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1. 发明授权

US08481624B2 Methods for producing flameproofed thermoplastic moulding compounds 失效
标题翻译：用于生产隔热热塑性模塑料的方法
公开(公告)号：US08481624B2
公开(公告)日：2013-07-09
申请号：US12680571
申请日：2008-09-23
申请人： Maarten Pieter Bram Staal , Norbert Güntherberg , Piyada Charoensirisomboon , Hartmut Heinen , Norbert Nieβner , Walter Heckmann
发明人： Maarten Pieter Bram Staal , Norbert Güntherberg , Piyada Charoensirisomboon , Hartmut Heinen , Norbert Nieβner , Walter Heckmann
IPC分类号： C08K5/51 , C08L27/12
CPC分类号： C08K5/523 , B29C47/0004 , B29C47/0014 , B29C47/0021 , B29C47/1045 , B29C47/1081 , B29K2105/0005 , B29K2105/0026 , B29K2995/0016 , B29K2995/0059 , C08K3/04 , C08K5/0066
摘要： The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said thermoplastic molding materials for the production of fibers, films, moldings and foams, and these fibers, films, moldings and foams themselves.
摘要翻译：本发明涉及一种制备热塑性模塑材料的方法，其包括A）39至99重量％的至少一种热塑性聚合物，B）1至60重量％的防火组分，其包含B1）可膨胀石墨，和C）0至60重量％的其它添加剂，所述重量百分比基于每种情况下基于组分A）至C）的总重量，并且通过混合组分A的熔体并一起产生100重量％），B），如果存在，C）在螺杆挤出机中，螺杆挤出机沿着输送方向按该顺序包括至少一个计量区，一个塑化区，一个均化区和一个排放区，其中计量可膨胀石墨B1）进入螺杆挤出机是在输送方向观察的位置上实现的 - 挤出机螺杆基本上不包括剪切元件，以及可以通过这些方法制备的热塑性模塑材料，使用所述热塑性成型材料来生产纤维，薄膜，模制品和泡沫，以及这些纤维，薄膜，模制品和泡沫本身。

2. 发明申请

US20100305253A1 Methods For Producing Flameproofed Thermoplastic Moulding Compounds 失效
标题翻译：用于生产隔爆热塑性模塑料的方法
公开(公告)号：US20100305253A1
公开(公告)日：2010-12-02
申请号：US12680571
申请日：2008-09-23
申请人： Maarten Pieter Bram Staal , Norbert Güntherberg , Piyada Charoensirisomboon , Hartmut Heinen , Norbert Niessner , Walter Heckmann
发明人： Maarten Pieter Bram Staal , Norbert Güntherberg , Piyada Charoensirisomboon , Hartmut Heinen , Norbert Niessner , Walter Heckmann
IPC分类号： C09K21/14
CPC分类号： C08K5/523 , B29C47/0004 , B29C47/0014 , B29C47/0021 , B29C47/1045 , B29C47/1081 , B29K2105/0005 , B29K2105/0026 , B29K2995/0016 , B29K2995/0059 , C08K3/04 , C08K5/0066
摘要： The invention relates to a process for the preparation of thermoplastic molding materials comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flameproofing component comprising B1) an expandable graphite, and C) from 0 to 60% by weight of further additives, the percentages by weight being based in each case on the total weight of the components A) to C) and together giving 100% by weight, by mixing melts of the components A), B) and, if present, C) in a screw extruder, the screw extruder comprising at least one metering zone, one plasticating zone, one homogenization zone and one discharge zone in this sequence along the conveying direction, wherein the metering of the expandable graphite B1) into the screw extruder is effected at a point behind which—viewed in the conveying direction—the extruder screw comprises substantially no shearing elements, and thermoplastic molding materials which can be prepared by these processes, the use of said thermoplastic molding materials for the production of fibers, films, moldings and foams, and these fibers, films, moldings and foams themselves.
摘要翻译：本发明涉及一种制备热塑性模塑材料的方法，其包括A）39至99重量％的至少一种热塑性聚合物，B）1至60重量％的防火组分，其包含B1）可膨胀石墨，和C）0至60重量％的其它添加剂，所述重量百分比基于每种情况下基于组分A）至C）的总重量，并且通过混合组分A的熔体并一起产生100重量％），B），如果存在，C）在螺杆挤出机中，螺杆挤出机沿着输送方向按该顺序包括至少一个计量区，一个塑化区，一个均化区和一个排放区，其中计量可膨胀石墨B1）进入螺杆挤出机是在输送方向观察的位置进行的 - 挤出机螺杆基本上不包含剪切元件，以及可以通过这些方法制备的热塑性模塑材料，使用所述热塑性成型材料来生产纤维，薄膜，模制品和泡沫，以及这些纤维，薄膜，模制品和泡沫本身。

3. 发明申请

US20110118371A1 RUBBER-MODIFIED FLAME-RETARDANT MOLDING COMPOUNDS 审中-公开
标题翻译：橡胶改性阻燃模塑料
公开(公告)号：US20110118371A1
公开(公告)日：2011-05-19
申请号：US13002948
申请日：2009-07-03
申请人： Maarten Staal , Piyada Charoensirisomboon , Norbert Güntherberg , Hartmut Heinen , Günter Kehr , Michel Pepers
发明人： Maarten Staal , Piyada Charoensirisomboon , Norbert Güntherberg , Hartmut Heinen , Günter Kehr , Michel Pepers
IPC分类号： C09K21/14 , C08K3/32 , C08K5/521 , C08K5/5333 , C08K5/5397 , C08L25/00
CPC分类号： C09K21/04 , C08K3/04 , C08K5/49 , C08K7/24 , C08L51/04 , C08L55/02 , C09K21/12 , C08L2666/02 , C08L2666/04
摘要： The invention relates to thermoplastic molding compositions comprising A) from 55 to 98% by weight of at least one vinylaromatic copolymer impact-modified with a particulate graft rubber, B) from 1 to 44% by weight of a flame retardant comprising B1) an expandable graphite, B2) a phosphorus-comprising flame-retardant compound, and B3) a fluorine-comprising polymer, C) from 1 to 20% by weight of a non-particulate rubber comprising polar groups, and D) from 0 to 40% by weight of further additives, where the percentages by weight are in each case based on the total weight of components A) to D) and give a total of 100% by weight, and also to processes for the preparation of these molding compositions, to the use of these molding compositions for the production of moldings, of fibers, of foams, or of foils, and also to the resultant moldings, fibers, foams, and foils.
摘要翻译：本发明涉及热塑性模塑组合物，其包含A）55至98重量％的至少一种用颗粒接枝橡胶冲击改性的乙烯基芳族共聚物，B）1至44重量％的阻燃剂，其包含B1）可膨胀石墨，B2）含磷阻燃化合物，B3）含氟聚合物，C）1〜20重量％的包含极性基团的非粒状橡胶，D）0〜40重量％其他添加剂的重量，其中每种情况下的重量百分比都是基于组分A）至D）的总重量，并且总计为100重量％，以及制备这些模塑组合物的方法，使用这些模塑组合物来生产模制品，纤维，泡沫或箔，以及所得模制品，纤维，泡沫和箔。

4. 发明申请

US20110257335A1 PHASE-SEPARATING BLOCK COPOLYMERS COMPOSED OF INCOMPATIBLE HARD BLOCKS AND MOLDING MATERIALS WITH HIGH STIFFNESS 审中-公开
标题翻译：组成不可分割硬块的相分离块状共聚物和具有高刚度的成型材料
公开(公告)号：US20110257335A1
公开(公告)日：2011-10-20
申请号：US13141840
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08F297/04 , C08L25/06 , C08L25/10 , C08L51/04 , C08L51/06 , C08L53/02 , C08L2205/02 , C08L2205/03 , C08L2666/02 , C08L2666/24 , C08L2666/04
摘要： A block copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprisinga) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, andb) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., andc) at least one copolymer block (S/B)B composed of from 20 to 60% by weight of vinylaromatic monomers and from 40 to 80% by weight of dienes, with glass transition temperature TgB in the range from 0 to −80° C.,where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, and the proportion by weight of the entirety of all of the blocks (S/B)A and (S/B)B is in the range from 30 to 50% by weight, based in each case on the block copolymer A, and also mixtures thereof, and their use.
摘要翻译：一种重均摩尔质量Mw至少为100000g / mol的嵌段共聚物，包含a）至少一种由95-100％（重量）乙烯基芳族单体和0-5％（重量）二烯组成的嵌段S，和b）由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的至少一种共聚物嵌段（S / B）A，玻璃化转变温度TgA在5至30℃的范围内 C）和c）由20至60重量％的乙烯基芳族单体和40至80重量％的二烯组成的至少一种共聚物嵌段（S / B）B，玻璃化转变温度TgB为0 至-80℃，其中全部块S的重量比例在50至70重量％的范围内，并且全部块的重量比（S / B ）A和（S / B）B在30至50重量％的范围内，基于嵌段共聚物A的每种情况，以及它们的混合物及其用途。

5. 发明申请

US20110028613A1 FLAME-RETARDENT THERMOPLASTIC COMPOSITIONS 审中-公开
标题翻译：阻燃热塑性组合物
公开(公告)号：US20110028613A1
公开(公告)日：2011-02-03
申请号：US12935617
申请日：2009-03-30
申请人： Maarten Staal , Piyada Charoensirisomboon
发明人： Maarten Staal , Piyada Charoensirisomboon
IPC分类号： C08K5/51 , C07F9/40
CPC分类号： C09K21/12 , C08K5/53 , C08L25/12 , C08L27/18 , C08L55/02 , C08L2666/02 , C08L2666/24
摘要： The invention relates to thermoplastic molding compositions comprising A) from 39 to 99% by weight of at least one thermoplastic polymer, B) from 1 to 60% by weight of a flame-retardant component comprising B1) a compound of the formula (I), and C) from 0 to 60% by weight of further additives, where the percentages by weight are always based on the total weight of components A) to C) and their total is 100% by weight, and also to processes for the preparation of these molding compositions, to the use of these molding compositions for the production of moldings, of fibers, of foams, or of foils, and also to the resultant moldings, fibers, foams, or foils and moreover to the use of the compound of the formula (I) as flame retardant for thermoplastic polymers.
摘要翻译：本发明涉及热塑性模塑组合物，其包含A）39至99重量％的至少一种热塑性聚合物，B）1至60重量％的阻燃组分，其包含B1）式（I）化合物，和C）0至60重量％的其它添加剂，其中重量百分比总是基于组分A）至C）的总重量，其总量为100重量％，并且还涉及制备方法这些成型组合物的用途是使用这些模制组合物用于生产模制品，纤维，泡沫或箔，以及所得模制品，纤维，泡沫或箔，以及使用化合物式（I）作为热塑性聚合物的阻燃剂。

6. 发明授权

US09024050B2 Hydrophobic, functionalized particles 有权
标题翻译：疏水性，官能化颗粒
公开(公告)号：US09024050B2
公开(公告)日：2015-05-05
申请号：US13434176
申请日：2012-03-29
申请人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , David F. Blackwood , Christian Eichholz , Robert Bayer , Dennis Loesch , Igor Shishkov
发明人： Stephan Deuerlein , Imme Domke , Alexej Michailovski , Reinhold Rieger , Piyada Charoensirisomboon , David F. Blackwood , Christian Eichholz , Robert Bayer , Dennis Loesch , Igor Shishkov
IPC分类号： C07F7/08 , H01F1/00
CPC分类号： C07F7/0836 , H01F1/0054
摘要： The present invention relates to a stable mixture comprising surface-modified particles which are obtained by reacting metal oxide or semimetal oxide particles with at least one compound selected from among silicon-comprising compounds bearing at least one metaloxy radical and optionally further alkoxy and/or hydroxy radical(s) and at least one solvent, at least one surface-active substance or a mixture thereof, a process for producing the mixture, the use of these particles in systems in which they are brought into contact with at least one solvent, where the mass ratio of solvent to modified particle is greater than 500, and also the use of these particles in agglomeration-deagglomeration cycles.
摘要翻译：本发明涉及包含表面改性颗粒的稳定混合物，其通过使金属氧化物或半金属氧化物颗粒与至少一种选自含有至少一个金属氧基的含硅化合物和任选的其它烷氧基和/或羟基的化合物反应而获得自由基和至少一种溶剂，至少一种表面活性物质或其混合物，制备该混合物的方法，在与至少一种溶剂接触的体系中使用这些颗粒，其中溶剂与改性颗粒的质量比大于500，并且还使用这些颗粒在聚集 - 解聚缩循环中。

7. 发明授权

US08466215B2 Thermoplastic linoleum 失效
标题翻译：热塑性油毡
公开(公告)号：US08466215B2
公开(公告)日：2013-06-18
申请号：US12747369
申请日：2008-12-11
申请人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
发明人： Konrad Knoll , Michel Pepers , Peter Wolf , Piyada Charoensirisomboon
IPC分类号： C08K9/00 , C09B67/00
CPC分类号： D06N1/00
摘要： The present invention relates to a thermoplastic molding composition comprising (A) as component A, particles composed of at least one oxidatively crosslinked vegetable oil as core, encapsulated by at least one thermoplastic, (B) as component B, at least one further thermoplastic compatible with the at least one thermoplastic present in the shell of component A, (C) as component C, at least one resin compatible with the at least one thermoplastic present in the shell of component A, (D) as component D, at least one filler, and (E) as component E, if appropriate, further additives, and also to a process for the production of the thermoplastic molding composition.
摘要翻译：本发明涉及一种热塑性模塑组合物，其包含（A）作为组分A，由至少一种氧化交联的植物油作为芯组成的颗粒，由至少一种热塑性塑料包封，（B）作为组分B，至少一种另外的热塑性相容性存在于组分A的外壳中的至少一种热塑性材料（C）作为组分C，至少一种与组分A壳体中存在的至少一种热塑性塑料相容的树脂，（D）作为组分D，至少一种填充剂和（E）作为组分E，如果合适的话，还可以使用其它添加剂，以及制备热塑性模塑组合物的方法。

8. 发明申请

US20120220678A1 THERMOPLASTIC COMPOSITIONS HAVING IMPROVED FLOWABILITY 审中-公开
标题翻译：具有改善流动性的热塑性组合物
公开(公告)号：US20120220678A1
公开(公告)日：2012-08-30
申请号：US13505966
申请日：2010-11-02
申请人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
发明人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
IPC分类号： C08K5/12 , C08J9/22 , C08L55/02
CPC分类号： C08L55/02 , C08K5/12 , C08K5/1539 , C08K2201/014 , C08L25/12 , D01F6/56 , C08L2666/04
摘要： The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
摘要翻译：本发明涉及包含（i）组分（I）的组合物，至少一种包含组分A和B的模塑组合物，其中A）是作为组分A的接枝共聚物，B）是作为组分B的热塑性共聚物; 和（ii）至少一种式（I）的环己烷多羧酸衍生物; 作为其中R 1为C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基的组分（II），m为0,1,2或3，n为2,3或4，并且R为氢或C 1 -C 30 - 烷基; 或（COOR）基团形成下式的酸酐，其中组分（I）占组分A的11至19.9重量％和组分B的80.1至89重量％是本发明必需的，其中每个重量百分比值基于组分A和B的全部，并且这些值的总和为100重量％，并且还涉及制备本发明组合物的方法，使用组合物用于生产模制品，箔，泡沫或纤维的本发明以及包含本发明组合物的模制品，箔，泡沫或纤维。

9. 发明申请

US20100304067A1 TRANSPARENT, TOUGH AND RIGID MOLDING COMPOSITIONS BASED ON STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES 失效
标题翻译：基于苯乙烯 - 丁二烯嵌段共聚物混合物的透明，粗糙和刚性成型组合物
公开(公告)号：US20100304067A1
公开(公告)日：2010-12-02
申请号：US12677960
申请日：2008-09-03
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner
IPC分类号： C08L53/02 , B32B3/12 , B32B1/08
CPC分类号： C08L25/06 , C08K5/0016 , C08L25/10 , C08L53/02 , C08L2205/02 , C08L2205/035 , C08L2666/24 , C08L2666/02
摘要： A mixture which comprises a) from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., and comprising at least one diene block B or one copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −100° to 0° C., e) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.
摘要翻译：包含a）95至30重量％的共聚物或嵌段共聚物A，其包含一种或多种共聚物嵌段（B / S）A，其分别由65至95重量％的乙烯基芳族单体和 35〜5重量％的二烯，玻璃化转变温度TgA在40℃〜90℃的范围内，b）5〜45重量％的嵌段共聚物B，其包含至少一个硬嵌段S，由乙烯基芳族单体组成，并且包含一种或多种共聚物嵌段（B / S）B，其分别由20至60重量％的乙烯基芳族单体和80至40重量％的二烯组成，并且其玻璃化转变温度TgB在-70℃至0℃的范围内，c）0至40重量％的聚苯乙烯C，以及d）0至30重量％的嵌段共聚物D，其包含至少一个共聚物嵌段（B / S）A，其分别由65至95重量％的乙烯基芳族单体和35至5重量％的重量并且其玻璃化转变温度TgA在40℃至90℃的范围内，并且包含至少一个二烯嵌段B或一个共聚物嵌段（B / S）B，其分别由1至60个乙烯基芳族单体的重量百分比和99至40重量％的二烯，其玻璃化转变温度TgB在-100℃至0℃的范围内，e）0至6重量％的塑化代理商及其用于生产电子元件包装的用途。

10. 发明授权

US08536279B2 Phase-separating block or graft copolymers comprising incompatible hard blocks and moulding compositions having a high stiffness 有权
标题翻译：包含不相容的硬块和具有高刚度的模塑组合物的相分离嵌段或接枝共聚物
公开(公告)号：US08536279B2
公开(公告)日：2013-09-17
申请号：US13141870
申请日：2009-12-14
申请人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
发明人： Konrad Knoll , Jürgen Koch , Piyada Charoensirisomboon , Daniel Wagner , Geert Verlinden , Roland Weidisch
IPC分类号： C08L53/02 , C08F279/00
CPC分类号： C08L25/10 , C08F257/02 , C08F279/02 , C08F297/04 , C08F297/044 , C08L25/06 , C08L51/003 , C08L51/06 , C08L53/02 , C08L2666/24 , C08L2666/02 , C08L2666/04 , C08L2666/06
摘要： A block copolymer or graft copolymer with weight-average molar mass Mw of at least 100 000 g/mol, comprising a) at least one block S composed of from 95 to 100% by weight of vinylaromatic monomers and from 0 to 5% by weight of dienes, and b) at least one copolymer block (S/B)A composed of from 63 to 80% by weight of vinylaromatic monomers and from 20 to 37% by weight of dienes, with glass transition temperature TgA in the range from 5 to 30° C., where the proportion by weight of the entirety of all of the blocks S is in the range from 50 to 70% by weight, based on the block copolymer or graft copolymer, and also mixtures thereof, and their use.
摘要翻译：包含重量平均摩尔质量Mw至少为100 000g / mol的嵌段共聚物或接枝共聚物，其包含a）至少一种由95至100重量％的乙烯基芳族单体和0至5重量％的二烯，和b）至少一种由63至80重量％的乙烯基芳族单体和20至37重量％的二烯组成的共聚物嵌段（S / B）A，玻璃化转变温度TgA为5 至30℃，其中基于嵌段共聚物或接枝共聚物，所有嵌段S的总重量的比例为50至70重量％，以及它们的混合物及其用途。

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