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1. 发明授权

US06723869B1 Method for producing acrylonitrile, catalyst for use therein and method for preparing the same 有权
标题翻译：生产丙烯腈的方法，其中使用的催化剂及其制备方法
公开(公告)号：US06723869B1
公开(公告)日：2004-04-20
申请号：US10110129
申请日：2002-04-09
申请人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
发明人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
IPC分类号： C07C25326
CPC分类号： C07C253/26 , B01J23/8876 , Y02P20/52 , C07C255/08
摘要： For the production of acrylonitrile by ammoxidation of propylene, there is provided a catalyst capable of giving a high yield for a long period of time. In producing acrylonitrile by ammoxidation of propylene, there is used a metal oxide as a catalyst, which metal oxide contains iron, antimony, molybdenum, bismuth, potassium, an F element, a G element, an H element and silica as essential components in a specific composition ratio, and in which metal oxide iron antimonate exists as a crystal phase, provided that the F element is at least one element selected from the group consisting of magnesium, calcium, strontium, barium, manganese, cobalt, nickel, copper, silver, zinc and cadmium, the G element is at least one element selected from the group consisting of chromium, aluminum, gallium and indium, and the H element is at least one element selected from the group consisting of yttrium, lanthanum, cerium, praseodymium, neodymium and samarium.
摘要翻译：为了通过丙烯的氨氧化生产丙烯腈，提供了能够长期获得高产率的催化剂。在通过丙烯氨氧化制备丙烯腈时，使用金属氧化物作为催化剂，该金属氧化物含有铁，锑，钼，铋，钾，F元素，G元素，H元素和二氧化硅作为必需成分 F元素是选自镁，钙，锶，钡，锰，钴，镍，铜，银中的至少一种元素，其中金属氧化物锑酸铁作为结晶相存在。，锌和镉，G元素是选自铬，铝，镓和铟中的至少一种元素，H元素是选自钇，镧，铈，镨，钕和钐。

2. 发明授权

US06653496B1 Method for producing acrylonitrile, catalyst for use therein and method for preparing the same 有权
标题翻译：制备丙烯腈的方法，其中使用的催化剂及其制备方法
公开(公告)号：US06653496B1
公开(公告)日：2003-11-25
申请号：US10110061
申请日：2002-04-08
申请人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
发明人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
IPC分类号： C07C25300
CPC分类号： C07C253/26 , B01J21/08 , B01J23/002 , B01J23/04 , B01J23/18 , B01J23/31 , B01J23/745 , B01J23/8435 , B01J23/8876 , B01J23/8878 , B01J27/192 , B01J35/0006 , B01J37/0045 , B01J2523/00 , Y02P20/52 , B01J2523/13 , B01J2523/305 , B01J2523/3712 , B01J2523/41 , B01J2523/51 , B01J2523/53 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/22 , B01J2523/3718 , B01J2523/3737 , B01J2523/55 , B01J2523/64 , B01J2523/27 , B01J2523/3706 , B01J2523/42 , B01J2523/31 , B01J2523/56 , B01J2523/3725 , B01J2523/48 , B01J2523/845 , B01J2523/15 , B01J2523/821 , B01J2523/14 , B01J2523/72 , B01J2523/824 , B01J2523/33 , B01J2523/69 , C07C255/08
摘要： For the production of acrylonitrile by ammoxidation of propylene, there is provided a process capable of giving a high yield and maintaining such an effect for a long period of time. In producing acrylonitrile by ammoxidation of propylene, a fluidized bed catalyst is used and the reaction is carried out while appropriately adding a molybdenum-containing material, wherein the fluidized bed catalyst, in which iron antimonate exists as a crystal phase, contains molybdenum, bismuth, iron, potassium, an M component, an N component and silica as essential components, and has a number of Mo/Me of from 0.8 to 1, wherein the Mo/Me is a number obtained by dividing the product 20 of a valence number of molybdenum as molybdic acid and an atomic ratio of molybdenum by the sum of respective products of respective valence numbers and atomic ratios of respective metal molybdate-producible metal elements other than iron antimonate, that is, bismuth, iron, potassium, the M component element, the N component element and a T component element.
摘要翻译：为了通过丙烯的氨氧化生产丙烯腈，提供了能够长期获得高产率并保持这种效果的方法。在通过丙烯氨氧化制备丙烯腈时，使用流化床催化剂，并且反应在适当添加含钼材料的同时进行，其中作为结晶相存在锑酸锑的流化床催化剂含有钼，铋，铁，钾，M成分，N成分和二氧化硅作为必要成分，并且具有0.8至1的Mo / Me数量，其中Mo / Me是通过将钼的价数的钼作为钼酸和钼的原子比除以产物20得到的数各种金属钼酸盐生产金属元素除铁锑以外的价数和原子比，即铋，铁，钾，M成分元素，N成分 ent元素和T分量元素。

3. 发明授权

US06642405B1 Method for producing acrylonitrile, catalyst for use therein and method for preparing the same 有权
标题翻译：制备丙烯腈的方法，其中使用的催化剂及其制备方法
公开(公告)号：US06642405B1
公开(公告)日：2003-11-04
申请号：US10089079
申请日：2002-04-10
申请人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
发明人： Kunio Mori , Yutaka Sasaki , Kenichi Miyaki , Hirokazu Watanabe
IPC分类号： C07C25300
CPC分类号： B01J27/192 , B01J23/8876 , B01J23/8885 , C07C253/26 , Y02P20/52 , C07C255/08
摘要： For the production of acrylonitrile by ammoxidation of propylene, there is provided a process capable of giving a high yield and maintaining such an effect for a long period of time. In producing acrylonitrile by ammoxidation of propylene, a fluidized bed catalyst is used and the reaction is carried out while appropriately adding a molybdenum-containing material, wherein the fluidized bed catalyst contains molybdenum, bismuth, iron, nickel, chromium, potassium, an F component and silica as essential components, and has a number of Mo/Me of from 0.8 to 1, wherein the Mo/Me is a number obtained by dividing the product 20 of a valence number of molybdenum as molybdic acid and an atomic ratio of molybdenum by the sum of respective products of respective valence numbers and atomic ratios of bismuth, iron, nickel, chromium, potassium, the F component element, a G component element and a Y component element.
摘要翻译：为了通过丙烯的氨氧化生产丙烯腈，提供了能够长期获得高产率并保持这种效果的方法。在通过丙烯氨氧化制备丙烯腈时，使用流化床催化剂，并且反应在适当添加含钼材料的同时进行，其中流化床催化剂含有钼，铋，铁，镍，铬，钾，F成分和二氧化硅作为必要成分，并且Mo / Me的数量为0.8 至1，其中Mo / Me是通过将钼的价数的钼的产物20除以钼酸的原子比和钼的原子比除以各价数的相应乘积和铋，铁，镍，铬，钾，F成分元素，G成分元素和Y成分元素。

4. 发明授权

US06479691B1 Catalyst for producing unsaturated nitrile 有权
标题翻译：用于生产不饱和腈的催化剂
公开(公告)号：US06479691B1
公开(公告)日：2002-11-12
申请号：US09673571
申请日：2000-10-18
申请人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Takao Shimizu , Yuichi Tagawa , Kenichi Miyaki , Seiichi Kawato
发明人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Takao Shimizu , Yuichi Tagawa , Kenichi Miyaki , Seiichi Kawato
IPC分类号： C07C25300
CPC分类号： B01J27/192 , B01J23/8876
摘要： A catalyst composition represented by the following empirical formula which is useful in production of unsaturated nitrites by ammoxidation: Mo10BiaFebSbcNidCreFfGgHhKkXxYyOi(SiO2)j wherein F represents at least one element selected from the group consisting of zirconium, lanthanum and cerium, G represents at least one element selected from the group consisting of magnesium, cobalt, manganese and zinc, H represents at least one element selected from the group consisting of vanadium, niobium, tantalum and tungsten, x represents at least one element selected from the group consisting of phosphorus, boron, and tellurium, Y represents at least one element selected from the group consisting of lithium, sodium, rubidium and cesium, the suffixes a-k, x and y represent a ratio of atoms or atomic groups, and a=0.1-3, b=0.3-15, c=0-20, d=3-8, e=0.2-2, f=0.05-1, e/f>1, g=0-5, h=0-3, k=0.1-1, x=0-3, y=0-1, i is the number of oxygen produced by bonding of the above respective components, and j=0-100.
摘要翻译：由以下经验式表示的催化剂组合物，其可用于通过氨氧化反应生产不饱和亚硝酸盐：其中F表示选自锆，镧和铈中的至少一种元素，G表示选自以下的至少一种元素：的镁，钴，锰和锌，H表示选自钒，铌，钽和钨中的至少一种元素，x表示选自磷，硼和碲中的至少一种元素，Y表示选自锂，钠，铷和铯中的至少一种元素，后缀ak，x和y表示原子或原子团的比例，a = 0.1-3，b = 0.3-15，c = 0 -20，d = 3-8，e = 0.2-2，f = 0.05-1，e / f> 1，g = 0-5，h = 0-3，k = 0.1-1，x = 0-3 y = 0-1，i是上述各成分的结合产生的氧数，j = 0〜100。

5. 发明授权

US5139988A Iron-antimony-containing metal oxide catalyst composition and process for producing the same 失效
标题翻译：含铁抗氧化金属氧化物催化剂组合物及其制造方法
公开(公告)号：US5139988A
公开(公告)日：1992-08-18
申请号：US761079
申请日：1991-09-17
申请人： Yutaka Sasaki , Hiroshi Utsumi , Kenichi Miyaki
发明人： Yutaka Sasaki , Hiroshi Utsumi , Kenichi Miyaki
IPC分类号： B01J23/85 , B01J23/88 , B01J23/881 , B01J23/887 , B01J27/057 , C01C3/02 , C07B61/00 , C07C253/28 , C07C255/50
CPC分类号： C01C3/0216 , B01J23/881 , B01J23/8876 , B01J23/8877 , C01C3/0241
摘要： A composition which contains as essential components: crystalline iron antimonate and at least one element selected from the group consisting of vanadium, molybdenum, and tungsten; is useful as a catalyst in the oxidation reaction of organic compounds. Also, a process for producing the composition is disclosed.
摘要翻译：作为必要成分的组合物：结晶的锑酸锑和至少一种选自钒，钼和钨的元素; 可用作有机化合物的氧化反应中的催化剂。另外，公开了制造该组合物的方法。

6. 发明授权

US5976482A Process for production of prussic acid 失效
标题翻译：普鲁士酸生产工艺
公开(公告)号：US5976482A
公开(公告)日：1999-11-02
申请号：US38947
申请日：1998-03-12
申请人： Yutaka Sasaki , Hiroshi Utsumi , Kazuo Morishita , Kenichi Miyaki
发明人： Yutaka Sasaki , Hiroshi Utsumi , Kazuo Morishita , Kenichi Miyaki
IPC分类号： B01J23/843 , B01J27/198 , B01J27/199 , C01C3/02
CPC分类号： C01C3/0241 , B01J23/002 , B01J23/8435 , B01J27/198 , B01J27/199 , B01J2523/00
摘要： A process for producing prussic acid by subjecting methanol to a gas-phase contact reaction with molecular oxygen and ammonia in the presence of a catalyst, wherein said catalyst is an oxide composition containing iron, antimony, phosphorus and vanadium with a content of vanadium content being at least 0.6 in terms of atomic ratio relative to iron content taken as 10, and a mixed raw material gas for the gas-phase contact reaction contains oxygen at an oxygen-to-methanol molar ratio of less than 1.6.
摘要翻译：一种通过在催化剂存在下使甲醇与分子氧和氨进行气相接触反应生产氢氰酸的方法，其中所述催化剂是含有钒含量的铁，锑，磷和钒的氧化物组合物，其含量为相对于铁含量为10原子比为至少0.6，气相接触反应的混合原料气体含有氧与甲醇摩尔比小于1.6的氧。

7. 发明授权

US4826802A Method for preparation of antimony and tellurium-containing metal oxide catalysts 失效
标题翻译：制备锑和碲的金属氧化物催化剂的方法
公开(公告)号：US4826802A
公开(公告)日：1989-05-02
申请号：US159997
申请日：1988-02-24
申请人： Yutaka Sasaki , Yoshimi Nakamura , Hiroshi Utsumi , Kunio Mori
发明人： Yutaka Sasaki , Yoshimi Nakamura , Hiroshi Utsumi , Kunio Mori
IPC分类号： B01J27/057 , B01J27/186 , C07B61/00 , C07C67/00 , C07C253/00 , C07C253/24 , C07C255/08 , B01J21/08 , B01J23/18
CPC分类号： B01J27/0576
摘要： A process for preparing an antimony/tellurium-containing metal oxide catalyst, comprising preparing a slurry containing an antimony compound, a polyvalent metal compound, and a silica support starting material selected from silica sol and mixtures of silica sol and white carbon, fumed silica or silica hydrogel, heating the slurry at a pH or 7 or less and a temperature of at least 40.degree. C., mixing the above heat treated slurry with a tellurium solution which has been independently prepared by oxidizing metallic tellurium with hydrogen peroxide in the presence of the oxide, oxyacid or oxyacid salt of at least one metal selected from the group consisting of vanadium, molybdenum and tungsten, and then drying and calcining the resulting mixture.

8. 发明授权

US06559085B1 Method for regenerating molybdenum-containing oxide fluidized-bed catalyst 有权
标题翻译：含钼氧化物流化床催化剂再生方法
公开(公告)号：US06559085B1
公开(公告)日：2003-05-06
申请号：US09700216
申请日：2000-11-13
申请人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Akimitsu Morii
发明人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Akimitsu Morii
IPC分类号： B01J2034
CPC分类号： B01J38/68 , B01J23/94 , B01J38/485
摘要： A method for regeneration of a molybdenum-containing oxide fluidized bed catalyst which comprises impregnating a fluidized catalyst of a metal oxide containing molybdenum, bismuth and iron which has been deteriorated by being used for a reaction in production of acrylonitrile by ammoxidation of propylene, with a solution of a molybdenum compound and a solution of at least one compound containing at least one element selected from the group consisting of iron, chromium, lanthanum and cerium which are prepared separately or with a previously prepared mixed solution of the above compounds, drying the resulting catalyst and, then, firing the catalyst at a temperature of 500-700° C.
摘要翻译：一种含钼氧化物流化床催化剂的再生方法，其特征在于，浸渍含有钼，铋和铁的金属氧化物的流化催化剂，所述钼，铋和铁已经通过用丙烯腈的氨氧化反应生产丙烯腈而被劣化，钼化合物的溶液和至少一种含有选自铁，铬，镧和铈中的至少一种元素的化合物的溶液，其分别制备或与预先制备的上述化合物的混合溶液，干燥所得催化剂，然后在500-700℃的温度下焙烧催化剂。

9. 发明授权

US5160721A Process for maintaining high level of yield of acrylonitrile and hydrogen cyanide in ammoxidation of propylene 失效
标题翻译：在丙烯酰胺中维持丙烯腈和氰化物的高水平的方法
公开(公告)号：US5160721A
公开(公告)日：1992-11-03
申请号：US253526
申请日：1988-10-05
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Kunio Mori , Akimitsu Morii
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Kunio Mori , Akimitsu Morii
IPC分类号： B01J23/85 , B01J23/90 , B01J23/94 , B01J27/186 , B01J27/192 , B01J27/28 , B01J27/30 , B01J38/00 , B01J38/04 , C01C3/02 , C07B61/00 , C07C253/26 , C07C255/08
CPC分类号： C07C253/26 , B01J23/94 , B01J27/285 , B01J27/30 , C01C3/0216 , Y02P20/52 , Y02P20/584
摘要： A process for conducting long-term ammoxidation of propylene in the presence of a metal oxide catalyst for ammoxidation of propylene at a temperature of from 300.degree. C. to 500.degree. C. to produce acrylonitrile and hydrogen cyanide, wherein in the process each of (A) elemental phosphorus or a phosphorus compound and (B) elemental tellurium or a tellurium compound is added as a regenerating agent at least once to the ammoxidation reaction system in accordance with the progress of the reaction, the regenerating agent (A) being added when the yields of both of acrylonitrile and hydrogen cyanide are reduced, and the regenerating agent (B) is chosen when the yield of acrylonitrile is reduced and the yield of hydrogen cyanide is unchanged or increased, to thereby maintain high levels of yields of acrylonitrile and hydrogen cyanide.

10. 发明授权

US4410450A Process for producing fluid catalyst having good activity from coarse catalyst 失效
标题翻译：从粗催化剂制备具有良好活性的流动催化剂的方法
公开(公告)号：US4410450A
公开(公告)日：1983-10-18
申请号：US278154
申请日：1981-06-29
申请人： Yutaka Sasaki , Kunio Mori , Kiyoshi Moriya
发明人： Yutaka Sasaki , Kunio Mori , Kiyoshi Moriya
IPC分类号： B01J27/057 , B01J23/18 , B01J23/20 , B01J23/24 , B01J23/34 , B01J23/36 , B01J23/64 , B01J23/68 , B01J23/76 , B01J23/84 , B01J23/90 , B01J27/30 , B01J37/00 , B01J38/00 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , B01J23/92 , B01J27/02
CPC分类号： B01J37/0036 , B01J23/90 , B01J27/30
摘要： A process for producing a fluid catalyst having good activity from a coarse catalyst wherein said fluid catalyst is suitable for oxidation, ammoxidation or oxidative dehydrogenation reaction of hydrocarbons which comprises crushing a fluid catalyst, a greater part of which is composed of particles having a large particle size, to produce finely-divided particles, adjusting the distribution of particle size of said catalyst so that the amount of particles of a size of about 20.mu. or less is about 30% by weight or less of the total weight of catalyst particles and the amount of particles having a weight average particle size is 90% or less based on the catalyst prior to crushing, and thereafter calcining said catalyst at a temperature of about 500.degree. C. - about 1000.degree. C. under a non-reducing atmosphere.
摘要翻译：一种从粗催化剂生产具有良好活性的流体催化剂的方法，其中所述流体催化剂适用于烃的氧化，氨氧化或氧化脱氢反应，其包括粉碎流体催化剂，其中大部分由具有大颗粒的颗粒组成以产生细碎颗粒，调节所述催化剂的粒度分布，使得约20微米或更小的颗粒的数量为催化剂颗粒总重量的约30重量％或更少，并且在粉碎之前基于催化剂的重均粒径的粒子的量为90％以下，然后在非还原气氛下在约500℃〜约1000℃的温度下煅烧所述催化剂。

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