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1. 发明申请

US20110224390A1 PROCESS FOR PRODUCING COPOLYMER 失效
标题翻译：制备共聚物的方法
公开(公告)号：US20110224390A1
公开(公告)日：2011-09-15
申请号：US13114577
申请日：2011-05-24
申请人： Jun KAWASHIMA , Katsunari INAGAKI , Tatsuo SASSA
发明人： Jun KAWASHIMA , Katsunari INAGAKI , Tatsuo SASSA
IPC分类号： C08F4/68 , C08F10/14 , C08F10/04 , C08F36/00
CPC分类号： C08F210/18 , C08F4/68 , C08F4/631 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/03
摘要： There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.
摘要翻译：提供（I）制备乙烯，具有3至20个碳原子的α-烯烃和任选的多烯的共聚物的方法，该方法包括通过进料以下组分（A（A））将这些单体在聚合反应器中共聚的步骤），（B），（C1）和（D））：（A）过渡金属络合物，（B）有机铝化合物，（C1）含卤素化合物和（D）（A）与组分（B），（2）组分（A）与组分（C1），（3）的组分进行预先接触，将组分进料到聚合反应器中，（B）和（4）成分（B）与成分（D）的组成（B）。（II）生产所述共聚物的方法，其包括通过将聚合反应器中的组分（A），（B），（D），（C2）a 含有芳基的羧酸的衍生物的含卤素化合物和（C3）不是羧酸衍生物的含卤素化合物，或（ii）向其中加入组分（A），（B），（D），（C3）和（C4）含卤素化合物，其是含有不饱和键的线性有机基团的羧酸的衍生物。

2. 发明申请

US20070088139A1 PROCESS FOR PRODUCING COPOLYMER 审中-公开
标题翻译：制备共聚物的方法
公开(公告)号：US20070088139A1
公开(公告)日：2007-04-19
申请号：US11562812
申请日：2006-11-22
申请人： Jun KAWASHIMA , Katsunari Inagaki , Tatsuo Sassa
发明人： Jun KAWASHIMA , Katsunari Inagaki , Tatsuo Sassa
IPC分类号： C08F4/68
CPC分类号： C08F210/18 , C08F4/68 , C08F4/631 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/03
摘要： There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.
摘要翻译：提供（I）制备乙烯，具有3至20个碳原子的α-烯烃和任选的多烯的共聚物的方法，该方法包括通过将以下组分（A ），（B），（C1）和（D））：（A）过渡金属络合物，（B）有机铝化合物，（C1）含卤素化合物和（D）（A）与组分（B），（2）组分（A）与组分（C1），（3）的组分进行预先接触，将组分进料到聚合反应器中，（B）和（4）成分（B）与成分（D）的组成（B）。（II）生产所述共聚物的方法，其包括通过将聚合反应器中的组分（A），（B），（D），（C2）a 含有芳基的羧酸的衍生物的含卤素化合物和（C3）不是羧酸衍生物的含卤素化合物，或（ii）向其中加入组分（A），（B），（D），（C3）和（C4）含卤素化合物，其是含有不饱和键的线性有机基团的羧酸的衍生物。

3. 发明授权

US3257369A Catalysts having an improved activity in the stereospecific polymerization of alpha-olefins and process for preparing same 失效
标题翻译：在α-烯烃的立体有择聚合中具有改进的活性的催化剂及其制备方法
公开(公告)号：US3257369A
公开(公告)日：1966-06-21
申请号：US10826561
申请日：1961-05-08
申请人： MONTEDISON SPA
发明人： RENATO SERRA , ETTORE GIACHETTI
IPC分类号： C08F4/68 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/907 , C08F4/631

4. 发明授权

US07871952B1 2-hydroxypyridine N-oxide-modified ziegler-natta catalyst system 失效
标题翻译： 2-羟基吡啶N-氧化物改性的齐格勒 - 纳塔催化剂体系
公开(公告)号：US07871952B1
公开(公告)日：2011-01-18
申请号：US12587188
申请日：2009-10-02
申请人： Sandor Nagy , Joachim T. M. Pater , Giampiero Morini
发明人： Sandor Nagy , Joachim T. M. Pater , Giampiero Morini
IPC分类号： C08F4/02 , B01J31/00 , C08F4/44 , C08F2/00
CPC分类号： B01J31/143 , B01J31/0201 , B01J31/0232 , B01J31/0244 , B01J31/0271 , B01J2231/122 , B01J2531/46 , B01J2531/56 , C08F10/00 , C08F110/02 , C08F210/16 , C08F4/6355 , C08F4/631 , C08F210/08 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F4/6295
摘要： A modified Ziegler-Natta catalyst system, a method for preparing the catalyst system, and a process for polymerizing an olefin in the presence of the catalyst system are disclosed. The catalyst system comprises a titanium or vanadium compound, an aluminum compound, and a 2-hydroxypyridine N-oxide. Improved properties such as increased molecular weight are obtained.
摘要翻译：公开了改进的齐格勒 - 纳塔催化剂体系，制备催化剂体系的方法和在催化剂体系存在下使烯烃聚合的方法。催化剂体系包括钛或钒化合物，铝化合物和2-羟基吡啶N-氧化物。获得改进的性能，例如分子量增加。

5. 发明授权

US3888789A Preparation of polymerization catalyst systems 失效
标题翻译：聚合催化剂体系的制备
公开(公告)号：US3888789A
公开(公告)日：1975-06-10
申请号：US31572072
申请日：1972-12-15
申请人： UNIVERSAL OIL PROD CO
发明人： DOMBRO ROBERT A , ILLINGWORTH GEORGE E , FRONCZAK RICHARD A
IPC分类号： C08F4/62 , C08F10/00 , B01J11/84
CPC分类号： C08F10/00 , C08F4/631 , C08F4/025
摘要： Polymerization catalyst systems which are prepared by admixing an oxide of a metal of Group IIa, IIB, IIIA, or IVA with a halide of a metal selected from Group IVB, VB or VIB to chemically fix the metal halide thereon and thereafter adding an organo Group IA, IIA or IIIA metal or derivative thereof and a Lewis Base modifier to the admixture are improved by treating the oxide or the mixture of said oxide and said metal halide with a halogenating agent so that the atomic ratio of halide to Group IVB, VB or VIB metal is greater than 10:1 and preferably greater than 20:1.

6. 发明授权

US3045001A Polymerization process 失效
公开(公告)号：US3045001A
公开(公告)日：1962-07-17
申请号：US72309758
申请日：1958-03-24
申请人： SHELL OIL CO
发明人： BERGER RICHARD S
IPC分类号： C08F2/00 , C08F4/64 , C08F10/00
CPC分类号： C08F10/00 , C08F4/631

7. 发明授权

US08278404B2 Process for producing copolymer 失效
标题翻译：制备共聚物的方法
公开(公告)号：US08278404B2
公开(公告)日：2012-10-02
申请号：US13114577
申请日：2011-05-24
申请人： Jun Kawashima , Katsunari Inagaki , Tatsuo Sassa
发明人： Jun Kawashima , Katsunari Inagaki , Tatsuo Sassa
IPC分类号： C08F4/622 , C08F4/68
CPC分类号： C08F210/18 , C08F4/68 , C08F4/631 , C08F210/06 , C08F236/20 , C08F2500/25 , C08F2500/03
摘要： There are provided (I) a process for producing a copolymer of ethylene, an α-olefin having from 3 to 20 carbon atoms and optionally a polyene, which comprises the step of copolymerizing those monomers in a polymerization reactor by feeding the following components (A), (B), (C1) and (D) to the polymerization reactor: (A) a transition metal complex, (B) an organic aluminum compound, (C1) a halogen-containing compound, and (D) a Lewis base, wherein those components are fed to the polymerization reactor without a preliminary contact of (1) the component (A) with the component (B), (2) the component (A) with the component (C1), (3) the component (B) with the component (C1), and (4) the component (B) with the component (D); and (II) a process for producing said copolymer, which comprises the step of copolymerizing those monomers in a polymerization reactor (i) by feeding to the polymerization reactor the components (A), (B), (D), (C2) a halogen-containing compound, which is a derivative of an aryl group-containing carboxylic acid, and (C3) a halogen-containing compound, which is not a derivative of a carboxylic acid, or (ii) by feeding thereto the components (A), (B), (D), (C3), and (C4) a halogen-containing compound, which is a derivative of a carboxylic acid containing an unsaturated bond-carrying linear organic group.
摘要翻译：提供（I）制备乙烯，具有3至20个碳原子的α-烯烃和任选的多烯的共聚物的方法，该方法包括通过进料以下组分（A（A））将这些单体在聚合反应器中共聚的步骤），（B），（C1）和（D））：（A）过渡金属络合物，（B）有机铝化合物，（C1）含卤素化合物和（D）（A）与组分（B），（2）组分（A）与组分（C1），（3）的组分进行预先接触，将组分进料到聚合反应器中，（B）和（4）成分（B）与成分（D）的组成（B）。（II）生产所述共聚物的方法，其包括通过将聚合反应器中的组分（A），（B），（D），（C2）a 含有芳基的羧酸的衍生物的含卤素化合物和（C3）不是羧酸衍生物的含卤素化合物，或（ii）向其中加入组分（A），（B），（D），（C3）和（C4）含卤素化合物，其是含有不饱和键的线性有机基团的羧酸的衍生物。

8. 发明授权

US3882046A Catalyst for polymerization and copolymerization of olefines and a method for preparing same 失效
标题翻译：烯烃聚合和共聚催化剂及其制备方法
公开(公告)号：US3882046A
公开(公告)日：1975-05-06
申请号：US32071073
申请日：1973-01-03
申请人： POMOGAILO ANATOLY DMITRIEVICH , MAMBETOV URAKBAI ALIMBAEVICH , SOKOLSKY DMITRY VLADIMIROVICH , BOLSHOV ALEXANDR AVRAAMOVICH , GLUZMAN MOISEI KHARITONOVICH , KOCHUROVSKAYA GERTA GENNADIEVN , GLUZMAN EVGENY MOISEEVICH , MATKOVSKY PETR EVGENIEVICH , BEIKHOLD GALINA ALBERTOVNA , AFANASIEVA IRINA IVANOVNA , BURYMCHENKO MIKHAIL IVANOVICH , BAISHIGANOV ESENGELDY
发明人： POMOGAILO ANATOLY DMITRIEVICH , MAMBETOV URAKBAI ALIMBAEVICH , SOKOLSKY DMITRY VLADIMIROVICH , BOLSHOV ALEXANDR AVRAAMOVICH , GLUZMAN MOISEI KHARITONOVICH , KOCHUROVSKAYA GERTA GENNADIEVN , GLUZMAN EVGENY MOISEEVICH , MATKOVSKY PETR EVGENIEVICH , BEIKHOLD GALINA ALBERTOVNA , AFANASIEVA IRINA IVANOVNA , BURYMCHENKO MIKHAIL IVANOVICH , BAISHIGANOV ESENGELDY
IPC分类号： C08F4/64 , C08F10/00 , B01J11/84
CPC分类号： C08F10/00 , C08F4/631
摘要： A catalyst for polymerization and copolymerization of olefins is a binary system consisting of a complex compound formed by a halide of a transition metal belonging to Groups IVA-VA of the periodic system with polyglycolic ethers of mono- or polyfunctional alcohols, or polyglycolic esters of carboxylic acids or their anhydrosorbitols, in combination with aluminumorganic compounds. The said complex compounds are prepared by the interaction between said ethers (esters) and halides of transition metals in organic solvents in an inert medium.
摘要翻译：用于烯烃的聚合和共聚的催化剂是由属于周期系统的IVA-VA族的过渡金属的卤化物与单官能或多官能醇的聚乙醇醚或羧酸的聚乙醇酸形成的络合物组成的二元体系酸或它们的脱水山梨糖醇与铝有机化合物的组合。

9. 发明授权

US3738944A Compositions for initiating olefin polymerisation and the use thereof 失效
标题翻译：用于启动烯烃聚合的组合物及其用途
公开(公告)号：US3738944A
公开(公告)日：1973-06-12
申请号：US3738944D
申请日：1971-03-01
申请人： ICI LTD
发明人： CANDLIN J , MAGUIRE J , WYATT R
IPC分类号： C08F2/00 , C08F4/12 , C08F4/16 , C08F4/68 , C08F10/00 , C08F36/04 , B01J11/84
CPC分类号： C08F10/00 , C08F4/12 , C08F36/04 , C08F4/631 , C08F4/642 , C08F4/025 , C08F4/02
摘要： A TRANSITION METAL COMPOSITION USEFUL FOR POLYMERIZING OLEFINS, WHICH IS FORMED BY THE REACTION OF (1) A MATERIAL INSOLUBLE IN ORGANIC SOLVENT HAVING SURFACE HYDROXYL GROUPS FREE FROM ADSORBED WATER, (2) A TRANSITION METAL COMPOUND HAVING AT LEAST ONE HYDROCARBYL LIGAND, THE TRANSITION METAL BEING SELECTED FROM THOSE OF GROUPS IV-A AND V-A OF THE PERIODIC TABLE OF ELEMENTS, AND (3) A COMPOUND OF A METAL OF GROUPS I TO III OF THE SAID PERIODIC TABLE HAVING AT LEAST ONE HYDROCARBYL LIGAND. THE COMPOSITION IS USEFUL IN THE POLYMERISATION AND COPOLYMERISATION OF OLEFINICALLY UNSATURATED MONOMERS, ESPECIALLY ETHYLENE.

10. 发明授权

US3396155A Transition metal catalysts for the polymerization and copolymerization of olefins 失效
标题翻译：用于烯烃聚合和共聚的过渡金属催化剂
公开(公告)号：US3396155A
公开(公告)日：1968-08-06
申请号：US45686465
申请日：1965-05-18
申请人： SOLVAY
发明人： ANDRE DELBOURILLE , HENRI TOUSSAINT
IPC分类号： C08F4/64 , C08F10/00 , C08F210/18 , C08F261/04
CPC分类号： C08F10/00 , C08F210/18 , C08F261/04 , Y10S526/904 , C08F4/631 , C08F4/611 , C08F4/651 , C08F210/00 , C08F210/06 , C08F2500/25

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