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1. 发明申请

US20090054609A1 Process for the Preparation of Unsymmetric Bis(Imino) Compounds 有权
标题翻译：制备不对称双（亚氨基）化合物的方法
公开(公告)号：US20090054609A1
公开(公告)日：2009-02-26
申请号：US12087554
申请日：2007-01-08
申请人： Shahram Mihan , Benno Bildstein , Lars Kolling , Alexander Solchinger , Sascha Schlawjinski
发明人： Shahram Mihan , Benno Bildstein , Lars Kolling , Alexander Solchinger , Sascha Schlawjinski
IPC分类号： C08F4/26 , C07D213/50 , C07F15/02
CPC分类号： C07F15/025 , B01J2531/0238 , B01J2531/842 , C07D213/44 , C07D213/53 , C08F10/00 , C08F110/02 , C08F2500/17 , C08F2500/04 , C08F4/7042
摘要： Process for the preparation of monoimine compounds, wherein a dicarbonyl compound is reacted in an aliphatic, non-aromatic solvent with aniline. Monoimine compounds having electron-withdrawing substituents in the ortho position and unsymmetric bis(imino) compounds and unsymmetric iron complexes prepared therefrom and the use thereof in the polymerization of olefins.
摘要翻译：制备单亚胺化合物的方法，其中二羰基化合物在脂族，非芳族溶剂中与苯胺反应。在邻位具有吸电子取代基的单亚胺化合物和由其制备的不对称双（亚氨基）化合物和不对称铁络合物及其在烯烃聚合中的用途。

2. 发明申请

US20050085603A1 Metal complexes of iminohydroxamic acids 失效
公开(公告)号：US20050085603A1
公开(公告)日：2005-04-21
申请号：US10961074
申请日：2004-10-12
申请人： Marc Kristen , Peter Preishuber-Pflugl , Benno Bildstein , Alexander Krajete
发明人： Marc Kristen , Peter Preishuber-Pflugl , Benno Bildstein , Alexander Krajete
IPC分类号： C07C259/18 , C07C43/04 , C07C257/22 , C07F15/00 , C07F15/04 , C08F2/00 , C08F4/70 , C08F4/80 , C08F10/00 , C07F15/02 , C07F15/06
CPC分类号： C07F15/0066 , C07F15/045
摘要： Complexes of the formula I where M═Ni, Pd; process for preparing the metal complexes and the use of the complexes obtainable in this way for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.

3. 发明授权

US08252875B2 Process for the preparation of unsymmetric bis(imino) compounds 有权
标题翻译：制备不对称双（亚氨基）化合物的方法
公开(公告)号：US08252875B2
公开(公告)日：2012-08-28
申请号：US12087554
申请日：2007-01-08
申请人： Shahram Mihan , Benno Bildstein , Lars Kölling , Alexander Solchinger , Sascha Schlawjinski
发明人： Shahram Mihan , Benno Bildstein , Lars Kölling , Alexander Solchinger , Sascha Schlawjinski
IPC分类号： C08F4/80 , C08F4/70 , C08F4/60 , C07F15/02 , B01J31/28
CPC分类号： C07F15/025 , B01J2531/0238 , B01J2531/842 , C07D213/44 , C07D213/53 , C08F10/00 , C08F110/02 , C08F2500/17 , C08F2500/04 , C08F4/7042
摘要： Process for the preparation of monoimine compounds, wherein a dicarbonyl compound is reacted in an aliphatic, non-aromatic solvent with aniline. Monoimine compounds having electron-withdrawing substituents in the ortho position and unsymmetric bis(imino) compounds and unsymmetric iron complexes prepared therefrom and the use thereof in the polymerization of olefins.
摘要翻译：制备单亚胺化合物的方法，其中二羰基化合物在脂族，非芳族溶剂中与苯胺反应。在邻位具有吸电子取代基的单亚胺化合物和由其制备的不对称双（亚氨基）化合物和不对称铁络合物及其在烯烃聚合中的用途。

4. 发明授权

US07776980B2 Monocyclopentadienyl complexes 有权
标题翻译：单环戊二烯基络合物
公开(公告)号：US07776980B2
公开(公告)日：2010-08-17
申请号：US11887039
申请日：2006-03-18
申请人： Shahram Mihan , Benno Bildstein , Georg Steiner
发明人： Shahram Mihan , Benno Bildstein , Georg Steiner
IPC分类号： C08F4/78 , C08F4/76 , B01J31/34 , B01J31/38 , C07F17/00
CPC分类号： C08F10/00 , C08F4/63912 , C08F4/6392 , C08F110/02 , C08F210/16 , C08F2420/01 , Y10S526/904 , Y10S526/941 , Y10S526/943 , C08F4/69 , C08F2500/01 , C08F2500/17 , C08F210/14
摘要： Monocyclopentadienyl complexes in which the cyclopentadienyl system bears at least one bridged keto, thioketo, imino or phosphino group, a catalyst system comprising at least one of the monocyclopentadienyl complexes and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.
摘要翻译：单环戊二烯基络合物，其中环戊二烯基体系具有至少一个桥连酮，硫酮酮，亚氨基或膦基，包含至少一种单环戊二烯基络合物的催化剂体系和通过烯烃在催化剂存在下的聚合或共聚制备聚烯烃的方法系统。

5. 发明授权

US06933400B2 Complex compounds and their use in olefin polymerization 失效
标题翻译：复合物及其在烯烃聚合中的应用
公开(公告)号：US06933400B2
公开(公告)日：2005-08-23
申请号：US10467931
申请日：2002-02-07
申请人： Marc Oliver Kristen , Benno Bildstein , Alexander Krajete
发明人： Marc Oliver Kristen , Benno Bildstein , Alexander Krajete
IPC分类号： C07C251/24 , C07F15/04 , C08F4/60 , C08F4/642 , C08F4/80 , C08F10/00 , B01J31/00 , C07F7/00 , C08F4/44
CPC分类号： C07F15/04 , C08F10/00 , C08F2410/03 , C08F4/7022 , C08F4/7004 , C08F4/7021
摘要： Complexes of the formulae I a to d, where M is an element of groups 6 to 10 of the Periodic Table of the Elements, preferably Ni, can be used for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes, bulk polymerization processes and emulsion polymerization processes.
摘要翻译：式I a至d的络合物，其中M是元素周期表第6至10族的元素，优选为Ni，可用于烯烃的聚合和共聚，例如在悬浮聚合方法中，相聚合方法，本体聚合方法和乳液聚合方法。

6. 发明授权

US06846771B2 Metal complexes of iminohydroxamic acids 失效
标题翻译：亚氨基肟酸的金属络合物
公开(公告)号：US06846771B2
公开(公告)日：2005-01-25
申请号：US10359263
申请日：2003-02-06
申请人： Marc Oliver Kristen , Peter Preishuber-Pflügl , Benno Bildstein , Alexander Krajete
发明人： Marc Oliver Kristen , Peter Preishuber-Pflügl , Benno Bildstein , Alexander Krajete
IPC分类号： C07C259/18 , C07F7/00 , C07F7/28 , C07F9/00 , C07F13/00 , C07F15/00 , C07F15/04 , C08F4/602 , C08F4/76 , C08F4/80 , C08F10/00 , C08F12/00 , B01J31/38 , C08F4/44
CPC分类号： C07F13/005 , C07F7/003 , C07F9/005 , C07F15/0066 , C07F15/045 , Y10S526/905
摘要： Complexes of the formulae Ia and Ib where M=Ti, Zr, Hf, V, Nb, Ta, Cr, Ni, Pd, can be used for the polymerization and copolymerization of olefins, for example in suspension polymerization processes, gas-phase polymerization processes and bulk polymerization processes.
摘要翻译：其中M = Ti，Zr，Hf，V，Nb，Ta，Cr，Ni，Pd的式Ia和Ib的络合物可用于烯烃的聚合和共聚，例如在悬浮聚合方法中，气相聚合方法和本体聚合方法。

7. 发明授权

US5945367A Metallocenes with silyl-substituted bridges and their use for olefin polymerization 失效
标题翻译：具有甲硅烷基取代桥的金属茂及其用于烯烃聚合的用途
公开(公告)号：US5945367A
公开(公告)日：1999-08-31
申请号：US981257
申请日：1997-12-22
申请人： Karl Heinz Thiele , Christine Schliessburg , Eberhard Ernst , Jens Reussner , Benno Bildstein , Peter Denifl
发明人： Karl Heinz Thiele , Christine Schliessburg , Eberhard Ernst , Jens Reussner , Benno Bildstein , Peter Denifl
IPC分类号： C07F17/00 , C08F4/619 , C08F4/6192 , C08F4/64 , C08F4/642 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16
CPC分类号： C07F17/00 , C08F10/00 , C08F110/02 , C08F110/06 , C08F210/16 , C08F4/61912 , C08F4/61927 , Y10S526/943
摘要： The invention pertains to metallocenes of formula (I), wherein M is a metal group of the group of Ti, Zr, Hf, V, Nb and Ta or an element from the group of lanthanides; X.sub.1 and X.sub.2 stand for an alkyl, alkoxy, aryl, aryloxy, alkenyl, arylalkyl, alkylaryl or arylalkenyl group, hydrogen or halogen; L.sub.1 and L.sub.2 stand for a hydrocarbon which can form a sandwich structure with M; R stands for C, Si, Ge or Sn; and A and B stand for a trimethylsilyl radical, B optionally for an alkyl or aryl radical. ##STR1##
摘要翻译： PCT No.PCT / EP96 / 02828 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1996年6月28日PCT公布。公开号WO97 / 02276 日本1997年1月23日本发明涉及式（I）的金属茂，其中M是Ti，Zr，Hf，V，Nb和Ta族的金属基团或来自镧系元素的元素; X1和X2代表烷基，烷氧基，芳基，芳氧基，烯基，芳基烷基，烷基芳基或芳基烯基，氢或卤素; L1和L2代表可以形成具有M的夹层结构的烃; R代表C，Si，Ge或Sn; A和B代表三甲基甲硅烷基，任选用于烷基或芳基。

8. 发明授权

US07589223B2 Polymerization catalysts, preparation of polyolefins, organotransition metal compounds and ligands 失效
标题翻译：聚合催化剂，聚烯烃的制备，有机过渡金属化合物和配体
公开(公告)号：US07589223B2
公开(公告)日：2009-09-15
申请号：US10573228
申请日：2004-09-16
申请人： Benno Bildstein , Alexander Krajete
发明人： Benno Bildstein , Alexander Krajete
IPC分类号： C07F15/00 , C07F13/00 , C07F11/00 , C07F9/00
CPC分类号： C07F15/045 , C08F10/00 , C08F110/02 , C08F4/7006
摘要： The invention relates to non-metallocene catalyst systems useful for preparing olefin homopolymers or copolymers. The catalyst systems comprise a cocatalyst and a Group 3-10 transition metal compound that incorporates a diimine ligand in which sp2-hybridized carbons of the imine groups are joined by a specific divalent one- or two-membered bridge (Y) comprising nitrogen and/or oxygen. The invention includes the diimine ligands, the transition metal compounds, the catalyst systems, and processes for making the ligands, transition metal compounds, catalyst systems, and olefin homopolymers or copolymers.
摘要翻译：本发明涉及用于制备烯烃均聚物或共聚物的非茂金属催化剂体系。催化剂体系包含助催化剂和3-10族过渡金属化合物，该化合物含有二亚胺配体，其中亚胺基团的sp2杂化的碳通过特定的二价一元或二元桥（Y）与氮和/ 或氧气。本发明包括二亚氨配体，过渡金属化合物，催化剂体系以及制备配体，过渡金属化合物，催化剂体系和烯烃均聚物或共聚物的方法。

9. 发明申请

US20090156768A1 Transition Metal Compound, Ligand System, Catalyst System and Process for Preparing Polyolefins 失效
公开(公告)号：US20090156768A1
公开(公告)日：2009-06-18
申请号：US12085611
申请日：2006-11-27
申请人： Shahram Mihan , Benno Bildstein , Alexander Solchinger , Lars Kölling
发明人： Shahram Mihan , Benno Bildstein , Alexander Solchinger , Lars Kölling
IPC分类号： B01J31/12 , C07F15/02 , C07F15/06 , C08F4/26
CPC分类号： C07F15/025 , C07D231/56 , C07D401/06 , C07D401/14 , C07F15/065 , C08F10/00 , C08F110/02 , C08F2500/17 , C08F2500/04 , C08F4/7042
摘要： The present invention relates to transition metal compounds of the formula (I); where M is an element of group 3, 4, 5, 6, 7, 8, 9 or 10 of the Periodic Table of the Elements or the lanthanide's, the radicals X are identical or different and are each an organic or inorganic radical, with two radicals X also being able to be joined to one another to form a divalent radical, is 1, 2, 3 or 4, L1 is an organic or inorganic uncharged ligand, is an integer from 0 to 4, R1 is an organic radical having from 1 to 40 carbon atoms, R2 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R1 and R2 together form a divalent organic group T1 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more further heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R3 is hydrogen or an organic radical having from 1 to 40 carbon atoms, R4 is hydrogen or an organic radical having from 1 to 40 carbon atoms, or R3 and R4 together form a divalent organic group T2 which has from 2 to 40 carbon atoms and together with the atoms connecting its ends forms a monocyclic or polycyclic ring system which may in turn be substituted and may comprise one or more heteroatoms selected from the group consisting of the elements O, S, Se, Te, N, P and As in the ring system, R5 is an uncharged or negatively charged organic radical which has from 1 to 40 carbon atoms and may comprise a heteroatom selected from the group consisting of the elements N, O, P, S, As and Sb, and m is an integer from 1 to 10, ligand systems having such a substitution pattern, ligand systems comprising at least one of the transition metal compounds according to the invention, a process for preparing polyolefins by polymerization or copolymerization of at least one olefin in the presence of at least one of the catalyst systems according to the invention and the use of the ligand systems according to the invention for preparing transition metal compounds.

10. 发明申请

US20090018292A1 Monocyclopentadienyl Complexes 有权
标题翻译：单环戊二烯基络合物
公开(公告)号：US20090018292A1
公开(公告)日：2009-01-15
申请号：US11887039
申请日：2006-03-18
申请人： Shahram Mihan , Benno Bildstein , Georg Steiner
发明人： Shahram Mihan , Benno Bildstein , Georg Steiner
IPC分类号： C08F4/78 , C07F11/00
CPC分类号： C08F10/00 , C08F4/63912 , C08F4/6392 , C08F110/02 , C08F210/16 , C08F2420/01 , Y10S526/904 , Y10S526/941 , Y10S526/943 , C08F4/69 , C08F2500/01 , C08F2500/17 , C08F210/14
摘要： Monocyclopentadienyl complexes in which the cyclopentadienyl system bears at least one bridged keto, thioketo, imino or phosphino group, a catalyst system comprising at least one of the monocyclopentadienyl complexes and a process for preparing polyolefins by polymerization or copolymerization of olefins in the presence of the catalyst system.
摘要翻译：单环戊二烯基络合物，其中环戊二烯基体系具有至少一个桥连酮，硫酮酮，亚氨基或膦基，包含至少一种单环戊二烯基络合物的催化剂体系和通过烯烃在催化剂存在下的聚合或共聚制备聚烯烃的方法系统。

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