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1. 发明授权

US5160721A Process for maintaining high level of yield of acrylonitrile and hydrogen cyanide in ammoxidation of propylene 失效
标题翻译：在丙烯酰胺中维持丙烯腈和氰化物的高水平的方法
公开(公告)号：US5160721A
公开(公告)日：1992-11-03
申请号：US253526
申请日：1988-10-05
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Kunio Mori , Akimitsu Morii
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Kunio Mori , Akimitsu Morii
IPC分类号： B01J23/85 , B01J23/90 , B01J23/94 , B01J27/186 , B01J27/192 , B01J27/28 , B01J27/30 , B01J38/00 , B01J38/04 , C01C3/02 , C07B61/00 , C07C253/26 , C07C255/08
CPC分类号： C07C253/26 , B01J23/94 , B01J27/285 , B01J27/30 , C01C3/0216 , Y02P20/52 , Y02P20/584
摘要： A process for conducting long-term ammoxidation of propylene in the presence of a metal oxide catalyst for ammoxidation of propylene at a temperature of from 300.degree. C. to 500.degree. C. to produce acrylonitrile and hydrogen cyanide, wherein in the process each of (A) elemental phosphorus or a phosphorus compound and (B) elemental tellurium or a tellurium compound is added as a regenerating agent at least once to the ammoxidation reaction system in accordance with the progress of the reaction, the regenerating agent (A) being added when the yields of both of acrylonitrile and hydrogen cyanide are reduced, and the regenerating agent (B) is chosen when the yield of acrylonitrile is reduced and the yield of hydrogen cyanide is unchanged or increased, to thereby maintain high levels of yields of acrylonitrile and hydrogen cyanide.

2. 发明授权

US4590175A Process for the production of antimony-containing metal oxide catalysts 失效
标题翻译：用于生产含锑金属氧化物催化剂的方法
公开(公告)号：US4590175A
公开(公告)日：1986-05-20
申请号：US655612
申请日：1984-09-28
申请人： Yutaka Sasaki , Hiroshi Utsumi , Kunio Mori , Hiroshi Yamamoto , Yoshimi Nakamura , Kiyoshi Moriya , Akimitsu Morii , Mikio Noda , Miki Kunitani
发明人： Yutaka Sasaki , Hiroshi Utsumi , Kunio Mori , Hiroshi Yamamoto , Yoshimi Nakamura , Kiyoshi Moriya , Akimitsu Morii , Mikio Noda , Miki Kunitani
IPC分类号： C07B33/00 , B01J23/16 , B01J23/18 , B01J23/22 , B01J23/24 , B01J23/80 , B01J23/843 , B01J23/85 , B01J23/88 , B01J27/057 , B01J27/188 , B01J37/00 , B01J37/04 , C01G30/00 , C07B31/00 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/08 , B01J21/08
CPC分类号： C07C253/26 , B01J23/16 , B01J23/18 , B01J23/8435 , B01J23/85 , B01J27/0576 , C01G30/004 , B01J2523/00 , C01P2002/72 , C01P2004/03 , C01P2004/61 , Y02P20/52
摘要： A process for the production of antimony-containing metal oxide catalysts, comprising preparing a slurry containing as essential components an antimony component, a polyvalent metal compound, and silica sol, heating and drying the slurry to form a solid product, and then calcining the solid product, wherein the antimony component is a mixture of (A) at least one of antimonic acid, polyantimonic acid and the salts thereof and (B) antimony trioxide, and is prepared by mixing (A) and (B) in such a manner that the antimony provided by the (B) constitutes from 0.1 to 70 atomic % of the total amount of antimony and further in an aqueous slurry state. These antimony-containing metal oxide catalysts have superior activity and physical properties, and further reproducibility in the preparation thereof. Thus they are useful for production of aldehydes and acids through oxidation, nitriles through ammoxidation, and dienes, unsaturated aldehydes and unsaturated acids through oxidative dehydrogenation.
摘要翻译：一种制备含锑金属氧化物催化剂的方法，包括制备含有锑组分，多价金属化合物和二氧化硅溶胶作为必要组分的浆料，加热和干燥该浆料以形成固体产物，然后煅烧该固体产品，其中锑组分是（A）锑酸，聚锑酸及其盐中的至少一种和（B）三氧化锑中的至少一种的混合物，并且通过混合（A）和（B）以下列方式制备：由（B）提供的锑构成锑总量的0.1〜70原子％，进一步为含水浆状态。这些含锑金属氧化物催化剂具有优异的活性和物理性能，并且在制备时具有进一步的再现性。因此，它们可用于通过氧化制备醛和酸，通过氨氧化生成腈，通过氧化脱氢可用于二烯，不饱和醛和不饱和酸。

3. 发明授权

US06559085B1 Method for regenerating molybdenum-containing oxide fluidized-bed catalyst 有权
标题翻译：含钼氧化物流化床催化剂再生方法
公开(公告)号：US06559085B1
公开(公告)日：2003-05-06
申请号：US09700216
申请日：2000-11-13
申请人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Akimitsu Morii
发明人： Yutaka Sasaki , Kunio Mori , Yoshimi Nakamura , Akimitsu Morii
IPC分类号： B01J2034
CPC分类号： B01J38/68 , B01J23/94 , B01J38/485
摘要： A method for regeneration of a molybdenum-containing oxide fluidized bed catalyst which comprises impregnating a fluidized catalyst of a metal oxide containing molybdenum, bismuth and iron which has been deteriorated by being used for a reaction in production of acrylonitrile by ammoxidation of propylene, with a solution of a molybdenum compound and a solution of at least one compound containing at least one element selected from the group consisting of iron, chromium, lanthanum and cerium which are prepared separately or with a previously prepared mixed solution of the above compounds, drying the resulting catalyst and, then, firing the catalyst at a temperature of 500-700° C.
摘要翻译：一种含钼氧化物流化床催化剂的再生方法，其特征在于，浸渍含有钼，铋和铁的金属氧化物的流化催化剂，所述钼，铋和铁已经通过用丙烯腈的氨氧化反应生产丙烯腈而被劣化，钼化合物的溶液和至少一种含有选自铁，铬，镧和铈中的至少一种元素的化合物的溶液，其分别制备或与预先制备的上述化合物的混合溶液，干燥所得催化剂，然后在500-700℃的温度下焙烧催化剂。

4. 发明授权

US4774352A Process for ammoxidation 失效
公开(公告)号：US4774352A
公开(公告)日：1988-09-27
申请号：US808684
申请日：1985-12-17
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
IPC分类号： B01J23/18 , B01J23/22 , B01J23/28 , B01J23/90 , B01J27/057 , C01C3/02 , C07C120/00 , C07C120/14
CPC分类号： B01J23/18 , B01J23/22 , B01J23/28 , B01J23/90 , B01J27/0576 , C01C3/0216 , C01C3/0233 , C01C3/0241 , C07C253/26 , C07C253/28 , Y02P20/52 , Y02P20/584
摘要： The activity of a tellurium-free metal oxide catalyst used for ammoxidation of organic compounds at a temperature of from 300.degree. C. to 600.degree. C. is improved in the presence of (a) elemental tellurium or a tellurium compound which is in contact with said catalyst or in the presence of (a) elemental tellurium or a tellurium compound and (b) a molybdenum compound which are in contact with said catalyst. This activity improvement process can be applied to both the fresh catalysts and the spent catalyst having a deteriorated activity. The above described component (a) is preferably composed of a tellurium containing solid to be used in a state of a dry physical mixture with said catalyst. The above described components (a) and (b) are preferably composed of a tellurium containing solid and a molybdenum containing solid respectively or a tellurium-molybdenum containing solid to be used in a state of a dry physical mixture with said catalyst.The tellurium containing solid, the molybdenum containing solid or the tellurium-molybdenum containing solid may be at least a member selected from the following group:(1) A solid wherein a tellurium component and/or a molybdenum component is supported or unsupported on an inert carrier,(2) A solid wherein a tellurium component and/or a molybdenum component is added to a metal oxide catalyst (fresh or spent) and/or said metal oxide catalyst is enriched with the tellurium component and/or the molybdenum component, and(3) A solid composed of a compound containing at least one element selected from the group consisting of an alkali metal, an alkaline earth metal, La, Ce, V, Nb, Cr, W, Mn, Fe, Co, Ni, Cu, Zn, Cd, B, Al, Ga, Ge, Sn, Pb, P, AS, Sb, Bi, S and Se in addition to tellurium, molybdenum or tellurium and molybdenum, or a mixture of these compounds, supported or unsupported on an inert carrier.The present invention is advantageously applied to ammoxidation in a fluidized bed.

5. 发明授权

US4757038A Regeneration of iron-antimony metallic oxide catalysts 失效
标题翻译：铁 - 锑金属氧化物催化剂的再生
公开(公告)号：US4757038A
公开(公告)日：1988-07-12
申请号：US52226
申请日：1987-05-15
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Yoshimi Nakamura , Masanori Yamaguchi
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Yoshimi Nakamura , Masanori Yamaguchi
IPC分类号： B01J27/057 , B01J23/94 , B01J27/28 , B01J37/04 , B01J38/04 , C01C3/02 , C07B61/00 , C07C67/00 , C07C253/00 , C07C253/26 , C07C255/08 , B01J23/92 , C07C121/14 , C07C121/32
CPC分类号： B01J27/28 , B01J23/94 , B01J37/04
摘要： Iron-antimony metallic oxide catalysts which have become deactivated after being used for the production of aldehydes, acids, nitriles, or dienes through oxidation, ammoxidation, or oxidative dehydrogenation of organic compounds in fluidized-bed reactors are regenerated by adding to the catalyst a molybdenum-enriched catalyst formed by supporting a molybdenum component which is volatile or capable of forming a volatile compound under reaction conditions on a metallic oxide catalyst. The metallic oxide catalysts contain as essential components (I) Fe, (II) Sb, (III) at least one element selected from the group consisting of V, Mo and W, and (IV) Te.
摘要翻译：通过在流化床反应器中通过氧化，氨氧化或有机化合物的氧化脱氢用于生产醛，酸，腈或二烯而失活的铁 - 锑金属氧化物催化剂通过向催化剂中加入钼通过在金属氧化物催化剂上在反应条件下支持挥发性或能够形成挥发性化合物的钼组分形成的富含催化剂。金属氧化物催化剂含有作为必要成分（I）Fe，（II）Sb，（III）至少一种选自V，Mo和W的元素和（IV）Te。

6. 发明授权

US4536483A Process for regeneration of iron-antimony metallic oxide catalysts 失效
标题翻译：铁 - 锑金属氧化物催化剂再生方法
公开(公告)号：US4536483A
公开(公告)日：1985-08-20
申请号：US545713
申请日：1983-10-26
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Yoshimi Nakamura , Masanori Yamaguchi
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura , Yoshimi Nakamura , Masanori Yamaguchi
IPC分类号： B01J27/057 , B01J23/94 , B01J27/28 , B01J27/30 , B01J38/04 , C01C3/02 , C07B61/00 , C07C67/00 , C07C253/00 , C07C253/26 , C07C255/08 , C07C120/14 , C07C121/32
CPC分类号： B01J23/94 , B01J27/30
摘要： Iron-antimony metallic oxide catalysts which have become deactivated after being used for the production of aldehydes, acids, nitriles, or dienes through oxidation, ammoxidation, or oxidative dehydrogenation of organic compounds in fluidized-bed reactors are regenerated by adding to the catalyst a solid molybdenum component which is volatile or capable of forming a volatile compound under reaction conditions. The metallic oxide catalysts contain as essential components (I) Fe, (II) Sb, (III) at least one element selected from the group consisting of V, MO, and W, and (IV) Te.
摘要翻译：通过在流化床反应器中通过氧化，氨氧化或有机化合物的氧化脱氢用于生产醛，酸，腈或二烯而失活的铁 - 锑金属氧化物催化剂通过向催化剂中加入固体而再生钼组分，其在反应条件下挥发或能够形成挥发性化合物。金属氧化物催化剂含有作为必要成分（I）Fe，（II）Sb，（III）选自V，MO和W的至少一种元素和（IV）Te。

7. 发明授权

US4709071A Process for improving activity of tellurium containing metal oxide catalysts 失效
标题翻译：提高含碲金属氧化物催化剂活性的方法
公开(公告)号：US4709071A
公开(公告)日：1987-11-24
申请号：US847074
申请日：1986-05-21
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
IPC分类号： B01J37/08 , B01J23/90 , B01J27/02 , B01J27/057 , B01J27/30 , C01B19/00 , C01B21/087 , C01C3/02 , C07C5/48 , C07C15/00 , C07C120/14 , C07C120/00
CPC分类号： B01J27/0576 , C01C3/0216 , C01C3/0233 , C01C3/0241 , C07C253/26 , C07C5/48 , Y02P20/52 , Y02P20/584
摘要： A process for improving the activity of tellurium containing metal oxide catalysts useful as catalysts for oxidation, ammoxidation or oxidative dehydrogenation of organic compounds by heating the catalysts together with a tellurium containing solid and an optional molybdenum containing solid to a temperature up to about 900.degree. C. in a gaseous atmosphere. The process can be effectively applied to deteriorated or spent catalysts, the activity of which has been deteriorated due to use for a long period of time. The tellurium containing solid used as an activity improving agent is elemental tellurium and the molybdenum containing solid is selected from the group consisting of (i) a molybdenum compound, (ii) at least one molybdenum compound supported on an inert carrier, and (iii) a molybdenum enriched catalyst prepared by adding a Mo component to a metal oxide catalyst (which may be a fresh catalyst or a deteriorated catalyst). In a particularly preferred embodiment, the process for improving the activity according to the present invention can be carried out by contacting the deteriorated tellurium containing metal oxide catalyst with the elemental tellurium and optional molybdenum-containing solid in a fluidized-bed. More preferably, the contact is carried out during the oxidation, ammoxidation or oxidative dehydrogenation reaction.
摘要翻译：通过将催化剂与含碲固体和任选的含钼固体加热至高达约900℃的温度，来改善含碲金属氧化物催化剂的活性的方法，所述催化剂用作有机化合物的氧化，氨氧化或氧化脱氢催化剂在气态气氛中。该方法可以有效地应用于恶化或废催化剂，其活性由于长期使用而劣化。用作活性改进剂的含碲固体是元素碲，含钼固体选自（ⅰ）钼化合物，（ⅱ）负载在惰性载体上的至少一种钼化合物，和（ⅲ）通过将Mo组分添加到金属氧化物催化剂（其可以是新鲜催化剂或劣化的催化剂）中制备的富钼催化剂。在特别优选的实施方案中，根据本发明的改进活性的方法可以通过使劣化的含碲的金属氧化物催化剂与元素碲和任选的含钼固体在流化床中接触来进行。更优选地，在氧化，氨氧化或氧化脱氢反应期间进行接触。

8. 发明授权

US4709070A Process for improving activity of tellurium containing metal oxide catalysts 失效
标题翻译：提高含碲金属氧化物催化剂活性的方法
公开(公告)号：US4709070A
公开(公告)日：1987-11-24
申请号：US669978
申请日：1984-11-09
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
IPC分类号： B01J37/08 , B01J23/90 , B01J27/02 , B01J27/057 , B01J27/30 , C01B19/00 , C01B21/087 , C01C3/02 , C07C5/48 , C07C15/00 , C07C120/00 , C07C120/14
CPC分类号： B01J27/0576 , C01C3/0216 , C01C3/0233 , C01C3/0241 , C07C253/26 , C07C5/48 , Y02P20/52 , Y02P20/584
摘要： A process for improving the activity of tellurium containing metal oxide catalysts useful as catalysts for oxidation, ammoxidation or oxidative dehydrogenation of organic compounds by heating the catalysts together with an activity-improving agent to a temperature up to about 900.degree. C. in a gaseous atmosphere. The process can be effectively applied to deteriorated or spent catalysts, the activity of which has been deteriorated due to use for a long period of time. The activity improviding agent is selected from the group consisting of(i) a tellurium-molybdenum compound unsupported or supported on an inert carrier;(ii) a dry mixture of a tellurium compound and a molybdenum containing material selected from the group consisting of a molybdenum compound, a molybdenum enriched catalyst and a molybdenum compound supported on an inert carrier;(iii) a dry mixture of a tellurium enriched catalyst and a molybdenum compound unsupported or supported on an inert carrier; and(iv) a dry mixture of a tellurium compound supported on an inert carrier and a molybdenum containing material selected from the group consisting of a molybdenum compound, a molybdenum enriched catalyst and a molybdenum compound supported on an inert carrier. In a particularly preferred embodiment, the process according to the present invention can be carried out by contacting the tellurium containing metal oxide catalysts with the activity-improving agent in a fluidized-bed. More preferably, the contact is carried out during the oxidation, ammoxidation or oxidative hydrogenation reaction.
摘要翻译：一种用于提高含碲的金属氧化物催化剂的活性的方法，其可用作催化剂用于有机化合物的氧化，氨氧化或氧化脱氢，通过将催化剂与活性改进剂一起加热至高达约900℃的温度在气氛中。该方法可以有效地应用于恶化或废催化剂，其活性由于长期使用而劣化。活性成分剂选自（i）无载体或负载在惰性载体上的碲钼化合物; （ii）选自钼化合物，富钼催化剂和负载在惰性载体上的钼化合物的碲化合物和含钼材料的干混合物; （iii）不含碲的催化剂和不含负载或负载在惰性载体上的钼化合物的干混合物; 和（iv）负载在惰性载体上的碲化合物和选自钼化合物，富钼催化剂和负载在惰性载体上的钼化合物的含钼材料的干混合物。在特别优选的实施方案中，根据本发明的方法可以通过在流化床中使含碲金属氧化物催化剂与活性改进剂接触来进行。更优选地，在氧化，氨氧化或氧化氢化反应期间进行接触。

9. 发明授权

US4618593A Process for improving activity of tellurium containing metal oxide catalysts 失效
标题翻译：提高含碲金属氧化物催化剂活性的方法
公开(公告)号：US4618593A
公开(公告)日：1986-10-21
申请号：US379205
申请日：1982-05-17
申请人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
发明人： Yutaka Sasaki , Yutaka Kiyomiya , Toshio Nakamura
IPC分类号： B01J37/08 , B01J23/90 , B01J27/02 , B01J27/057 , B01J27/30 , C01B19/00 , C01B21/087 , C01C3/02 , C07C5/48 , C07C15/00 , B01J23/92 , C07C120/14 , C07C121/32
CPC分类号： B01J27/0576 , C01C3/0216 , C01C3/0233 , C01C3/0241 , C07C253/26 , C07C5/48 , Y02P20/52 , Y02P20/584
摘要： A regeneration process for tellurium-containing metal oxide catalysts used in the process for oxidation, ammoxidation or oxidative dehydrogenation of organic compounds at a temperature of about 300.degree. C. to about 600.degree. C. The process can be effectively applied to such catalysts which have become partially deactivated during the reaction. According to the present process, the deactivated catalyst is regenerated at the reaction temperature under a non-reductive atompshere by contacting the deactivated catalyst with a tellurium-enriched metal oxide catalyst having a tellurium content higher than that of a fresh metal oxide catalyst used in the reaction, or by contacting the deactivated catalyst at the reaction temperature with a tellurium-molybdenum-enriched catalyst system selected from the group consisting of (i) a physical blend of a tellurium-enriched catalyst and a molybdenum-enriched catalyst and (ii) a tellurium-molybdenum-enriched catalyst, the tellurium and molybdenum contents being higher than those of the fresh metal oxide catalyst used in the reaction. In a particularly preferred embodiment, the process is applied to tellurium-containing metal oxide catalysts in a fluidized bed. More preferably, the process is carried out during the oxidation, ammoxidation or oxidative dehydrogenation reaction.
摘要翻译：在约300℃至约600℃的温度下，用于氧化，氨氧化或氧化脱氢有机化合物的方法中的含碲金属氧化物催化剂的再生方法。该方法可有效地应用于具有在反应过程中部分失活。根据本发明的方法，通过使失活的催化剂与碲含量高于新鲜金属氧化物催化剂的碲含量的富碲化金属氧化物催化剂接触而在非还原性原子团体的反应温度下再生失活催化剂或通过使反应温度下的失活的催化剂与选自以下的碲 - 钼 - 富集催化剂体系接触：（i）富含碲的催化剂和富钼催化剂的物理共混物和（ii）碲钼钼催化剂，碲和钼含量高于反应中使用的新鲜金属氧化物催化剂。在特别优选的实施方案中，该方法在流化床中应用于含碲金属氧化物催化剂。更优选地，该过程在氧化，氨氧化或氧化脱氢反应期间进行。

10. 发明授权

US06392048B1 Process for preparing carbocyclic or heterocyclic nitriles by vapor phase ammoxidation 有权
标题翻译：通过气相氨氧化制备碳环或杂环腈的方法
公开(公告)号：US06392048B1
公开(公告)日：2002-05-21
申请号：US09629418
申请日：2000-07-31
申请人： Yutaka Sasaki , Hiroshi Utsumi , Akimitsu Morii , Kazuo Morishita
发明人： Yutaka Sasaki , Hiroshi Utsumi , Akimitsu Morii , Kazuo Morishita
IPC分类号： C07D21500
CPC分类号： B01J23/002 , B01J23/8435 , B01J27/199 , B01J2523/00 , C07C253/28 , C07D213/85 , C07D215/48 , C07D241/24 , C07D333/38 , B01J2523/15 , B01J2523/41 , B01J2523/51 , B01J2523/53 , B01J2523/55 , B01J2523/67 , B01J2523/842 , B01J2523/68 , B01J2523/69 , B01J2523/847 , B01J2523/17 , B01J2523/27 , B01J2523/31 , B01J2523/3706 , B01J2523/13 , B01J2523/845 , B01J2523/22 , B01J2523/64 , C07C255/51 , C07C255/50
摘要： The present invention provides a process for preparing carbocyclic or heterocyclic nitrites by the vapor phase contact ammoxidation of carbocyclic compounds or heterocyclic compounds, in which the reaction is carried out effectively without the increase of the amount of ammonia or oxygen used or the introduction of steam to give the nitrites as the objective products stably with the passage of time in a high yield with a high selectivity. A process for preparing carbocyclic or heterocyclic nitrites comprising subjecting the corresponding starting carbocyclic or heterocyclic compounds to ammoxidation via the vapor phase catalytic reaction in a fluidized bed reactor, in which the reaction is carried out in the presence of a metal oxide fluidized bed catalyst containing vanadium and/or molybdenum as the catalyst, oxygen-containing gas being supplied through an oxygen-containing gas inlet provided at the bottom of the fluidized bed reactor, the starting cyclic compound and ammonia being supplied at a level higher than the oxygen-containing gas inlet, a fluidized bed being formed so that the ratio of the amount of catalyst (Wb) fluidized at a level higher than the inlet of the starting cyclic compound to the amount of catalyst (Wa) fluidized at a level higher than the oxygen-containing gas inlet in the reaction zone is in the range of Wb/Wa=0.01-0.95 by weight.
摘要翻译：本发明提供了通过碳环化合物或杂环化合物的气相接触氨氧化制备碳环或杂环亚硝酸盐的方法，其中反应在没有增加使用的氨或氧气或引入蒸汽的情况下有效地进行以高选择性，以高产率稳定地以亚硝酸盐为目标产物。一种制备碳环或杂环亚硝酸盐的方法，包括使相应的起始碳环或杂环化合物经过气相催化反应在流化床中进行氨氧化其中反应在含有钒和/或钼作为催化剂的金属氧化物流化床催化剂存在下进行，含氧气体通过设置在流化床的底部的含氧气体入口提供床反应器，起始循环化合物和氨为反应器在高于含氧气体入口的水平面上形成流化床，使得流化的催化剂（Wb）的量比起始环状化合物的入口高到催化剂量（Wa ）在高于反应区中的含氧气体入口的水平上流动，其重量在Wb / Wa = 0.01-0.95的范围内。

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