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1. 发明授权

US07985478B2 Method for producing moulded parts, in particular for use in the car industry, and a film comprising a coating which is suitable therefor 有权
标题翻译：用于制造模制零件的方法，特别是用于汽车工业的模制件，以及包括适合于其的涂层的薄膜
公开(公告)号：US07985478B2
公开(公告)日：2011-07-26
申请号：US11718457
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Brüning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B32B27/08 , B29C51/08
CPC分类号： C09D175/16 , B29C37/0032 , C08G18/672 , Y10T428/31547
摘要： A process for producing moldings, in which a solventborne or aqueous, pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet, a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free- radically crosslinkable component (KK) which comprises carbamate and/or biuret and/or allophanate and/or urea and/or amide groups.
摘要翻译：一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的溶剂型或水性着色涂料组合物（P）和可自由基交联的涂料组合物（K）施加到载体片材上，从涂料组合物（K）制备干燥但尚未完全交联的涂层（KT），涂覆的支撑片被成形并用液体聚合材料注射回模制或泡沫背衬，并且涂层（KT）这还没有发生 - 固化或后固化; 包含可自由基交联的组分（KK）的可交联涂料组合物（K），其包含氨基甲酸酯和/或缩二脲和/或脲基甲酸酯和/或脲和/或酰胺基团。

2. 发明申请

US20090061215A1 METHOD FOR PRODUCING MOLDED PARTS, ESPECIALLY FOR USE IN AUTOMOBILE MANUFACTURE, AND CORRESPONDING APPROPRIATE FILMS COMPRISING A COATING 有权
标题翻译：生产模具的方法，特别适用于汽车制造，以及对应包装涂料的适当膜
公开(公告)号：US20090061215A1
公开(公告)日：2009-03-05
申请号：US11718566
申请日：2005-10-17
申请人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
发明人： Hubert Baumgart , Horst Hintze-Bruning , Fatmir Raka , Gabriele Dlugosch , Frank Dietsche , Nick Gruber , Erich Beck , Reinhold Schwalm , Klaus Menzel , Yvonne Heischkel , Berthold Austrup
IPC分类号： B32B27/40
CPC分类号： B29C37/0032 , B29C2037/0042 , C08G18/3212 , C08G18/672 , C08G18/722 , C09D175/16 , Y10T428/265
摘要： A process for producing moldings, in which a pigmented coating composition (P) and a free-radically crosslinkable coating composition (K), which after crosslinking to completion produces a transparent coating (KE) are applied to a support sheet a dried but as yet not completely crosslinked coating (KT) is produced from the coating composition (K), the coated support sheet is shaped and is injection backmolded or foam-backed with a liquid polymeric material, and the coating (KT)—if this has not already taken place—is cured or aftercured; the crosslinkable coating composition (K) comprising a free-radically crosslinkable component (KK) which contains hydrogen bond forming structural elements in an amount such that 1. a coating (MT) produced from the mixture (M) of component (KK) with additives, but as yet not crosslinked to completion, has a ratio of storage modulus G(MT)′ to loss modulus G(MT)″ of from 5 to 200, G(MT)′ and G(MT)″ having been determined at 20° C. by means of rheological oscillation measurements, and 2. a coating (ME) produced from the mixture (M) of component (KK) with additives and crosslinked to completion has a storage modulus E(ME)″ of from 1.0*107.0 to 8.0*107.0 Pa, E(ME)′ having been measured in the rubber-elastic range by dynamic mechanical thermal analysis.
摘要翻译：一种制造模制品的方法，其中在交联完成后产生透明涂层（KE）的着色涂料组合物（P）和可自由交联的涂料组合物（K）被施加到干燥但仍然由涂料组合物（K）制备未完全交联的涂料（KT），涂覆的支撑片材成型并用液体聚合物材料注射回模塑或泡沫背衬，并且涂层（KT） - 如果尚未采用地方治愈或后固化; 所述可交联涂料组合物（K）包含可自由基交联的组分（KK），其含有形成氢键的结构元素，其量使得1.由组分（KK）的混合物（M）与添加剂，但尚未交联完成，具有5至200，G（MT）'和G（MT）“的储能模量G（MT）'与损耗模量G（MT）”的比率已被确定在20℃下，通过流变振动测量，和2.由组分（KK）与添加剂的混合物（M）产生并交联至完成的涂层（ME）具有的储能模量E（ME）通过动态机械热分析在橡胶弹性范围内测量的1.0 * 107.0至8.0 * 107.0 Pa，E（ME）'。

3. 发明申请

US20090011189A1 REFINISH SHEETS AND THEIR USE 有权
标题翻译：精品及其使用
公开(公告)号：US20090011189A1
公开(公告)日：2009-01-08
申请号：US12092411
申请日：2006-11-09
申请人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
发明人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
IPC分类号： B32B38/10 , B32B5/00 , B32B27/32 , B32B9/00 , B32B27/36 , B32B27/40 , B32B33/00 , B32B5/16
CPC分类号： B05D1/286 , B05D5/005 , Y10T428/24355 , Y10T428/25 , Y10T428/28 , Y10T428/2848 , Y10T428/31507 , Y10T428/31511 , Y10T428/31551 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： Disclosed herein is a refinish sheet produced by (1) coating one side of a temporary carrier sheet (A) with at least one aqueous coating material (B) comprising at least one free-radically crosslinkable binder (B1) having a glass transition temperature of −70 to +50° C., an olefinically unsaturated double bond content of 2 to 10 eq/kg, and an acid group content of 0.05 to 15 eq/kg to produce at least one resultant layer (B); and (2) drying but not curing, or only part-curing, the at least one resultant layer (B) to produce at least one dried, uncured or part-cured layer (B). Also disclosed is a method of repairing a surface of a coated substrate using the refinish sheet.
摘要翻译：本文公开了一种修补片，其通过（1）用至少一种水性涂料（B）涂覆临时载体片（A）的一侧而制备的，所述水性涂料包含至少一种可自由基交联的粘合剂（B1），所述粘合剂的玻璃化转变温度为 -70〜+ 50℃，烯属不饱和双键含量为2〜10eq / kg，酸基含量为0.05〜15eq / kg，生成至少一个所得层（B）。和（2）干燥但不固化或仅部分固化所述至少一个所得层（B）以产生至少一个干燥，未固化或部分固化的层（B）。还公开了使用修补片来修复涂布的基材的表面的方法。

4. 发明申请

US20080255308A1 Powder Slurries Which can be Thermally Hardened with Actinic Radiation and Method for the Production and Use Thereof 审中-公开
标题翻译：可以用光化辐射热固化的粉末浆料及其生产和使用方法
公开(公告)号：US20080255308A1
公开(公告)日：2008-10-16
申请号：US10595209
申请日：2004-10-12
申请人： Berthold Austrup , Hubert Baumgart , Guido Wilke
发明人： Berthold Austrup , Hubert Baumgart , Guido Wilke
IPC分类号： C08L75/04
CPC分类号： C09D175/16 , C08G18/6229 , C08G18/6254 , C08G18/671 , C08G18/807 , C08G18/8096 , C08G18/8116 , C08G18/8175 , C08G18/62
摘要： Powder slurries curable thermally and with actinic radiation and comprising solid and/or highly viscous particles dimensionally stable under storage and application conditions, including at least one binder free of carbon-carbon double bonds activatable with actinic radiation, comprising at least one (meth)acrylate copolymer containing on average per molecule at least one isocyanate-reactive functional group and at least one ion-forming group; at least one blocked and/or part-blocked polyisocyanate; and at least one olefinically unsaturated constituent which is free of isocyanate-reactive functional groups and contains on average per molecule at least one isocyanate group blocked with pyrazole or with at least one substituted pyrazole and at least two carbon-carbon double bonds which can be activated with actinic radiation, prepared by reacting at least one polyisocyanate with pyrazole and/or with at least one substituted pyrazole and also with at least one compound containing an isocyanate-reactive functional group and at least two carbon-carbon double bonds activatable with actinic radiation, processes for preparing them, and their use.
摘要翻译：粉末浆料可热固化并具有光化辐射，并且在储存和使用条件下包括固体和/或高粘度颗粒尺寸稳定，包括至少一种不含可活化光化辐射的碳 - 碳双键的粘合剂，其包含至少一种（甲基）丙烯酸酯每个分子平均含有至少一个异氰酸酯反应性官能团和至少一个离子形成基团的共聚物; 至少一种封端和/或部分封端的多异氰酸酯; 和至少一种不含异氰酸酯反应性官能团的烯属不饱和组分，平均每分子含有至少一个被吡唑或至少一个取代的吡唑封端的异氰酸酯基团和至少两个可被活化的碳 - 碳双键通过使至少一种多异氰酸酯与吡唑和/或与至少一种取代的吡唑反应制备，并且还含有至少一种含有异氰酸酯反应性官能团的化合物和至少两种可用光化辐射活化的碳 - 碳双键，制备它们的过程及其用途。

5. 发明授权

US09371469B2 Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof 有权
标题翻译：涂层剂组合物，由其制成并具有高抗擦伤性和良好抛光性的涂层及其用途
公开(公告)号：US09371469B2
公开(公告)日：2016-06-21
申请号：US14124972
申请日：2012-05-23
申请人： Matthijs Groenewolt , Guenter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
发明人： Matthijs Groenewolt , Guenter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
IPC分类号： C09D183/08 , B05D1/38 , B05D1/36 , C09D175/04 , B05D7/00 , C08G18/62 , C08G18/79 , C08G18/28 , C08K5/521
CPC分类号： C09D175/04 , B05D7/53 , B05D7/56 , C08G18/289 , C08G18/6229 , C08G18/791 , C08K5/521 , Y10T428/31551
摘要： Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR″x(OR′)3-x) (I), structural unit (II) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structural units (II).
摘要翻译：包含（B1）至少一种具有游离或封闭的异氰酸酯基团的含异氰酸酯基的化合物（B1）和脂环族多异氰酸酯母体结构的组合物和/或由其衍生的多异氰酸酯和（B2）至少一种含有多异氰酸酯基团具有游离或封闭的异氰酸酯基团的化合物（B2）和非环状脂族多异氰酸酯母体结构和/或由其衍生的多异氰酸酯，其中组分（B1）和组分（B2）中的至少一种包含至少一种选自结构单元（I）-NR-（X-SiR“x（OR'）3-x）（I），结构单元（II）-N（X-SiR”x（OR'）3-x）n （X'-SiR“y（OR'）3-y）m（II）以及上述两种或更多种的混合物，其中化合物（B1）的量使得化合物（B1 ）为5〜45重量％，基于化合物（B1）和化合物（B2）的粘合剂组分和组分（B1 ）和（B2）包括结构单元（I）和结构单元（II）。

6. 发明授权

US08337649B2 Repair film and use thereof 有权
标题翻译：修复胶片及其使用
公开(公告)号：US08337649B2
公开(公告)日：2012-12-25
申请号：US12092411
申请日：2006-11-09
申请人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
发明人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
IPC分类号： B32B38/10 , B32B5/00 , B32B27/32 , B32B9/00 , B32B27/36 , B32B27/40 , B32B33/00 , B32B5/16
CPC分类号： B05D1/286 , B05D5/005 , Y10T428/24355 , Y10T428/25 , Y10T428/28 , Y10T428/2848 , Y10T428/31507 , Y10T428/31511 , Y10T428/31551 , Y10T428/31931 , Y10T428/31935 , Y10T428/31938
摘要： Disclosed herein is a refinish sheet produced by (1) coating one side of a temporary carrier sheet (A) with at least one aqueous coating material (B) comprising at least one free-radically crosslinkable binder (B1) having a glass transition temperature of −70 to +50° C., an olefinically unsaturated double bond content of 2 to 10 eq/kg, and an acid group content of 0.05 to 15 eq/kg to produce at least one resultant layer (B); and (2) drying but not curing, or only part-curing, the at least one resultant layer (B) to produce at least one dried, uncured or part-cured layer (B). Also disclosed is a method of repairing a surface of a coated substrate using the refinish sheet.
摘要翻译：本文公开了一种修补片，其通过（1）用至少一种水性涂料（B）涂覆临时载体片（A）的一侧而制备的，所述水性涂料包含至少一种可自由基交联的粘合剂（B1），所述粘合剂的玻璃化转变温度为 -70〜+ 50℃，烯属不饱和双键含量为2〜10eq / kg，酸基含量为0.05〜15eq / kg，生成至少一个所得层（B）。和（2）干燥但不固化或仅部分固化所述至少一个所得层（B）以产生至少一个干燥，未固化或部分固化的层（B）。还公开了使用修补片来修复涂布的基材的表面的方法。

7. 发明申请

US20090324843A1 PROCESS FOR PRODUCING MULTICOAT COLOR AND/OR EFFECT PAINT SYSTEMS 审中-公开
标题翻译：生产多色彩和/或影响油漆系统的方法
公开(公告)号：US20090324843A1
公开(公告)日：2009-12-31
申请号：US12305230
申请日：2007-06-29
申请人： Egon Wegner , Berthold Austrup , Hubert Baumgart , Michael Richert
发明人： Egon Wegner , Berthold Austrup , Hubert Baumgart , Michael Richert
IPC分类号： C08J7/18 , B05D3/02
CPC分类号： B05D7/534 , B05D3/0254 , B05D7/14 , B05D2202/10 , C08F290/067 , C08G18/0823 , C08G18/4263 , C09D5/02 , C09D5/03 , C09D5/36 , C09D175/04
摘要： Process for producing multicoat color and/or effect paint systems comprising a color and/or effect basecoat (A) and a transparent topcoat (B) by a wet-on-wet method using a color and/or effect coating material (A) and a transparent coating material (B), the coating material (A) being prepared by separately preparing an aqueous, structurally viscous powder dispersion (A1), in an amount, based on (A), of 50% to 100% by weight, mixing it with the other constituents (A2) of the coating material (A), and homogenizing the resulting mixtures (A).
摘要翻译：通过使用彩色和/或效果涂层材料（A）的湿式湿式方法制备包含颜色和/或效果底漆（A）和透明面漆（B）的多色彩色和/或效果漆系统的方法和透明涂料（B），涂料（A）通过分别制备基于（A）的50重量％至100重量％的量的水性结构粘性粉末分散体（A1），混合它与涂料（A）的其它组分（A2）一起，并均化所得的混合物（A）。

8. 发明申请

US20090298997A1 AQUEOUS POWDER DISPERSION, WHICH CAN BE CURED BY RADICAL POLYMERIZATION, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE 审中-公开
标题翻译：水性粉末分散体，可以通过放射性聚合固化，其生产方法及其使用方法
公开(公告)号：US20090298997A1
公开(公告)日：2009-12-03
申请号：US12097120
申请日：2006-11-09
申请人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
发明人： Hubert Baumgart , Berthold Austrup , Bostjan Muhic
IPC分类号： C09D5/03
CPC分类号： C09D5/02 , C08G18/672 , C08G18/7837 , C09D5/03 , C09D175/16
摘要： Aqueous, structurally viscous powder dispersions curable by free-radical polymerization, substantially or entirely free from volatile organic compounds, and comprising as their disperse phase solid and/or highly viscous particles (A) which are dimensionally stable under storage and application conditions and have a z-mean average particle size as measured by photon correlation spectroscopy of 80 to 750 nm, the particles (A) comprising at least one free-radically crosslinkable binder (A1) having a glass transition temperature of −70 to +50° C., an olefinically unsaturated double bond content of 2 to 10 eq/kg and an acid group content of 0.05 to 15 eq/kg, in an amount, based on (A), of 50 to 100% by weight; process for their preparation, and their use.
摘要翻译：通过自由基聚合可固化的水性结构粘性粉末分散体，基本上或完全不含挥发性有机化合物，并且包含其分散相固体和/或高粘度颗粒（A），其在储存和使用条件下尺寸稳定，并具有通过80至750nm的光子相关光谱测量的z-平均粒度，包含玻璃化转变温度为-70至+ 50℃的至少一种可自由基交联的粘合剂（A1）的颗粒（A）基于（A），为50〜100重量％的烯属不饱和双键含量为2〜10当量/ kg，酸基含量为0.05〜15当量/ kg。他们的准备过程及其使用。

9. 发明申请

US20080003372A1 Method for Curing Radically Curable Compounds in a Protective Atmosphere and Device for Carrying Out Said Method 审中-公开
标题翻译：用于固化保护性气氛中的可自由基固化的化合物的方法和用于进行所述方法的装置
公开(公告)号：US20080003372A1
公开(公告)日：2008-01-03
申请号：US11569213
申请日：2005-05-24
申请人： Martin Kamps , Fatmir Raka , Hubert Baumgart , Berthold Austrup
发明人： Martin Kamps , Fatmir Raka , Hubert Baumgart , Berthold Austrup
IPC分类号： B05D1/18 , B05C3/02
CPC分类号： F26B21/14 , B05D3/0466 , B05D3/0486 , B05D3/067 , F26B3/28
摘要： A method of curing free-radically curable compositions under an inert gas atmosphere, where the curing, which proceeds in accordance with a free-radical mechanism, is initiated, or initiated and maintained, in the free-radically curable compositions by radiation and the lateral escape of the inert gas atmosphere is prevented, which involves (1) immersing the free-radically curable compositions in an inert gas atmosphere below a depth from which the inert gas atmosphere constantly exhibits its lowest oxygen concentration, and (2) irradiating the free-radically curable compositions below this depth in the inert gas atmosphere, at least one of the radiation sources being arranged beneath the inert gas/air interface, and then (3) emersing the resultant cured compositions again from the inert gas atmosphere, and apparatus (1) according to FIG. 1 for its implementation.
摘要翻译：一种在惰性气体气氛下固化可自由基固化的组合物的方法，其中根据自由基机理进行的固化通过辐射和侧向起始或启动并保持在可自由基固化的组合物中防止惰性气体气体的逸出，其包括（1）将自由基可固化组合物浸入惰性气体气氛中低于惰性气体气氛持续显示其最低氧浓度的深度，以及（2）在惰性气体气氛中低于该深度的可自由基固化的组合物，至少一个辐射源设置在惰性气体/空气界面的下方，然后（3）再次从惰性气体气氛中排出所得的固化组合物，以及装置（1 ）。 1执行。

10. 发明申请

US20150037590A1 Coating Agent Compositions, Coatings Made Therefrom And Exhibiting High Scratch Resistance And Good Polishability, And Use Thereof 有权
标题翻译：涂层剂组合物，制成的涂料，具有高耐刮擦性和良好的耐腐蚀性及其用途
公开(公告)号：US20150037590A1
公开(公告)日：2015-02-05
申请号：US14124972
申请日：2012-05-23
申请人： Matthijs Groenewolt , Günter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
发明人： Matthijs Groenewolt , Günter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
IPC分类号： C09D183/08 , B05D1/38 , B05D1/36
CPC分类号： C09D175/04 , B05D7/53 , B05D7/56 , C08G18/289 , C08G18/6229 , C08G18/791 , C08K5/521 , Y10T428/31551
摘要： Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR″x(OR′)3−x) (I), structural unit (II) —N(X—SiR″x(OR′)3−x)n(X′—SiR″y(OR′)3−y)m (II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structural units (II).
摘要翻译：包含（B1）至少一种具有游离或封闭的异氰酸酯基团的含异氰酸酯基的化合物（B1）和脂环族多异氰酸酯母体结构的组合物和/或由其衍生的多异氰酸酯和（B2）至少一种含有多异氰酸酯基团具有游离或封闭的异氰酸酯基团的化合物（B2）和非环状脂族多异氰酸酯母体结构和/或由其衍生的多异氰酸酯，其中组分（B1）和组分（B2）中的至少一种包含至少一种选自结构单元（I）-NR-（X-SiR“x（OR'）3-x）（I），结构单元（II）-N（X-SiR”x（OR'）3-x）n （X'-SiR“y（OR'）3-y）m（II）以及上述两种或更多种的混合物，其中化合物（B1）的量使得化合物（B1 ）为5〜45重量％，基于化合物（B1）和化合物（B2）的粘合剂组分的总和和组分的混合物 ts（B1）和（B2）包括结构单元（I）和结构单元（II）。

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