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    • 4. 发明授权
    • Sulfur-containing cyclic olefin resin and its production method
    • 含硫环烯烃树脂及其制备方法
    • US07709583B2
    • 2010-05-04
    • US11914806
    • 2006-05-15
    • Takashi OkadaToshihide YamamotoHiroshi Yamakawa
    • Takashi OkadaToshihide YamamotoHiroshi Yamakawa
    • C08G75/00
    • C08G61/12C07D339/00C08G61/122G11B7/2538
    • A sulfur-containing cyclic olefin resin comprising a unit represented by the following general formula (1) and having a weight average molecular weight of from 1,000 to 1,000,000. (Here, R1 to R6 each independently represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, an aralkyl group having from 1 to 20 carbon atoms, an aromatic group having from 1 to 20 carbon atoms, a cyano group, an alkoxy group having from 1 to 10 carbon atoms or a heterocyclic compound, further R3 to R6 may be a halogen atom, R3 and R4, and R5 and R6 may form a ring containing carbon, oxygen, sulfur or nitrogen, R7 and R8′ each independently represents a hydrogen atom or a methyl group, . . . represents a single bond or a double bond, and l and m each is 0 or 1.)
    • 一种含硫环状烯烃树脂,其含有下述通式(1)表示的单元,重均分子量为1,000〜1,000,000。 (这里,R 1〜R 6各自独立地表示氢原子,碳原子数1〜20的烷基,碳原子数1〜20的芳烷基,碳原子数1〜20的芳香族基,氰基, 具有1至10个碳原子的烷氧基或杂环化合物,另外R 3至R 6可以是卤素原子,R 3和R 4,并且R 5和R 6可以形成含有碳,氧,硫或氮的环,R 7和R 8' 各自独立地表示氢原子或甲基,...表示单键或双键,l和m各自为0或1.)
    • 7. 发明申请
    • SULFUR-CONTAINING CYCLIC OLEFIN RESIN AND ITS PRODUCTION METHOD
    • 含硫的环烯烃树脂及其生产方法
    • US20090069503A1
    • 2009-03-12
    • US11914806
    • 2006-05-15
    • Takashi OkadaToshihide YamamotoHiroshi Yamakawa
    • Takashi OkadaToshihide YamamotoHiroshi Yamakawa
    • C08F28/06C07D339/00
    • C08G61/12C07D339/00C08G61/122G11B7/2538
    • An object of the present invention is to provide a novel sulfur-containing cyclic olefin resin having high transparency and high refractive index and being expected to utilization to optical materials such as various plastic lenses represented by a condensing lens, prism sheets, antireflective films, transparent coating materials such as an optical fiber coating material, optical films and the like, and its production method.The present invention relates to a sulfur-containing cyclic olefin resin comprising a unit represented by the following general formula (1) and having a weight average molecular weight of from 1,000 to 1,000,000. (Here, R1 to R6 each independently represents a hydrogen atom, an alkyl group having from 1 to 20 carbon atoms, an aralkyl group having from 1 to 20 carbon atoms, an aromatic group having from 1 to 20 carbon atoms, a cyano group, an alkoxy group having from 1 to 10 carbon atoms or a heterocyclic compound, further R3 to R6 may be a halogen atom, R3 and R4, and R5 and R6 may form a ring containing carbon, oxygen, sulfur or nitrogen, R7 and R8′, each independently represents a hydrogen atom or a methyl group, . . . represents a single bond or a double bond, and 1 and m each is 0 or 1.)
    • 本发明的目的是提供一种具有高透明度和高折射率的新型含硫环状烯烃树脂,并且预期可用于诸如由聚光透镜,棱镜片,抗反射膜,透明膜 涂布材料如光纤涂层材料,光学膜等及其制造方法。 本发明涉及含有下述通式(1)所示的单元且重均分子量为1,000〜1,000,000的含硫环状烯烃树脂。 (这里,R 1〜R 6各自独立地表示氢原子,碳原子数1〜20的烷基,碳原子数1〜20的芳烷基,碳原子数1〜20的芳香族基,氰基, 具有1至10个碳原子的烷氧基或杂环化合物,另外R 3至R 6可以是卤素原子,R 3和R 4,并且R 5和R 6可以形成含有碳,氧,硫或氮的环,R 7和R 8' ,各自独立地表示氢原子或甲基,...表示单键或双键,1和m各自为0或1.)