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1. 发明授权

US3976721A Method of producing polystyrene composition 失效
标题翻译：生产聚苯乙烯组合物的方法
公开(公告)号：US3976721A
公开(公告)日：1976-08-24
申请号：US583265
申请日：1975-06-03
申请人： Kunio Satake , Tsuyoshi Yamada , Kuniaki Sakamoto , Kiyoshi Hayakawa , Isaburo Fukawa
发明人： Kunio Satake , Tsuyoshi Yamada , Kuniaki Sakamoto , Kiyoshi Hayakawa , Isaburo Fukawa
IPC分类号： C08F279/00 , C08F279/02 , C08L9/06
CPC分类号： C08F279/02
摘要： A novel high-impact polystyrene composition superior to conventional high-impact polystyrene composition, in low temperature high-impact properties, tensile strength, processability, toughness, stiffness, etc. can be obtained by a radical polymerization of a mixture of (1) 2-20% by weight of a random copolymer having a composition of continuously and gradually reduced styrene content along the polymer chain of the copolymer which is obtained by the solution polymerization of butadiene and styrene in the presence of a lithium base catalyst and (2) 80-98% by weight of styrene, carried out in bulk polymerization manner or in a manner in which bulk and suspension polymerizations are used in series.
摘要翻译：通过（1）2（1）的混合物的自由基聚合，可获得优于常规高抗冲聚苯乙烯组合物，低温高冲击性能，拉伸强度，加工性，韧性，刚度等的新型高抗冲聚苯乙烯组合物 -20重量％的无规共聚物，其具有沿着共聚物的聚合物链连续且逐渐降低的苯乙烯含量的组合物，其通过在锂碱催化剂的存在下通过丁二烯和苯乙烯的溶液聚合获得，和（2）80 -98重量％的苯乙烯，以本体聚合的方式进行，或以串联使用本体和悬浮聚合的方式进行。

2. 发明授权

US4423190A Block copolymer mixture of conjugated diene and vinyl aromatic hydrocarbon 失效
标题翻译：共轭二烯和乙烯基芳烃的嵌段共聚物混合物
公开(公告)号：US4423190A
公开(公告)日：1983-12-27
申请号：US333656
申请日：1981-12-23
申请人： Isaburo Fukawa , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa , Yasushi Sato
发明人： Isaburo Fukawa , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa , Yasushi Sato
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： A novel block copolymer mixture of conjugated diene (C.D.) and vinylaromatic hydrocarbon (V.H.) having a superior transparency and impact-resistance is produced by the following two step polymerizations using an organolithium compound as a catalyst and a solvent consisting mainly of an aliphatic hydrocarbon: a first step (A) of preparing a living (co)polymer of C.D. or C.D. and V.H., by polymerizing the monomer(s) in a ratio by weight of V. H. to C.D. of 0/100 to 60/40 and in an amount of 1 to 80% by weight of total monomers to be used, in the presence of said catalyst and solvent, and a second step (B) of preparing V.H. polymer or block copolymer of V.H. and C.D., by adding to said living (co)polymer, remaining monomer(s), in a ratio by weight of V.H. to C.D. of 100/0 to 65/35 and in an amount of 99 to 20% by weight of total monomers to be used, and said catalyst and solvent, and polymerizing the remaining monomer(s) to obtain a block copolymer mixture, this block copolymer mixture having a ratio of V.H. content of ultimate block copolymers to that of the (co)polymers obtained only in step (B), of at least 1/1.8, and a ratio of V.H. portion to C.D. portion of 60/40 to 95/5.
摘要翻译：通过使用有机锂化合物作为催化剂和主要由脂肪族烃组成的溶剂进行以下两步聚合，制备具有优异的透明性和耐冲击性的共轭二烯（CD）和乙烯基芳烃（VH）的新型嵌段共聚物混合物：制备CD的活性（共）聚合物的第一步骤（A）或C.D. 和V.H.通过以V H.与C.D.重量比的比例聚合单体。在所述催化剂和溶剂的存在下，使用的总单体重量为0/100至60/40且为1至80重量％，以及制备VH聚合物或嵌段共聚物的第二步骤（B） VH和CD，通过以VH与CD的重量比加入所述活性（共）聚合物，剩余单体为100/0至65/35，并且使用的总单体的重量为99至20重量％，所述催化剂和溶剂，并使剩余的单体聚合以获得嵌段共聚物混合物，该嵌段共聚物最终嵌段共聚物的VH含量与仅在步骤（B）中获得的（共）聚合物的VH含量的比率为至少1 / 1.8，VH部分与CD的比例部分为60/40至95/5。

3. 发明授权

US4208356A Process for producing mixture of block copolymers 失效
标题翻译：制备嵌段共聚物混合物的方法
公开(公告)号：US4208356A
公开(公告)日：1980-06-17
申请号：US609684
申请日：1975-09-02
申请人： Isaburo Fukawa , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa , Yasushi Sato
发明人： Isaburo Fukawa , Kunio Satake , Tsuyoshi Yamada , Kiyoshi Hayakawa , Yasushi Sato
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： A novel block copolymer mixture of conjugated diene (C.D.) and vinylaromatic hydrocarbon (V.H.) having a superior transparency and impact-resistance is produced by the following two step polymerizations using an organolithium compound as a catalyst and a solvent consisting mainly of an aliphatic hydrocarbon:a first step (A) of preparing a living (co)polymer of C.D. or C.D. and V.H., by polymerizing the monomer(s) in a ratio by weight of V.H. to C.D. of 0/100 to 60/40 and in an amount of 1 to 80% by weight of total monomers to be used, in the presence of said catalyst and solvent, anda second step (B) of preparing V.H. polymer or block copolymer of V.H. and C.D., by adding to said living (co)polymer, remaining monomer(s), in a ratio by weight of V.H. to C.D. of 100/0 to 65/35 and in an amount of 99 to 20% by weight of total monomers to be used, and said catalyst and solvent, and polymerizing the remaining monomer(s) to obtain a block copolymer mixture,this block copolymer mixture having a ratio of V.H. content of ultimate block copolymers to that of the (co)polymers obtained only in step (B), of at least 1/1.8, and a ratio of V.H. portion to C.D. portion of 60/40 to 95/5.
摘要翻译：通过使用有机锂化合物作为催化剂和主要由脂肪族烃组成的溶剂进行以下两步聚合，制备具有优异的透明性和耐冲击性的共轭二烯（CD）和乙烯基芳烃（VH）的新型嵌段共聚物混合物：制备CD的活性（共）聚合物的第一步（A）或C.D. 和V.H.通过以V.H.至C.D.的重量比将聚合单体进行聚合。在所述催化剂和溶剂的存在下，使用的总单体重量为0/100至60/40且为1至80重量％，以及制备VH聚合物或嵌段共聚物的第二步骤（B） VH和CD，通过以VH与CD的重量比加入所述活性（共）聚合物，剩余单体为100/0至65/35，并且使用的总单体的重量为99至20重量％，所述催化剂和溶剂，并使剩余的单体聚合以获得嵌段共聚物混合物，该嵌段共聚物最终嵌段共聚物的VH含量与仅在步骤（B）中获得的（共）聚合物的VH含量的比率为至少1 / 1.8，VH部分与CD的比例部分为60/40至95/5。

4. 发明授权

US4772679A Crystalline aromatic polyketone and process for producing the same 失效
标题翻译：结晶芳族聚酮及其制备方法
公开(公告)号：US4772679A
公开(公告)日：1988-09-20
申请号：US808502
申请日：1985-12-13
申请人： Isaburo Fukawa , Haruyuki Yoneda , Hisaya Sakurai
发明人： Isaburo Fukawa , Haruyuki Yoneda , Hisaya Sakurai
IPC分类号： C08G61/12 , C08G75/02 , C08G75/04 , C08G75/23 , C08G2/00 , C08G4/00
CPC分类号： C08G61/127 , C08G75/024 , C08G75/0272
摘要： Crystalline aromatic polyketones having a linear polymer structure comprising repeating units [I] of ##STR1## and repeating units [II] of ##STR2## the repeating units [I] and [II] are bonded alternately, and the polymer has an intrinsic viscosity of at least 0.4, has excellent properties, particularly heat resistance, and can be used as shaped articles, coatings, films, fibers, etc.
摘要翻译：具有包含重复单元[I]＆lt; IMAGE＆gt;＆gt;和重复单元[II]的重复单元[I]和[II]的线性聚合物结构的结晶芳族聚酮交替键合，聚合物特性粘度至少为0.4，具有优异的性能，特别是耐热性，可用作成型制品，涂料，薄膜，纤维等。

5. 发明授权

US4525546A Process for producing polyethylene and an ethylene-.alpha.-olefin copolymer 失效
标题翻译：生产聚乙烯和乙烯-α-烯烃共聚物的方法
公开(公告)号：US4525546A
公开(公告)日：1985-06-25
申请号：US552564
申请日：1983-11-16
申请人： Isaburo Fukawa , Kazutoshi Sato
发明人： Isaburo Fukawa , Kazutoshi Sato
IPC分类号： C08F6/02 , C08F10/02
CPC分类号： C08F6/02 , C08F10/02
摘要： Polyethylene and an ethylene-.alpha.-olefin copolymer are produced by polymerizing ethylene or a mixture of ethylene with an .alpha.-olefin having 3 to 18 carbon atoms by use of a coordination polymerization catalyst containing a transition metal compound and an organometallic compound, deactivating said catalyst by adding a copolymer of at least one monomer selected from the group consisting of vinyl monomers having a carbonyl group represented by the formula: ##STR1## wherein R.sup.1 represents a hydrogen atom or a hydrocarbon group having 1 to 5 carbon atoms; R.sup.2 is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms; M represents a metal element; and m represents the valence of M,or maleic anhydride with ethylene to be mixed with said catalyst, separating unaltered monomers from the polymer mixture.
摘要翻译：通过使用含有过渡金属化合物和有机金属化合物的配位聚合催化剂聚合乙烯或乙烯与具有3至18个碳原子的α-烯烃的混合物来制备聚乙烯和乙烯-α-烯烃共聚物，使所述催化剂失活通过添加至少一种选自由下式表示的具有羰基的乙烯基单体组成的组的共聚物：其中R 1表示氢原子或具有1至5个碳原子的烃基; R2是氢原子或碳原子数1〜20的烃基; M表示金属元素; m表示与所述催化剂混合的M或马来酸酐与乙烯的化合价，将未改变的单体与聚合物混合物分离。

6. 发明授权

US4804735A Crystalline aromatic polyketone copolymer produced from 4-mercaptophenol, dihaloterephtalophenone, and hydroquinone or dihydroxybenzophenone 失效
标题翻译：由4-巯基苯酚，二卤代对苯二酚和氢醌或二羟基二苯甲酮制得的结晶芳族聚酮共聚物
公开(公告)号：US4804735A
公开(公告)日：1989-02-14
申请号：US24031
申请日：1987-03-10
申请人： Isaburo Fukawa , Haruyuki Yoneda
发明人： Isaburo Fukawa , Haruyuki Yoneda
IPC分类号： C08G65/40 , C08G75/12 , C08G75/04 , C08G75/23
CPC分类号： C08G75/12 , C08G65/4056
摘要： A copolymer which can be employed for various molded articles, particularly for uses which require a high nonflammability, which copolymer is a crystalline aromatic polyketone type copolymer which has an intrinsic viscosity of not less than 0.40 and has a linear polymer structure comprising structural units (A) represented by the formula (A) ##STR1## structural units (B) represented by the formula (B) ##STR2## and structural units (C) represented by the formula (C.sub.1) ##STR3## or by the formula (C.sub.2) ##STR4## the molar ratio of said units (B) to said units (C) being in the range from 30:70 to 99:1, and the unit (A) and either the unit (B) or the unit (C) being linked alternately; and a process producing the same.
摘要翻译：可用于各种模制品的共聚物，特别是需要高不可燃性的用途，该共聚物是特性粘度不低于0.40并且具有包含结构单元（A）的直链聚合物结构的结晶芳族聚酮型共聚物）由式（A）表示的结构单元（B）由式（B）表示的结构单元（B）和由式（C1）或式（C2）表示的结构单元（C）所述单元（B）与所述单元（C）的摩尔比在30:70至99:1的范围内，单元（A）和单元（B）或单元（C）的摩尔比为交替交替及其制造方法。

7. 发明授权

US5225526A Stabilized aromatic polycarbonate composition and process for producing same 失效
标题翻译：稳定的芳族聚碳酸酯组合物及其生产方法
公开(公告)号：US5225526A
公开(公告)日：1993-07-06
申请号：US667398
申请日：1991-03-29
申请人： Isaburo Fukawa , Haruyuki Yoneda , Hiroshi Hachiya
发明人： Isaburo Fukawa , Haruyuki Yoneda , Hiroshi Hachiya
IPC分类号： C08K5/00 , C08K5/524
CPC分类号： C08K5/00 , C08K5/524
摘要： The present invention relates to an aromatic polycarbonate composition which is stabilized by adding to an aromatic polycarbonate (containing substantially no chlorine atom) a very slight amount of at least one compound selected from a phosphorous acid diester and a phosphorous acid monoester and at least one compound selected from a phenolic antioxidant, a phosphorous acid triester and an organic phosphonite. This composition has the characteristics that molded products made therefrom are superior in hot-water resistance and steam resistance and recycling molding thereof causes substantially no coloration. Thus, this composition is high in industrial applicability.

8. 发明授权

US5204377A Porous, crystallized, aromatic polycarbonate prepolymer, a porous, crystallized aromatic polycarbonate, and production methods 失效
标题翻译：多孔，结晶，芳香族聚碳酸酯预聚物，多孔，结晶芳族聚碳酸酯和生产方法
公开(公告)号：US5204377A
公开(公告)日：1993-04-20
申请号：US442353
申请日：1989-10-17
申请人： Isaburo Fukawa , Shinsuke Fukuoka , Kyosuke Komiya , Yoro Sasaki
发明人： Isaburo Fukawa , Shinsuke Fukuoka , Kyosuke Komiya , Yoro Sasaki
IPC分类号： C08G64/04 , C08G63/80 , C08G64/20
CPC分类号： C08G64/20 , Y10S521/918
摘要： A porous, crystallized, aromatic polycarbonate prepolymer is disclosed, which comprises recurring aromatic carbonate units and terminal hydroxyl and aryl carbonate groups, wherein these terminal groups are in a specific molar ratio, and has specific number average molecular weight, surface area and crystallinity. The prepolymer can readily be converted by solid-state condensation polymerization to a porous, crystallized, aromatic polycarbonate having excellent properties. The porous, crystallized, aromatic polycarbonate of the present invention can readily be molded to obtain a shaped, porous, crystallized polycarbonate. The porous, crystallized, aromatic polycarbonate and the shaped, porous, crystallized polycarbonate of the present invention have excellent heat resistance and solvent resistance and exhibit advantageously low water absorption so that these are suited for use as a filter material, an adsorbent or the like. The porous, crystallized, aromatic polycarbonate and the shaped porous, crystallized polycarbonate of the present invention can also readily be molded by a melt process into an article useful as engineering plastics, such as an optical element and an electronic component, which is appreciated since it is free of impurities, such as chlorine-containing compounds, and has excellent properties.
摘要翻译： PCT No.PCT / JP89 / 00994 Sec。 371日期：1989年10月17日 102（e）1989年10月17日PCT 1989年9月29日PCT。公开了一种多孔，结晶的芳族聚碳酸酯预聚物，其包含重复芳族碳酸酯单元和末端羟基和芳基碳酸酯基团，其中这些末端基团具体的数均分子量，表面积和结晶度。预聚物可以容易地通过固态缩聚转化成具有优异性能的多孔，结晶的芳族聚碳酸酯。本发明的多孔，结晶的芳族聚碳酸酯可以容易地模制，以获得成形的，多孔的，结晶的聚碳酸酯。本发明的多孔，结晶化的芳族聚碳酸酯和成形多孔结晶的聚碳酸酯具有优异的耐热性和耐溶剂性，并且显示出有利的低吸水性，因此它们适合用作过滤材料，吸附剂等。本发明的多孔，结晶的芳族聚碳酸酯和成型的多孔，结晶的聚碳酸酯也可以通过熔融方法容易地被模制成用作工程塑料如光学元件和电子部件的制品，由于它是可以理解的不含杂质，如含氯化合物，具有优异的性能。

9. 发明授权

US4757126A Process for preparing crystalline aromatic polyetherketone 失效
标题翻译：制备结晶芳香聚醚酮的方法
公开(公告)号：US4757126A
公开(公告)日：1988-07-12
申请号：US833076
申请日：1986-02-26
申请人： Isaburo Fukawa , Tsuneaki Tanabe
发明人： Isaburo Fukawa , Tsuneaki Tanabe
IPC分类号： C08G65/38 , C08G65/40 , C08G8/02 , C08G14/00
CPC分类号： C08G65/4093 , C08G65/38 , C08G65/4012
摘要： A process for preparing a crystalline aromatic polyetherketone having a reduced viscosity of 0.6 or more is disclosed. The process includes polycondensing an aromatic dihydroxy compound with a dihalogeno aromatic ketone in a solvent having the following general formula (I) or (II): ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 is independently a hydrogen atom, a C.sub.1-3 alkyl group or a phenyl group; X is an oxygen atom, a sulfur atom or a direct bond; Y is an oxygen atom or a ketone group; and n is 0 or 1;in the presence of an alkali compound.
摘要翻译：公开了一种制备粘度为0.6以上的结晶性芳香族聚醚酮的方法。该方法包括使芳族二羟基化合物与二卤代芳族酮在具有下列通式（I）或（II）的溶剂中缩聚：其中R1，R2和R3各自为独立地为氢原子，C 1-3烷基或苯基; X是氧原子，硫原子或直接键; Y是氧原子或酮基; 并且n为0或1; 在碱性化合物的存在下。

10. 发明授权

US4465812A Linear medium- or low-density polyethylene composition 失效
标题翻译：线性中密度或低密度聚乙烯组合物
公开(公告)号：US4465812A
公开(公告)日：1984-08-14
申请号：US427202
申请日：1982-09-29
申请人： Kisoo Moriguchi , Isaburo Fukawa
发明人： Kisoo Moriguchi , Isaburo Fukawa
IPC分类号： C08L23/00 , C08F8/00 , C08F8/50 , C08K5/14 , C08L7/00 , C08L21/00 , C08L23/04 , C08L101/00
CPC分类号： B29C47/92 , C08F8/00 , C08J5/18 , C08K5/14 , B29C2947/92514 , B29C2947/92704 , B29C47/0004 , B29C47/802 , C08F2800/20 , C08F2810/10 , C08F2810/20
摘要： A modified linear medium- or low-density polyethylene composition obtained by uniformly melt kneading a mixture of a linear medium- or low-density polyethylene having a density of not less than 0.90 g/cm.sup.3 but less than 0.94 g/cm.sup.3 and a melt index (MI).sub.1 of not more than 3 g/10 minutes and a radical initiator in an amount of not less than 0.0005% by weight but less than 0.1% by weight based on the weight of the linear medium- or low-density polyethylene at a temperature of from the melting point of the linear medium- or low-density polyethylene to a temperature of less than the thermal decomposition temperature of the linear medium- or low-density polyethylene to such an extent that the ratio of the melt index of the modified linear medium- or low-density polyethylene composition (MI).sub.2 to that of the linear medium- or low-density polyethylene (MI).sub.1 [(MI).sub.2 /(MI).sub.1 ] is 0.05 to 0.9.
摘要翻译：通过将密度不小于0.90g / cm 3，但小于0.94g / cm 3的线性中密度或低密度聚乙烯的混合物均匀熔融捏合得到的改性线性中密度或低密度聚乙烯组合物，（MI）1为3g / 10分钟以下，自由基引发剂为不低于0.0005重量％但小于0.1重量％，基于线性中等密度或低密度聚乙烯的重量从直链中密度或低密度聚乙烯的熔点到低于线性中密度或低密度聚乙烯的热分解温度的温度，使得熔融指数线性中密度或低密度聚乙烯（MI）1 [（MI）2 /（MI）1]的改性线性中密度或低密度聚乙烯组合物（MI）2为0.05〜0.9。

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