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1. 发明授权

US08022120B2 Comb polymers and their use as additives for preparations of mineral binders 有权
标题翻译：梳状聚合物及其作为矿物粘合剂制剂添加剂的用途
公开(公告)号：US08022120B2
公开(公告)日：2011-09-20
申请号：US12092586
申请日：2006-11-06
申请人： Stefan Becker , Markus Klumpe , Joachim Pakusch , Thomas Goetz , Christian Knoll , Rolf Gulden
发明人： Stefan Becker , Markus Klumpe , Joachim Pakusch , Thomas Goetz , Christian Knoll , Rolf Gulden
IPC分类号： C04B24/26 , C08G63/60 , C08G69/26 , C08G63/06
CPC分类号： C08F283/06 , C04B24/2647 , C04B24/2658 , C04B28/02 , C04B28/14 , C04B2103/006 , C04B2103/32 , C08F290/00 , C08F290/142 , C08L51/08 , C04B24/18 , C04B24/2676 , C04B24/383 , C04B24/226 , C04B24/2641 , C04B24/32 , C08L2666/02
摘要： The present invention relates to novel comb polymers which bear poly-C2-C4-alkylene ether side chains A and functional groups B which at a pH of >12 are present in the form of anionic groups on a carbon backbone and also the salts of such comb polymers. The invention also relates to the use of these comb polymers as additives in preparations comprising a mineral binder. The polyalkylene ether side chains A have the following formula: *—U—(C(O))k—X-(Alk-O)n—Y—Z A.
摘要翻译：本发明涉及具有聚-C2-C4-亚烷基醚侧链A和官能团B的新型梳状聚合物，其pH> 12是以碳骨架上的阴离子基团的形式存在，以及其中的盐梳状聚合物。本发明还涉及这些梳状聚合物作为添加剂在包含矿物粘合剂的制剂中的用途。聚亚烷基醚侧链A具有下式：* -U-（C（O））k -X-（Alk-O）n -Y-Z A

2. 发明申请

US20080300343A1 Comb Polymers and Their Use as Additives for Preparations of Mineral Binders 有权
标题翻译：梳子聚合物及其作为添加剂用于矿物粘合剂的制备
公开(公告)号：US20080300343A1
公开(公告)日：2008-12-04
申请号：US12092586
申请日：2006-11-06
申请人： Stefan Becker , Markus Klumpe , Joachim Pakusch , Thomas Gotz , Christian Knoll , Rolf Gulden
发明人： Stefan Becker , Markus Klumpe , Joachim Pakusch , Thomas Gotz , Christian Knoll , Rolf Gulden
IPC分类号： C08K3/00 , C08G63/02 , C08G69/26
CPC分类号： C08F283/06 , C04B24/2647 , C04B24/2658 , C04B28/02 , C04B28/14 , C04B2103/006 , C04B2103/32 , C08F290/00 , C08F290/142 , C08L51/08 , C04B24/18 , C04B24/2676 , C04B24/383 , C04B24/226 , C04B24/2641 , C04B24/32 , C08L2666/02
摘要： The present invention relates to novel comb polymers which bear poly-C2-C4-alkylene ether side chains A and functional groups B which at a pH of >12 are present in the form of anionic groups on a carbon backbone and also the salts of such comb polymers. The invention also relates to the use of these comb polymers as additives in preparations comprising a mineral binder. The polyalkylene ether side chains A have the following formula: *—U—(C(O))k—X-(Alk-O)n—Y-Z A where * indicates the point of bonding to the carbon backbone of the comb polymer, U is a chemical bond or an alkylene group having from 1 to 8 carbon atoms, X is oxygen or an NR group, k is 0 or 1, n is an integer whose average value, based on the comb polymer, is in the range from 5 to 300, Alk is C2-C4-alkylene, with the Alk radicals within the group (Alk-O)n being able to be identical or different, Y is a linear or branched alkylene group which has from 2 to 8 carbon atoms and may bear a phenyl ring, Z is a 5- to 10-membered nitrogen heterocycle which is bound via nitrogen and can have, in addition to the nitrogen atom and carbon atoms, 1, 2 or 3 additional heteroatoms selected from among oxygen, nitrogen and sulfur as ring members, with the nitrogen ring members being able to bear a group R′ and 1 or 2 carbon ring members being able to be present as carbonyl groups, R is hydrogen, C1-C4-alkyl or benzyl and R′ is hydrogen, C1-C4-alkyl or benzyl.
摘要翻译：本发明涉及具有聚-C2-C4-亚烷基醚侧链A和官能团B的新型梳状聚合物，其pH> 12是以碳骨架上的阴离子基团的形式存在，以及其中的盐梳状聚合物。本发明还涉及这些梳状聚合物作为添加剂在包含矿物粘合剂的制剂中的用途。聚亚烷基醚侧链A具有以下公式：<？in-line-formula description =“In-line formula”end =“lead”？> * - U-（C（O））kX-（Alk-O） nYZ A <？in-line-formula description =“In-line Formulas”end =“tail”？>其中*表示与梳形聚合物的碳骨架键合的点，U是化学键或具有 1〜8个碳原子，X为氧或NR基，k为0或1，n为基于梳形聚合物的平均值为5〜300的整数，Alk为C2-C4- 亚烷基，其中基团中的Alk基团（Alk-O）n能够相同或不同，Y是具有2至8个碳原子并且可以带有苯环的直链或支链亚烷基，Z是5 至10元氮杂环，其通过氮结合并且除了氮原子和碳原子之外，还可以具有1,2或3个选自氧，氮和硫作为环成员的另外的杂原子，与氮环成员贝宁能够承载能够以羰基存在的基团R'和1或2个碳环成员，R是氢，C 1 -C 4 - 烷基或苄基，R'是氢，C 1 -C 4 - 烷基或苄基。

3. 发明申请

US20100069532A1 PROCESS FOR PREPARING POLYMERIZABLE CARBOXYLIC ESTERS WITH ALKOXY GROUPS 审中-公开
标题翻译：用烷基聚合物制备可聚合羧酸酯的方法
公开(公告)号：US20100069532A1
公开(公告)日：2010-03-18
申请号：US12516628
申请日：2007-12-03
申请人： Paola Uribe Arocha , Joachim Pakusch , Stefan Becker , Thomas Goetz , Sylke Haremza , Rolf Gulden
发明人： Paola Uribe Arocha , Joachim Pakusch , Stefan Becker , Thomas Goetz , Sylke Haremza , Rolf Gulden
IPC分类号： C08K3/00 , C07C69/54 , C07C69/60 , C08F20/26 , C08F22/20
CPC分类号： C04B24/2647 , C04B2103/32 , C08F220/26 , C08G65/3324
摘要： A process for preparing free-radically polymerizable carboxylic esters by reacting ethyllenically unsaturated carboxylic acids, carboxylic anhydrides or carbonyl halides (referred to collectively as carboxylic acid component) with a hydroxyl compound composed of at least 60% by weight of C2 to C4 alkoxy groups (and referred to for short as polyalkoxy compound), which comprises said reacting taking place in the presence of a polymerization inhibitor and of a reducing agent.
摘要翻译：通过使不饱和羧酸，羧酸酐或羰基卤化物（统称为羧酸组分）与由至少60重量％的C 2至C 4烷氧基组成的羟基化合物反应制备可自由基聚合的羧酸酯的方法（简称为聚烷氧基化合物），其包括在聚合抑制剂和还原剂的存在下发生的所述反应。

4. 发明授权

US08119727B2 Use of comb polymers as a grinding agent for preparations containing cement 有权
标题翻译：使用梳形聚合物作为含水泥制剂的研磨剂
公开(公告)号：US08119727B2
公开(公告)日：2012-02-21
申请号：US12095799
申请日：2006-11-23
申请人： Joachim Pakusch , Stefan Becker , Thomas Goetz , Rainer Dyllick-Brenzinger , Rolf Gulden
发明人： Joachim Pakusch , Stefan Becker , Thomas Goetz , Rainer Dyllick-Brenzinger , Rolf Gulden
IPC分类号： C04B7/02 , C08L33/02
CPC分类号： C04B24/2605 , C04B24/2647 , C04B24/267 , C04B28/02 , C04B2103/006 , C04B2103/52 , Y02P40/20
摘要： The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y—Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.
摘要翻译：本发明涉及具有碳骨架的梳状聚合物的用途，其具有式A * -U-（C（O））k-X-（Alk-O）n -W A的聚醚基团，其中*表示与梳状聚合物的碳骨架的结合位置，U表示化学键或具有1至8个C原子的亚烷基，X表示氧或NR基团，k表示0或1，n表示整数，基于梳形聚合物的平均值在5至300的范围内，Alk表示C2-C4亚烷基，其中基团（Alk-O）n中的Alk可以相同或不同，W表示氢， C1-C6烷基残基或芳基残基，或指Y-Z基团，Y代表具有2至8个C原子的直链或支链亚烷基，可带有苯环，Z代表5-至10- 可以具有氮原子以及氮原子以及碳原子，1,2或3个选自氧，氮和硫的另外的杂原子的氮键连接的氮原子杂环。硫，其中氮环成员可以含有基团R'，并且其中1或2个碳环成员可以作为羰基存在，R代表氢，C1-C4烷基或苄基，R'代表氢，C1- C4烷基或苄基; 和以pH> 12的阴离子基团形式存在的官能团B及其盐作为含水泥制剂中的助磨剂。

5. 发明申请

US20080293850A1 Use of Comb Polymers as a Grinding Agent for Preparations Containing Cement 有权
标题翻译：使用梳子聚合物作为含水泥制剂的研磨剂
公开(公告)号：US20080293850A1
公开(公告)日：2008-11-27
申请号：US12095799
申请日：2006-11-23
申请人： Joachim Pakusch , Stefan Becker , Thomas Gotz , Rainer Dyllick-Brenzinger , Rolf Gulden
发明人： Joachim Pakusch , Stefan Becker , Thomas Gotz , Rainer Dyllick-Brenzinger , Rolf Gulden
IPC分类号： C04B7/02 , C08L33/02
CPC分类号： C04B24/2605 , C04B24/2647 , C04B24/267 , C04B28/02 , C04B2103/006 , C04B2103/52 , Y02P40/20
摘要： The present invention relates to the use of comb polymers which have a carbon backbone which bears polyether groups of the formula A *—U—(C(O))k—X-(Alk-O)n—W A wherein * indicates the binding site to the carbon backbone of the comb polymer, U stands for a chemical bond or an alkylene group with 1 to 8 C atoms, X means oxygen or a NR group, k is 0 or 1, n stands for a whole number, the mean value whereof, based on the comb polymer, lies in the range from 5 to 300, Alk stands for C2-C4 alkylene, where Alk within the group (Alk-O)n can be the same or different, W means a hydrogen, a C1-C6 alkyl residue or an aryl residue or means the group Y-Z, Y stands for a linear or branched alkylene group with 2 to 8 C atoms, which may bear a phenyl ring, Z stands for a 5- to 10-membered nitrogen heterocycle bound via nitrogen, which can have as ring members, as well as the nitrogen atom and as well as carbon atoms, 1, 2 or 3 additional hetero atoms, selected from oxygen, nitrogen and sulfur, wherein the nitrogen ring members can contain a group R′, and wherein 1 or 2 carbon ring members can be present as carbonyl groups, R stands for hydrogen, C1-C4 alkyl or benzyl, and R′ stands for hydrogen, C1-C4 alkyl or benzyl; and functional groups B, which are present in the form of anionic groups at pH>12, and salts thereof as grinding aids in cement-containing preparations.
摘要翻译：本发明涉及具有碳骨架的梳状聚合物的用途，所述主骨架具有式A的聚醚基团。在线式描述=“在线公式”末端=“铅”→* - U-（ C（O））kX-（Alk-O）nW A <βin-line-formula description =“In-line Formulas”end =“tail”？>其中*表示梳形聚合物的碳骨架的结合位点，U表示1〜8个C原子的化学键或亚烷基，X表示氧或NR基，k表示0或1，n表示整数，其基于梳形聚合物的平均值， AlK代表C2-C4亚烷基，其中Alk（O-O）n中的Al可以相同或不同，W表示氢，C1-C6烷基或芳基残基或者表示基团YZ，Y表示具有2至8个C原子的直链或支链亚烷基，其可以带有苯环，Z表示通过氮键合的5至10元氮杂环，其可以具有环成员，以及硝基原子以及碳原子，1,2或3个选自氧，氮和硫的另外的杂原子，其中氮环成员可以含有基团R'，并且其中1或2个碳环成员可以以羰基，R代表氢，C 1 -C 4烷基或苄基，R'代表氢，C 1 -C 4烷基或苄基; 和以pH> 12的阴离子基团形式存在的官能团B及其盐作为含水泥制剂中的助磨剂。

6. 发明授权

US06469135B2 Preparation of polymer powders 失效
标题翻译：聚合物粉末的制备
公开(公告)号：US06469135B2
公开(公告)日：2002-10-22
申请号：US09932932
申请日：2001-08-21
申请人： Mario Sandor , Joachim Pakusch , Heinrich Sack , Markus Koppers , Hans-Jürgen Denu , Rolf Gulden
发明人： Mario Sandor , Joachim Pakusch , Heinrich Sack , Markus Koppers , Hans-Jürgen Denu , Rolf Gulden
IPC分类号： C08F600
CPC分类号： C04B28/02 , C04B40/0042 , C04B2103/0057 , C04B2103/0091 , C08J3/16 , Y02W30/97 , C04B24/16 , C04B24/22 , C04B24/2676 , C04B14/06 , C04B16/06 , C04B18/24 , C04B40/0608 , C04B2103/54
摘要： The present invention provides a process for preparing polymer powders by evaporating the volatile constituents from aqueous dispersions of film-forming polymers P in the presence of drying assistants T selected from the salts of oligomeric arylsulfonic acid-formaldehyde condensates wherein prior to the evaporation of the volatile constituents the aqueous polymer dispersion comprises at least 1.5% by weight, preferably at least 1.7% by weight, based on the polymer in the dispersion, of at least one anionic surface-active compound AO having at least one C6-C32 alkyl group; the polymer powders obtainable by the process; and their use in binding mineral building materials.
摘要翻译：本发明提供了一种制备聚合物粉末的方法，该方法是在选自低聚芳基磺酸 - 甲醛缩合物的盐的干燥助剂T的存在下，从成膜聚合物P的水性分散体中蒸发挥发性成分，其中在蒸发挥发性含水聚合物分散体包含至少一种具有至少一个C 6 -C 32烷基的至少一种阴离子表面活性化合物AO至少1.5重量％，优选至少1.7重量％，基于分散体中的聚合物; 通过该方法可获得的聚合物粉末; 并将其用于结合矿物建筑材料。

7. 发明授权

US06559221B2 Silane-containing polymer dispersions for tile cements 失效
公开(公告)号：US06559221B2
公开(公告)日：2003-05-06
申请号：US09927390
申请日：2001-08-13
申请人： Mario Sandor , Joachim Pakusch , Wolfgang Hümmer , Hans-Jürgen Denu , Rolf Gulden
发明人： Mario Sandor , Joachim Pakusch , Wolfgang Hümmer , Hans-Jürgen Denu , Rolf Gulden
IPC分类号： C08L4304
CPC分类号： C08F290/06 , C08F246/00 , C08F257/02 , C09D143/04 , C09D151/003 , C09J151/003
摘要： An aqueous polymer dispersion, wherein the dispersion contains from 0.0001 to 1 mol of a hydrolyzable silicon group and from 0.0001 to 1 mol of a urea or thiourea group, based, in each case, on 100 g of the polymer present in the dispersion.

8. 发明授权

US6075075A Use of aqueous polymer dispersions for modifying mineral building materials 失效
标题翻译：使用聚合物水分散体改性矿物建筑材料
公开(公告)号：US6075075A
公开(公告)日：2000-06-13
申请号：US679568
申请日：1996-07-15
申请人： Andree Dragon , Rolf Gulden , Maximilian Angel
发明人： Andree Dragon , Rolf Gulden , Maximilian Angel
IPC分类号： C04B24/12 , C04B24/26 , C04B28/02 , C08F2/24 , C08F257/02 , C08F279/02 , C08J5/10 , C08K3/00 , C08L33/00
CPC分类号： C04B24/2641 , C04B28/02 , C08F257/02 , C08F279/02 , C04B2103/0057
摘要： Aqueous polymer dispersions whose polymer is composed of up to
摘要翻译：聚合物聚合物分散体，其聚合物由（甲基）丙烯酸至多5重量％，至多5重量％的（甲基）丙烯酰胺和90至97.5重量％的其它非离子不饱和单体组成，并且存在由于使用重均粒径为100〜300nm的分散聚合物粒子来改性矿物建筑材料。

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