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1. 发明授权

US4491662A Aminomethyl group containing cationic dyes 失效
标题翻译：含氨基甲基的阳离子染料
公开(公告)号：US4491662A
公开(公告)日：1985-01-01
申请号：US370266
申请日：1982-04-20
申请人： Manfred Patsch , Manfred Ruske
发明人： Manfred Patsch , Manfred Ruske
IPC分类号： C09B69/02 , C09B19/02 , C09B69/00 , C07D498/04 , C07D521/00
CPC分类号： C09B69/00 , C09B19/02
摘要： Dyes of the formula ##STR1## where F is an (m+n)-valent radical of a quinophthalone, dioxazine, indigo, quinacridone, triphenylmethane or rhodamine dye, M.sup..sym. is H.sup..sym. or one equivalent of a metal cation, m is 0, 1 or 2 and n is 1, 2, 3 or 4, and their salts, are very useful for dyeing and printing paper. If they are used for wet-end dyeing, the waste water is virtually colorless. The colorations obtained exhibit good lightfastness and good bleeding fastness.
摘要翻译：其中F是喹酞酮，二恶嗪，靛蓝，喹吖啶酮，三苯基甲烷或罗丹明染料的（m + n）价基团，式（I）的染料M（+）是H（+）或1当量金属阳离子，m为0,1或2，n为1,2,3或4，它们的盐对于染色和印刷纸非常有用。如果它们用于湿染染色，废水几乎是无色的。获得的着色具有良好的耐光性和良好的耐渗透性。

2. 发明授权

US4942232A Imidazolylmethylene-containing triphendioxazine dyes 失效
标题翻译：含咪唑基亚甲基的三苯并二恶嗪染料
公开(公告)号：US4942232A
公开(公告)日：1990-07-17
申请号：US279202
申请日：1988-12-02
申请人： Manfred Ruske , Manfred Patsch
发明人： Manfred Ruske , Manfred Patsch
IPC分类号： C09B19/00 , C09B19/02 , D06P1/42 , D06P3/60 , D21H21/28
CPC分类号： C09B19/02 , Y10S8/919
摘要： Imidazolylmethylene-containing triphendioxazine dyes of the formula I ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4, m and n each have defined meanings, A.sup..crclbar. is an anion and F is the radical of a triphendioxazine chromophore of the formula II ##STR2## where X.sup.1, X.sup.2, X.sup.3, X.sup.4, X.sup.5, L and p each have defined meanings, are useful for dyeing and printing material containing cellulose fibers.
摘要翻译：其中R 1，R 2，R 3，R 4，m和n各自具有定义的含义的含咪唑基亚甲基的三苯并二恶嗪染料，其中R 1，R 2，R 3，R 4，m和n各自具有定义的含义，A（ - ）是阴离子，F是三苯并二恶嗪发色团的基团其中X1，X2，X3，X4，X5，L和p各自具有定义的含义的式II（II）可用于含有纤维素纤维的染色和印刷材料。

3. 发明授权

US5175259A Mono- and bis-azo compounds containing 6-hydroxy-3-heterocyclic onium-pyridone-2-groupings coupled to diazo components containing diazine or triazine rings 失效
标题翻译：含有6-羟基-3-杂环基的β-吡咯烷酮-2-基团的单 - 和双 - 异氰酸酯化合物与含有二氮杂环或三嗪环的DIAZO组分相连
公开(公告)号：US5175259A
公开(公告)日：1992-12-29
申请号：US843193
申请日：1992-02-28
申请人： Joerg L. Jessen , Manfred Ruske , Knut Kessel , Manfred Patsch
发明人： Joerg L. Jessen , Manfred Ruske , Knut Kessel , Manfred Patsch
IPC分类号： C09B62/085 , C09B62/04 , C09B62/245 , C09B62/44 , C09B62/51 , D06P1/38
CPC分类号： C09B62/245 , C09B62/04 , C09B62/4411
摘要： Reactive dyes of the formula ##STR1## where n is 1 or 2,X is a six-membered halogen-containing nitrogen heterocycle,L.sup.1, depending on n, is fluorine, chlorine, C.sub.1 -C.sub.4 -alkoxy, phenoxy, C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl or a bridge member which has one or two hydroxysulfonyl groups,D is the radical of a diazo component of the aniline or naphthalene series which has at least one hydroxysulfonyl group,L.sup.2 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 -alkyl,L.sup.3 is the cationic radical of an aromatic heterocycle which is linked to the pyridone ring via a nitrogen atom, andL.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl,with the proviso that the number of hydroxysulfonyl groups in the molecule exceeds that of the cationic groups by at least one, are useful for dyeing and printing hydroxyl- or nitrogen-containing substrates.
摘要翻译：式中，n为1或2的反应性染料，X为6元含卤素的氮杂环，L1取决于n，为氟，氯，C 1 -C 4 - 烷氧基，苯氧基，C 1 -C 4 - 烷基，取代或未取代的苯基或具有一个或两个羟基磺酰基的桥连构件，D是具有至少一个羟基磺酰基的苯胺或萘系的重氮组分的基团，L2是氢或取代或未取代的C1-C8 - 烷基，L3是通过氮原子与吡啶酮环连接的芳族杂环的阳离子基团，L4是氢或C1-C4-烷基，条件是分子中羟基磺酰基的数目超过通过至少一个的阳离子基团可用于染色和印刷含羟基或含氮底物。

4. 发明授权

US4472581A Imidazomethylene dyes 失效
标题翻译：咪唑亚甲基染料
公开(公告)号：US4472581A
公开(公告)日：1984-09-18
申请号：US407892
申请日：1982-08-13
申请人： Manfred Patsch , Manfred Ruske
发明人： Manfred Patsch , Manfred Ruske
IPC分类号： C09B11/28 , C09B25/00 , C09B55/00 , C09B69/00 , C09B9/04 , C07D401/02
CPC分类号： C09B25/00 , C09B69/00
摘要： Cationic dyes of the general formula ##STR1## where A and A' may be identical or different and are each a monovalent radical of a dye from the series comprising the azo or quinophthalone dyes, or A and A' independently of one another are each one of the radicals of the formulae ##STR2## R is C.sub.1 -C.sub.6 -alkyl, benzyl or aryl, R.sup.1 is hydrogen, C.sub.1 -C.sub.4 -alkyl or aryl, D' and D" are respectively a monovalent and a divalent radical of a dye from the series comprising the triphenylmethane or xanthene dyes, n is an integer .gtoreq.1 and m is an integer .gtoreq.1, the sum (n+m) being .ltoreq.10 on average, are soluble in dilute acids, and, when they are used for wet-end dyeing of paper, give bleeding-fast, bleachable dyeings and a colorless effluent.
摘要翻译：其中A和A'可以相同或不同并且各自为包含偶氮或喹酞酮染料或A和A'的系列中的染料的单价基团彼此独立的阳离子染料分别为式中的基团R 1为C 1 -C 6 - 烷基，苄基或芳基，R 1为氢，C 1 -C 4 - 烷基或芳基，D'和D“分别为一价和二价来自包含三苯基甲烷或呫吨染料的系列的染料的基团，n是整数> / = 1，m是整数> / = 1，平均值（n + m）平均为

5. 发明授权

US4451398A Dyes containing imidazolymethylene groups 失效
标题翻译：含有咪唑聚亚甲基的染料
公开(公告)号：US4451398A
公开(公告)日：1984-05-29
申请号：US233479
申请日：1981-02-11
申请人： Manfred Patsch , Manfred Ruske
发明人： Manfred Patsch , Manfred Ruske
IPC分类号： C09B1/00 , C09B3/00 , C09B5/00 , C09B7/00 , C09B11/04 , C09B19/02 , C09B29/00 , C09B31/00 , C09B35/00 , C09B47/12 , C09B48/00 , C09B57/02 , C09B57/06 , C09B57/08 , C09B57/12 , C09B69/00 , D21C5/02 , D21H21/28 , C09B15/00 , C09B25/00
CPC分类号： C09B29/00 , C09B1/00 , C09B11/04 , C09B19/02 , C09B3/00 , C09B31/00 , C09B35/00 , C09B47/12 , C09B48/00 , C09B5/00 , C09B57/02 , C09B57/06 , C09B57/08 , C09B57/12 , C09B69/00 , C09B7/00 , D21C5/022 , D21H21/28 , Y02W30/648 , Y10S8/919
摘要： Dyes of the formula ##STR1## where R.sup.1 is hydrogen, C.sub.1 -C.sub.6 -alkyl or C.sub.2 -C.sub.6 -alkenyl, R.sup.2 and R.sup.3 independently of one another are hydrogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl, R.sup.4 is C.sub.1 -C.sub.12 -alkyl or hydroxy-C.sub.2 -C.sub.4 -alkyl, X.sup..crclbar. is one equivalent of an anion, mis from 0 to 5 and n is from 0 to 5, with 1.ltoreq.(m+n).ltoreq.5, and F is an (m+n)-valent radical of a monoazo dye, a disazo dye, a polyazo dye, a quinophthalone, a bis-dioxazine, a compound of the 5,6-arylo-2-pyrone series, a naphtholactam dye, a triphenylmethane dye, a xanthene dye, a phthalocyanine, an indigoid, an anthraquinone dye containing one or more phenyl or naphthyl groups, a more highly fused carbonyl-containing dye, a quinacridone, a perylene-3,4,9,10-tetracarboxylic acid diimide, an anthrapyrimidine, a pyrazoloanthrone, a diaminonaphthoquinone, a naphthazarine or a naphthalene-1,4,5,8-tetracarboxylic acid diimide.The dyes give brilliant wet-fast colorations on cellulose-containing fiber material, especially on paper. When used for wet-end coloring of paper, the waste water is virtually or completely colorless.
摘要翻译：其中R 1是氢，C 1 -C 6 - 烷基或C 2 -C 6 - 烯基，R 2和R 3彼此独立的式（I）的染料是氢，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基，R 4 是C 1 -C 12 - 烷基或羟基-C 2 - C 4 - 烷基，X（ - ）是1当量的阴离子，0至5的错，n为0至5，且1（=（m + n） / = 5，F是单偶氮染料，双偶氮染料，多偶氮染料，喹酞酮，双二恶嗪，5,6-芳氧基-2-吡喃酮的化合物的（m + n）系列，萘内酰胺染料，三苯基甲烷染料，呫吨染料，酞菁，靛类，含有一个或多个苯基或萘基的蒽醌染料，更高熔融的含羰基染料，喹吖啶酮，苝-3,4 ，9,10-四羧酸二酰亚胺，蒽并嘧啶，吡唑烷酮，二氨基萘醌，萘并噻唑或萘-1,4,5,8-四羧酸二酰亚胺。这些染料在含纤维素的纤维材料上，特别是在纸上产生了明亮的湿快色。当用于纸张的湿端着色时，废水几乎或完全无色。

6. 发明授权

US4393005A Cationic phthalocyanine dyes 失效
标题翻译：阳离子酞菁染料
公开(公告)号：US4393005A
公开(公告)日：1983-07-12
申请号：US357808
申请日：1982-03-15
申请人： Manfred Patsch , Manfred Ruske , Erwin Hahn
发明人： Manfred Patsch , Manfred Ruske , Erwin Hahn
IPC分类号： C09B47/16 , C09B47/24 , C09B47/32 , D21H19/10 , D21H21/28 , C09B47/04
CPC分类号： D21H21/28 , C09B47/16 , C09B47/24 , C09B47/32
摘要： Cationic phthalocyanine dyes of the formula ##STR1## where Pc is an (m+n+p)-valent phthalocyanine radical, R.sup.1 is H or alkyl, R.sup.2 and R.sup.3 independently of one another are alkyl, hydroxyalkyl, cycloalkyl, benzyl, phenyl or tolyl, or ##STR2## is pyrrolidinyl, imidazolyl, 2-ethyl-4-methylimidazolyl, morpholinyl, piperazinyl or N'-alkylpiperazinyl, or is ##STR3## R.sup.4 is H or methyl, R.sup.5 is alkyl, hydroxyalkyl or benzyl, X.sup..sym. is one equivalent of an anion, M.sup..crclbar. is one equivalent of a cation, z is 1 or 2, p is 0 or 1, m is 0 or 1 and n is from 1 to 4, and 1
摘要翻译：其中Pc是（m + n + p）价的酞菁基，R 1是H或烷基，R 2和R 3彼此独立地是烷基，羟烷基，环烷基，苄基，苯基或甲苯基的阳离子酞菁染料或者是“吡咯烷基”，“咪唑基”，2-乙基-4-甲基咪唑基，吗啉基，哌嗪基或N'-烷基哌嗪基，或者R 4是H或甲基，R 5是烷基，羟基烷基或苄基，X（+ 是1当量的阴离子，M（ - ）是1当量的阳离子，z为1或2，p为0或1，m为0或1，n为1至4，1（（m + n））<4，容易或高度溶于水，在纸上非常实用，因此特别适用于染色和印刷纸张。用（I）染色的纸具有非常好的止血牢度，当纸被湿端染色时获得无色流出液。

7. 发明申请

US20070172647A1 Glass coating 失效
标题翻译：玻璃涂层
公开(公告)号：US20070172647A1
公开(公告)日：2007-07-26
申请号：US10589157
申请日：2004-04-03
申请人： Gerd Kleideiter , Anton Zmelty , Armin Reus , Manfred Ruske , Michael Geisler
发明人： Gerd Kleideiter , Anton Zmelty , Armin Reus , Manfred Ruske , Michael Geisler
IPC分类号： G11B5/64 , B32B15/04
CPC分类号： C03C17/3435 , Y10T428/2495 , Y10T428/265
摘要： The invention relates to a coating for temperable substrates, in particular of glass panes. This coating comprises for example directly on the substrate an Si3N4 layer, thereon a CrN layer, thereon a TiO2 layer and lastly an Si3N4 layer.
摘要翻译：本发明涉及一种用于可调节基材，特别是玻璃板的涂层。该涂层例如在衬底上直接包含Si 3 N 4 N 4层，其上具有CrN层，其上具有TiO 2层，最后包括 Si 3 N 4 N 4层。

8. 发明授权

US06180247B2 Thermally-insulating coating system 有权
标题翻译：绝热涂层系统
公开(公告)号：US06180247B2
公开(公告)日：2001-01-30
申请号：US09222361
申请日：1998-12-29
申请人： Joachim Szczyrbowski , Manfred Ruske , Anton Zmelty
发明人： Joachim Szczyrbowski , Manfred Ruske , Anton Zmelty
IPC分类号： B32B1500
CPC分类号： C03C17/3618 , C03C17/36 , C03C17/3626 , C03C17/366 , C03C17/3681 , Y10T428/2495 , Y10T428/24975 , Y10T428/265
摘要： A thermally insulating coating system for curved and/or hardened glass panes includes at least one layer of noble metal enclosed by a lower and an upper blocker layer. An underoxidic NiCrOx layer with a thickness between one Å and two nm is embedded into the noble-metal layer. The advantage is that the optical qualities of the coating system are not influenced by the tempering and curving of the glass pane.
摘要翻译：用于弯曲和/或硬化的玻璃板的绝热涂层系统包括由下部和上部阻挡层包围的至少一层贵金属。在贵金属层中嵌入厚度为1埃到2纳米的低氧NiCrOx层。优点是涂层系统的光学质量不受玻璃板的回火和弯曲的影响。

9. 发明授权

US5496378A Imidazolymethylated copper phthalocyanine dyes 失效
标题翻译：咪唑多甲基化铜酞菁染料
公开(公告)号：US5496378A
公开(公告)日：1996-03-05
申请号：US304191
申请日：1994-09-12
申请人： Heidi Hengelsberg , Manfred Ruske , Udo Mayer
发明人： Heidi Hengelsberg , Manfred Ruske , Udo Mayer
IPC分类号： C09B47/32 , C09B69/06 , D21H21/28 , C09B47/04
CPC分类号： C09B69/06 , C09B47/32 , D21H21/28 , Y10S8/918 , Y10S8/919
摘要： Basic dyes of the formula ##STR1## where n is from 1 to 3,CuPc is a copper phthalocyanine radical,R.sup.1 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.2 is C.sub.1 -C.sub.4 -alkyl,R.sup.3 is hydrogen or C.sub.1 -C.sub.4 -alkyl,R.sup.4 is C.sub.1 -C.sub.4 -alkyl andAn.sup..crclbar. is the equivalent of an anion,with the proviso that R.sup.1 and R.sup.3 are not both hydrogen, are useful for dyeing or printing polymeric material.
摘要翻译：其中n为1-3的碱性染料，CuPc为铜酞菁基，R 1为氢或C 1 -C 4 - 烷基，R 2为C 1 -C 4 - 烷基，R 3为氢或C 1 -C 4烷基 R 4是C 1 -C 4 - 烷基，并且An（ - ）是阴离子的当量，条件是R 1和R 3不同时为氢，可用于染色或印刷聚合物材料。

10. 发明授权

US4935499A Cationic azo dyes with a 1-hydroxynaphthalene 3-sulfonic acid coupling component, useful for coloring paper 失效
标题翻译：具有1-羟基萘-3-磺酸偶合成分的阳离子偶氮染料，用于着色纸
公开(公告)号：US4935499A
公开(公告)日：1990-06-19
申请号：US250994
申请日：1988-09-27
申请人： Manfred Ruske , Hans-Juergen Degen
发明人： Manfred Ruske , Hans-Juergen Degen
IPC分类号： C09B44/02 , D21H21/28
CPC分类号： C09B44/02 , D21H21/28 , Y10S8/919
摘要： Paper is colored by a process in which a compound which, in the form of the free acid, is of the formula I ##STR1## where, in each case independently of one another, A is unsubstituted or methyl substituted C.sub.1 -C.sub.6 -alkylene or vinylene,R is each hydrogen or C.sub.1 -C.sub.4 -alkyl,X is each --CO-- or --SO.sub.2 --,K is each a cationic group andY is hydrogen, chlorine or bromine.
摘要翻译：纸通过一种方法着色，其中游离酸形式为式I的化合物，其中在每种情况下彼此独立地是A是未取代的或甲基取代的C 1 -C 6 - 亚烷基或亚乙烯基，R各自为氢或C 1 -C 4 - 烷基，X为-CO-或-SO 2 - ，K为阳离子基团，Y为氢，氯或溴。

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