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    • 4. 发明申请
    • Ligands, complexes, and their use for the polymerization of olefins
    • 配体,络合物及其用于烯烃聚合的用途
    • US20050038212A1
    • 2005-02-17
    • US10932124
    • 2004-09-02
    • Marc KristenBenno BildsteinChristoph AmortMichael Malaun
    • Marc KristenBenno BildsteinChristoph AmortMichael Malaun
    • C07D207/50C07D209/08C07D209/50C07D209/86C07F9/50C07F15/00C07F15/04C08F4/06C08F4/42C08F4/70C08F4/80C08F10/00C08F110/02C07F1/00
    • C07F15/045C07D209/08C07D209/50C07D209/86C07F15/006C08F110/02C08F4/80C08F2500/17C08F2500/10C08F2500/03C08F2500/04
    • Ethylene and other 1-olefins and optionally other non-1-olefins are (co)polymerized in the presence of a catalyst which is a complex of formula I, where the variables are defined as follows: M is an element of Groups 6 to 10 of the Periodic Table of the Elements, Nu1 is O, S or Se; Nu2, Nu3 are each N or P, A1 is N or C—R7 or Si—R7, A2 is N or C—R8 or Si—R8, R1 to R5 are hydrogen, R6 to R9 are selected from the group consisting of (i) hydrogen, (ii) substituted or unsubstituted C1-C8-alkyl, (iii) substituted or unsubstituted C2-C8-alkenyl having from one to 4 isolated or conjugated double bonds, (iv) substituted or unsubstituted C3-C12-cycloalkyl, (v) C7-C13-aralkyl, (vi) C6-C14-aryl that is unsubstituted or monosubstituted or polysubstituted by identical or different substituents selected from the group consisting of substituted or unsubstituted C1-C8-alkyl, C3-C12-cycloalkyl, C7-C13-aralkyl, C6-C14-aryl, halogen, substituted or unsubstituted C1-C6-alkoxy, C6-C14-aryloxy, SiR10R11R12 and O—SiR10R11R12; and (vii) five- and six-membered nitrogen-containing heteroaryl radicals, unsubstituted or monosubstituted or polysubstituted by identical or different substituents selected from the group consisting of substituted or unsubstituted C1-C8-alkyl, C3-C12-cycloalkyl, C7-C13-aralkyl, C6-C14-aryl, halogen, C1-C6-alkoxy, C6-C14-aryloxy, SiR10R11R12 and O—SiR10R11R12, where adjacent radicals R1 to R9 optionally joined to one another to form a 5- to 12-membered ring; L1 is an uncharged organic or inorganic ligand, L2 is an organic or inorganic anionic ligand, where L1 and L2 may be joined to one another by one or more covalent bonds, and z is an integer from 1 to 3, and where R10 to R12 are identical or different and are selected from among the group consisting of hydrogen, C1-C8-alkyl, C3-C12-cycloalkyl, C7-C13-aralkyl and C6-C14-aryl.
    • 乙烯和其它1-烯烃和任选的其它非1-烯烃在式I化合物的催化剂存在下进行(共)聚合,其中变量定义如下:M是第6至10族的元素 元素周期表,Nu 1是O,S或Se; Nu 2,Nu 3各自为N或P,A 1为N或CR 7或Si-R 7,A 2为N或CR 8或Si-R 7, R 1至R 5为氢,R 6至R 9选自(i)氢,(ii)取代或未取代的C 1 -C 8 - 烷基,(iii )取代或未取代的具有1至4个分离或共轭双键的C 2 -C 8 - 烯基,(iv)取代或未取代的C 3 -C 12 - 环烷基,(v)C 7 -C 13 - 芳烷基,(vi)C 6 -C 14 - 芳基, 被取代或未取代的C 1 -C 8 - 烷基,C 3 -C 12 - 环烷基,C 7 -C 13 - 芳烷基,C 6 -C 14 - 芳基,卤素,取代或未取代的C1 C 1-6 - 烷氧基,C 6 -C 14 - 芳氧基,SiR 10 R 11和O-SiR 10 R 11; 和(vii)五元和六元含氮杂芳基,其被选自取代或未取代的C 1 -C 8 - 烷基,C 3 -C 12 - 环烷基,C 7 -C 13的相同或不同的取代基未取代或单取代或多取代 芳烷基,C 6 -C 14 - 芳基,卤素,C 1 -C 6 - 烷氧基,C 6 -C 14 - 芳氧基,SiR 10 R 11和O-SiR <