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    • 1. 发明授权
    • Polymer dispersions as an additive in building materials
    • 聚合物分散体作为建筑材料中的添加剂
    • US06809148B1
    • 2004-10-26
    • US10383609
    • 2003-03-10
    • Markus KoppersJoachim PakuschHermann AndersMarco SchmidtHans-Jürgen Denu
    • Markus KoppersJoachim PakuschHermann AndersMarco SchmidtHans-Jürgen Denu
    • C08F22010
    • C04B24/2641C04B24/2647C04B24/2676C04B24/2688C04B28/02C04B2103/0057C04B2111/00586C04B2111/0075C08F212/04C08F236/10C08F290/062
    • Polymer dispersions comprise at least one copolymer which contains, as polymerized monomers, a) from 25 to 70% by weight of at least one conjugated aliphatic diene, b) from 25 to 70% by weight of at least one vinylaromatic monomer, c) from 2.5 to 15% by weight of at least one monoester of a C2-C10-alkanediol with acrylic acid or methacrylic acid or c′) from 0.1 to 10% by weight of at least one alkylpolyethylene glycol (meth)acrylate of the formula (I) where R1 is hydrogen or methyl, R2 is C1-C4-alkyl and n is an integer from 1 to 100, or c″) from 2 to 15% by weight of a mixture of the monoester c) and the alkylpolyethylene glycol (meth)acrylate c′), d) from 0 to 1.0% by weight of ethylenically unsaturated monomers which have at least one acid group, or salts thereof, e) from 0 to 5.0% by weight of ethylenically unsaturated nitriles and f) from 0 to 1.0% by weight of amides of &agr;,&bgr;-ethylenically unsaturated mono- and dicarboxylic acids. The polymer dispersions described are suitable, inter alia, as additives in building materials based on hydraulic binders.
    • 聚合物分散体包含至少一种共聚物,其包含作为聚合单体的a)25至70重量%的至少一种共轭脂族二烯,b)25至70重量%的至少一种乙烯基芳族单体,c) 2.5至15重量%的至少一种C2-C10-链烷二醇与丙烯酸或甲基丙烯酸orc'的单酯)0.1至10重量%的至少一种式(I)的烷基聚乙二醇(甲基)丙烯酸酯, 其中R 1是氢或甲基,R 2是C 1 -C 4 - 烷基,n是1至100的整数,orc“)2至15重量%的单酯c)和 烷基聚乙二醇(甲基)丙烯酸酯c'),d)0至1.0重量%的具有至少一个酸基的烯键式不饱和单体或其盐,e)0-5.0重量%的烯属不饱和腈和 )0至1.0重量%的α,β-烯键式不饱和单羧酸和二羧酸的酰胺。所述聚合物分散体是合适的,i 特别是作为基于水泥粘合剂的建筑材料中的添加剂。
    • 3. 发明授权
    • Nonaqueous plastics formulations
    • 非质量塑料配方
    • US5120795A
    • 1992-06-09
    • US451187
    • 1989-12-15
    • Ulrich FilgesOral AydinHermann Anders
    • Ulrich FilgesOral AydinHermann Anders
    • C09K3/10C08L33/06C08L33/12C08L33/14C09D133/04C09D133/08C09D133/12C09J133/04C09J133/08C09J133/12
    • C09D133/12C08L33/12C08L33/14C09J133/12C08L33/068Y10S525/913
    • A) 100 parts by weight of at least one finely divided plastic which consists ofa) from 30 to 100% by weight of methyl methacrylate (monomer I),b) from 0 to 70% by weight of an acrylate of a C.sub.1 -C.sub.8 alkanol or of a methacrylate of a C.sub.2 -C.sub.8 -alkanol or of a mixture of these monomers (monomers II),c) from 0 to 15% by weight of an .alpha.,.beta.-monoethylenically unsaturated mono- and/or dicarboxylic acid of 3 to 5 carbon atoms (monomers III),d) from 0 to 20% by weight of copolymerizable monomers which contain at least one nitrogen base group and/or one hyroxyl group (monomers IV) ande) from 0 to 5% by weight of other copolymerizable monomers (monomers V), in polymerized form,B) from 30 to 300 parts by weight of at least one polymer which consists ofa) from 5 to 100% by weight of glycidyl acrylate and/or methacrylate (monomers VI),b) from 0 to 95% by weight of an acrylate or methacrylate of a C.sub.1 -C.sub.8 -alkanol or of a mixture of these monomers (monomers VII) andc) from 0 to 30% by weight of other copolymerizable monomers (monomers VIII), in polymerized form,C) from 0 to 300 parts by weight of one or more inert fillers andD) from 0 to 50 parts by weight of one or more adhesion-improviding agents.
    • A)100重量份至少一种细分塑料,其由a)30-100重量%的甲基丙烯酸甲酯(单体I)组成,b)0-70重量%的C1-C8烷醇的丙烯酸酯 或C2-C8-链烷醇的甲基丙烯酸酯或这些单体(单体II)的混合物的甲基丙烯酸酯,c)0至15重量%的α,β-单烯属不饱和单 - 和/或二羧酸,其3〜 5个碳原子(单体III),d)0至20重量%的含有至少一个氮基和/或一个羟基(单体IV)的可共聚单体和e)0至5重量%的其它 共聚单体(单体V),B)30至300重量份的至少一种聚合物,其由以下组成:a)5至100重量%的丙烯酸缩水甘油酯和/或甲基丙烯酸缩水甘油酯(单体VI),b )0至95重量%的C1-C8烷醇的丙烯酸酯或甲基丙烯酸酯或这些单体(单体VII)的混合物的丙烯酸酯或甲基丙烯酸酯,和c)0至30重量% 其它可聚合形式的可共聚单体(单体VIII)C)0-300重量份一种或多种惰性填料和D)0-50份重量的一种或多种附着力改进剂。