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    • 6. 发明授权
    • Chromophore-containing compounds for opto-electronic applications
    • 用于光电子应用的含有发色团的化合物
    • US5290630A
    • 1994-03-01
    • US754014
    • 1991-09-03
    • David P. DevonaldIan FergusonMichael G. HutchingsTimothy G. Ryan
    • David P. DevonaldIan FergusonMichael G. HutchingsTimothy G. Ryan
    • C08F220/34C07C205/40C07C217/84C07C245/08C07C255/65C07C317/32C08F20/34C08F246/00C08G59/20C08G73/00C08G73/06C09B29/08C09K9/02G02F1/065G02F1/361G03C1/72G03F7/038G02F1/35
    • G02F1/065G02F1/3615Y10T428/261Y10T428/31935
    • The use of a multi-functional, chromophore containing, polymerizable compound for producing an optical element having non-linear optical properties (an NLO element) wherein the multi-functional chromophore is a compound capable of being polymerized into a cross-linked network and of being poled under the influence of an electric field whilst being polymerized into the cross-linked network, the compound having the generalized formula(D) (C) (A) (F)D, C, A and F representing covalently linked moieties where C represents at least one conjugated system of .pi.-bonds,A and D represent at least one respectively .pi.-electron acceptor and .pi.-electron donor groups linked at opposite ends of the conjugated system, and are preferably conjugated with the conjugated system of .pi.-bonds (C) and where more than one moiety A, C or D is present they may be the same or different,F represents at least two polymerizable functional groups, which may be the same or different, attached to the .pi.-conjugated system C or the groups A and D via substituent groups R.sub.1, and R.sub.2, where R.sub.1 and R.sub.2 are selected from alkyl, cycloalkyl, aryl heteroalkyl, alkenyl, cycloalkenyl, and alkynyl including groups which have been substituted or contain heteroatom replacement, the groups F being linked to the compound so that after the compound has been polymerized to give a cross-linked network the interpolymerized functional groups prevent significant realignment of the chromophore groups when the optical element is subject to temperature changes during any further fabrication and in use.
    • 使用多功能发色团的可聚合化合物来制造具有非线性光学性质的光学元件(NLO元件),其中多功能发色团是能够聚合成交联网络的化合物和 在聚合成交联网络的同时在电场的影响下被极化,具有通式(D)(C)(A)(F)D,C,A和F的化合物表示共价连接的部分,其中C 代表(pi) - 键的至少一个共轭体系,A和D表示在共轭系统的相对端连接的至少一个分别(π)电子受体和(pi)电子给体基团,并且优选与 (π) - 键(C)的共轭体系,并且其中存在多于一个部分A,C或D的化合物,它们可以相同或不同,F表示至少两个可相同或不同的可连接的可聚合官能团 到(pi)-co 连接体系C或基团A和D通过取代基R1和R2,其中R1和R2选自烷基,环烷基,芳基杂烷基,烯基,环烯基和炔基,包括被取代或含有杂原子取代基团,基团 F与化合物连接,使得在化合物已经聚合以产生交联网络之后,当在任何进一步的制造和使用期间光学元件经受温度变化时,互聚官能团可防止发色团的显着重新对准。