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1. 发明授权

US11571683B2 Honeycomb-structured catalyst for organic substance decomposition and organic substance decomposing apparatus 有权
公开(公告)号：US11571683B2
公开(公告)日：2023-02-07
申请号：US17018869
申请日：2020-09-11
申请人： Murata Manufacturing Co., Ltd.
发明人： Naoya Mori , Satoshi Kuretake , Nario Sugahara , Kentaro Ishihara
IPC分类号： B01J21/04 , B01J21/06 , B01J23/00 , B01J23/34 , B01J23/68 , B01J23/78 , B01J23/88 , B01J35/02 , B01J35/04 , B01J35/10 , B01D53/86 , B01D53/94 , A61L9/03 , B01J23/889 , C01G45/12 , C01G51/00 , C01G53/00 , B01J37/00 , B01J21/16
摘要： A honeycomb-structured catalyst for decomposing an organic substance, which includes a catalyst particle. The catalyst particle contains a perovskite-type composite oxide represented by AxByMzOw, where the A contains at least of Ba and Sr, the B contains Zr, the M is at least one of Mn, Co, Ni, and Fe, y+z=1, 1.001≤x≤1.05, 0.05≤z≤0.2, and w is a positive value that satisfies electrical neutrality. The toluene decomposition rate is greater than 90% when toluene is decomposed using the honeycomb-structured catalyst subjected to a heat treatment at 1200° C. for 48 hours and a gas that contains 50 ppm toluene, 80% nitrogen, and 20% oxygen as a volume concentration as a target at a space velocity of 30,000/h and a catalyst temperature of 400° C.

2. 发明授权

US11213802B2 Mesoporous mixed oxide catalyst comprising silicon 有权
公开(公告)号：US11213802B2
公开(公告)日：2022-01-04
申请号：US15744106
申请日：2016-07-05
申请人： IFP Energies Nouvelles , Compagnie Generale Des Etablissements Michelin
发明人： Nicolas Cadran , Alexandra Chaumonnot , Arnold Lambert
IPC分类号： B01J21/08 , B01J37/03 , B01J37/10 , B01J23/20 , B01J35/10 , B01J37/02 , C07C1/20 , B01J37/08 , B01J23/06 , B01J23/68 , B01J23/847
摘要： A mesoporous mixed oxide catalyst that comprises silicon and at least one metal M that is selected from the group that consists of the elements of groups 4 and 5 of the periodic table and mixtures thereof, with the mass of metal M being between 0.1 and 20% of the mixed oxide mass.

3. 发明授权

US11123712B2 Catalysts utilizing carbon dioxide for the epoxidation of olefins 有权
公开(公告)号：US11123712B2
公开(公告)日：2021-09-21
申请号：US16320116
申请日：2017-07-26
申请人： Research Triangle Institute
发明人： Marty Lail , Paul Mobley , Jonathan Peters , Sree Nandita Akunuri , Joshua J. Hlebak
IPC分类号： C01B32/40 , B01J23/68 , B01J21/04 , B01J23/652 , B01J37/02 , B01J37/03 , B01J37/08 , C07D301/03 , B01J29/03
摘要： The present disclosure provides mixed molybdenum oxide catalysts, methods for preparing epoxides from olefins and CO2 using them, and methods of making the mixed molybdenum oxide catalysts by impregnation or co-precipitation. In a preferred embodiment, the mixed molybdenum oxide catalysts are silver/molybdenum oxide catalysts, ruthenium/molybdenum oxide catalysts, or a combination thereof.

4. 发明授权

US10857523B2 Catalyst for production of hydrogen and process for producing hydrogen using the catalyst, and catalyst for combustion of ammonia, process for producing the catalyst and process for combusting ammonia using the catalyst 有权
公开(公告)号：US10857523B2
公开(公告)日：2020-12-08
申请号：US16299550
申请日：2019-03-12
申请人： NIPPON SHOKUBAI CO., LTD.
发明人： Junji Okamura , Masanori Yoshimune , Masaru Kirishiki , Hideaki Tsuneki
IPC分类号： B01J23/83 , B01J23/00 , B01J23/34 , B01J23/44 , B01J23/50 , B01J23/68 , B01J23/882 , B01J23/889 , B01J23/89 , B01J35/00 , B01J35/10 , B01J37/02 , B01J37/03 , C01B3/04 , C01B3/06 , B01J21/04 , B01J23/42
摘要： Disclosed is a catalyst which can be used in the process for producing hydrogen by decomposing ammonia, can generate heat efficiently in the interior of a reactor without requiring excessive heating the reactor externally, and can decompose ammonia efficiently and steadily by utilizing the heat to produce hydrogen. Also disclosed is a technique for producing hydrogen by decomposing ammonia efficiently utilizing the catalyst. Specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising an ammonia-combusting catalytic component and an ammonia-decomposing catalytic component. Also specifically disclosed is a catalyst for use in the production of hydrogen, which is characterized by comprising at least one metal element selected from the group consisting of cobalt, iron, nickel and molybdenum.

5. 发明授权

US10369550B2 Catalyst system and process for the production of glycols 有权
公开(公告)号：US10369550B2
公开(公告)日：2019-08-06
申请号：US15776863
申请日：2016-11-17
申请人： SHELL OIL COMPANY
发明人： Smita Edulji , Evert Van Der Heide
IPC分类号： C07C29/00 , B01J23/00 , B01J23/89 , B01J23/68 , B01J25/02 , B01J27/188 , C07C29/132 , C07C29/60 , B01J35/00 , B01J23/40 , B01J23/56 , B01J23/74
摘要： The invention provides a catalyst system comprising: a) one or more silver tungstate-containing species; and b) one or more catalytic species suitable for hydrogenation, wherein the weight ratio of said one or more silver tungstate-containing species to the one or more catalytic species suitable for hydrogenation is greater than 2.5:1, on the basis of the total weight of the catalyst system; and a process for the preparation of monoethylene glycol from starting material comprising one or more saccharides, by contacting said starting material with hydrogen in a reactor at a reactor temperature in the range of from 145 to 190° C. in the presence of a solvent and said catalyst system.

6. 发明申请

US20190184377A1 PROPYLENE DIRECT OXIDATION REACTION CATALYST, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING PROPYLENE OXIDE THROUGH PROPYLENE DIRECT OXIDATION REACTION USING SAME 审中-公开
公开(公告)号：US20190184377A1
公开(公告)日：2019-06-20
申请号：US16327262
申请日：2017-08-22
申请人： LOTTE CHEMICAL CORPORATION , SEOUL NATIONAL UNIVERSITY R&DB FOUNDATION
发明人： Joong Won LEE , Hyung Ki MIN , Young Jong SEO , In Kyu SONG , Eo Jin LEE , Jong Heop YI
IPC分类号： B01J23/68 , B01J23/30 , B01J23/28 , B01J21/06 , B01J37/04 , B01J37/00 , B01J37/08 , B01J35/10 , C07D301/10 , C07D303/04
摘要： Disclosed is a propylene direct oxidation reaction catalyst capable of preparing a propylene oxide from propylene and oxygen at a higher yield than catalysts prepared by conventional methods, by applying a specific transition metal oxide promoter in preparation of a catalyst containing silver, a transition metal oxide promoter and a carrier through a slurry process. The present invention provides a propylene direct oxidation reaction catalyst, which is a supported silver catalyst used for preparing a propylene oxide from the propylene direct oxidation reaction, the catalyst including a molybdenum oxide and a tungsten oxide as a catalyst promoter.

7. 发明授权

US10266475B2 Method for producing acrylic acid 有权
公开(公告)号：US10266475B2
公开(公告)日：2019-04-23
申请号：US15752181
申请日：2017-01-31
申请人： LG CHEM, LTD. , KOREA ADVANCED INSTITUTE OF SCIENCE AND TECHNOLOGY
发明人： Won Jae Lee , Dong Su Song , Yong Jin Choe , Hyun Joo Lee , Min Su Kim
IPC分类号： C07C51/25 , C07C51/44 , C07C51/50 , C07C57/04 , B01J23/44 , B01J23/58 , B01J23/60 , B01J23/66 , B01J23/68 , B01J23/74 , B01J23/78 , B01J23/80 , B01J23/89 , B01J35/00 , B01J35/02 , B01J35/08 , B01J37/00 , B01J37/02 , B01J23/46 , B01J23/52 , B01J37/16
摘要： A method for preparing acrylic acid, more specifically, to a method for preparing acrylic acid under a neutral condition at high yield in a short time without using a base, unlike the prior art in which a base is essentially used. The acrylic acid is produced using a supported catalyst having a specific composition when preparing acrylic acid by oxidation of allyl alcohol. Particularly, the preparation method can recover acrylic acid rather than acrylic acid salt as a final product, and thus has an advantage that the overall process cost can be reduced by eliminating essential processes in the prior art, such as ion exchange after the acidification process required for the conversion of acrylic acid salt to acrylic acid.

8. 发明授权

US10232353B2 Gold-based catalyst for the oxidative esterification of aldehydes to obtain carboxylic esters 有权
公开(公告)号：US10232353B2
公开(公告)日：2019-03-19
申请号：US15543291
申请日：2015-12-29
申请人： Alexander Lygin , Steffen Krill , Matthias Groemping , Andreas Tepperis
发明人： Alexander Lygin , Steffen Krill , Matthias Groemping , Andreas Tepperis
IPC分类号： B01J23/02 , B01J23/04 , B01J23/10 , B01J23/14 , B01J23/18 , B01J23/34 , B01J23/52 , B01J23/66 , B01J23/68 , B01J23/89 , B01J35/00 , B01J35/02 , B01J35/08 , B01J37/02 , B01J37/04 , C07C67/39 , C07C69/54
摘要： Catalysts for oxidative esterification can be used, for example, for converting (meth)acrolein to methyl (meth)acrylate. The catalysts are especially notable for high mechanical and chemical stability even over very long time periods, including activity and/or selectivity relatively in continuous operation in media having even a small water content.

9. 发明授权

US10213780B2 Multivalence semiconductor photocatalytic materials 有权
公开(公告)号：US10213780B2
公开(公告)日：2019-02-26
申请号：US15510621
申请日：2015-09-11
申请人： NITTO DENKO CORPORATION
发明人： Ekambaram Sambandan , Bin Zhang
IPC分类号： B01J35/00 , B01J37/08 , B01J37/16 , B01J21/06 , B01J23/72 , B01J23/75 , A61L9/18 , B01D53/00 , B01J23/02 , B01J23/68 , B01J27/18 , B01J37/04 , C02F1/32 , C02F1/72 , C02F101/32
摘要： Described herein are heterogeneous materials comprising a p-type semiconductor comprising two metal oxide compounds of the same metal in two different oxidation states and an n-type semiconductor having a deeper valence band than the p-type semiconductor valence bands, wherein the semiconductor types are in ionic communication with each other. The heterogeneous materials enhance photocatalytic activity.

10. 发明授权

US10208005B2 Process for manufacturing ethylene oxide using scaled selectivity values 有权
公开(公告)号：US10208005B2
公开(公告)日：2019-02-19
申请号：US15540076
申请日：2015-09-30
申请人： Dow Technology Investments LLC
发明人： Ailene Gardner Phillips
IPC分类号： C07D301/10 , B01J23/68
摘要： Disclosed herein are methods of using scaled selectivities to assist in determining whether changes to the value of a target ethylene oxide production parameter—such as ethylene oxide production rate—used in the process of epoxidizing ethylene with a high-selectivity catalyst, have caused the process to move away from optimal operation. If the deviation from optimal operation has not worsened, it is generally unnecessary to perform a full optimization study even if the value of a target ethylene oxide production parameter has changed, which reduces or eliminates process disturbances caused by carrying out such studies. Methods are also disclosed which use both scaled selectivities and scaled reaction temperatures. If scaled selectivities reveal that a change in the value of a target ethylene oxide production parameter has moved the process away from optimal operation, scaled reaction temperatures can, under certain conditions, provide an indication of the directions in which the reaction temperature and/or overall catalyst chloriding effectiveness should be changed to move toward optimal operation. If a change in the value of a target ethylene oxide production parameter has improved the scaled selectivity, the scaled reaction temperature may also be used to guide further adjustments which may further improve scaled selectivity.

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