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1. 发明授权

US06828381B1 Sol-gel coating 失效
标题翻译：溶胶 - 凝胶涂层
公开(公告)号：US06828381B1
公开(公告)日：2004-12-07
申请号：US10049532
申请日：2002-02-12
申请人： Manuela Armbrust , Wolfgang Bremser , Horst Hintze-Brüning , Wilfried Stübbe , Peter Betz , Christel Ehlig
发明人： Manuela Armbrust , Wolfgang Bremser , Horst Hintze-Brüning , Wilfried Stübbe , Peter Betz , Christel Ehlig
IPC分类号： C08L8306
CPC分类号： C09D133/066 , C08L83/04 , C08L85/00 , C09D183/04 , C09D183/14 , Y10T428/31663 , C08L2666/14 , C08L2666/02
摘要： A sol-gel coating material, containing (A) an acrylate copolymer solution, consisting of at least one acrylate copolymer; (B) a parent lacquer which can be produced by the hydrolysis and condensation of at least one hydrolysable silane of the formula (I): SiR4; wherein: R=hydrolysable groups, hydroxy groups and non-hydrolysable groups, with the proviso that there should be at least one hydrolysable group; and (C) a sol which can be produced by the hydrolysis, condensation and complexing of (C1) at least one hydrolysable metal compound of the (II): MRn; wherein: M=aluminium, titanium or zirconium, R=the aforementioned given groups and n=3 or 4; of (C2) at least one organic thio compound of the formula (III): S(R1X)2, wherein R1 represents a two-bond organic radical and X represents hydroxyl, thiol and/or primary and/or secondary amino groups; and of (C3) a hydrolysable silane of the general formula (I).
摘要翻译：一种溶胶凝胶涂层材料，其包含（A）丙烯酸酯共聚物溶液，由至少一种丙烯酸酯共聚物组成; （B）可以通过至少一种式（I）的可水解硅烷：SiR 4的水解和缩合产生的母漆; 其中：R =可水解基团，羟基和不可水解基团，条件是应存在至少一个可水解基团; 和（C）可以通过（C1）至少一种（II）的可水解金属化合物：MRn的水解，缩合和络合来制备的溶胶; 其中：M =铝，钛或锆，R =上述给定的基团，n = 3或4; 的（C2）至少一种式（III）的有机硫代化合物：S（R 1 X）2，其中R 1表示双键有机基团，X表示羟基，硫醇和/或伯和 /或仲氨基; 和（C3）通式（I）的可水解硅烷。

2. 发明授权

US06713559B1 Sol-gel coating 失效
标题翻译：溶胶 - 凝胶涂层
公开(公告)号：US06713559B1
公开(公告)日：2004-03-30
申请号：US10069188
申请日：2002-02-21
申请人： Manuela Armbrust , Horst Hintze-Brüning , Wilfried Stübbe , Peter Betz , Christel Ehlig
发明人： Manuela Armbrust , Horst Hintze-Brüning , Wilfried Stübbe , Peter Betz , Christel Ehlig
IPC分类号： C08L8306
CPC分类号： C09D133/064 , C08L83/04 , Y10T428/31663 , C08L2666/14
摘要： The invention relates to a sol-gel coating material, containing (A) an acrylate copolymer solution, consisting of at least one acrylate copolymer (A1), (B) a sol which can be produced by the hydrolysis, condensation and complexing of at least one hydrolysable metal compound (B1) of the dormula (1): MRn; wherein the variable and the index have the following meanings: M=aluminium, titanium or zirconium; R=hydrolysable group, hydroxy groups and non-hydrolysable groups, with the proviso that there should be at least one, preferable two hydrolysable groups; and n=3 or 4; by the hydrolysis, condensation and complexing of at least one hydrolysable silane (B2) of the formula (II): Si(R1)2(R2)2; wherein the varible R1 and R2 have the following meanings: R1=alkyl and/or cycloalkyl radicals and R2=alkoxy and/or cycloakoxy radicals; and by the hydrolysis, condensation and complexing of at least one hydrollysable silane (B3) of the formula (III): SiR4; wherein the variable R has the aforementioned given meaning: with the proviso that the silane (B3) is not a silane (B2) according to the general formula (II); and (C) between 0 and 40% by weight in relation to the total quantity of the coating material, of a parent lacquer which can be produced by the hydrolysis and condensation of least one hydrolysable silane (B3) of general formula (III).
摘要翻译：本发明涉及一种溶胶 - 凝胶涂层材料，其包含（A）丙烯酸酯共聚物溶液，其由至少一种丙烯酸酯共聚物（A1），（B）可通过至少水解，缩合和络合制备的溶胶多层（1）的一种可水解金属化合物（B1）：MRn; 其中所述变量和所述指数具有以下含义：M =铝，钛或锆; R =可水解基团，羟基和不可水解基团，条件是应至少有一个，优选两个可水解基团; n = 3或4; 通过式（II）的至少一种可水解硅烷（B2）的水解，缩合和络合：Si（R 1）2（R 2）2; 其中可变R 1和R 2具有以下含义：R 1 =烷基和/或环烷基，R 2 =烷氧基和/或环烷氧基; 并且通过式（III）的至少一种可水解硅烷（B3）的水解，缩合和络合：SiR 4; 其中所述变量R具有上述给定含义：条件是硅烷（B3）不是根据通式（II）的硅烷（B2）; 和（C）相对于涂料总量的0-40重量％，可以通过水解和缩合通式（III）的至少一个可水解硅烷（B3）制备的母漆。

3. 发明授权

US06872765B1 Sol-gel coating for single-layer or multi-layer varnishes 失效
标题翻译：单层或多层清漆的溶胶 - 凝胶涂层
公开(公告)号：US06872765B1
公开(公告)日：2005-03-29
申请号：US09914937
申请日：2000-03-06
申请人： Peter Betz , Horst Hintze-Brüning , Wilfried Stübbe , Heinz-Peter Rink
发明人： Peter Betz , Horst Hintze-Brüning , Wilfried Stübbe , Heinz-Peter Rink
IPC分类号： B05D7/00 , C08L83/14 , C09D133/06 , C09D183/04 , C09D183/14 , C08K5/24
CPC分类号： B05D7/536 , B05D7/576 , C08L83/14 , C09D133/066 , C09D183/04 , C09D183/14 , C08L2666/04 , C08L2666/28
摘要： The invention relates to a sol-gel coating material containing (A) an acrylate copolymer solution containing at least one acrylate copolymer (A1); (B) a parent varnish which can be prepared by hydrolysis and condensation of at least one hydrolysable silane (B1) of the general formula (I) SiR4, in which the variable R=hydrolysable groups, hydroxy groups and non-hydrolysable groups, provided that there should be at least one, preferably two, hydrolysable groups; and (C) an additive solution containing c1) at least one ethylenically unsaturated compound containing at least one epoxide group; c2) at least one silane (B1) with at least one non-hydrolysable group R presenting at least one epoxide group; and c3) at least one adduct of at least one silane (B1) with at least one non-hydrolysable group R presenting at least one amino group and at least one cyclic ethylenically unsaturated dicarboxylic acid anhydride. The invention also relates to the use of said sol-gel coating material for producing scratchproof sol-gel coatings.
摘要翻译：本发明涉及含有（A）含有至少一种丙烯酸酯共聚物（A1）的丙烯酸酯共聚物溶液的溶胶 - 凝胶涂料; （B）可以通过水解和缩合通式（I）SiR 4的至少一种可水解硅烷（B1）制备的母体清漆，其中可变的R =可水解基团，羟基和不可水解的基团提供应该有至少一个，优选两个可水解基团; 和（C）含有c1）至少一种含有至少一个环氧基团的烯属不饱和化合物的添加剂溶液; c2）至少一种具有至少一个具有至少一个环氧基团的不可水解基团R的硅烷（B1）; 和c3）至少一种至少一种硅烷（B1）与至少一种具有至少一个氨基的至少一种不可水解基团R和至少一种环状烯键式不饱和二羧酸酐的加合物。本发明还涉及所述溶胶 - 凝胶涂层材料用于制备防刮溶胶 - 凝胶涂层的用途。

4. 发明授权

US06818303B2 Powder clearcoat dispersions (powder slurry clearcoats), method for producing them and the use thereof 失效
标题翻译：粉末透明涂料分散体（粉末浆料清漆），其制造方法及其用途
公开(公告)号：US06818303B2
公开(公告)日：2004-11-16
申请号：US10296029
申请日：2002-11-19
申请人： Walter Lassmann , Horst Hintze-Brüning , Wolfgang Bremser , Ulrike Röckrath
发明人： Walter Lassmann , Horst Hintze-Brüning , Wolfgang Bremser , Ulrike Röckrath
IPC分类号： B32B2718
CPC分类号： B05D7/572 , B05D7/577 , C09D5/02 , C09D7/47 , Y10S524/904 , Y10T428/31504
摘要： Powder clearcoat dispersions (powder slurry clearcoats) preparable by dispersing a powder clearcoat in an aqueous medium and wet milling the resulting powder slurry, at least one adduct of ethylene oxide and/or propylene oxide with at least one glycol being added to the powder slurry prior to wet milling; and the use of the powder slurry clearcoats for producing clearcoat finishes, especially as part of multicoat color and/or effect finishes.
摘要翻译：通过将粉末透明涂料分散在水性介质中并湿法研磨所得粉末浆料，将至少一种环氧乙烷和/或环氧丙烷的加合物与至少一种二醇加入到粉末浆料中，可制备粉末透明涂料分散体（粉末浆料透明涂层）湿磨; 以及使用粉末浆料清漆来生产透明涂层，特别是作为多色彩和/或效果整理的一部分。

5. 发明授权

US06706333B2 Aqueous coating substances for imparting a color and/or effect and use thereof for producing deformable laminates for imparting a color and/or effect 失效
标题翻译：用于赋予颜色和/或效果的水性涂料物质和用于制造用于赋予颜色和/或效果的可变形层压材料的用途
公开(公告)号：US06706333B2
公开(公告)日：2004-03-16
申请号：US10276030
申请日：2002-12-16
申请人： Wolfgang Bremser , Horst Hintze-Brüning , Walter Lassmann
发明人： Wolfgang Bremser , Horst Hintze-Brüning , Walter Lassmann
IPC分类号： B05D302
CPC分类号： C08F265/06 , C08F212/32 , C09D151/003
摘要： The use of a copolymer (A) preparable by free-radical polymerization of a) at least one olefinically unsaturated monomer, and b) at least one olefinically unsaturated monomer different than the olefinically unsaturated monomer (a), of the general formula I R1R2C═CR3R4 (I) in which the radicals R1, R2, R3 and R4 each independently of one another are hydrogen atoms or substituted or unsubstituted alkyl, cycloalkyl, alkylcycloalkyl, cycloalkylalkyl, aryl, alkylaryl, cycloalkylaryl, arylalkyl or arylcycloalkyl radicals, with the proviso that at least two of the variables R1, R2, R3 and R4 are substituted or unsubstituted aryl, arylalkyl or arylcycloalkyl radicals, especially substituted or unsubstituted aryl radicals; in an aqueous medium; to produce deformable color and/or effect laminates and dry-paint films.
摘要翻译：使用通过自由基聚合制备的共聚物（A）至少一种烯属不饱和单体，和b）至少一种不同于烯属不饱和单体（a）的烯属不饱和单体，通式Ⅰin的基团R R 1，R 3和R 4各自独立地为氢原子或取代或未取代的烷基，环烷基，烷基环烷基，环烷基烷基，芳基，烷基芳基，环烷基芳基，芳基烷基或芳基环烷基，与条件是至少两个变量R 1，R 2，R 3和R 4是取代或未取代的芳基，芳基烷基或芳基环烷基，特别是取代或未取代的芳基;在水性介质中 ; 以产生可变形的颜色和/或效果层压板和干漆膜。

6. 发明申请

US20120135246A1 WATERBORNE EFFECT BASE COATS HAVING IMPROVED OPTICAL PROPERTIES 有权
标题翻译：具有改进的光学性能的水波效应基层
公开(公告)号：US20120135246A1
公开(公告)日：2012-05-31
申请号：US13320403
申请日：2010-02-25
申请人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier-Thuilliez , Thomas Stimpfling
发明人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier-Thuilliez , Thomas Stimpfling
IPC分类号： B32B27/20 , C08K5/42
CPC分类号： C09K19/52 , C08K3/013 , C08K3/22 , C08L75/04 , C09D5/36 , C09D7/61 , C09D167/06 , C09K19/542 , Y10T428/31609 , C08L2666/20
摘要： Disclosed is an aqueous effect basecoat material comprising at least one liquid-crystalline aqueous preparation (WZ) in fractions of 1% to 99% by weight, based on the aqueous basecoat material, at least one film-forming polymer (FP), and at least one effect pigment (EP).
摘要翻译：公开了一种含水效果底漆材料，其包含至少一种基于水性底漆材料，至少一种成膜聚合物（FP）和1重量％成膜聚合物（FP）的1％至99重量％的液晶水性制剂（WZ）至少一种效果颜料（EP）。

7. 发明授权

US07985478B2 Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor 有权
标题翻译：用于制造模制零件的方法，特别是用于汽车工业的模制件，以及包括适合于其的涂层的薄膜
公开(公告)号：US07985478B2
公开(公告)日：2011-07-26
申请号：US11718457
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B32B27/08 , B29C51/08
CPC分类号： C09D175/16 , B29C37/0032 , C08G18/672 , Y10T428/31547
摘要： A process for producing moldings, in which a solventborne or aqueous, pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free- radically crosslinkable component (KK) which comprises carbamate and/or biuret and/or allophanate and/or urea and/or amide groups.
摘要翻译：一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的溶剂型或水性着色涂料组合物（P）和可自由基交联的涂料组合物（K）施加到载体片材上，从涂料组合物（K）制备干燥但尚未完全交联的涂层（KT），涂覆的支撑片被成形并用液体聚合材料注射回模制或泡沫背衬，并且涂层（KT）这还没有发生 - 固化或后固化; 包含可自由基交联的组分（KK）的可交联涂料组合物（K），其包含氨基甲酸酯和/或缩二脲和/或脲基甲酸酯和/或脲和/或酰胺基团。

8. 发明申请

US20100323114A1 COATING AGENTS BASED ON INCOMPATIBLE POLYMERS AND ELECTRICALLY CHARGED PARTICLES 审中-公开
标题翻译：基于不溶性聚合物和电荷充填颗粒的涂料
公开(公告)号：US20100323114A1
公开(公告)日：2010-12-23
申请号：US12742800
申请日：2008-11-06
申请人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier
发明人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier
IPC分类号： B05D1/36 , C09D201/00
CPC分类号： C09D5/028 , C08G18/0823 , C08G18/4288 , C08G18/6659 , C08G18/706 , C08G18/758 , C08G18/8077 , C08G2150/90 , C08K3/22 , C08L75/04 , C09D7/61 , C09D7/67 , C09D7/68 , C09D167/00 , C08L2666/20
摘要： Coating materials that comprise at least one polymer (P1), at least one polymer (P2) which is incompatible with polymer (P1) in the solid phase and/or a crosslinking agent (V) which is incompatible with the polymer (P1) in the solid phase, where the polymers (P1) and/or (P2) have at least one functional group (a) which reacts in the course of curing of the coating material to form covalent bonds, wherein the coating material comprises 0.1 to 30% by weight, based on the nonvolatile constituents of the coating material, of electrically charged inorganic particles (AT) whose average particle diameter (D) is 50. Also disclosed is a method for producing antistonechip OEM coat systems using the disclosed coating material.
摘要翻译：包含至少一种聚合物（P1），至少一种与固相中的聚合物（P1）不相容的聚合物（P2）和/或与聚合物（P1）不相容的交联剂（V）的涂料固相，其中聚合物（P1）和/或（P2）具有至少一个在涂料固化过程中反应形成共价键的官能团（a），其中涂料含有0.1-30％基于涂料的不挥发成分，平均粒径（D）小于1μm并且平均粒径（D）与平均粒径（D）的平均D / d比的平均粒径（D）的带电无机颗粒（AT）颗粒厚度（d）> 50。还公开了使用所公开的涂层材料制造抗静电芯片OEM涂层系统的方法。

9. 发明授权

US09492843B2 Method for the production of high-impact layers 有权
标题翻译：生产高冲击层的方法
公开(公告)号：US09492843B2
公开(公告)日：2016-11-15
申请号：US12742798
申请日：2008-11-06
申请人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier
发明人： Horst Hintze-Brüning , Hans-Peter Steiner , Fabrice Leroux , Anne-Lise Troutier
IPC分类号： B05D5/00 , B05D7/14 , B05D7/00 , C09D167/00 , C09D175/04
CPC分类号： B05D5/00 , B05D7/14 , B05D7/577 , B05D2202/10 , B05D2601/20 , C09D167/00 , C09D175/04 , C08L2666/54
摘要： The invention relates to a method of increasing the stonechip resistance of OEM coat systems composed of an anticorrosion coat, a surfacer coat, and a concluding topcoat, in which 0.1% to 30% by weight, based on the nonvolatile fractions of the coating material, of electrically charged inorganic particles AT whose ratio D/d, the ratio of the average particle diameter (D) to the average particle thickness (d), is >50 and whose charge is at least partly compensated by singly charged organic counterions OG, are incorporated into the coating material that is used to produce at least one of said coats and that comprises at least one polymer P, and the coating material is applied and, lastly, is cured.
摘要翻译：本发明涉及一种增加由防腐涂层，表面涂层和最终面漆组成的OEM涂层系统的石芯片电阻的方法，其中基于涂层材料的不挥发成分为0.1〜30重量％的电荷无机粒子AT的平均粒径（D）与平均粒子厚度（d）的比值D / d> 50并且其电荷至少部分地通过单电荷的有机抗衡离子OG补偿为止掺入到用于生产至少一种所述涂层并且包含至少一种聚合物P的涂料中，涂覆涂料，最后固化。

10. 发明授权

US07625630B2 Color and/or effect coating system comprising a combination effect coat 失效
标题翻译：包含组合效果涂层的彩色和/或效果涂层系统
公开(公告)号：US07625630B2
公开(公告)日：2009-12-01
申请号：US10257075
申请日：2001-03-15
申请人： Walter Lassmann , Klaus-Dieter Stegemann , Horst Hintze-Brüning , Joachim Woltering , Wolfgang Reckordt
发明人： Walter Lassmann , Klaus-Dieter Stegemann , Horst Hintze-Brüning , Joachim Woltering , Wolfgang Reckordt
IPC分类号： B32B5/16 , B32B27/32 , B05D3/02
CPC分类号： B05D7/57 , C09D5/02 , Y10S428/936 , Y10T428/25 , Y10T428/26
摘要： Disclosed is a combination effect coat that simultaneously provides at least one function selected from the group consisting of color, effect, or the combination thereof as well as at least one function selected from the group consisting of corrosion protection, adhesion promotion, absorption of mechanical energy, or the combination of two or more of the foregoing. The combination effect coat is produced by the application and curing of a pigmented powder slurry wherein the pigmented powder slurry is curable thermally, or curable thermally and with actinic radiation. The pigmented powder slurry consists of finely divided dimensionally stable constituents having an average particle size of from 0.8 to 40 μm, has a residual volatile solvent content of less than 1% by weight, and comprises a (meth)acrylate copolymer having an epoxide equivalent weight of 400 to 2500; and a color pigment, an effect pigment, or a combination thereof.
摘要翻译：公开了一种组合效应涂层，其同时提供从由颜色，效果或其组合组成的组中选择的至少一种功能以及至少一种选自腐蚀保护，粘附促进，吸收机械能的功能，或上述两种或更多种的组合。组合效果涂层是通过施加和固化着色的粉末浆料来生产的，其中着色的粉末浆料是可热固化的或可热固化的和光化辐射的固化。着色的粉末浆料由平均粒度为0.8至40μm的细碎的尺寸稳定的组分组成，其挥发性溶剂的残留物含量小于1重量％，并且包含具有环氧当量的（甲基）丙烯酸酯共聚物 400至2500; 和彩色颜料，效果颜料或其组合。

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