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1. 发明授权

US4327109A Novel alkadienylcyclopropanecarboxylates 失效
标题翻译：新型的链二烯基环丙烷羧酸酯
公开(公告)号：US4327109A
公开(公告)日：1982-04-27
申请号：US142698
申请日：1980-04-22
申请人： Toshio Mizutani , Nobushige Itaya , Nobuo Ohno , Takashi Matsuo , Shigeyoshi Kitamura , Yositosi Okuno
发明人： Toshio Mizutani , Nobushige Itaya , Nobuo Ohno , Takashi Matsuo , Shigeyoshi Kitamura , Yositosi Okuno
IPC分类号： C07C69/74 , A01N53/00 , A01N53/02 , A01N53/04 , C07D207/44 , C07D207/452 , C07D209/46 , C07D209/48 , C07D307/45 , C07D307/58 , C07D307/80 , C07D333/16 , C07D333/78 , C07D493/04 , A01N43/10 , C07C69/587
CPC分类号： C07D207/452 , A01N53/00 , C07D209/46 , C07D209/48 , C07D209/49 , C07D307/42 , C07D307/58 , C07D307/80 , C07D333/16 , C07D333/78 , C07D493/04
摘要： A compound of the formula, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are respectively hydrogen atom or methyl, R.sub.5 is a member of ##STR2## wherein R.sub.6 is hydrogen atom or methyl, R.sub.7 is alkenyl, alkadienyl, alkynyl or benzyl, R.sub.8 is hydrogen atom, ethynyl or cyano, R.sub.9 is hydrogen atom, a halogen atom or alkyl, R.sub.10 is a halogen atom, alkyl, alkenyl, alkynyl, benzyl, thenyl, furylmethyl, phenoxy, substituted phenoxy of phenylthio, or R.sub.9 and R.sub.10 are bonded at the ends to form polymethylene chain containing or not containing oxygen or sulfur atom, Y is oxygen atom, sulfur atom or --CH.dbd.CH--, n is 1 or 2, Z is phthalimido, thiophthalimido, di- or tetra-hydrophthalimido or dialkylmaleimido, R.sub.11 is phenyl, thienyl or furyl and X is a halogen atom, which is useful as an active ingredient of insecticides.
摘要翻译：下式化合物，其中R 1，R 2，R 3和R 4分别是氢原子或甲基，R 5是其中R 6是氢原子或甲基，R 7是链烯基，，炔基或苄基，R8是氢原子，乙炔基或氰基，R9是氢原子，卤素原子或烷基，R10是卤素原子，烷基，烯基，炔基，苄基，噻吩基，呋喃基甲基，苯氧基，苯硫基的取代苯氧基，或R 9和R 10在末端键合以形成含有或不含氧原子或硫原子的多亚甲基链，Y为氧原子，硫原子或-CH = CH-，n为1或2，Z为苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基，或四邻苯二甲酰亚胺基或二烷基马来酰亚胺基，R 11为苯基，噻吩基或呋喃基，X为卤素原子，其可用作杀虫剂的活性成分。

2. 发明授权

US4263463A Acetylenic secondary alcohols 失效
标题翻译：乙酸仲醇
公开(公告)号：US4263463A
公开(公告)日：1981-04-21
申请号：US735733
申请日：1976-10-26
申请人： Shigeyoshi Kitamura , Norbushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
发明人： Shigeyoshi Kitamura , Norbushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
IPC分类号： C07C33/048 , C07D307/28 , C07D307/45 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16
CPC分类号： C07D307/42 , C07C403/12 , C07D307/28 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16 , C07C2101/02 , C07C2101/08 , C07C2101/16
摘要： Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub. 1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentylidenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are as defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropanecarboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.
摘要翻译：由式表示的新型炔基环丙烷羧酸酯，其中R 1表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，低至5个碳原子的低级炔基，C1-C4烷氧基 C 1 -C 4烷基，C 1 -C 4烷硫基C 1 -C 4烷基，芳基，芳基C 1 -C 4烷基，呋喃基，取代的呋喃基，噻吩基，取代的噻吩基，糠基，取代的糠基，噻吩基，取代的芳基，环C 3 -C 6烷基，取代的环 C 3 -C 6烷基，环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，具有至多5个碳原子的低级炔基，芳基，芳基C 1 -C 4烷基或可形成碳 - 碳键; 或者R 1和R 3在末端彼此键合形成含有或不含有氧原子或不含硫原子的多亚甲基链，或者R 1和R 2在末端彼此键合形成含有或不含有氧或硫原子; R4代表氢或甲基; 当R 4为氢时，R 5表示氢，甲基，乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲氧基甲基-1-丙烯基，2-甲氧基羰基-1-丙烯基，2,2-二氯乙烯基或环戊烯基甲基，R5 当R 4为甲基时为甲基; 并且R 6和R 7表示氢或甲基。这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与下式的环丙烷羧酸反应来制备：其中R1，R2，R3和R6如上所定义，A是羟基，卤素或芳基磺酰基，，其中R4，R5和R7如上定义，或其反应性衍生物。这些酯可用作对哺乳动物无害的杀虫剂。

3. 发明授权

US4008268A Process for isomerization of a cyclopropanecarboxylic acid 失效
标题翻译：环丙烷羧酸异构化的方法
公开(公告)号：US4008268A
公开(公告)日：1977-02-15
申请号：US585592
申请日：1975-06-10
申请人： Toshio Mizutani , Nobushige Itaya , Toshiko Nishijima , Osamu Magara
发明人： Toshio Mizutani , Nobushige Itaya , Toshiko Nishijima , Osamu Magara
IPC分类号： C07C61/40 , B01J27/00 , C07B61/00 , C07C51/00 , C07C51/353 , C07C67/00 , C07C61/18
CPC分类号： C07C51/353
摘要： A process for isomerizing 2-(.beta.,.beta.-dichlorovinyl)-3,3-dimethylcyclopropanecarboxylic acid represented by the formula, ##STR1## which comprises heating the acid of the formula (I) in the presence of the anhydride of the acid or a reagent producing the acid anhydride in the reaction system.The ester resulting from 2-(.beta.,.beta.-dichlorovinyl)-3,3-dimethylcyclopropanecarboxylic acid and, for example, 3-phenoxybenzyl alcohol is a compound which has a very wide range of insecticidal spectrum and has a very high controlling effect as a low-toxicity insecticide not only for domestic use and public health but also against insects injurious to agriculture or forestry, and in the case of the 3-phenoxybenzyl ester or 5-benzyl-3-furylmethyl ester of the 2-(.beta.,.beta.-dichlorovinyl)-3,3-dimethylcyclopropanecarboxylic acid, the trans-isomer is lower than the cis-isomer in toxicity to warm-blooded animals.
摘要翻译：异构化由式（I）表示的2-（β，β-二氯乙烯基）-3,3-二甲基环丙烷甲酸的方法，其包括在存在下述的酸酐的情况下加热式（I）的酸酸或在反应体系中产生酸酐的试剂。

4. 发明授权

US3995432A Collector 失效
标题翻译：集电极
公开(公告)号：US3995432A
公开(公告)日：1976-12-07
申请号：US599559
申请日：1975-07-28
申请人： Leonard Noryk , Toshio Mizutani
发明人： Leonard Noryk , Toshio Mizutani
IPC分类号： F01D25/30
CPC分类号： F01D25/30
摘要： A toroidal shaped collector with a radial inlet and a single discharge outlet includes a pair of substantially parallel spaced baffle plates extending from the inlet partway into the collector chamber, disposed in the plane of the collector and serves to receive and discharge the airflow from a gas generator such as a gas turbine engine particularly adapted for nonaircraft applications.
摘要翻译：具有径向入口和单个排放出口的环形收集器包括一对基本上平行隔开的挡板，其从入口中途延伸到收集器室中，设置在收集器的平面内，用于从气体中接收和排出气流发电机，例如特别适用于非飞机应用的燃气涡轮发动机。

5. 发明授权

US4266074A Novel insecticidal composition 失效
标题翻译：新型杀虫剂组合物
公开(公告)号：US4266074A
公开(公告)日：1981-05-05
申请号：US596332
申请日：1975-07-16
申请人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
发明人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
IPC分类号： C07C67/00 , A01N37/00 , A01N37/04 , A01N37/06 , A01N37/10 , A01N37/32 , A01N37/34 , A01N37/38 , A01N37/42 , A01N37/48 , A01N43/06 , A01N43/16 , A01N43/30 , A01N49/00 , C07C43/29 , C07C51/00 , C07C51/08 , C07C57/30 , C07C57/42 , C07C57/58 , C07C57/60 , C07C59/48 , C07C59/56 , C07C59/64 , C07C69/00 , C07C69/612 , C07C69/614 , C07C69/618 , C07C69/635 , C07C69/66 , C07C69/74 , C07C69/743 , C07C69/76 , C07C255/53 , C07C317/00 , C07D209/48 , C07D227/093 , C07D307/34 , C07D307/40 , C07D307/54 , C07D317/48 , C07D317/60 , C07D333/04 , C07D333/16 , C07D333/24 , C07D333/38 , C07D409/06 , A01N41/02 , C07C79/46 , C07C143/67 , C07C147/107 , C07C149/40
CPC分类号： C07D307/54 , C07C323/00 , C07C51/08 , C07C57/42 , C07C59/64 , C07C69/608 , C07C69/612 , C07C69/618 , C07C69/65 , C07C69/734 , C07C69/738 , C07C2101/16 , C07C2102/08 , C07C2102/10
摘要： Substituted acetate compounds represented by the formula ##STR1## which are useful as pesticides and pesticidal composition containing the substituted acetate compounds as active ingredients, as well as processes for preparing the compounds and the compositions are disclosed.
摘要翻译：公开了用作农药和由取代的乙酸酯化合物作为活性成分的杀虫组合物的式“IMAGE”代表的取代的乙酸酯化合物，以及制备化合物和组合物的方法。

6. 发明授权

US4062968A Insecticidal substituted acetate compounds 失效
公开(公告)号：US4062968A
公开(公告)日：1977-12-13
申请号：US596334
申请日：1975-07-16
申请人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
发明人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
IPC分类号： A01N37/36 , A01N43/06 , C07D307/54 , A01N9/00
CPC分类号： C07D307/54 , C07C323/00
摘要： Substituted acetate compounds represented by the formula ##STR1## which are useful as pesticides and pesticidal composition containing the substituted acetate compounds as active ingredients, as well as processes for preparing the compounds and the compositions are disclosed.

7. 发明授权

US4058622A Substituted phenyl acetate, insecticidal composition and method of use 失效
标题翻译：取代的乙酸苯酯，杀虫剂组合物和使用方法
公开(公告)号：US4058622A
公开(公告)日：1977-11-15
申请号：US557694
申请日：1975-03-12
申请人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
发明人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
IPC分类号： C07C69/612 , C07D307/54 , A01N9/24 , C07C69/76
CPC分类号： C07D307/54 , C07C323/00
摘要： Substituted acetate compounds represented by the formula ##STR1## which are useful as pesticides and pesticidal compositions containing the substituted acetate compounds as active ingredients, as well as processes for preparing the compounds and the compositions are disclosed.
摘要翻译：公开了用作农药和由取代的乙酸酯化合物作为活性成分的杀虫组合物的式“IMAGE”代表的取代的乙酸酯化合物，以及制备化合物和组合物的方法。

8. 发明授权

US4039680A Insecticidal substituted acetate compounds 失效
标题翻译：杀虫剂取代的乙酸酯化合物
公开(公告)号：US4039680A
公开(公告)日：1977-08-02
申请号：US596335
申请日：1975-07-16
申请人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
发明人： Keimei Fujimoto , Nobuo Ohno , Yoshitoshi Okuno , Toshio Mizutani , Isao Ohno , Masachika Hirano , Nobushige Itaya , Takashi Matsuo
IPC分类号： A01N37/08 , A01N37/36 , A01N43/06 , C07D307/54 , A01N9/00
CPC分类号： C07D307/54 , C07C323/00
摘要： Substituted acetate compounds represented by the formula ##STR1## which are useful as pesticides and pesticidal composition containing the substituted acetate compounds as active ingredients, as well as processes for preparing the compounds and the compositions are disclosed.

9. 发明授权

US4003945A Novel cyclopropanecarboxylates 失效
标题翻译：新型环丙烷羧酸酯
公开(公告)号：US4003945A
公开(公告)日：1977-01-18
申请号：US461029
申请日：1974-04-15
申请人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
发明人： Shigeyoshi Kitamura , Nobushige Itaya , Yoshitoshi Okuno , Nobuo Ohno , Takashi Matsuo , Masachika Hirano , Toshio Mizutani , Hisami Takeda
IPC分类号： C07C69/743 , A01N53/10 , C07C69/74 , C07D307/28 , C07D307/45 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16
CPC分类号： C07D307/42 , C07C403/12 , C07D307/28 , C07D309/06 , C07D309/22 , C07D317/54 , C07D333/16 , C07C2101/02 , C07C2101/08 , C07C2101/14 , C07C2101/16 , Y10S514/937 , Y10S514/952 , Y10S514/953 , Y10S514/957
摘要： Novel alkynylcyclopropanecarboxylic acid esters represented by the formula, ##STR1## wherein R.sub.1 represents hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, C.sub.1 -C.sub.4 alkoxy C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkylthio C.sub.1 -C.sub.4 alkyl, aryl, aryl C.sub.1 -C.sub.4 alkyl, furyl, substituted furyl, thienyl, substituted thienyl, furfuryl, substituted furfuryl, thenyl, substituted thenyl, cyclo C.sub.3 -C.sub.6 alkyl, substituted cyclo C.sub.3 -C.sub.6 alkyl, cyclo C.sub.3 -C.sub.6 alkenyl or substituted cyclo C.sub.3 -C.sub.6 alkenyl; R.sub.2 and R.sub.3 individually represent hydrogen, halogen, lower alkyl having up to 5 carbon atoms, lower alkenyl having up to 5 carbon atoms, lower alkynyl having up to 5 carbon atoms, aryl, aryl C.sub.1 -C.sub.4 alkyl or may form a carbon-carbon bond; or R.sub.1 and R.sub.3 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom, or R.sub.1 and R.sub.2 are bonded to each other at the ends to form a polymethylene chain containing or not containing an oxygen or a sulfur atom; R.sub.4 represents hydrogen or methyl; R.sub.5 represents hydrogen, methyl, vinyl, 1-propenyl, 2-methyl-1-propenyl, 2-methoxymethyl-1-propenyl, 2-methoxycarbonyl-1-propenyl, 2,2-dichlorovinyl or cyclopentyl-idenemethyl when R.sub.4 is hydrogen, and R.sub.5 represents methyl when R.sub.4 is methyl; and R.sub.6 and R.sub.7 represent hydrogen or methyl. These novel esters are produced by reacting an alcohol or its halide or arylsulfonate of the formula, ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.6 are defined above, and A is hydroxy, halogen or arylsulfoxy, with a cyclopropane-carboxylic acid of the formula, ##STR3## wherein R.sub.4, R.sub.5 and R.sub.7 are as defined above, or its reactive derivative. These esters are useful as an insecticide harmless to mammals.
摘要翻译：由式表示的新型炔基环丙烷羧酸酯，其中R 1表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，低至5个碳原子的低级炔基，C1-C4烷氧基 C 1 -C 4烷基，C 1 -C 4烷硫基C 1 -C 4烷基，芳基，芳基C 1 -C 4烷基，呋喃基，取代的呋喃基，噻吩基，取代的噻吩基，糠基，取代的糠基，噻吩基，取代的芳基，环C 3 -C 6烷基，取代的环 C 3 -C 6烷基，环C 3 -C 6烯基或取代的环C 3 -C 6烯基; R 2和R 3各自表示氢，卤素，具有至多5个碳原子的低级烷基，具有至多5个碳原子的低级链烯基，具有至多5个碳原子的低级炔基，芳基，芳基C 1 -C 4烷基或可形成碳 - 碳键; 或者R 1和R 3在末端彼此键合以形成含有或不含有氧原子或硫原子的多亚甲基链，或者R 1和R 2在末端彼此结合形成含有或不含有氧或硫原子; R4代表氢或甲基; 当R4为氢时，R5代表氢，甲基，乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲氧基甲基-1-丙烯基，2-甲氧基羰基-1-丙烯基，2,2-二氯乙烯基或环戊基 - 当R 4为甲基时，R 5表示甲基; 并且R 6和R 7表示氢或甲基。这些新型酯通过使下式的醇或其卤化物或芳基磺酸盐与其中R1，R2，R3和R6定义如上，A是羟基，卤素或芳基磺酰基的醇或其卤化物或芳基磺酸酯与式，其中R 4，R 5和R 7如上所定义，或其反应性衍生物。这些酯可用作对哺乳动物无害的杀虫剂。

10. 发明授权

US3969393A Process for preparing cyclopropane-carboxylic acid esters 失效
标题翻译：制备环丙烷 - 羧酸酯的方法
公开(公告)号：US3969393A
公开(公告)日：1976-07-13
申请号：US495154
申请日：1974-08-06
申请人： Toshio Mizutani , Yoshitaka Ume , Takashi Matsuo
发明人： Toshio Mizutani , Yoshitaka Ume , Takashi Matsuo
IPC分类号： C07C67/00
CPC分类号： C07C67/00 , C07C2101/02
摘要： A process for preparing an organic acid ester of the formula (I), ##EQU1## wherein R.sub.1 is a hydrogen atom or a methyl group, R.sub.2 is a methyl group, a vinyl group, a 2,2-dichlorovinyl group, a 1-propenyl group, a 2-methyl-1-propenyl group, a 2-carbomethoxy-1-propenyl group, a 2-methoxymethyl-1-propenyl group, a 1,3-butadienyl group, a 2-methyl-1,3-butadienyl group or a cyclopentylidenemethyl group when R.sub.1 is a hydrogen atom, and R.sub.2 is a methyl group when R.sub.1 is a methyl group; which comprises reacting an acid of the formula (II), ##EQU2## wherein R.sub.1 and R.sub.2 are each as defined above, or its reactive derivative, or mixture of the acid and its reactive derivative with a quaternary ammonium salt of the formula (III), ##SPC1##wherein X is a halogen atom, A is an alkylamine, pyridine or an N-alkylaniline.
摘要翻译：制备式（I）的有机酸酯的方法，CH 3 CH 3 ANGLE ANGLE CH 2 OC -----R 1（I）PARALLEL OR2其中R1是氢原子或甲基，R2是甲基，乙烯基基团，2,2-二氯乙烯基，1-丙烯基，2-甲基-1-丙烯基，2-甲酯基-1-丙烯基，2-甲氧基甲基-1-丙烯基，1,3 当R 1为氢原子时，2-甲基-1,3-丁二烯基或环戊烯基甲基，当R 1为甲基时，R 2为甲基; 其包括使式（II）的酸，其中R 1和R 2各自如上定义的CH 3 CH 3 ANGLE ANGLE R1 ----- COOH（II）R2或其反应性衍生物，或其酸及其反应性衍生物的混合物与式（III）的季铵盐，其中X是卤素原子，A是烷基胺，吡啶或N-烷基苯胺。

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