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1. 发明授权

US5071943A Process for the isolation of tetrachlorobutane and for the production of phenolic resins from mixtures of chlorine-substituted hydrocarbons 失效
标题翻译：分离四氯化碳和从氯代烃类混合物中生产酚醛树脂的方法
公开(公告)号：US5071943A
公开(公告)日：1991-12-10
申请号：US655716
申请日：1991-02-15
申请人： Manfred Abele , Hans-Josef Buysch , Michael Happ , Werner Obrecht , Heinrich Schrage , Hugo Vernaleken
发明人： Manfred Abele , Hans-Josef Buysch , Michael Happ , Werner Obrecht , Heinrich Schrage , Hugo Vernaleken
IPC分类号： C07C17/38 , C08G61/02 , C08L21/00
CPC分类号： C08G61/02 , C07C17/38 , C08L21/00
摘要： Secondary products formed in the chlorination of butadiene can be reacted with phenols in the absence of iron catalysts to form novolak-like phenolic resins in such a way that the tetrachlorobutane present in the secondary products does not react. It can be distilled off with the excess phenol and isolated in pure form from the distillate obtained.
摘要翻译：在不存在铁催化剂的情况下，在丁二烯氯化中形成的二次产物可以与酚反应形成酚醛清漆型酚醛树脂，使得二次产物中存在的四氯丁烷不反应。可以用过量的苯酚蒸馏除去，并从所得馏出物中以纯净的形式分离。

2. 发明授权

US5219976A Process for the preparation of phenol resins using by-products of the chlorination of butadiene as reactants 失效
标题翻译：使用二苯乙烯作为反应物的氯化物副产物制备酚醛树脂的方法
公开(公告)号：US5219976A
公开(公告)日：1993-06-15
申请号：US655769
申请日：1991-02-15
申请人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
发明人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
IPC分类号： C08G61/02 , C08L21/00
CPC分类号： C08G61/02 , C08L21/00
摘要： By-products from the chlorination of butadiene may be reacted with phenols in the presence of iron catalysts to form Novolak type phenol resins.
摘要翻译：在铁催化剂存在下，来自丁二烯氯化的副产物可以与酚反应形成酚醛清漆型酚醛树脂。

3. 发明授权

US5214100A Use of certain phenolic resins for reinforcing rubber vulcanizates 失效
标题翻译：某些酚醛树脂用于增强橡胶硬化剂的使用
公开(公告)号：US5214100A
公开(公告)日：1993-05-25
申请号：US655717
申请日：1991-02-15
申请人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
发明人： Manfred Abele , Hans-Josef Buysch , Heinrich Schrage , Hugo Vernaleken
IPC分类号： C08G61/02 , C08L21/00
CPC分类号： C08G61/02 , C08L21/00 , C08L7/00 , C08L9/00 , Y10T152/10846
摘要： Phenolic resins obtainable by Friedel-Crafts alkylation of phenols with polyfunctional compounds are eminently suitable as a reinforcing resin for rubber vulcanizates.
摘要翻译：通过Friedel-Crafts可以通过酚类与多官能化合物烷基化获得的酚醛树脂非常适合用作橡胶硫化橡胶的增强树脂。

4. 发明授权

US4080399A Sulphenamides, their production and their use as vulcanization retarders 失效
标题翻译：苯甲酰胺，它们的生产和用作硫化缓凝剂
公开(公告)号：US4080399A
公开(公告)日：1978-03-21
申请号：US650305
申请日：1976-01-19
申请人： Paul Uhrhan , Ernst Roos , Manfred Abele , Rudiger Schubart , Theo Kempermann
发明人： Paul Uhrhan , Ernst Roos , Manfred Abele , Rudiger Schubart , Theo Kempermann
IPC分类号： C07D209/48 , C07D405/12 , C08K5/43 , C08K5/44 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L101/00 , C07D209/34 , C08F28/00
CPC分类号： C07D209/48 , C08K5/44
摘要： Sulphenamides are obtained by reacting N-chlorothiophthalimide with compounds containing one or two olefinic double bonds. These products retard vulcanization of natural or synthetic rubber.
摘要翻译：通过N-氯硫代邻苯二甲酰亚胺与含有一个或两个烯属双键的化合物反应获得苯甲酰胺。这些产品阻止天然或合成橡胶硫化。

5. 发明授权

US4280004A Mixtures of azodicarbonamide and .alpha.-amidosulphones and their production and use as a blowing agent 失效
标题翻译：偶氮二甲酰胺和α-氨基砜的混合物及其生产和用作发泡剂
公开(公告)号：US4280004A
公开(公告)日：1981-07-21
申请号：US189736
申请日：1980-09-22
申请人： Werner Jeblick , Ernst Roos , Theo Kempermann , Manfred Abele
发明人： Werner Jeblick , Ernst Roos , Theo Kempermann , Manfred Abele
IPC分类号： C08J9/06 , C07C67/00 , C07C313/00 , C07C317/28 , C07C325/00 , C07C335/08 , C08J9/10
CPC分类号： C08J9/102 , Y10S264/05 , Y10S521/91
摘要： A mixture of azodicarbonamide and an .alpha.-amidosulphone corresponding to the general formula: ##STR1## in which R represents hydrogen, a C.sub.1 -C.sub.4 -alkyl residue and/or halogen,x represents numbers from 0 to 5,y represents numbers from 1 to 3, corresponding to the valency of R.sub.1,R.sup.1 represents an aromatic carboxylic acid residue or sulphonic acid residue with 6 carbon atoms, which is optionally substituted once or several times by halogen, C.sub.1 -C.sub.4 alkyl residues, C.sub.1 -C.sub.4 alkoxy residues, nitro and/or cyano, or represents an aliphatic carboxylic acid residue or a sulphonic acid residue with 1-4 carbon atoms, a carbonic acid residue, a thiocarbonic acid residue or a phosphoric acid residue which, corresponding to the numerical value of y, contains 0-2 phenoxy residues or C.sub.1 -C.sub.4 alkoxy residues optionally substituted with C.sub.1 -C.sub.4 alkyl or halogen,R.sup.2 represents R.sup.1, or hydrogen, a C.sub.1 -C.sub.4 alkyl residue, a C.sub.5 -C.sub.7 cycloalkyl residue, a phenyl residue, which is optionally substituted once or several times by C.sub.1 -C.sub.4 -alkyl or halogen, a phenyl alkyl residue whose phenyl group is optionally substituted once or several times by C.sub.1 -C.sub.4 -alkyl or halogen and whose alkyl group has 1-3 carbon atoms or R.sub.1 and R.sub.2 together with the nitrogen atom form a cyclic lactam ring which has 4-6 carbon atoms, can be used as a blowing agent for rubber.
摘要翻译：对应于以下通式的偶氮二甲酰胺和α-氨基砜的混合物：其中R表示氢，C1-C4烷基和/或卤素，其中x表示0至5的数，y表示1至 3，对应于R1的化合价，R1表示具有6个碳原子的芳族羧酸残基或磺酸残基，其任选被卤素，C 1 -C 4烷基残基，C 1 -C 4烷氧基残基，硝基和 /或氰基，或表示具有1-4个碳原子的脂族羧酸残基或磺酸残基，对应于y的数值的碳酸残基，硫代碳酸残基或磷酸残基含有0- 2个苯氧基残基或任选被C 1 -C 4烷基或卤素取代的C 1 -C 4烷氧基残基，R 2表示R 1或氢，C 1 -C 4烷基残基，C 5 -C 7环烷基残基，苯基残基，其任选被一次取代或几次通过C 1 -C 4烷基或卤素取代苯基烷基，其苯基任选被C 1 -C 4烷基或卤素取代一次或几次，并且其烷基具有1-3个碳原子，或者R 1和R 2与氮原子一起形成具有4-6个碳原子的环状内酰胺环，可以用作橡胶的发泡剂。

6. 发明授权

US4745172A Phenolic resins using polyamines and polyethers in their production 失效
标题翻译：酚醛树脂在生产中使用多胺和聚醚
公开(公告)号：US4745172A
公开(公告)日：1988-05-17
申请号：US896061
申请日：1986-08-13
申请人： Thomas Scholl , Reinhard Preuss , Manfred Abele , Hermann Fries , Theo Kempermann
发明人： Thomas Scholl , Reinhard Preuss , Manfred Abele , Hermann Fries , Theo Kempermann
IPC分类号： C08G14/00 , C08G14/06 , C08G14/12 , C08G14/14 , C08L21/00
CPC分类号： C08G14/14 , C08G14/12 , C08L21/00
摘要： Phenolic resins obtained by condensation from alkylphenol, aldehyde, polyamine and polyether in a molar ratio of 1:0.7 to 1.3:0.005 to 0.2:0.001 to 0.3 are suitable as tackifiers for rubber mixtures.
摘要翻译：通过从烷基酚，醛，多胺和聚醚以1:0.7至1.3:0.00:0.001-0.3的摩尔比缩合获得的酚醛树脂适合用作橡胶混合物的增粘剂。

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