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    • 2. 发明授权
    • Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
    • 共轭二烯系聚合物,共轭二烯类聚合物组合物,以及共轭二烯类聚合物的制造方法
    • US08367765B2
    • 2013-02-05
    • US13206167
    • 2011-08-09
    • Mana ItoKatsunari InagakiMayumi Oshima
    • Mana ItoKatsunari InagakiMayumi Oshima
    • C08L43/04C08F230/08C08F36/04
    • C08F236/10C08K3/36C08F4/48C08L9/06
    • Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and elongation at break can be obtained, a polymer composition containing the conjugated diene-based polymer and a reinforcing agent, and a process for producing the conjugated diene-based polymer. There is provided a conjugated diene-based polymer having a conjugated diene unit, a monomer unit based on a compound represented by the following formula (1) and a monomer unit based on a compound represented by the following formula (2). wherein R11 represents a hydrogen atom or a hydrocarbyl group, m is 0 or 1, R12 represents a hydrocarbylene group, and X1, X2 and X3 each independently represent a substituted amino group, or a hydrocarbyl group optionally having a substituent, provided that at least one of X1, X2 and X3 is a substituted amino group. wherein R21 represents a hydrogen atom or a hydrocarbyl group, n is 0 or 1, R22 represents a hydrocarbylene group, and A represents a substituted amino group, or a nitrogen-containing heterocyclic group.
    • 公开了一种共轭二烯类聚合物,其中可以获得具有优异的燃料成本节约性能和断裂伸长率的聚合物组合物,含有共轭二烯系聚合物和增强剂的聚合物组合物,以及制备共轭二烯系聚合物的方法 二烯基聚合物。 提供具有共轭二烯单元的共轭二烯系聚合物,基于下述式(1)所示的化合物的单体单元和基于下述式(2)表示的化合物的单体单元。 其中R11表示氢原子或烃基,m为0或1,R12表示亚烃基,X1,X2和X3各自独立地表示取代的氨基或任选具有取代基的烃基,条件是至少 X 1,X 2和X 3中的一个是取代的氨基。 其中R21表示氢原子或烃基,n为0或1,R22表示亚烃基,A表示取代氨基或含氮杂环基。
    • 3. 发明申请
    • PROCESS FOR PRODUCING COPOLYMER
    • 制备共聚物的方法
    • US20070088139A1
    • 2007-04-19
    • US11562812
    • 2006-11-22
    • Jun KAWASHIMAKatsunari InagakiTatsuo Sassa
    • Jun KAWASHIMAKatsunari InagakiTatsuo Sassa
    • C08F4/68
    • C08F210/18C08F4/68C08F4/631C08F210/06C08F236/20C08F2500/25C08F2500/03
    • There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.
    • 提供(I)制备乙烯,具有3至20个碳原子的α-烯烃和任选的多烯的共聚物的方法,该方法包括通过将以下组分(A ),(B),(C1)和(D)):(A)过渡金属络合物,(B)有机铝化合物,(C1)含卤素化合物和(D) (A)与组分(B),(2)组分(A)与组分(C1),(3)的组分进行预先接触,将组分进料到聚合反应器中, (B)和(4)成分(B)与成分(D)的组成(B)。 (II)生产所述共聚物的方法,其包括通过将聚合反应器中的组分(A),(B),(D),(C2)a 含有芳基的羧酸的衍生物的含卤素化合物和(C3)不是羧酸衍生物的含卤素化合物,或(ii)向其中加入组分(A) ,(B),(D),(C3)和(C4)含卤素化合物,其是含有不饱和键的线性有机基团的羧酸的衍生物。
    • 10. 发明授权
    • Conjugated diene-based polymer, conjugated diene-based polymer composition, and process for producing conjugated diene-based polymer
    • 共轭二烯系聚合物,共轭二烯类聚合物组合物,以及共轭二烯类聚合物的制造方法
    • US08299179B2
    • 2012-10-30
    • US13206171
    • 2011-08-09
    • Mana ItoKatsunari Inagaki
    • Mana ItoKatsunari Inagaki
    • C08F8/42C08F8/30C08K3/36C08F236/04
    • C08C19/44C08C19/25
    • Disclosed are a conjugated diene-based polymer from which a polymer composition excellent in fuel cost-saving properties and elongation at break can be obtained, a polymer composition containing the conjugated diene-based polymer and a reinforcing agent, and a process for producing the conjugated diene-based polymer. A conjugated diene-based polymer obtained by reacting one end of a polymer having a monomer unit based on a conjugated diene, a monomer unit based on a compound represented by the following formula (1), and a monomer unit based on a compound represented by the following formula (2) with an alkoxysilane compound. V1—S1  (1) wherein V1 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and S1 represents a substituted silyl group. V2-A2  (2) wherein V2 represents a hydrocarbyl group having a polymerizable carbon-carbon double bond, and A2 represents a substituted amino group, or a nitrogen-containing heterocyclic group.
    • 公开了一种共轭二烯类聚合物,其中可以获得具有优异的燃料成本节约性能和断裂伸长率的聚合物组合物,含有共轭二烯系聚合物和增强剂的聚合物组合物,以及制备共轭二烯系聚合物的方法 二烯基聚合物。 一种共轭二烯类聚合物,其通过使具有基于共轭二烯的单体单元的聚合物的一端,基于由下式(1)表示的化合物的单体单元和基于由下式(1)表示的化合物的单体单元) 下述式(2)表示烷氧基硅烷化合物。 V1-S1(1)其中V1表示具有可聚合碳 - 碳双键的烃基,S1表示取代甲硅烷基。 V2-A2(2)其中V2表示具有可聚合碳 - 碳双键的烃基,A2表示取代的氨基或含氮杂环基。