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1. 发明授权

US06514632B1 Fluorene-containing polymers and compounds useful in the preparation thereof 有权
标题翻译：含有芴的聚合物和可用于其制备的化合物
公开(公告)号：US06514632B1
公开(公告)日：2003-02-04
申请号：US09661264
申请日：2000-09-13
申请人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
发明人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
IPC分类号： B32B900
CPC分类号： H01L51/0043 , C07C17/2637 , C07C17/266 , C07C25/22 , C07C25/24 , C07C211/48 , C07C2602/44 , C07C2603/18 , C08G61/00 , C08G61/02 , C08G61/10 , C09B69/105 , C09B69/109 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0081 , H01L51/42 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C120 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group and, R5 is independantly in each occurrence a C2-10 alkylene group.
摘要翻译：下式的化合物和下式的化合物：其中R 1在每次出现时独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基，C 4 -16芳基（三烷基甲硅烷氧基）或两者R 1可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1-20 烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X各自独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2或其中R 4在每次出现时独立地为C 1-10烷基，并且R 5在每次出现时独立地为C 2-10亚烷基。

2. 发明授权

US06309763B1 Fluorene-containing polymers and electroluminescent devices therefrom 失效
标题翻译：含芴聚合物及其电致发光器件
公开(公告)号：US06309763B1
公开(公告)日：2001-10-30
申请号：US09063615
申请日：1998-04-21
申请人： Edmund P. Woo , Mark T. Bernius , Michael Inbasekaran , Weishi Wu
发明人： Edmund P. Woo , Mark T. Bernius , Michael Inbasekaran , Weishi Wu
IPC分类号： C08G6100
CPC分类号： H05B33/14 , C07C25/22 , C08G61/00 , C08G61/02 , C08G61/12 , C08G73/02 , C08G73/026 , C09K11/06 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5012 , Y10S428/917 , Y10T428/31678
摘要： A copolymer comprising 10-90 percent by weight of groups of Formula (I): and from 10-90 percent by weight of groups selected from Formulas (II), (III), and (IV): and mixtures thereof; wherein R1 is independently in each occurrence H, C1-C20 hydrocarbyl or C1-C20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-C16 hydrocarbyl carbonyloxy, C4-C16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-C20 cycloaliphatic structure or a C4-C20 cycloaliphatic structure containing one or more heteroatoms of S, N, or O; R2 is independently in each occurrence C1-C20 hydrocarbyl, C1-C20 hydrocarbyloxy, C1-C20 thioether, C1-C20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence carboxyl, C1-C20 alkyl, C1-C20 alkoxy or a group of the formula —CO2R4 wherein R4 is a C1-C20 alkyl; and a and b are independently in each occurrence an integer from 0 to 3.
摘要翻译：包含10-90重量％的式（I）的基团和10-90重量％的选自式（II），（III）和（IV）的基团的共聚物及其混合物; 其中R 1在每次出现时独立地为H，C 1 -C 20烃基或含有一个或多个S，N，O，P或Si原子的C 1 -C 20烃基，C 4 -C 16烃基羰氧基，C 4 -C 16芳基（三烷基甲硅烷氧基）或两个R 1 与芴环上的9-碳形成C5-C20脂环族结构或含有一个或多个S，N或O的杂原子的C 4 -C 20脂环族结构; R2各自独立地为C1-C20烃基，C1-C20烃氧基，C1-C20硫醚，C1-C20烃基羰基氧基或氰基; R3各自独立地为羧基，C 1 -C 20烷基，C 1 -C 20烷氧基或式-CO 2 R 4基团，其中R 4为C 1 -C 20烷基; 并且a和b各自独立地为0至3的整数。

3. 发明授权

US06512083B1 Fluorene-containing polymers and compounds useful in the preparation thereof 有权
标题翻译：含有芴的聚合物和可用于其制备的化合物
公开(公告)号：US06512083B1
公开(公告)日：2003-01-28
申请号：US09661237
申请日：2000-09-13
申请人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
发明人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
IPC分类号： C08G6100
CPC分类号： H01L51/0043 , C07C17/2637 , C07C17/266 , C07C25/22 , C07C25/24 , C07C211/48 , C07C2602/44 , C07C2603/18 , C08G61/00 , C08G61/02 , C08G61/10 , C09B69/105 , C09B69/109 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0081 , H01L51/42 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurrence a C2-10 alkylene group.
摘要翻译：下式的化合物及下式的化合物：其中R1各自独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基， 16芳基（三烷基甲硅烷氧基）或两者可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O的杂原子的C 4-20环结构; R 2在每次出现时独立地 C 1-20烃基，C 1-20烃基氧基，C 1-20硫醚，C 1-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基， 20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2或其中R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时独立地为C 2-10亚烷基。

4. 发明授权

US06383664B2 Electroluminescent or photocell device having protective packaging 有权
标题翻译：具有保护性包装的电致发光或光电池装置
公开(公告)号：US06383664B2
公开(公告)日：2002-05-07
申请号：US09309846
申请日：1999-05-11
申请人： Mark T. Bernius , Edmund P. Woo
发明人： Mark T. Bernius , Edmund P. Woo
IPC分类号： H05B3304
CPC分类号： H01G9/2077 , H01L25/047 , H01L51/42 , H01L51/524 , H01L51/525 , H01L2924/0002 , H01L2924/09701 , Y02E10/542 , H01L2924/00
摘要： The device of this invention comprises a optoelectronic element, a cover, and an adhesive. The optoelectronic element comprises a substrate bearing an anode, a film comprising an optoelectronic material, and a cathode. The cover comprises a lid and a raised rim which is recessed from the outer edge of the lid. The cover contacts the element so that the film comprising the optoelectronic material is located between the substrate and the lid, and within the region defined by the raised rim. An adhesive, located in a channel defined by the bottom surface of the lid from the outer edge to the rim, the rim, and the top surface of the optoelectronic element outside of the region defined by the rim, serves to attach the cover to the optoelectronic element.
摘要翻译：本发明的装置包括光电子元件，盖子和粘合剂。光电子元件包括承载阳极的基板，包含光电子材料的膜和阴极。盖子包括盖子和从盖子的外边缘凹进的凸起边缘。盖与元件接触，使得包含光电子材料的膜位于基板和盖之间，并且在由凸起边缘限定的区域内。粘合剂位于由盖的底表面限定的通道中，从外边缘到边缘的边缘，边缘以及由边缘限定的区域外部的光电元件的顶表面用于将盖附接到光电元件。

5. 发明授权

US06362310B1 Fluorene-containing polymers and compounds useful in the preparation thereof 有权
标题翻译：含有芴的聚合物和可用于其制备的化合物
公开(公告)号：US06362310B1
公开(公告)日：2002-03-26
申请号：US09661263
申请日：2000-09-13
申请人： Edmund P. Woo , Michael Inbasekaran , William R. Shiang , Gordon R. Roof , Mark T. Bernius , Weishi Wu
发明人： Edmund P. Woo , Michael Inbasekaran , William R. Shiang , Gordon R. Roof , Mark T. Bernius , Weishi Wu
IPC分类号： C08L2712
CPC分类号： H01L51/0043 , C07C17/2637 , C07C17/266 , C07C25/22 , C07C25/24 , C07C211/48 , C07C2602/44 , C07C2603/18 , C08G61/00 , C08G61/02 , C08G61/10 , C09B69/105 , C09B69/109 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0081 , H01L51/42 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A compound of the formula: and compounds of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C14-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group and R5 is independently in each occurence a C2-10 alkylene group.
摘要翻译：下式的化合物及下式的化合物：其中R1各自独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-6烃基羰基氧基，C 14 -16芳基（三烷基甲硅烷氧基）或两者R 1可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基，C 2-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1 -20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 并且Z各自独立地为-B（OH）2，-B（OR 4）2，或其中R 4在每次出现时独立地为C 1-10烷基，R 5在每次出现时为C 2-10亚烷基。

6. 发明授权

US06353083B1 Fluorene copolymers and devices made therefrom 有权
标题翻译：芴共聚物和由其制成的装置
公开(公告)号：US06353083B1
公开(公告)日：2002-03-05
申请号：US09289344
申请日：1999-04-09
申请人： Michael Inbasekaran , Weishi Wu , Edmund P. Woo , Mark T. Bernius
发明人： Michael Inbasekaran , Weishi Wu , Edmund P. Woo , Mark T. Bernius
IPC分类号： C08F6160
CPC分类号： H01L51/5012 , C08G61/02 , C08G61/10 , C09K11/06 , H01L51/0036 , H01L51/0038 , H01L51/0039 , H01L51/0043 , H01L51/0059 , Y02E10/549
摘要： This invention relates to: (a) fluorene copolymers comprising at least 10% (by residual monomeric units) of 9-substituted and/or 9,9-disubstituted fluorene moieties and at least two other monomeric units containing delocalized p-electrons, (b) polymer blends comprising at least 10 weight % of a copolymer specified in (a), and (c) electronic devices (such as polymer light emitting diodes) containing one or more films derived from these copolymers.
摘要翻译：本发明涉及：（a）包含至少10％（通过残留的单体单元）的9-取代和/或9,9-二取代的芴部分的芴共聚物和至少两种含有离域p-电子的其它单体单元，（b ）聚合物共混物，其包含至少10重量％的（a）中规定的共聚物和（c）含有一种或多种衍生自这些共聚物的膜的电子器件（例如聚合物发光二极管）。

7. 发明授权

US06255449B1 Fluorene-containing polymers and compounds useful in the preparation thereof 有权
标题翻译：含有芴的聚合物和可用于其制备的化合物
公开(公告)号：US06255449B1
公开(公告)日：2001-07-03
申请号：US09661234
申请日：2000-09-13
申请人： Edmund P. Woo , Michael Inbasekaran , William R. Shiang , Gordon R. Roof , Mark T. Bernius , Weishi Wu
发明人： Edmund P. Woo , Michael Inbasekaran , William R. Shiang , Gordon R. Roof , Mark T. Bernius , Weishi Wu
IPC分类号： C08G7324
CPC分类号： H01L51/0043 , C07C17/2637 , C07C17/266 , C07C25/22 , C07C25/24 , C07C211/48 , C07C2602/44 , C07C2603/18 , C08G61/00 , C08G61/02 , C08G61/10 , C09B69/105 , C09B69/109 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0081 , H01L51/42 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A compound of the formula: and compound of the formulas: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-16 hydrocarbyl carbonyloxy, C4-16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-20 ring structure or a C4-20 ring structure containing one or more heteroatoms of S, N or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl substituted with di(C1-20 alkyl)amino, C1-20 hydrocarbyloxy or C1-20 hydrocarbyl or tri(C1-10 alkyl)siloxy; a is independently in each occurrence 0 or 1; X is independently in each occurrence a halogen moiety; and Z is independently in each occurrence —B(OH)2, —B(OR4)2 or wherein R4 is independently in each occurrence a C1-10 alkyl group. and R5 is independently in each occurrence a C2-10 alkylene group
摘要翻译：下式化合物及下式化合物：其中R 1在每次出现时独立地为C 1-20烃基或含有一个或多个S，N，O，P或Si原子的C 1-20烃基，C 4-16烃基羰氧基，C 4 -16芳基（三烷基甲硅烷氧基）或两者可以与芴环上的9-碳形成C5-20环结构或含有一个或多个S，N或O杂原子的C 4-20环结构; R 2各自独立地表示 C 1-20烃基，C 1-20烃基，C 2-20烃基羰基氧基或氰基; R 3在每次出现时独立地为C 1-20烃基或被二（C 1-20烷基）氨基取代的C 1-20烃基，C 1 -20烃氧基或C 1-20烃基或三（C 1-10烷基）甲硅烷氧基; a各自独立地为0或1; X在每次出现时独立地为卤素部分; 和Z各自独立地为-B（OH）2，-B（OR 4）2，或者R 4在每次出现时独立地为C 1-10烷基。在每次出现时，R 5独立地为C 2-10亚烷基

8. 发明授权

US06900285B2 Fluorene-containing polymers and compounds useful in the preparation thereof 失效
标题翻译：含有芴的聚合物和可用于其制备的化合物
公开(公告)号：US06900285B2
公开(公告)日：2005-05-31
申请号：US10318579
申请日：2002-12-13
申请人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
发明人： Edmund P. Woo , William R. Shiang , Michael Inbasekaran , Gordon R. Roof , Mark T. Bernius , Weishi Wu
IPC分类号： C07C17/26 , C07C17/266 , C07C25/22 , C07C25/24 , C07C43/225 , C07C69/00 , C07C211/48 , C07C211/52 , C08G61/00 , C08G61/02 , C08G61/10 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/42 , H01L51/50 , C08G75/00
CPC分类号： H01L51/0043 , C07C17/2637 , C07C17/266 , C07C25/22 , C07C25/24 , C07C211/48 , C07C2602/44 , C07C2603/18 , C08G61/00 , C08G61/02 , C08G61/10 , C09B69/105 , C09B69/109 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , H01L51/0036 , H01L51/0037 , H01L51/0038 , H01L51/0039 , H01L51/0042 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0081 , H01L51/42 , H01L51/5012 , H01L2251/308 , Y10S428/917
摘要： A polymer comprising repeat units of the formula: wherein R1 is independently in each occurrence C1-20 hydrocarbyl or C1-20 hydrocarbyl containing one or more heteroatoms of S, N, O, P or Si or both R1 may form, with the 9-carbon of the fluorene ring, a C5-20 ring structure containing one or more heteroatoms of S, N, or O; R2 is independently in each occurrence C1-20 hydrocarbyl, C1-20 hydrocarbyloxy, C1-20 thioether, C1-20 hydrocarbyloxycarbonyl, hydrocarbylcarbonyloxy, or cyano; a is independently in each occurrence a number from about 0 to about 1; m is a number from about 1 to about 2; and n is a number from about 3 or greater.
摘要翻译：包含下式重复单元的聚合物：其中R 1在每次出现时独立地为含有一个或多个S，N的杂原子的烃基或C 1-20烃基，O，P或Si或两者R 1可以与芴环的9-碳形成含有一个或多个杂原子的C 5-20-20环结构， S，N或O; R 2在每次出现时独立地为C 1-20烃基，C 1-20烃氧基，C 1-20 >硫醚，C 1-20烃氧基羰基，烃基羰基氧基或氰基; a在每次出现时独立地为约0至约1的数; m为约1至约2的数; n为约3以上的数。

9. 发明授权

US06605373B2 Fluorene-containing polymers and electroluminescent devices therefrom 失效
标题翻译：含芴聚合物及其电致发光器件
公开(公告)号：US06605373B2
公开(公告)日：2003-08-12
申请号：US09808788
申请日：2001-03-15
申请人： Edmund P. Woo , Mark T. Bernius , Michael Inbasekaran , Weishi Wu
发明人： Edmund P. Woo , Mark T. Bernius , Michael Inbasekaran , Weishi Wu
IPC分类号： H05B3312
CPC分类号： H05B33/14 , C07C25/22 , C08G61/00 , C08G61/02 , C08G61/12 , C08G73/02 , C08G73/026 , C09K11/06 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/5012 , Y10S428/917 , Y10T428/31678
摘要： A copolymer comprising 10-90 percent by weight of groups of Formula (I): and from 10-90 percent by weight of groups selected from Formulas (II), (III), and (IV): and mixtures thereof; wherein R1 is independently in each occurrence H, C1-C20 hydrocarbyl or C1-C20 hydrocarbyl containing one or more S, N, O, P or Si atoms, C4-C16 hydrocarbyl carbonyloxy, C4-C16 aryl(trialkylsiloxy) or both R1 may form with the 9-carbon on the fluorene ring a C5-C20 cycloaliphatic structure or a C4-C20 cycloaliphatic structure containing one or more heteroatoms of S, N, or O; R2 is independently in each occurrence C1-C20 hydrocarbyl, C1-C20 hydrocarbyloxy, C1-C20 thioether, C1-C20 hydrocarbylcarbonyloxy or cyano; R3 is independently in each occurrence carboxyl, C1-C20 alkyl, C1-C20 alkoxy or a group of the formula —CO2R4 wherein R4 is a C1-C20 alkyl; and a and b are independently in each occurrence an integer from 0 to 3.
摘要翻译：包含10-90重量％的式（I）的基团和10-90重量％的选自式（II），（III）和（IV）的基团的共聚物及其混合物; 其中R 1在每次出现时独立地为H，C 1 -C 20烃基或含有一个或多个S，N，O，P或Si原子的C 1 -C 20烃基，C 4 -C 16烃基羰氧基，C 4 -C 16芳基（三烷基甲硅烷氧基）或两个R 1 与芴环上的9-碳形成C5-C20脂环族结构或含有一个或多个S，N或O的杂原子的C 4 -C 20脂环族结构; R2各自独立地为C1-C20烃基，C1-C20烃氧基，C1-C20硫醚，C1-C20烃基羰基氧基或氰基; R3各自独立地为羧基，C 1 -C 20烷基，C 1 -C 20烷氧基或式-CO 2 R 4基团，其中R 4为C 1 -C 20烷基; 并且a和b各自独立地为0至3的整数。

10. 发明授权

US06204515B1 Semiconducting polymer field effect transistor 有权
标题翻译：半导体聚合物场效应晶体管
公开(公告)号：US06204515B1
公开(公告)日：2001-03-20
申请号：US09470367
申请日：1999-12-22
申请人： Mark T. Bernius , Edmund P. Woo
发明人： Mark T. Bernius , Edmund P. Woo
IPC分类号： H01L3544
CPC分类号： H01L51/0038 , H01L51/0036 , H01L51/0039 , H01L51/0043 , H01L51/0059 , H01L51/0516 , H01L51/052 , H01L51/0525 , H01L51/0545
摘要： A field effect transistor is made of five parts. The first part is an insulator layer, the insulator layer being an electrical insulator such as silica, the insulator layer having a first side and a second side. The second part is a gate, the gate being an electrical conductor such as silver, the gate being positioned on the first side of the insulator layer. The third part is a semiconductor layer, the semiconductor layer including a polymer, at least ten weight percent of the monomer units of the polymer being a 9-substituted fluorene unit and/or a 9,9-substituted fluorene unit, the semiconductor layer having a first side, a second side, a first end and a second end, the second side of the semiconductor layer being on the second side of the insulator layer. The fourth part is a source, the source being an electrical conductor such as silver, the source being in electrical contact with the first end of the semiconductor layer. The fifth part is a drain, the drain being an electrical conductor such as silver, the drain being in electrical contact with the second end of the semiconductor layer. A negative voltage bias applied to the gate causes the formation of a conduction channel in the semiconductor layer from the source to the drain. On the other hand, a positive bias applied to the gate causes the formation of an electron conducting channel in the semiconductor layer.
摘要翻译：场效应晶体管由五部分组成。第一部分是绝缘体层，绝缘体层是诸如二氧化硅的电绝缘体，绝缘体层具有第一面和第二面。第二部分是栅极，栅极是诸如银的电导体，栅极位于绝缘体层的第一侧上。第三部分是半导体层，半导体层包括聚合物，聚合物的单体单元的至少10重量％是9-取代的芴单元和/或9,9-取代的芴单元，所述半导体层具有第一侧，第二侧，第一端和第二端，所述半导体层的第二侧在绝缘体层的第二侧上。第四部分是源，源是诸如银的电导体，源与半导体层的第一端电接触。第五部分是漏极，漏极是诸如银的电导体，漏极与半导体层的第二端电接触。施加到栅极的负电压偏压导致从源极到漏极在半导体层中形成导电沟道。另一方面，施加到栅极的正偏压导致在半导体层中形成电子传导沟道。

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