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1. 发明申请

US20120220678A1 THERMOPLASTIC COMPOSITIONS HAVING IMPROVED FLOWABILITY 审中-公开
标题翻译：具有改善流动性的热塑性组合物
公开(公告)号：US20120220678A1
公开(公告)日：2012-08-30
申请号：US13505966
申请日：2010-11-02
申请人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
发明人： Christof Mehler , Rolf Minkwitz , Christian Schade , Piyada Charoensirisomboon , Norbert Niessner , Kyung Ho Shon
IPC分类号： C08K5/12 , C08J9/22 , C08L55/02
CPC分类号： C08L55/02 , C08K5/12 , C08K5/1539 , C08K2201/014 , C08L25/12 , D01F6/56 , C08L2666/04
摘要： The present invention relates to compositions comprising (i) as component (I), at least one molding composition comprising components A and B, where A) is a graft copolymer as component A, and B) is a thermoplastic copolymer as component B; and (ii) at least one cyclohexanepolycarboxylic acid derivative of the formula (I); as component (II) in which R1 is C1-C10-alkyl or C3-C8-cycloalkyl, m is 0, 1, 2, or 3, n is 2, 3, or 4, and R is hydrogen or C1-C30-alkyl; or the group —(COOR)n forms an anhydride of the formula where it is essential to the invention that component (I) comprises from 11 to 19.9% by weight of component A and from 80.1 to 89% by weight of component B, where each of the % by weight values is based on the entirety of components A and B, and the total of those values is 100% by weight, and also to a process for producing the composition of the invention, to the use of the composition of the invention for producing moldings, foils, foams, or fibers, and to moldings, foils, foams, or fibers comprising the composition of the invention.
摘要翻译：本发明涉及包含（i）组分（I）的组合物，至少一种包含组分A和B的模塑组合物，其中A）是作为组分A的接枝共聚物，B）是作为组分B的热塑性共聚物; 和（ii）至少一种式（I）的环己烷多羧酸衍生物; 作为其中R 1为C 1 -C 10 - 烷基或C 3 -C 8 - 环烷基的组分（II），m为0,1,2或3，n为2,3或4，并且R为氢或C 1 -C 30 - 烷基; 或（COOR）基团形成下式的酸酐，其中组分（I）占组分A的11至19.9重量％和组分B的80.1至89重量％是本发明必需的，其中每个重量百分比值基于组分A和B的全部，并且这些值的总和为100重量％，并且还涉及制备本发明组合物的方法，使用组合物用于生产模制品，箔，泡沫或纤维的本发明以及包含本发明组合物的模制品，箔，泡沫或纤维。

2. 发明申请

US20140329100A1 THERMOPLASTIC MOULDING COMPOSITIONS FOR METAL PLATED ARTICLES WITH IMPROVED RESISTANCE AGAINST REPEATED IMPACT 有权
标题翻译：用于金属制品的热塑性成型组合物具有改善的抗重复性影响的电阻
公开(公告)号：US20140329100A1
公开(公告)日：2014-11-06
申请号：US13992602
申请日：2011-12-15
申请人： Michel Pepers , Christian Schade , Davy Roger Suwier , Norbert Niessner
发明人： Michel Pepers , Christian Schade , Davy Roger Suwier , Norbert Niessner
IPC分类号： C08L25/12 , C23C18/31 , C23C18/16
CPC分类号： C08L25/12 , C08L9/00 , C08L21/00 , C08L25/10 , C08L51/00 , C08L55/02 , C08L2205/02 , C08L2205/03 , C08L2207/04 , C23C18/1601 , C23C18/1641 , C23C18/31 , C25D5/14 , C25D5/56 , Y10T428/31696
摘要： Thermoplastic moulding composition (F), comprising: A) from 5 to 80% by weight of a graft polymer (A) having bimodal particle size distribution and a moisture content of 0 to 27% by weight, made, based on (A), a1) from 40 to 90% by weight of an elastomeric particulate graft base (a1), obtained by emulsion polymerization of based on (a1), a11) from 70 to 100% by weight of at least one conjugated diene, or of at least one C1-8-alkyl acrylate, or of mixtures of these, a12) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer and a13) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; a2) from 10 to 60% by weight of a graft a2), made, based on a2), a21) from 64 to 76% by weight of at least one vinyl aromatic monomer, a22) from 24 to 36% by weight of acrylonitrile, a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a24) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; B) from 10 to 94% by weight of a thermoplastic polymer (B) having a viscosity number VN of from 50 to 120 ml/g, made, based on (B), b1) from 64 to 72% by weight of at least one vinyl aromatic monomer, b2) from 28 to 36% by weight of acrylonitrile, and b3) from 0 to 4% by weight of at least one other monoethylenically unsaturated monomer; whereby, the difference of the acrylonitrile content in component (B) and that in the graft shell a2) is minimal 2% by weight and maximal 6% by weight and optionally further components, have preferred optical appearance when coated with metal.
摘要翻译：热塑性成型组合物（F），其包含：A）5-80重量％的具有双峰粒径分布的接枝聚合物（A）和0-27重量％的水分含量，基于（A）， a1）40〜90重量％的通过基于（a1），a11）的乳液聚合获得的弹性体颗粒接枝基质（a1），70〜100重量％的至少一种共轭二烯，或至少一种C 1-8 - 烷基丙烯酸酯，或它们的混合物，a12）0至30重量％的至少一种其它单烯属不饱和单体和（ⅰ）0至10重量％的至少一种多官能交联单体 ; a2）10至60重量％的基于a2）制备的接枝物a2），a21）64至76重量％的至少一种乙烯基芳族单体，a22）24至36重量％的丙烯腈，a23）0至30重量％的至少一种其它单烯属不饱和单体，以及a24）0至10重量％的至少一种多官能交联单体; B）10至94重量％的基于（B），b1）的粘度VN为50至120ml / g的热塑性聚合物（B），至少64至72重量％一种乙烯基芳族单体，b2）28-36重量％的丙烯腈，和b3）0-4重量％的至少一种其它单烯属不饱和单体; 由此，组分（B）中的丙烯腈含量与接枝壳a2）中的丙烯腈含量的差异最小为2重量％，最多6重量％，任选的其它组分在涂覆金属时具有优选的光学外观。

3. 发明授权

US09650506B2 Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact 有权
公开(公告)号：US09650506B2
公开(公告)日：2017-05-16
申请号：US13992602
申请日：2011-12-15
申请人： Michel Pepers , Christian Schade , Davy Roger Suwier , Norbert Niessner
发明人： Michel Pepers , Christian Schade , Davy Roger Suwier , Norbert Niessner
IPC分类号： C08L51/00 , C08L25/12 , C23C18/16 , C08L25/10 , C08L21/00 , C08L55/02 , C25D5/56 , C23C18/31 , C08L9/00 , C25D5/14
CPC分类号： C08L25/12 , C08L9/00 , C08L21/00 , C08L25/10 , C08L51/00 , C08L55/02 , C08L2205/02 , C08L2205/03 , C08L2207/04 , C23C18/1601 , C23C18/1641 , C23C18/31 , C25D5/14 , C25D5/56 , Y10T428/31696
摘要： Thermoplastic moulding composition (F), comprising: A) from 5 to 80% by weight of a graft polymer (A) having bimodal particle size distribution and a moisture content of 0 to 27% by weight, made, based on (A), a1) from 40 to 90% by weight of an elastomeric particulate graft base (a1), obtained by emulsion polymerization of, based on (a1), a11) from 70 to 100% by weight of at least one conjugated diene, or of at least one C1-8-alkyl acrylate, or of mixtures of these, a12) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer and a13) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; a2) from 10 to 60% by weight of a graft a2), made, based on a2), a21) from 64 to 76% by weight of at least one vinyl aromatic monomer, a22) from 24 to 36% by weight of acrylonitrile, a23) from 0 to 30% by weight of at least one other monoethylenically unsaturated monomer, and a24) from 0 to 10% by weight of at least one polyfunctional, cross linking monomer; B) from 10 to 94% by weight of a thermoplastic polymer (B) having a viscosity number VN of from 50 to 120 ml/g, made, based on (B), b1) from 64 to 72% by weight of at least one vinyl aromatic monomer, b2) from 28 to 36% by weight of acrylonitrile, and b3) from 0 to 4% by weight of at least one other monoethylenically unsaturated monomer; whereby, the difference of the acrylonitrile content in component (B) and that in the graft shell a2) is minimal 2% by weight and maximal 6% by weight and optionally further components, have preferred optical appearance when coated with metal.

4. 发明申请

US20120080120A1 METHOD FOR PASSIVATING A METALLIC SURFACE 审中-公开
标题翻译：用于钝化金属表面的方法
公开(公告)号：US20120080120A1
公开(公告)日：2012-04-05
申请号：US13251672
申请日：2011-10-03
申请人： Achim Feßenbecker , Jens Haas , Frank Richter , Walter Bertkau , Christian Schade , Helmut Witteler
发明人： Achim Feßenbecker , Jens Haas , Frank Richter , Walter Bertkau , Christian Schade , Helmut Witteler
IPC分类号： C23C22/48 , B32B15/08 , C09D139/02 , C09D143/02 , C09D139/04 , C23C22/50 , C09D7/12
CPC分类号： C09D5/12 , C09D133/02
摘要： The present invention relates to a method for passivating metallic surfaces, wherein the metal surface is contacted with an aqueous composition comprising at least one water-soluble polymer (X) comprising acidic groups and with at least one polyamine (P), the pH of the composition being in the range from 0.5 to 2.
摘要翻译：本发明涉及一种钝化金属表面的方法，其中金属表面与包含至少一种包含酸性基团和至少一种多胺（P）的至少一种水溶性聚合物（X）的水性组合物接触，组合物在0.5至2的范围内。

5. 发明申请

US20110226723A1 HOLLOW BODY WITH IMPROVED BARRIER ACTION 审中-公开
标题翻译：带有改进障碍物的中空身体
公开(公告)号：US20110226723A1
公开(公告)日：2011-09-22
申请号：US13048352
申请日：2011-03-15
申请人： Christian Schade , Hans-Jürgen Renner , Stefan Burgdörfer , Klaus Wendel
发明人： Christian Schade , Hans-Jürgen Renner , Stefan Burgdörfer , Klaus Wendel
IPC分类号： B65D90/02 , B32B25/16 , B32B1/02 , B29C49/06
CPC分类号： B32B27/08 , B29B11/08 , B29B11/14 , B29B2911/14053 , B29B2911/14066 , B29B2911/1408 , B29B2911/14093 , B29B2911/14113 , B29B2911/1412 , B29B2911/1414 , B29B2911/14146 , B29B2911/14666 , B29B2911/1498 , B29C49/06 , B29K2009/06 , B29K2023/0633 , B29K2023/065 , B29K2023/12 , B29K2025/00 , B29K2995/0067 , B29L2031/7158 , B32B25/16 , B32B27/30 , B32B27/302 , B32B27/32 , B32B2274/00 , B32B2307/50 , B32B2307/514 , B32B2307/54 , B32B2307/7246 , B32B2307/75 , B32B2439/40 , B32B2439/70 , B65D1/0215 , Y10T428/1379
摘要： The present invention relates to hollow bodies with improved barrier action, where the hollow bodies are composed of a three-layer sandwich structure with a shell made of polystyrene and with a middle layer as vapor barrier.
摘要翻译：本发明涉及具有改进的屏障作用的中空体，其中中空体由具有由聚苯乙烯制成的壳体和中间层作为阻气层的三层夹心结构构成。

6. 发明申请

US20100168348A1 ANIONIC SPRAY POLYMERIZATION OF STYRENE 审中-公开
标题翻译：苯乙烯的阴离子喷涂聚合
公开(公告)号：US20100168348A1
公开(公告)日：2010-07-01
申请号：US12063166
申请日：2006-08-01
申请人： Wolfgang Loth , Volker Seidl , Stefan Bruhns , Klaus-Dieter Hungenberg , Juergen Koch , Christian Schade , Claudius Schwittay
发明人： Wolfgang Loth , Volker Seidl , Stefan Bruhns , Klaus-Dieter Hungenberg , Juergen Koch , Christian Schade , Claudius Schwittay
IPC分类号： C08L25/06 , C08F2/00
CPC分类号： C08F112/08 , C08F2/00
摘要： The invention relates to a process for continuously preparing styrene polymers by anionic spray polymerization, which comprises i) styrene and the initiator solution being mixed in a dynamic or static mixer and then the mixture being sprayed, ii) the resultant droplets passing from the liquid monomer state to the melted polymer state during their free fall in the spraying tower, iii) the melt droplets being collected as a melt at the foot of the tower, the melt having a monomer content of below 1%, preferably below 0.1% (
摘要翻译：本发明涉及通过阴离子喷雾聚合连续制备苯乙烯聚合物的方法，该方法包括i）苯乙烯和引发剂溶液在动态或静态混合器中混合，然后混合物喷雾，ii）从液体单体在熔融聚合物状态下在熔融聚合物状态下自由落体在喷雾塔中，iii）熔体液滴在塔的底部作为熔体收集，熔体的单体含量低于1％，优选低于0.1％（<1000 ppm），并通过合适的方式排出。

7. 发明授权

US06444767B1 Method for retarded anionic polymerization 失效
标题翻译：延迟阴离子聚合法
公开(公告)号：US06444767B1
公开(公告)日：2002-09-03
申请号：US09622174
申请日：2000-08-14
申请人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Rainer Klostermann , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
发明人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Rainer Klostermann , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
IPC分类号： C08F452
CPC分类号： C08F12/04 , C08F236/10 , C08F4/52
摘要： In a process for the homopolymerization of vinylaromatic monomers or the copolymerization of vinylaromatic monomers and dienes, the monomers are polymerized in the presence of at least one alkali metal organyl, at least one magnesium organyl and at least one aluminum organyl. The invention also provides an initiator composition for carrying out the process.
摘要翻译：在乙烯基芳族单体的均聚或乙烯基芳族单体和二烯的共聚合的方法中，单体在至少一种碱金属有机基团，至少一种镁有机基团和至少一种铝有机基团的存在下聚合。本发明还提供了用于进行该方法的引发剂组合物。

8. 发明授权

US06329483B1 Copolymers of carboxylic acids and quaternary ammonium compounds and the use thereof as thickeners of dispersants 失效
标题翻译：羧酸和季铵化合物的共聚物及其作为分散剂增稠剂的用途
公开(公告)号：US06329483B1
公开(公告)日：2001-12-11
申请号：US08313175
申请日：1994-09-29
申请人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
发明人： Christian Schade , Axel Sanner , Hans-Ulrich Wekel , Franz Frosch , Horst Westenfelder
IPC分类号： C08F22204
CPC分类号： A61Q19/00 , A61K8/817 , A61K2800/48 , C08F220/04 , C08F222/00
摘要： A copolymer obtainable by free-radical polymerization of A) 50-99.99% by weight of an olefinically unsaturated C3-C5 monocarboxylic acid, of an olefinically unsaturated C4-C8 dicarboxylic acid or the anhydride thereof or a mixture of such carboxylic acids or anhydrides with B) 0.01-50% by weight of an olefinically unsaturated quaternary ammonium compound of the formula I or II where R1 is C6-C20-alkyl, C6-C20-alkenyl, C5-C8-cycloalkyl, phenyl, phenyl(C1-C12-alkyl) or (C1-C12-alkyl)phenyl, R2 is hydrogen, methyl or phenyl, R3 and R4 are each H or C1-C4-alkyl, X is halogen, C1-C4-alkoxysulfonyloxy or C1-C4-alkanesulfonate, it also being possible for the latter to occur as R3 or R4 with the formation of a betaine structure, Y is O or NH, and A is C1-C6-alkylene, or a mixture of such ammonium compounds, C) 0 to 49.99% by weight of an acrylate or methacrylate of the formula III where R1, R2 and Y have the abovementioned meanings, R5 is hydrogen, methyl or ethyl, and n is a number from 0 to 25, D) 0-49.99% by weight of other copolymerizable monomers and E) 0-5% by weight of one or more compounds with at least two olefinically unsaturated groups in the molecule as crosslinker. The copolymers are suitable as thickeners and dispersants, especially in cosmetic compositions.
摘要翻译：可通过自由基聚合得到的共聚物，A）50-99.99重量％的烯属不饱和C 3 -C 5单羧酸，烯属不饱和C 4 -C 8二羧酸或其酸酐或这些羧酸或酸酐与B）的混合物， 0.01-50重量％的式I或II的烯属不饱和季铵化合物，其中R 1是C 6 -C 20 - 烷基，C 6 -C 20 - 烯基，C 5 -C 8 - 环烷基，苯基，苯基（C 1 -C 12 - 烷基）或（C 1 -C 12 - 烷基）苯基，R 2是氢，甲基或苯基，R 3和R 4各自为H或C 1 -C 4烷基，X为卤素，C 1 -C 4烷氧基磺酰氧基或C 1 -C 4烷基磺酸盐，也是可能的后者以R3或R4形成甜菜碱结构，Y为O或NH，A为C 1 -C 6亚烷基，或这些铵化合物的混合物，C）0至49.99重量％的丙烯酸酯或甲基丙烯酸酯，其中R 1，R 2和Y具有上述含义，R 5是氢，甲基或乙基，n是0至25的数，D）0-4 9.99重量％的其它可共聚单体和E）0-5重量％的一种或多种在分子中具有至少两个烯属不饱和基团的化合物作为交联剂。该共聚物适合用作增稠剂和分散剂，特别是在化妆品组合物中。

9. 发明授权

US06303721B1 Process for producing diene polymer solutions in vinyl aromatic monomers 失效
标题翻译：在乙烯基芳族单体中生产二烯聚合物溶液的方法
公开(公告)号：US06303721B1
公开(公告)日：2001-10-16
申请号：US09242466
申请日：1999-02-17
申请人： Stefan Lätsch , Wolfgang Fischer , Hermann Gausepohl , Volker Warzelhan , Christian Schade
发明人： Stefan Lätsch , Wolfgang Fischer , Hermann Gausepohl , Volker Warzelhan , Christian Schade
IPC分类号： C08F452
CPC分类号： C08F297/04 , C08F4/44 , C08F4/50 , C08F12/04 , C08F12/08 , C08F36/04 , C08F4/46 , C08F4/52 , C08F4/54 , C08F4/48
摘要： The anionic polymerization of dienes or copolymers of dienes and vinylaromatic monomers in a vinylaromatic monomer or monomer mixture to give homopolydienes or copolymers or mixed homopolydienes and copolymers is carried out in the presence of a metal alkyl or aryl of an element having a valence of at least two without addition of Lewis bases.
摘要翻译：二烯或二烯和乙烯基芳族单体在乙烯基芳族单体或单体混合物中的共聚物的阴离子聚合，以得到均聚二烯或共聚物或混合的均聚二烯和共聚物，在至少具有至少一个化合价的元素的金属烷基或芳基的存在下进行两个没有添加路易斯碱基。

10. 发明授权

US06300441B1 Method for the production of an initiator composition for retarded anionic polymerization 失效
标题翻译：用于制备用于延迟阴离子聚合的引发剂组合物的方法
公开(公告)号：US06300441B1
公开(公告)日：2001-10-09
申请号：US09622171
申请日：2000-08-14
申请人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Stephan Jüngling , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
发明人： Christian Schade , Wolfgang Fischer , Hermann Gausepohl , Stephan Jüngling , Volker Warzelhan , Michel Fontanille , Alain Deffieux , Philippe Desbois
IPC分类号： C08F452
CPC分类号： C08F4/46
摘要： Disclosed are a process for the preparation of an initiator composition comprising an alkali metal organyl and an aluminum organyl and a process for the polymerization of anionically polymerizable monomers.
摘要翻译：公开了一种制备包含碱金属有机基和铝有机基团的引发剂组合物的方法和用于聚合阴离子聚合单体的方法。

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