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1. 发明授权

US5258245A Lithium rechargeable battery and method of making the same 失效
标题翻译：锂可充电电池及其制作方法
公开(公告)号：US5258245A
公开(公告)日：1993-11-02
申请号：US904847
申请日：1992-06-26
申请人： Kenichi Takata , Nobuharu Koshiba , Atsushi Ohtsuka , Tatsuo Mori
发明人： Kenichi Takata , Nobuharu Koshiba , Atsushi Ohtsuka , Tatsuo Mori
IPC分类号： H01M4/485 , H01M4/505 , H01M4/525 , H01M10/05 , H01M10/052 , H01M10/0566 , H01M4/48
CPC分类号： H01M4/485 , H01M10/0525 , H01M4/131 , Y02P70/54
摘要： The subject invention is a lithium battery comprising a positive electrode mainly of vanadium pentoxide, a negative electrode mainly of lithium doped niobium pentoxide, and, an electrolyte mainly of an anhydrous solvent with dissolved lithium salt. By using for the said niobium pentoxide a mixture of T type and H type crystals heat treated at 850.degree. to 1300.degree. C., preferably 850.degree. to 1100.degree. C., a lithium battery having superior charging cycle characteristics and also having high discharge voltage is obtained.
摘要翻译：本发明是一种锂电池，其主要包括五氧化二钒的正电极，主要由掺杂锂的五氧化二铌的负极和主要具有溶解的锂盐的无水溶剂的电解质的锂电池。通过在上述五氧化二铌中使用在850℃〜1300℃，优选850℃〜1100℃下热处理的T型和H型结晶的混合物，具有优良的充电循环特性并且还具有高放电电压的锂电池获得。

2. 发明授权

US5015547A Lithium secondary cell 失效
标题翻译：锂二次电池
公开(公告)号：US5015547A
公开(公告)日：1991-05-14
申请号：US375468
申请日：1989-07-05
申请人： Nobuharu Koshiba , Shuichi Nishino , Kenichi Takata , Toshihiko Ikehata
发明人： Nobuharu Koshiba , Shuichi Nishino , Kenichi Takata , Toshihiko Ikehata
IPC分类号： H01M4/02 , H01M4/131 , H01M4/48 , H01M4/485 , H01M10/0525 , H01M10/36
CPC分类号： H01M4/485 , H01M10/0525 , H01M2004/027 , H01M2004/028 , H01M4/131
摘要： A chargeable lithium secondary cell comprising a positive electrode composed mainly of vanadium pentaoxide, a negative electrode of a compound of lithium with niobium pentaoxide and an electrolyte of an organic solvent in which a lithium salt is dissolved, wherein resistance to overdischarge is obtained by a constitution that the molar ratio of the niobium pentaoxide to vanadium pentaoxide is from not less than 0.5 to not more than 1 and the molar ratio of the total litium contained in the positive and negative electrodes to vanadium pentaoxide is from not less than 1.1 to not more than 2.

3. 发明授权

US4874680A Lithium secondary battery 失效
标题翻译：锂二次电池
公开(公告)号：US4874680A
公开(公告)日：1989-10-17
申请号：US283806
申请日：1988-12-13
申请人： Nobuharu Koshiba , Toshihiko Ikehata , Kenichi Takata
发明人： Nobuharu Koshiba , Toshihiko Ikehata , Kenichi Takata
IPC分类号： H01M4/02 , H01M4/40 , H01M4/48 , H01M4/64 , H01M10/05 , H01M10/052
CPC分类号： H01M10/052 , H01M4/131 , H01M4/134 , H01M4/40 , H01M4/64 , H01M10/0569
摘要： A lithium secondary battery which comprises a positive electrode made of vanadium pentoxide as a principle component, a negative electrode made of lithium absorbing alloy, and an electrolyte prepared from an organic solvent dissolved with lithium salt. The lithium absorbing alloy is an alloy containing aluminum as a principle component, and the amount of lithium absorbed by the alloy is not greater than 8 wt % relative to the weight of the vanadium pentoxide and not smaller than 4 wt % relative to the alloy containing the aluminum as the principal component.
摘要翻译：锂二次电池，其包含由五氧化二钒作为主要成分制成的正极，由锂吸收合金制成的负极和由溶解有锂盐的有机溶剂制备的电解质。锂吸收合金是含有铝作为主要成分的允许量，合金吸收的锂量相对于五氧化二钒的重量为8重量％以下，相对于含有以铝为主要成分。

4. 发明授权

US5545468A Rechargeable lithium cell and process for making an anode for use in the cell 失效
标题翻译：可充电锂电池和用于制造用于电池的阳极的方法
公开(公告)号：US5545468A
公开(公告)日：1996-08-13
申请号：US213900
申请日：1994-03-16
申请人： Nobuharu Koshiba , Kenichi Takata , Emi Asaka , Makoto Nakanishi
发明人： Nobuharu Koshiba , Kenichi Takata , Emi Asaka , Makoto Nakanishi
IPC分类号： C01B31/02 , H01M4/131 , H01M4/1391 , H01M10/05 , H01M10/0525 , H01M10/0568 , H01M4/02
CPC分类号： H01M4/485 , H01M10/0525 , H01M2300/0025 , H01M4/131 , H01M4/1391 , H01M4/505 , H01M4/525
摘要： A rechargeable lithium cell comprises a cathode having a discharge potential not less than 2 V relative to a Li/Li.sup.+ anode, an anode capable of doping and un-doping lithium and made of a material comprising a lithium titanate having a spinel structure and represented by the general formula, LixTiyO.sub.4 wherein 0.8.ltoreq.x.ltoreq.1.4 and 1.6.ltoreq.y.ltoreq.2.2, a separator separating the cathode and the anode from each other, and an electrolytic solution impregnated at least in the separator and dissolving a lithium salt in a non-aqueous solvent. When subjected to X-ray diffraction analysis, the material has peaks at least at 4.84.+-.0.02 angstroms, 2.53.+-.0.02 angstroms, 2.09.+-.0.02 angstroms and 1.48.+-.0.02 angstroms and a ratio of a peak intensity at 4.84.+-.0.02 angstroms and a peak intensity at 1.48.+-.0.02 angstroms of 100:30.+-.10. The material may consist of the lithium titanate or mixed crystals of the lithium titanate and rutile-type titanium dioxide. A process for making the anode is also described.
摘要翻译：可再充电锂电池包括相对于Li / Li +阳极具有不小于2V的放电电势的阴极，能够掺杂和不掺杂锂的阳极，并由包含尖晶石结构的钛酸锂的材料制成，并由通式为LixTiyO4，其中0.8≤x≤1.4且1.6≤y≤2.2，将阴极和阳极彼此分隔开的分离器，以及至少浸入分离器中并溶解的电解液在非水溶剂中的锂盐。当进行X射线衍射分析时，材料具有至少在4.84 +/- 0.02埃，2.53 +/- 0.02埃，2.09 +/- 0.02埃和1.48 +/- 0.02埃的峰值以及峰强度在4.84 +/- 0.02埃，峰值强度为1.48 +/- 0.02埃为100：30 +/- 10。该材料可以由钛酸锂或钛酸锂和金红石型二氧化钛的混合晶体组成。还描述了制造阳极的方法。

5. 发明授权

US06057058A Organic electrolyte lithium secondary battery 失效
标题翻译：有机电解质锂二次电池
公开(公告)号：US06057058A
公开(公告)日：2000-05-02
申请号：US886888
申请日：1997-07-02
申请人： Nobuharu Koshiba , Tatsuo Mori , Emi Asaka , Akira Kakinuma
发明人： Nobuharu Koshiba , Tatsuo Mori , Emi Asaka , Akira Kakinuma
IPC分类号： H01M10/05 , C01B31/02 , H01M4/505 , H01M6/16 , H01M10/052 , H01M10/0525 , H01M10/0568 , H01M10/0569 , H01M4/50
CPC分类号： H01M4/505 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M10/0525 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M6/164 , H01M6/166
摘要： The invention provides a lithium secondary battery with improved withstanding overcharge and overdischarge characteristics which employs a cathode active material of lithium-containing manganese dioxide having a crystal structure of the Ramsdellite-type. An electrolyte combined with the cathode includes LiN(CF.sub.3 SO.sub.2).sub.2 as a solute. The solute is preferably dissolved in ethylene carbonate. A graphite or LiAl alloy is applied for an anode. LiAl alloy is corrosion-resistant, thereby improving high temperature as well as charge-discharge cycle life characteristics.
摘要翻译：本发明提供一种锂二次电池，其具有改进的耐过充电和过放电特性，其采用具有Ramsdellite型晶体结构的含锂二氧化锰的正极活性材料。与阴极组合的电解质包括作为溶质的LiN（CF 3 SO 2）2。溶质优选溶解在碳酸亚乙酯中。将石墨或LiAl合金用于阳极。 LiAl合金是耐腐蚀的，从而改善高温以及充放电循环寿命特性。

6. 发明授权

US06274277B1 Organic electrolyte battery 有权
标题翻译：有机电解质电池
公开(公告)号：US06274277B1
公开(公告)日：2001-08-14
申请号：US09357225
申请日：1999-07-20
申请人： Tatsuo Mori , Tadayoshi Takahashi , Shinichi Waki , Nobuharu Koshiba , Takashi Akiyama
发明人： Tatsuo Mori , Tadayoshi Takahashi , Shinichi Waki , Nobuharu Koshiba , Takashi Akiyama
IPC分类号： H01M618
CPC分类号： H01M10/052 , H01M2/08 , H01M6/164 , H01M6/166 , H01M10/0568 , H01M10/0569 , H01M2300/0037 , H01M2300/004
摘要： The present invention relates to an organic electrolyte battery configured by sealing power generating elements comprising an organic electrolyte by a positive can, a negative can and a gasket, wherein said organic electrolyte includes a lithium salt containing a sulfonic acid group as a solute and at least one selected from a group consisting of sulfolane, 3-methyl sulfolane and Tetraglyme as a solvent. The aim of the invention is to provide an organic electrolyte battery having an excellent discharge performance in a low temperature environment and a superior reliability during long term storage, as well as a high temperature resistance which enables the battery to be mounted onto a substrate according to the Reflow method.
摘要翻译：本发明涉及一种有机电解质电池，其特征在于，所述有机电解质电池通过利用正型罐，负型罐和垫圈密封包含有机电解质的发电元件，其中所述有机电解质包括含有磺酸基作为溶质的锂盐，一种选自环丁砜，3-甲基环丁砜和作为溶剂的四氢呋喃溶胶。本发明的目的是提供一种在低温环境下具有优异的放电性能以及在长时间储存期间具有优异的可靠性的有机电解质电池，以及耐高温性，使得电池可以根据回流方法。

7. 发明申请

US20070077485A1 Thin film for package of alkaline battery and thin air battery using the same 审中-公开
标题翻译：薄膜用于包装碱性电池和稀薄空气电池使用相同
公开(公告)号：US20070077485A1
公开(公告)日：2007-04-05
申请号：US10581113
申请日：2005-04-19
申请人： Koshi Takamura , Harunari Shimamura , Nobuharu Koshiba
发明人： Koshi Takamura , Harunari Shimamura , Nobuharu Koshiba
IPC分类号： H01M2/12 , H01M12/06
CPC分类号： H01M12/06 , H01M2/0222 , H01M2/0255 , H01M2/0265 , H01M2/0287 , H01M4/8605
摘要： There is provided a thin air battery comprising a power-generating element including air diffusion paper and a water repellent film, the power-generating element sealed in a package composed of first and third sheet layers that cover the air electrode side and negative electrode side of the power-generating element, and a second sheet layer disposed in the peripheral portion between the two sheet layers and joined to the two sheet layers. The sheet layers are each composed of a thin film formed by stacking an alkali resistant polymer film having hydrogen gas permeability and a polymer film having gas barrier properties, and in each of the first and third sheet layers, the polymer film having hydrogen gas permeability is disposed on the internal surface side. According to the present invention, a thin air battery that has high energy density and has excellent long-term reliability is provided.
摘要翻译：提供了一种薄空气电池，其包括具有空气扩散纸和防水膜的发电元件，所述发电元件密封在由覆盖空气电极侧和负极侧的第一和第三片层组成的封装所述发电元件和设置在所述两个片层之间的周边部分中并且接合到所述两个片层的第二片层。片层各自由通过层叠具有氢气透过性的耐碱性聚合物膜和具有阻气性的聚合物膜形成的薄膜构成，并且在第一和第三片层中，具有氢气透过性的聚合物膜设置在内表面侧。根据本发明，提供了具有高能量密度并且具有优异的长期可靠性的稀薄空气电池。

8. 发明申请

US20070020171A1 Manganese dioxide, method and apparatus for producing the same, and battery active material and battery prepared by using the same 审中-公开
标题翻译：二氧化锰，其制造方法和装置，以及使用该二氧化锰制备的电池活性物质和电池
公开(公告)号：US20070020171A1
公开(公告)日：2007-01-25
申请号：US11491973
申请日：2006-07-25
申请人： Shinichi Waki , Nobuharu Koshiba , Tadafumi Ajiri
发明人： Shinichi Waki , Nobuharu Koshiba , Tadafumi Ajiri
IPC分类号： C01G45/12 , H01M4/50 , C01G45/02 , B01J8/04
CPC分类号： H01M4/50 , B01J3/008 , B01J19/2415 , B01J2219/00058 , B01J2219/00135 , C01G45/02 , C01P2002/72 , C01P2004/03 , C01P2004/61 , C01P2004/62 , H01M4/02 , H01M4/502 , H01M2004/021 , Y02P20/544
摘要： Manganese dioxide of this invention comprises monocrystalline particles with a β-type crystal structure. The use of such manganese dioxide as an active material of a battery makes it possible to improve the discharge characteristics and long-term reliability of the battery.
摘要翻译：本发明的二氧化锰包括具有β型晶体结构的单晶颗粒。使用这种二氧化锰作为电池的活性物质可以提高电池的放电特性和长期的可靠性。

9. 发明申请

US20060222959A1 Organic electrolyte battery 失效
标题翻译：有机电解质电池
公开(公告)号：US20060222959A1
公开(公告)日：2006-10-05
申请号：US11271851
申请日：2005-11-14
申请人： Nobuharu Koshiba , Youko Sano , Shinichi Kawaguchi
发明人： Nobuharu Koshiba , Youko Sano , Shinichi Kawaguchi
IPC分类号： H01M10/40 , H01M4/50 , H01M4/58 , H01M4/40
CPC分类号： H01M10/0567 , H01M10/052 , H01M10/4235 , H01M2300/0025
摘要： An organic electrolyte battery of this invention includes: a positive electrode comprising a positive electrode active material; a negative electrode comprising a negative electrode active material; an organic electrolyte comprising at least an organic solvent and a solute dissolved in the organic solvent; and an additive that suppresses an increase in internal resistance. The additive includes at least one of phthalazone and a phthalazone derivative. The addition of the additive to the battery suppresses an increase in internal resistance upon storage and upon charge/discharge cycling, thereby making it possible to improve the storage characteristics and charge/discharge cycle characteristic of the battery.
摘要翻译：本发明的有机电解质电池包括：正极，其包含正极活性物质; 包含负极活性物质的负极; 包含至少一种有机溶剂和溶解在有机溶剂中的溶质的有机电解质; 和抑制内阻增加的添加剂。添加剂包括酞嗪酮和酞嗪衍生物中的至少一种。向电池添加添加剂抑制了储存时和充放电循环时的内部电阻的增加，从而可以提高电池的存储特性和充放电循环特性。

10. 发明申请

US20090023068A1 Alkaline battery 审中-公开
标题翻译：碱性电池
公开(公告)号：US20090023068A1
公开(公告)日：2009-01-22
申请号：US10588061
申请日：2005-03-17
申请人： Harunari Shimamura , Koshi Takamura , Nobuharu Koshiba
发明人： Harunari Shimamura , Koshi Takamura , Nobuharu Koshiba
IPC分类号： H01M4/42
CPC分类号： H01M6/06 , H01M4/244 , H01M6/04 , H01M6/045 , H01M2300/0085
摘要： An alkaline battery of this invention includes: a negative electrode including a negative electrode mixture that contains a zinc alloy as an active material, the zinc alloy containing at least aluminum; an alkaline electrolyte; and a positive electrode. The alkaline electrolyte includes an aqueous KOH solution and LiOH and an aluminum compound that are dissolved in the aqueous KOH solution. The alkaline battery has excellent high-rate discharge characteristics.
摘要翻译：本发明的碱性电池包括：负极，其包含含有锌合金作为活性物质的负极混合物，所述锌合金至少含有铝; 碱性电解液和正极。碱性电解质包括KOH水溶液和溶解在KOH水溶液中的LiOH和铝化合物。碱性电池具有优异的高倍率放电特性。

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