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    • 4. 发明授权
    • Solid oxide fuel cell having composition gradient between electrode and electrolyte
    • 固体氧化物燃料电池在电极和电解质之间具有组成梯度
    • US06287716B1
    • 2001-09-11
    • US09418001
    • 1999-10-14
    • Ikiko HashimotoNorikazu KomadaKazunori Adachi
    • Ikiko HashimotoNorikazu KomadaKazunori Adachi
    • H01M810
    • H01M4/9033H01M2004/8689H01M2008/1293H01M2300/0074
    • A solid oxide fuel cell and method of making same is disclosed. An electrolyte layer of an oxide ion conductor material that may be specified by La1−aAaGa1−(b+c)BbCocO3 and an air electrode layer of an electron conductor material that may be specified by La1−dAdCoO3 are laminated, preferably with an intermediate layer of an electron and ion mixed conductor material that may be specified by La1−eAeGa1−(f+g)BfCogO3 interposed therebetween. The laminate may be sintered to integrate the layers, and may then subjected to a heat treatment to cause elements to diffuse through an interface between adjoining layers. The composition in each interface is thus continuously changed. Here, A may be at least one element selected from the group consisting of Sr and Ca, B may be at least one element selected from the group consisting of Mg, Al, and In, and 0.05≦a≦0.3, 0≦b, e≦0.3, 0≦c≦0.15, b+c≦0.3, 0≦d≦0.5, 0≦f≦0.15, 0.15
    • 公开了一种固体氧化物燃料电池及其制造方法。 可以由La1-aAaGa1-(b + c)BbCocO3规定的氧化物离子传导体材料的电解质层和可由La1-dAdCoO3规定的电子导体材料的空气电极层层压,优选层叠中间层 可以由La1-eAeGa1-(f + g)BfCogO3指定的电子和离子混合导体材料。 可以将层压体烧结以使各层结合,然后进行热处理以使元件通过相邻层之间的界面扩散。 因此,每个界面中的组成被连续地改变。 这里,A可以是选自Sr和Ca中的至少一种元素,B可以是选自Mg,Al和In中的至少一种元素,并且0.05 <= a <= 0.3,0 < = b,e <= 0.3,0 <= c <= 0.15,b + c <= 0.3,0 <= d <= 0.5,0 <= f <= 0.15,0.15
    • 10. 发明授权
    • Solid oxide fuel cell having composition gradient between electrode and electrolyte
    • 固体氧化物燃料电池在电极和电解质之间具有组成梯度
    • US06635376B2
    • 2003-10-21
    • US09897923
    • 2001-07-05
    • Ikiko HashimotoNorikazu KomadaKazunori Adachi
    • Ikiko HashimotoNorikazu KomadaKazunori Adachi
    • H01M810
    • H01M4/9033H01M2004/8689H01M2008/1293H01M2300/0074
    • A solid oxide fuel cell and method of making same is disclosed. An electrolyte layer of an oxide ion conductor material that may be specified by La1−aAaGa1−(b+c)BbCocO3 and an air electrode layer of an electron conductor material that may be specified by La1−dAdCoO3 are laminated, preferably with an intermediate layer of an electron and ion mixed conductor material that may be specified by La1−eAeGa1−(f+g)BfCogO3 interposed therebetween. The laminate may be sintered to integrate the layers, and may then subjected to a heat treatment to cause elements to diffuse through an interface between adjoining layers. The composition in each interface is thus continuously changed. Here, A may be at least one element selected from the group consisting of Sr and Ca, B may be at least one element selected from the group consisting of Mg, Al, and In, and 0.05≦a≦0.3, 0≦b, e≦0.3, 0≦c≦0.15, b+c≦0.3, 0≦d≦0.5, 0≦f≦0.15, 0.15
    • 公开了一种固体氧化物燃料电池及其制造方法。 可以由La1-aAaGa1-(b + c)BbCocO3规定的氧化物离子传导体材料的电解质层和可由La1-dAdCoO3规定的电子导体材料的空气电极层层压,优选层叠中间层 可以由La1-eAeGa1-(f + g)BfCogO3指定的电子和离子混合导体材料。 可以将层压体烧结以使各层结合,然后进行热处理以使元件通过相邻层之间的界面扩散。 因此,每个界面中的组成被连续地改变。 这里,A可以是选自Sr和Ca中的至少一种元素,B可以是选自Mg,Al和In中的至少一种元素,并且0.05 <= a <= 0.3,0 < = b,e <= 0.3,0 <= c <= 0.15,b + c <= 0.3,0 <= d <= 0.5,0 <= f <= 0.15,0.15