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    • 1. 发明授权
    • Low temperature method to form low k dielectric
    • 低温方法形成低k电介质
    • US06197706B1
    • 2001-03-06
    • US09607042
    • 2000-06-30
    • Lain-Jang LiCheng-Chung LinSyun-Ming Jang
    • Lain-Jang LiCheng-Chung LinSyun-Ming Jang
    • H01L2131
    • H01L21/3146
    • Black diamond films, deposited using PECVD at low substrate temperatures, have been effectively stabilized by immersing them in de-ionized water at a temperature of about 90° C. for about 20 minutes or in a hydrogen peroxide solution (typically at a concentration of 10%) for about 60 minutes. Since it has been observed that the dielectric constant of the stabilized film increases with both immersion time and/or peroxide concentration, this effect may be used as a means for adjusting the dielectric constant of a black diamond film. Standard analytical techniques confirm that these low temperature stabilized films have electrical properties that are at least as good as those of films stabilized using high temperature heat treatments.
    • 通过在约90℃的温度下将它们浸入去离子水中约20分钟或在过氧化氢溶液中(通常浓度为10),已经有效地稳定了在低基材温度下使用PECVD沉积的黑色金刚石膜 %)约60分钟。 由于已经观察到稳定的膜的介电常数随着浸渍时间和/或过氧化物浓度的增加而增加,所以该效果可以用作调整黑色金刚石膜的介电常数的手段。 标准分析技术证实这些低温稳定膜的电性能至少与使用高温热处理稳定的膜的电性能一样好。
    • 2. 发明授权
    • Soft plasma oxidizing plasma method for forming carbon doped silicon containing dielectric layer with enhanced adhesive properties
    • 软等离子体氧化等离子体法,用于形成具有增强的粘合性质的含碳掺杂的含硅介电层
    • US06407013B1
    • 2002-06-18
    • US09761422
    • 2001-01-16
    • Lain-Jong LiTien-I BaoCheng-Chung LinSyun-Ming Jang
    • Lain-Jong LiTien-I BaoCheng-Chung LinSyun-Ming Jang
    • H01L2131
    • H01L21/3105H01L21/76826H01L21/76829
    • Within a method for forming a dielectric layer within a microelectronic fabrication there is first provided a substrate. There is then formed over the substrate a carbon doped silicon containing dielectric layer. There is then treated the carbon doped silicon containing dielectric layer with an oxidizing plasma to form from the carbon doped silicon containing dielectric layer an oxidizing plasma treated carbon doped silicon containing dielectric layer. By treating the carbon doped silicon containing dielectric layer with the oxidizing plasma, particularly under mild conditions, to form therefrom the oxidizing plasma treated carbon doped silicon containing dielectric layer, adhesion of an additional microelectronic layer upon the oxidizing plasma treated carbon doped silicon containing dielectric layer is enhanced in comparison with adhesion of the additional microelectronic layer upon the carbon doped silicon containing dielectric layer, while not compromising dielectric properties of the carbon doped silicon containing dielectric layer.
    • 在微电子制造中形成电介质层的方法中,首先提供衬底。 然后在衬底上形成含碳掺杂的含硅电介质层。 然后用具有氧化等离子体的碳掺杂的含硅介电层处理从含碳掺杂的含硅介电层形成氧化等离子体处理的含碳的含硅介电层。 通过用氧化等离子体处理含碳掺杂的含硅电介质层,特别是在温和条件下由其形成氧化等离子体处理的含碳硅的介电层,附加的微电子层与氧化等离子体处理的碳掺杂的含硅介电层 与附加的微电子层对含碳的含硅介电层的粘附性相比增强,同时不损害含碳掺杂的含硅介电层的介电性质。