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    • 2. 发明申请
    • Use of Comb Polymers as a Grinding Agent for Preparations Containing Cement
    • 使用梳子聚合物作为含水泥制剂的研磨剂
    • US20080293850A1
    • 2008-11-27
    • US12095799
    • 2006-11-23
    • Joachim PakuschStefan BeckerThomas GotzRainer Dyllick-BrenzingerRolf Gulden
    • Joachim PakuschStefan BeckerThomas GotzRainer Dyllick-BrenzingerRolf Gulden
    • C04B7/02C08L33/02
    • C04B24/2605C04B24/2647C04B24/267C04B28/02C04B2103/006C04B2103/52Y02P40/20
    • The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W  A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y-Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.
    • 本发明涉及具有碳骨架的梳状聚合物的用途,所述主骨架具有式A的聚醚基团。在线式描述=“在线公式”末端=“铅”→* - U-( C(O))kX-(Alk-O)nW A <βin-line-formula description =“In-line Formulas”end =“tail”?>其中*表示梳形聚合物的碳骨架的结合位点 ,U表示1〜8个C原子的化学键或亚烷基,X表示氧或NR基,k表示0或1,n表示整数,其基于梳形聚合物的平均值, AlK代表C2-C4亚烷基,其中Alk(O-O)n中的Al可以相同或不同,W表示氢,C1-C6烷基或芳基残基 或者表示基团YZ,Y表示具有2至8个C原子的直链或支链亚烷基,其可以带有苯环,Z表示通过氮键合的5至10元氮杂环,其可以具有环 成员,以及硝基 原子以及碳原子,1,2或3个选自氧,氮和硫的另外的杂原子,其中氮环成员可以含有基团R',并且其中1或2个碳环成员可以以 羰基,R代表氢,C 1 -C 4烷基或苄基,R'代表氢,C 1 -C 4烷基或苄基; 和以pH> 12的阴离子基团形式存在的官能团B及其盐作为含水泥制剂中的助磨剂。
    • 4. 发明申请
    • Comb Polymers and Their Use as Additives for Preparations of Mineral Binders
    • 梳子聚合物及其作为添加剂用于矿物粘合剂的制备
    • US20080300343A1
    • 2008-12-04
    • US12092586
    • 2006-11-06
    • Stefan BeckerMarkus KlumpeJoachim PakuschThomas GotzChristian KnollRolf Gulden
    • Stefan BeckerMarkus KlumpeJoachim PakuschThomas GotzChristian KnollRolf Gulden
    • C08K3/00C08G63/02C08G69/26
    • C08F283/06C04B24/2647C04B24/2658C04B28/02C04B28/14C04B2103/006C04B2103/32C08F290/00C08F290/142C08L51/08C04B24/18C04B24/2676C04B24/383C04B24/226C04B24/2641C04B24/32C08L2666/02
    • The present invention relates to novel comb polymers which bear poly-C2-C4-alkylene ether side chains A and functional groups B which at a pH of >12 are present in the form of anionic groups on a carbon backbone and also the salts of such comb polymers. The invention also relates to the use of these comb polymers as additives in preparations comprising a mineral binder. The polyalkylene ether side chains A have the following formula: *—U—(C(O))k—X-(Alk-O)n—Y-Z  A where * indicates the point of bonding to the carbon backbone of the comb polymer, U is a chemical bond or an alkylene group having from 1 to 8 carbon atoms, X is oxygen or an NR group, k is 0 or 1, n is an integer whose average value, based on the comb polymer, is in the range from 5 to 300, Alk is C2-C4-alkylene, with the Alk radicals within the group (Alk-O)n being able to be identical or different, Y is a linear or branched alkylene group which has from 2 to 8 carbon atoms and may bear a phenyl ring, Z is a 5- to 10-membered nitrogen heterocycle which is bound via nitrogen and can have, in addition to the nitrogen atom and carbon atoms, 1, 2 or 3 additional heteroatoms selected from among oxygen, nitrogen and sulfur as ring members, with the nitrogen ring members being able to bear a group R′ and 1 or 2 carbon ring members being able to be present as carbonyl groups, R is hydrogen, C1-C4-alkyl or benzyl and R′ is hydrogen, C1-C4-alkyl or benzyl.
    • 本发明涉及具有聚-C2-C4-亚烷基醚侧链A和官能团B的新型梳状聚合物,其pH> 12是以碳骨架上的阴离子基团的形式存在,以及其中的盐 梳状聚合物。 本发明还涉及这些梳状聚合物作为添加剂在包含矿物粘合剂的制剂中的用途。 聚亚烷基醚侧链A具有以下公式:<?in-line-formula description =“In-line formula”end =“lead”?> * - U-(C(O))kX-(Alk-O) nYZ A <?in-line-formula description =“In-line Formulas”end =“tail”?>其中*表示与梳形聚合物的碳骨架键合的点,U是化学键或具有 1〜8个碳原子,X为氧或NR基,k为0或1,n为基于梳形聚合物的平均值为5〜300的整数,Alk为C2-C4- 亚烷基,其中基团中的Alk基团(Alk-O)n能够相同或不同,Y是具有2至8个碳原子并且可以带有苯环的直链或支链亚烷基,Z是5 至10元氮杂环,其通过氮结合并且除了氮原子和碳原子之外,还可以具有1,2或3个选自氧,氮和硫作为环成员的另外的杂原子,与氮环成员 贝宁 能够承载能够以羰基存在的基团R'和1或2个碳环成员,R是氢,C 1 -C 4 - 烷基或苄基,R'是氢,C 1 -C 4 - 烷基或苄基。
    • 10. 发明授权
    • Polymer dispersions as an additive in building materials
    • 聚合物分散体作为建筑材料中的添加剂
    • US06809148B1
    • 2004-10-26
    • US10383609
    • 2003-03-10
    • Markus KoppersJoachim PakuschHermann AndersMarco SchmidtHans-Jürgen Denu
    • Markus KoppersJoachim PakuschHermann AndersMarco SchmidtHans-Jürgen Denu
    • C08F22010
    • C04B24/2641C04B24/2647C04B24/2676C04B24/2688C04B28/02C04B2103/0057C04B2111/00586C04B2111/0075C08F212/04C08F236/10C08F290/062
    • Polymer dispersions comprise at least one copolymer which contains, as polymerized monomers, a) from 25 to 70% by weight of at least one conjugated aliphatic diene, b) from 25 to 70% by weight of at least one vinylaromatic monomer, c) from 2.5 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid or c′) from 0.1 to 10% by weight of at least one alkylpolyethylene glycol (meth)acrylate of the formula (I) where R1 is hydrogen or methyl, R2 is C1-C4-alkyl and n is an integer from 1 to 100, or c″) from 2 to 15% by weight of a mixture of the monoester c) and the alkylpolyethylene glycol (meth)acrylate c′), d) from 0 to 1.0% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) from 0 to 5.0% by weight of ethylenically unsaturated nitriles and f) from 0 to 1.0% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids. The polymer dispersions described are suitable, inter alia, as additives in building materials based on hydraulic binders.
    • 聚合物分散体包含至少一种共聚物,其包含作为聚合单体的a)25至70重量%的至少一种共轭脂族二烯,b)25至70重量%的至少一种乙烯基芳族单体,c) 2.5至15重量%的至少一种C2-C10-链烷二醇与丙烯酸或甲基丙烯酸orc'的单酯)0.1至10重量%的至少一种式(I)的烷基聚乙二醇(甲基)丙烯酸酯, 其中R 1是氢或甲基,R 2是C 1 -C 4 - 烷基,n是1至100的整数,orc“)2至15重量%的单酯c)和 烷基聚乙二醇(甲基)丙烯酸酯c'),d)0至1.0重量%的具有至少一个酸基的烯键式不饱和单体或其盐,e)0-5.0重量%的烯属不饱和腈和 )0至1.0重量%的α,β-烯键式不饱和单羧酸和二羧酸的酰胺。所述聚合物分散体是合适的,i 特别是作为基于水泥粘合剂的建筑材料中的添加剂。