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    • 2. 发明授权
    • Ultraviolet treatment of metal oxide electrodes
    • 金属氧化物电极的紫外线处理
    • US09082700B2
    • 2015-07-14
    • US13296191
    • 2011-11-14
    • Sean Andrew VailDavid R. EvansWei PanJong-Jan Lee
    • Sean Andrew VailDavid R. EvansWei PanJong-Jan Lee
    • H01L21/44H01L21/268H01G9/20H01L21/02H01L29/786
    • H01L21/2686H01G9/2031H01G9/2059H01L21/02554H01L29/7869Y02E10/542
    • An ultraviolet treatment method is provided for a metal oxide electrode. A metal oxide electrode is exposed to an ultraviolet (UV) light source in a humid environment. The metal oxide electrode is then treated with a moiety having at least one anchor group, where the anchor group is a chemical group capable of promoting communication between the moiety and the metal oxide electrode. As a result, the moiety is bound to the metal oxide electrode. In one aspect the metal oxide electrode is treated with a photoactive moiety. Exposing the metal oxide electrode to the UV light source in the humid environment induces surface defects in the metal oxide electrode in the form of oxygen vacancies. In response to the humidity, atmospheric water competes favorably with oxygen for dissociative adsorption on the metal oxide electrode surface, and hydroxylation of the metal oxide electrode surface is induced.
    • 为金属氧化物电极提供紫外线处理方法。 金属氧化物电极在潮湿环境中暴露于紫外(UV)光源。 然后用具有至少一个锚定基团的部分处理金属氧化物电极,其中锚定基团是能够促进部分和金属氧化物电极之间的连通的化学基团。 结果,该部分与金属氧化物电极结合。 在一个方面,用光活性部分处理金属氧化物电极。 在潮湿环境中将金属氧化物电极暴露于UV光源以氧空位的形式引起金属氧化物电极中的表面缺陷。 响应于湿度,大气水与氧反应,在金属氧化物电极表面上进行离解吸附,诱导金属氧化物电极表面的羟基化。