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    • 2. 发明申请
    • TRANSPARENT, TOUGH AND RIGID MOLDING COMPOSITIONS BASED ON STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES
    • 基于苯乙烯 - 丁二烯嵌段共聚物混合物的透明,粗糙和刚性成型组合物
    • US20100304067A1
    • 2010-12-02
    • US12677960
    • 2008-09-03
    • Konrad KnollJürgen KochPiyada CharoensirisomboonDaniel Wagner
    • Konrad KnollJürgen KochPiyada CharoensirisomboonDaniel Wagner
    • C08L53/02B32B3/12B32B1/08
    • C08L25/06C08K5/0016C08L25/10C08L53/02C08L2205/02C08L2205/035C08L2666/24C08L2666/02
    • A mixture which comprises a) from 95 to 30% by weight of a copolymer or block copolymer A comprising one or more copolymer blocks (B/S)A which are respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., b) from 5 to 45% by weight of a block copolymer B comprising at least one hard block S which is composed of vinylaromatic monomers, and comprising one or more copolymer blocks (B/S)B which are respectively composed of from 20 to 60% by weight of vinylaromatic monomers and of from 80 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −70° to 0° C., c) from 0 to 40% by weight of polystyrene C, and d) from 0 to 30% by weight of a block copolymer D comprising at least one copolymer block (B/S)A which is respectively composed of from 65 to 95% by weight of vinylaromatic monomers and of from 35 to 5% by weight of dienes, and whose glass transition temperature TgA is in the range from 40° to 90° C., and comprising at least one diene block B or one copolymer block (B/S)B which is respectively composed of from 1 to 60% by weight of vinylaromatic monomers and of from 99 to 40% by weight of dienes, and whose glass transition temperature TgB is in the range from −100° to 0° C., e) from 0 to 6% by weight of a plastifying agent, and its use for the production of packaging for electronics components.
    • 包含a)95至30重量%的共聚物或嵌段共聚物A,其包含一种或多种共聚物嵌段(B / S)A,其分别由65至95重量%的乙烯基芳族单体和 35〜5重量%的二烯,玻璃化转变温度TgA在40℃〜90℃的范围内,b)5〜45重量%的嵌段共聚物B,其包含至少一个硬嵌段S, 由乙烯基芳族单体组成,并且包含一种或多种共聚物嵌段(B / S)B,其分别由20至60重量%的乙烯基芳族单体和80至40重量%的二烯组成,并且其玻璃化转变 温度TgB在-70℃至0℃的范围内,c)0至40重量%的聚苯乙烯C,以及d)0至30重量%的嵌段共聚物D,其包含至少一个共聚物嵌段 (B / S)A,其分别由65至95重量%的乙烯基芳族单体和35至5重量%的重量 并且其玻璃化转变温度TgA在40℃至90℃的范围内,并且包含至少一个二烯嵌段B或一个共聚物嵌段(B / S)B,其分别由1至60个 乙烯基芳族单体的重量百分比和99至40重量%的二烯,其玻璃化转变温度TgB在-100℃至0℃的范围内,e)0至6重量%的塑化 代理商及其用于生产电子元件包装的用途。
    • 6. 发明授权
    • Highly transparent and tough-stiff styrene-butadiene block copolymer mixtures
    • 高度透明和坚韧的苯乙烯 - 丁二烯嵌段共聚物混合物
    • US08217104B2
    • 2012-07-10
    • US12306258
    • 2007-06-13
    • Jennifer StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • Jennifer StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • C08F293/00C08F295/00C08F297/04C08L53/00C08L53/02
    • C08F297/044C08F297/04C08L53/02C08L2205/025C08L2205/03C08L2666/02C08L2666/24C08L25/06
    • A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
    • 一种混合物,其包含a)25至75重量%的嵌段共聚物A,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种软块BA,每种情况由0至5重量% 的乙烯基芳族单体和95〜100重量%的二烯,其中嵌段共聚物A中的硬质块S的重量比为65〜90重量% b)5至25重量%的嵌段共聚物B,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种共聚物嵌段(B / S)B,每种情况下由20至60%由 乙烯基芳族单体的重量和80〜40重量%的二烯,其中嵌段共聚物B中的硬质块S的重量比为25〜70重量% c)0至70重量%的聚苯乙烯或除A和B之外的嵌段共聚物C,以及d)0至6重量%的增塑剂D,其中组分A)至D)的总量为100 重量%,用于透明热成型箔或透明注塑件。
    • 7. 发明授权
    • Transparent mixtures of linear styrene-butadiene block copolymers
    • 线性苯乙烯 - 丁二烯嵌段共聚物的透明混合物
    • US07470746B2
    • 2008-12-30
    • US11297470
    • 2005-12-09
    • Konrad KnollDaniel WagnerJürgen KochPeter Merkel
    • Konrad KnollDaniel WagnerJürgen KochPeter Merkel
    • C08L53/02
    • C08L53/025C08F297/04C08L51/003C08L53/02C08L2666/24C08L2666/02C08L53/00
    • Mixtures comprising linear block copolymers composed of vinylaromatic monomers and dienes of the structure (I) S1-B1-S2 and (II) B2-S3, where S1 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 40 000 to 100 000 g/mol, each of S2 and S3 is a block composed of vinylaromatic monomers whose number-average molar mass Mn is in the range from 5000 to 20 000 g/mol, each of B1 and B2 is one or more blocks composed of dienes or is copolymer blocks composed of dienes and vinylaromatic monomers whose number-average molar mass Mn is in the range from 15 000 to 100 000 g/mol, and the ratio of block copolymers (I)/(II) is in the range from 0.5 to 10, and their use for impact-modification of blends using polystyrene.
    • 包含由乙烯基芳族单体和结构(I)S1-B1-S2和(II)B2-S3组成的二烯的线性嵌段共聚物的混合物,其中S1是由数均摩尔质量Mn在该范围内的乙烯基芳族单体组成的嵌段 从40000至100000g / mol,S2和S3各自为数均摩尔质量Mn为5000〜200000g / mol的乙烯基芳族单体的组成,B1和B2各为1或 由二烯构成的更多嵌段或由二烯和乙烯基芳族单体组成的共聚物嵌段,其数均摩尔质量Mn在15000至100000g / mol的范围内,嵌段共聚物(I)/(II)的比例为 在0.5至10的范围内,以及它们用于使用聚苯乙烯的共混物的冲击改性的用途。
    • 8. 发明申请
    • HIGHLY TRANSPARENT AND TOUGH-STIFF STYRENE-BUTADIENE BLOCK COPOLYMER MIXTURES
    • 高透明度和韧性苯乙烯 - 丁二烯嵌段共聚物混合物
    • US20090286918A1
    • 2009-11-19
    • US12306258
    • 2007-06-13
    • Jennifer R. StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • Jennifer R. StewartPeter MerkelDaniel WagnerKonrad KnollJürgen Koch
    • C08L53/02
    • C08F297/044C08F297/04C08L53/02C08L2205/025C08L2205/03C08L2666/02C08L2666/24C08L25/06
    • A mixture which comprises a) from 25 to 75% by weight of a block copolymer A which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more soft blocks BA in each case composed of from 0 to 5% by weight of vinylaromatic monomers and from 95 to 100% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer A is from 65 to 90% by weight; b) from 5 to 25% by weight of a block copolymer B which comprises at least one hard block S composed of vinylaromatic monomers and comprises one or more copolymer blocks (B/S)B in each case composed of from 20 to 60% by weight of vinylaromatic monomers and from 80 to 40% by weight of dienes, where the proportion by weight of the hard blocks S in the block copolymer B is from 25 to 70% by weight; c) from 0 to 70% by weight of polystyrene or of a block copolymer C other than A and B, and d) from 0 to 6% by weight of a plasticizer D, where the entirety of components A) to D) gives 100% by weight, and use for transparent thermoforming foils or transparent injection-molded items.
    • 一种混合物,其包含a)25至75重量%的嵌段共聚物A,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种软块BA,每种情况由0至5重量% 的乙烯基芳族单体和95〜100重量%的二烯,其中嵌段共聚物A中的硬质块S的重量比为65〜90重量% b)5至25重量%的嵌段共聚物B,其包含至少一种由乙烯基芳族单体组成的硬质块S,并且包含一种或多种共聚物嵌段(B / S)B,每种情况下由20至60%由 乙烯基芳族单体的重量和80〜40重量%的二烯,其中嵌段共聚物B中的硬质块S的重量比为25〜70重量% c)0至70重量%的聚苯乙烯或除A和B之外的嵌段共聚物C,以及d)0至6重量%的增塑剂D,其中组分A)至D)的总量为100 重量%,用于透明热成型箔或透明注塑件。
    • 9. 发明授权
    • Thermoplastic linoleum
    • 热塑性油毡
    • US08466215B2
    • 2013-06-18
    • US12747369
    • 2008-12-11
    • Konrad KnollMichel PepersPeter WolfPiyada Charoensirisomboon
    • Konrad KnollMichel PepersPeter WolfPiyada Charoensirisomboon
    • C08K9/00C09B67/00
    • D06N1/00
    • The present invention relates to a thermoplastic molding composition comprising (A) as component A, particles composed of at least one oxidatively crosslinked vegetable oil as core, encapsulated by at least one thermoplastic, (B) as component B, at least one further thermoplastic compatible with the at least one thermoplastic present in the shell of component A, (C) as component C, at least one resin compatible with the at least one thermoplastic present in the shell of component A, (D) as component D, at least one filler, and (E) as component E, if appropriate, further additives, and also to a process for the production of the thermoplastic molding composition.
    • 本发明涉及一种热塑性模塑组合物,其包含(A)作为组分A,由至少一种氧化交联的植物油作为芯组成的颗粒,由至少一种热塑性塑料包封,(B)作为组分B,至少一种另外的热塑性相容性 存在于组分A的外壳中的至少一种热塑性材料(C)作为组分C,至少一种与组分A壳体中存在的至少一种热塑性塑料相容的树脂,(D)作为组分D,至少一种 填充剂和(E)作为组分E,如果合适的话,还可以使用其它添加剂,以及制备热塑性模塑组合物的方法。
    • 10. 发明授权
    • Tough and rigid mixtures of alpha-methylstyrene-acrylnitrile copolymers and of block copolymers
    • α-甲基苯乙烯 - 丙烯腈共聚物和嵌段共聚物的韧性和刚性混合物
    • US08158722B2
    • 2012-04-17
    • US12921043
    • 2009-03-04
    • Konrad KnollKoch JürgenPiyada Charoensirisomboon
    • Konrad KnollKoch JürgenPiyada Charoensirisomboon
    • B32B1/08C08L53/02
    • C08L25/16C08F297/02C08F297/04C08L25/06C08L53/00C08L53/02C08L2205/02Y10T428/139C08L2666/02C08L2666/04C08L2666/06
    • Composition comprising at least one copolymer A composed of at least one alkylated styrene, of acrylonitrile, and, if appropriate, of at least one further monomer, at least one block copolymer B which has at least one block forming a hard phase and composed of at least one vinylaromatic monomer and has at least one block forming a soft phase and composed of at least one vinylaromatic monomer and of at least one diene, and at least one further copolymer C, and, if appropriate, one polymer D, where the copolymer C is at least one triblock copolymer composed of a first block composed of at least one vinylaromatic monomer, of a second block composed of at least one diene, and of a third block composed of at least one methyl methacrylate monomer, or comprising at least 50% by weight of methyl methacrylate, and the polymer D is at least one styrene polymer selected from glass-clear and impact-resistant polystyrene. The present invention moreover relates to a process for the preparation of the inventive compositions, to the use of the inventive compositions for the production of moldings, of foils, of fibers, or of foams, to moldings, foils, fibers, or foams comprising the inventive composition, and also to the use of the inventive composition as packaging for electronic components, such as integrated circuits (microchips) (“electronic packing”), for applications in chemical engineering, in household products, in bathroom items, e.g. toothbrush tumblers, cosmetics holders, etc., as housings, as tubes, as profiles, for medical items or medical devices, and in toys.
    • 组合物,其包含至少一种由至少一种烷基化苯乙烯,丙烯腈和(如果合适的话)至少一种另外的单体组成的共聚物A,至少一种嵌段共聚物B,其具有至少一个形成硬相的嵌段, 至少一种乙烯基芳族单体,并且具有至少一个形成软相并由至少一种乙烯基芳族单体和至少一种二烯构成的嵌段和至少一种其它共聚物C,以及如果合适的话,一种聚合物D,其中共聚物C 是由至少一种乙烯基芳族单体组成的第一嵌段,至少由一种二烯构成的第二嵌段和由至少一种甲基丙烯酸甲酯单体组成的第三嵌段或至少包含至少50% 的甲基丙烯酸甲酯,聚合物D是选自玻璃透明和耐冲击聚苯乙烯的至少一种苯乙烯聚合物。 本发明还涉及制备本发明组合物的方法,本发明组合物用于生产模制品,箔,纤维或泡沫的用途,用于模制品,箔,纤维或泡沫,其包括 本发明的组合物,以及本发明组合物用作电子部件的包装,例如集成电路(微芯片)(“电子包装”),用于化学工程,家用产品,浴室用品中的应用,例如 牙刷滚筒,化妆品保持器等,作为外壳,作为管,用作医疗用品或医疗装置的型材,以及玩具。