无害的杀虫剂。

6. 发明授权

US3932459A Novel cyclopropanecarboxylic acid esters 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US3932459A
公开(公告)日：1976-01-13
申请号：US491636
申请日：1974-07-25
申请人： Yoshitoshi Okuno , Masachika Hirano , Isao Ohno , Hisami Takeda , Osamu Magara , Nobushige Itaya , Toshio Nishioka , Toshio Mizutani , Nobuo Ohno , Takashi Matsuo
发明人： Yoshitoshi Okuno , Masachika Hirano , Isao Ohno , Hisami Takeda , Osamu Magara , Nobushige Itaya , Toshio Nishioka , Toshio Mizutani , Nobuo Ohno , Takashi Matsuo
IPC分类号： C07C69/747 , A01N53/04 , A01N53/06 , C07C67/00 , C07C253/00 , C07C255/39 , C07D307/45 , C07D307/56 , C07D317/54 , C07D333/16 , C07D333/24 , C07D333/78
CPC分类号： C07D333/16 , C07D333/78
摘要： A new cyclopropanecarboxylic acid ester represented by the formula, ##SPC1##Wherein R.sub.1 is alkyl having up to four carbon atoms, alkenyl having up to five carbon atoms, cycloalkenyl having up to six carbon atoms, alkenyl having up to five carbon atoms, benzyl, phenoxy or halogen; R.sub.2 and R.sub.3 are hydrogen, halogen or methyl; and any adjacent two of R.sub.1, R.sub.2 and R.sub.3 may combine to form polymethylene, which is useful as insecticides and acaricides having a strong insecticidal activity but a low toxicity to mammals, in agriculture, horticulture as well as public health.
摘要翻译：由下式表示的新的环丙烷羧酸酯WHEREIN R1是具有至多4个碳原子的烷基，具有至多5个碳原子的烯基，具有至多6个碳原子的环烯基，具有至多5个碳原子的链烯基，苄基，苯氧基或卤素 ; R2和R3是氢，卤素或甲基; 并且R 1，R 2和R 3中的任何相邻的两个可以结合形成多亚甲基，其可用作具有强的杀虫活性但对哺乳动物毒性低，在农业，园艺以及公共卫生中的杀虫剂和杀螨剂。

7. 发明授权

US4394379A Amide phosphorothiolate derivatives and their use as pesticides 失效
标题翻译：酰胺二硫代磷酸衍生物及其作为农药的用途
公开(公告)号：US4394379A
公开(公告)日：1983-07-19
申请号：US113133
申请日：1980-01-17
申请人： Osamu Kirino , Masachika Hirano , Hisami Takeda , Toshiro Kato
发明人： Osamu Kirino , Masachika Hirano , Hisami Takeda , Toshiro Kato
IPC分类号： A01N57/14 , A01N57/30 , C07F9/165 , C07F9/24 , C07F9/40
CPC分类号： C07F9/1651 , A01N57/14 , A01N57/30 , C07F9/2408
摘要： Amide phosphorothiolate derivatives of the formula, ##STR1## wherein X is an oxygen or sulfur atom, Y is an oxygen or sulfur atom or imino group, R.sub.1 and R.sub.2, which may be the same or different, are each a C.sub.1 -C.sub.3 alkyl group, R.sub.3 is a C.sub.1 -C.sub.4 alkyl group, R.sub.4 is a hydrogen atom or methyl group, R.sub.5 is a C.sub.1 -C.sub.3 alkyl, methoxy or ethoxy group, Z is a hydrogen atom, a methyl group or chlorine atom and n is 1 or 2, a process for producing said derivatives characterized by reacting the salt of thiophosphoric ester represented by the formula, ##STR2## wherein X, Y, R.sub.1 and R.sub.2 are as defined above and M is a sodium or potassium atom or ammonium group, with a haloacetamide derivative of the formula, ##STR3## wherein R.sub.3, R.sub.4, R.sub.5, Z and n are as defined above and W is a halogen atom, and a combined insecticide, acaricide, nematocide and/or fungicide containing said derivatives as an active ingredient.
摘要翻译：下式的酰亚胺硫代衍生物，其中X是氧或硫原子，Y是氧或硫原子或亚氨基，可以相同或不同的R 1和R 2各自为C 1 -C 3烷基 R3为C1-C4烷基，R4为氢原子或甲基，R5为C1-C3烷基，甲氧基或乙氧基，Z为氢原子，甲基或氯原子，n为1或2 制备所述衍生物的方法，其特征在于使由下式表示的硫代磷酸酯的盐，其中X，Y，R 1和R 2如上所定义，M是钠或钾原子或铵基，与卤代乙酰胺衍生物，其中R3，R4，R5，Z和n如上所定义，W是卤素原子，以及含有所述衍生物作为活性成分的杀虫剂，杀螨剂，杀线虫剂和/或杀真菌剂的组合物。

8. 发明授权

US4118505A Novel cyclopropanecarboxylates 失效
公开(公告)号：US4118505A
公开(公告)日：1978-10-03
申请号：US636981
申请日：1975-12-02
申请人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
发明人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
IPC分类号： C07D307/28 , C07D307/45 , C07D309/06 , C07D317/54 , C07D333/16 , C07C69/74 , A01N9/24
CPC分类号： C07D307/42 , C07D307/28 , C07D309/06 , C07D317/54 , C07D333/16
摘要： Novel alkynyl esters of cyclopropanecarboxylic acid represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, lower alkyl having 1-4 carbon atoms, lower alkenyl having 2-4 carbon atoms, lower alkynyl having 2-4 carbon atoms, C.sub.1 -C.sub.2 alkoxy-C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.2 alkylthio-C.sub.1 -C.sub.4 alkyl, furyl, thienyl, furfuryl, thenyl, cyclo-C.sub.3 -C.sub.6 alkyl, oxygen atom-containing cyclo-C.sub.3 -C.sub.6 alkyl, cyclo-C.sub.5 -C.sub.6 alkenyl, oxygen atom-containing cyclo-C.sub.4 -C.sub.6 alkenyl, halo-C.sub.2 -C.sub.4 alkenyl, phenyloxymethyl, phenylthiomethyl, cyclo-C.sub.5 -C.sub.6 alkenylmethyl, oxygen atom-containing cyclo-C.sub.4 -C.sub.6 alkenylmethyl, cyclo-C.sub.5 -C.sub.6 alkylmethyl, oxygen atom-containing cyclo-C.sub.4 -C.sub.6 alkylmethyl or ##STR2## IN WHICH X is halogen, nitro, cyano, methylenedioxy, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.2 alkoxy, dimethylamino, m is 0, 1, 2 or 3, n is 0, 1, 2 or 3 and each X may be different when n is 2 or 3; R.sub.2 and R.sub.3 individually represent hydrogen, halogen (except R.sub.2), phenyl, benzyl, lower alkyl having 1 - 3 carbon atoms, lower alkenyl having 2 - 3 carbon atoms, lower alkynyl having 2 - 3 carbon atoms or may form a carbon-carbon bond or are bonded to each other at the ends to form C.sub.3 -C.sub.4 polymethylene chain, or R.sub.1 and R.sub.2 are bonded to each other at the ends to form C.sub.5 polymethylene chain; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxy-methyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 1,3-butadienyl, 2-methyl-1,3-butadienyl, 2,2-dichlorovinyl or cyclopentylidenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR3## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are as defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropanecarboxylic acid of the formula, ##STR4## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.

9. 发明授权

US3981903A Cyclopropane carboxylic acid esters 失效
标题翻译：环丙烷羧酸酯
公开(公告)号：US3981903A
公开(公告)日：1976-09-21
申请号：US491637
申请日：1974-07-25
申请人： Masachika Hirano , Isao Ohno , Yoshitoshi Okuno , Osamu Magara , Nobushige Itaya , Toshio Nishioka , Toshio Mizutani , Nobuo Ohno , Takashi Matsuo , Hisami Takeda
发明人： Masachika Hirano , Isao Ohno , Yoshitoshi Okuno , Osamu Magara , Nobushige Itaya , Toshio Nishioka , Toshio Mizutani , Nobuo Ohno , Takashi Matsuo , Hisami Takeda
IPC分类号： C07C69/747 , A01N53/02 , A01N53/06 , A01N53/10 , A01P7/04 , C07C69/743 , C07C69/74
CPC分类号： A01N53/00 , C07C69/743 , Y10S514/937 , Y10S514/953
摘要： A new pyrethroidal pesticide containing as an active ingredient a pesticidally effective amount of novel cyclopropanecarboxylic acid esters represented by the formula, ##EQU1## wherein R is a hydrogen atom, a halogen atom, a methyl or a methoxy group, and R.sub.1 and R.sub.2 are hydrogen atom, methyl group or a halogen atom, which have a low toxicity to mammals, excellent pesticidal effect on injurious pests in cereal storage, agriculture and forestry and a wide range of uses for prevention of epidemics.
摘要翻译：一种新的拟除虫菊酯农药，其含有杀虫有效量的由式R 1表示的新型环丙烷羧酸酯作为活性成分，其中C = CH-CH-CH-CO-CH 2 C = C-CH 2 Cl平行|角度角OR2 CH3CH3，其中R是氢原子，卤素原子，甲基或甲氧基，R1和R2是对哺乳动物毒性低的氢原子，甲基或卤素原子，对谷物中有害害虫具有优良的杀虫作用储存，农业和林业以及预防流行病的广泛用途。

10. 发明授权

US3949023A Novel oximino -phosphorothiolate derivatives 失效
标题翻译：新型肟基 - 硫代磷酸衍生物
公开(公告)号：US3949023A
公开(公告)日：1976-04-06
申请号：US422388
申请日：1973-12-06
申请人： Mitsuru Sasaki , Isao Ohno , Hisami Takeda , Takeo Satomi , Kunio Mukai
发明人： Mitsuru Sasaki , Isao Ohno , Hisami Takeda , Takeo Satomi , Kunio Mukai
IPC分类号： A01N57/12 , A01N57/10 , A01N57/14 , C07F9/165 , C07F9/59 , A01N9/36 , C07D211/08 , C07D317/14
CPC分类号： C07F9/1657 , A01N57/10
摘要： Oximino-phosphorothiolate derivatives represented by the formula, ##EQU1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as hereinafter defined, which are useful as a controlling agent for agricultural pests containing the oximino-phosphorothiolate derivatives as active ingredients, as well as processes for preparing the compounds and the composition are disclosed.
摘要翻译：由下式表示的肟基 - 硫代磷酸酯衍生物，其中R 1，R 2，R 3和R 4如下文所定义，其可用作含有肟基 - 硫代磷酸酯的农业害虫的控制剂衍生物作为活性成分，以及制备化合物和组合物的方法。

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