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    • 1. 发明授权
    • Process for producing aromatic polycarbonate
    • 制备芳香族聚碳酸酯的方法
    • US06320015B1
    • 2001-11-20
    • US09674435
    • 2000-11-01
    • Kyosuke KomiyaShinsuke FukuokaMuneaki AminakaKazumi Hasegawa
    • Kyosuke KomiyaShinsuke FukuokaMuneaki AminakaKazumi Hasegawa
    • C08G6400
    • C08G64/307
    • Disclosed is a method for producing an aromatic polycarbonate, which comprises treating a molten aromatic polycarbonate prepolymer (obtained by reacting an aromatic dihydroxy compound with a diaryl carbonate) with an inert gas under a predetermined pressure to thereby cause the molten prepolymer to absorb the inert gas, and subjecting the resultant molten prepolymer having the inert gas absorbed therein to polymerization, under a pressure lower than the above-mentioned predetermined pressure employed for the inert gas absorption, to thereby polymerize the prepolymer to a predetermined degree of polymerization. By the method of the present invention, a high quality aromatic polycarbonate which is colorless and has excellent mechanical properties can be produced at high polymerization rate even without using a large amount of an inert gas. Further, even if the production of an aromatic polycarbonate is conducted in a continuous manner, the molecular weight of the produced aromatic polycarbonate can be maintained at a desired level, so that the high quality polycarbonate can be stably produced for a prolonged period of time. Therefore, the method of the present invention is commercially very advantageous.
    • 公开了一种芳族聚碳酸酯的制造方法,其包括将熔融芳族聚碳酸酯预聚物(通过芳香族二羟基化合物与碳酸二芳基酯反应得到)与惰性气体在规定压力下进行处理,使熔融预聚物吸收惰性气体 并且在低于上述用于惰性气体吸收的预定压力的压力下,将其中吸收有惰性气体的所得熔融预聚物进行聚合,从而将预聚物聚合至预定聚合度。 通过本发明的方法,即使不使用大量的惰性气体,也可以高聚合速度生产无色且机械性能优异的高品质芳族聚碳酸酯。 此外,即使以连续的方式进行芳族聚碳酸酯的制造,也可以将所制造的芳香族聚碳酸酯的分子量保持在期望的水平,从而能够长时间稳定地制造高品质的聚碳酸酯。 因此,本发明的方法在商业上非常有利。
    • 2. 发明授权
    • Method for producing an aromatic polycarbonate
    • 芳香族聚碳酸酯的制造方法
    • US5912318A
    • 1999-06-15
    • US54506
    • 1998-04-03
    • Kazumi HasegawaKyosuke KomiyaMuneaki Aminaka
    • Kazumi HasegawaKyosuke KomiyaMuneaki Aminaka
    • C08G64/20C08G64/30C08G64/00
    • C08G64/307C08G64/205
    • A method for producing an aromatic polycarbonate which comprises subjecting to a transesterification polymerization reaction at least one polymerizable material for an aromatic polycarbonate, the transesterification reaction being performed in one or more polymerizers which is or are connected through a pipeline system toward an outlet for a final aromatic polycarbonate product, wherein the pipeline system comprises one or more pipes, through which a molten aromatic polycarbonate having a number average molecular weight increased by the transesterification polymerization reaction is passed while contacting an inner wall of the pipe or pipes, the pipeline system having at least one viscous polycarbonate passage region in which a molten aromatic polycarbonate having a number average molecular weight of 6,000 or more is passed through the pipe, wherein the pipe in the at least one viscous polycarbonate passage region is heated to provide a temperature difference in the range of from -3.degree. C. to 50.degree. C. between the temperature (.degree.C.) of the outer wall of the pipe and the temperature (.degree.C.) of the aromatic polycarbonate in the polymerizer from which the aromatic polycarbonate is passed through the pipe. By the method of the present invention, a high quality aromatic polycarbonate which is not only highly colorless but also has a low foreign matter content can be easily produced.
    • 一种芳族聚碳酸酯的制造方法,其特征在于,对至少一种芳族聚碳酸酯的聚合性材料进行酯交换聚合反应,所述酯交换反应是在一个或多个聚合反应器中进行的,所述聚合反应器是通过管道系统连接到出口, 芳族聚碳酸酯产品,其中管道系统包括一个或多个管道,使通过酯交换聚合反应增加数均分子量的熔融芳族聚碳酸酯通过该管道接触管道或管道的内壁,管道系统具有 至少一个粘性聚碳酸酯通道区域,其中数均分子量为6000以上的熔融芳族聚碳酸酯通过管,其中加热至少一个粘性聚碳酸酯通道区域中的管道以提供在该范围内的温度差 的-3 DE 在管道外壁的温度(℃)和温度(℃)之间,在聚合器中芳族聚碳酸酯通过管道的温度(℃)之间变化到50℃。 通过本发明的方法,可以容易地制备高品质的芳族聚碳酸酯,其不仅高度无色,而且异物含量低。
    • 3. 发明授权
    • Method for producing an aromatic polycarbonate
    • 芳香族聚碳酸酯的制造方法
    • US5952449A
    • 1999-09-14
    • US53656
    • 1998-04-02
    • Muneaki AminakaKyosuke KomiyaKazumi Hasegawa
    • Muneaki AminakaKyosuke KomiyaKazumi Hasegawa
    • B01J19/24C08G64/20C08G64/30C08G64/00
    • B01J19/2465B01J19/242B01J19/2425C08G64/205C08G64/307B01J2219/00094B01J2219/00162B01J2219/00168
    • A method for producing an aromatic polycarbonate, which comprises subjecting to a transesterification polymerization reaction at least one polymerizable material for an aromatic polycarbonate. The transesterification polymerization reaction is performed in one or more polymerizers which is or are connected through a pipeline system. The pipeline system comprises one or more pipes through which a molten aromatic polycarbonate having a number average molecular weight increased by the transesterification polymerization reaction is passed while contacting an inner wall of the pipe or pipes. The pipeline system has at least one viscous polycarbonate passage region in which a molten aromatic polycarbonate having a number average molecular weight of 4,000 or more is passed through the pipe. The pipes in the viscous polycarbonate passage region of the pipeline system have no bent portion or not more than 50 bent portions in total. A high quality aromatic polycarbonate is produced, which is colorless and has a low foreign matter content.
    • 一种芳族聚碳酸酯的制造方法,其特征在于,对至少一种芳香族聚碳酸酯的聚合性物质进行酯交换聚合反应。 酯交换聚合反应在一种或多种通过管道系统连接或通过管道系统连接的聚合反应器中进行。 管道系统包括一个或多个管道,通过其中通过酯交换聚合反应增加数均分子量的熔融芳族聚碳酸酯通过该管道,同时接触管道或管道的内壁。 管道系统具有至少一个粘性聚碳酸酯通道区域,其中数均分子量为4000以上的熔融芳族聚碳酸酯通过管道。 管道系统的粘性聚碳酸酯通路区域中的管道总共没有弯曲部分或不超过50个弯曲部分。 产生高品质的芳族聚碳酸酯,其是无色的并且具有低的异物含量。
    • 4. 发明授权
    • Method for producing an aromatic polycarbonate
    • 芳香族聚碳酸酯的制造方法
    • US6037437A
    • 2000-03-14
    • US987053
    • 1997-12-09
    • Kyosuke KomiyaKazumi Hasegawa
    • Kyosuke KomiyaKazumi Hasegawa
    • C08G64/30C08G64/00
    • C08G64/307
    • A method for producing an aromatic polycarbonate which comprises subjecting to a transesterification polymerization reaction at least one polymerizable material selected from a molten monomer mixture of an aromatic dihydroxy compound and a diaryl carbonate, and a molten prepolymer obtained from the monomer mixture, wherein the transesterification reaction is performed in one or more polymerizers which is or are connected through a pipeline system toward an outlet for a final aromatic polycarbonate product, wherein the pipeline system comprises one or more pipes through which a molten aromatic polycarbonate having a number average molecular weight increased by the transesterification polymerization reaction is passed while contacting an inner wall of the pipe or pipes, and wherein a molten aromatic polycarbonate having a number average molecular weight of less than 2,500 is passed through the pipe or pipes at a velocity of 0.05 m/sec. or more and a molten aromatic polycarbonate having a number average molecular weight of 2,500 or more is passed through the pipe or pipes at a velocity of 0.005 m/sec. or more. By the method of the present invention, a high quality aromatic polycarbonate which is not only highly colorless but also has a low foreign matter content can be produced by using an ordinary pipeline system comprising the pipe or pipes made of an ordinary material.
    • 一种芳族聚碳酸酯的制造方法,其特征在于,将酯交换聚合反应进行至少一种选自芳香族二羟基化合物和碳酸二芳基酯的熔融单体混合物的聚合性物质和由所述单体混合物得到的熔融预聚物,其中,所述酯交换反应 在一种或多种聚合反应器中进行,该聚合反应器是通过管道系统朝向最终芳族聚碳酸酯产品的出口连接的,其中管道系统包括一个或多个管,数均分子量增加的熔融芳族聚碳酸酯 酯交换聚合反应在与管子的内壁接触的同时通过,其中数均分子量小于2500的熔融芳族聚碳酸酯以0.05m / sec的速度通过管道。 以上,数均分子量为2500以上的熔融芳香族聚碳酸酯以0.005m / sec的速度通过管道。 或者更多。 通过本发明的方法,通过使用包括由普通材料制成的管或管的普通管道系统,可以生产不仅高度无色而且异物含量低的优质芳族聚碳酸酯。
    • 5. 发明授权
    • Printer having foreign material removing structure
    • 具有异物去除结构的打印机
    • US07354213B2
    • 2008-04-08
    • US11080664
    • 2005-03-16
    • Yasuo IwataKazumi HasegawaTakuro Kohyama
    • Yasuo IwataKazumi HasegawaTakuro Kohyama
    • B41J29/00
    • B41J29/38
    • In a printer, a sheet discharge port for discharging a sheet therefrom is provided on the upper surface of an exterior case, and a recess portion for preventing invasion of a foreign material into the sheet discharge port is formed in the neighborhood of the sheet discharge port. The recess portion passes by the sheet discharge port, and at least one of the ends thereof is opened to the side surface of the exterior case. The side surface of the exterior case to which the open end of the recess portion is adjacent forms a foreign material discharging passage along which a foreign material discharged from the open end of the recess portion falls down without invading the printer.
    • 在打印机中,在外壳的上表面上设置有用于排出片材的片材排出口,并且在排出口附近形成用于防止异物侵入排出口的凹部 。 凹部经过片材排出口,其端部中的至少一个与外壳的侧面开口。 凹部的开口端相邻的外壳的侧面形成异物排出通路,从凹部的开口端排出的异物沿着该异物排出通道而不会侵入打印机。
    • 7. 发明授权
    • Cutter device of a printer
    • 打印机的切割装置
    • US5505552A
    • 1996-04-09
    • US365481
    • 1994-12-28
    • Kazumi HasegawaMakoto Kawasaki
    • Kazumi HasegawaMakoto Kawasaki
    • B26D3/08B26D1/09B41J3/24B41J11/70
    • B41J3/24B41J11/70Y10T83/0333Y10T83/0348
    • A cutter device includes, in addition to one solenoid 17, two pairs of assemblies disposed in parallel with each other in a direction of movement of a cutter 2, the first pair having a rack 5, a pinion 10, and a clutch 49 to control rotation of the pinion, and the second pair having another rack 6, another pinion 11, and another clutch 50 to control rotation of the pinion. In partial-cutting operation, the cutter 2 is moved by engaging the rack 5 in the first pair with the pinion 10 in the first pair rotated through power from the clutch 49 in the first pair. In full-cutting operation, the cutter 2 is moved by engaging the pinions 10,11 in the first and second pairs concurrently rotated through power from the clutches 49,50 in the first and second pairs with the racks 5,6 in the first and second pairs. The pinion 10 in the first pair causes the full-cutting first half movement of the cutter, and the pinion 11 in the second pair causes the full-cutting latter half movement thereof.
    • 除了一个螺线管17之外,切割装置还包括在切割器2的移动方向上彼此平行设置的两对组件,第一对具有齿条5,小齿轮10和离合器49以控制 小齿轮的旋转,第二对具有另一个齿条6,另一个小齿轮11和另一个离合器50,以控制小齿轮的旋转。 在部分切割操作中,切割器2通过使第一对中的齿条5与第一对中的小齿轮10接合而移动,第一对中的小齿轮10通过来自第一对离合器49的动力旋转。 在全切割操作中,切割器2通过使第一和第二对中的小齿轮10,11与第一和第二对离合器49,50中的第一和第二对中的齿条5,6同时旋转而移动, 第二对 第一对中的小齿轮10引起切割器的全切割第一半运动,并且第二对中的小齿轮11引起全切割后半运动。
    • 10. 发明授权
    • Tractor units for push-pull printer
    • 拖拉机用拖拉机
    • US4953997A
    • 1990-09-04
    • US348110
    • 1989-05-02
    • Kazumi HasegawaHiroshi IkedaWataru Ito
    • Kazumi HasegawaHiroshi IkedaWataru Ito
    • B41J15/04B41J11/26B41J11/28B65H20/20
    • B41J11/28
    • A push-pull printer includes at least one tractor unit thus is formed to have both a pull function and a push function. Fork-like mounting portions are respectively formed at lower portions of a pair of frames provided at both ends of the tractor unit. A pair of tractor guides are located at each of push and pull feed positions of the printer body. Each guide detachably holds a corresponding fork-like mounting portion. When the tractor is to be used in the push type paper feed mode, the fork-like mounting portions are attached to the tractor guides located at the push feed position. However, for use in the pull type paper feed mode, the fork-like mounting portions are attached to the tractor guides located at the pull feed position. Two such tractors, one providing the pull function and the other the push function, can be used cooperatively.
    • 推拉式打印机包括至少一个拖拉机单元,因此形成为具有拉动功能和推动功能。 叉形安装部分分别形成在设置在牵引车单元的两端的一对框架的下部。 一对拖拉机导向件位于打印机主体的每个推拉进给位置。 各引导件可拆卸地保持相应的叉形安装部分。 当拖拉机用于推送式进纸模式时,叉形安装部分附接到位于推送进给位置的拖拉机导向件。 然而,为了在拉式给纸模式中使用,叉形安装部分附接到位于拉入位置的拖拉机导向件。 可以协同使用两台这样的拖拉机,一个提供牵引功能,另一个是推动功能。