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1. 发明授权

US07087767B2 Method for producing maleic anhydride 有权
公开(公告)号：US07087767B2
公开(公告)日：2006-08-08
申请号：US10522993
申请日：2003-07-22
申请人： Jens Weiguny , Wilhelm Ruppel , Mark Duda
发明人： Jens Weiguny , Wilhelm Ruppel , Mark Duda
IPC分类号： C07D307/60
CPC分类号： C07D307/60
摘要： Process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of hydrocarbons having at least four carbon atoms by means of oxygen-containing gases at from 350 to 500° C. in the presence of a volatile phosphorus compound over a vanadium-, phosphorus- and oxygen-containing catalyst in a shell-and-tube reactor unit having at least one reaction zone cooled by means of a heat transfer medium, in which the temperature and/or the amount of the heat transfer medium flowing into the first (relative to the feed direction) reaction zone are set so that the mean temperature of the heat transfer medium in the first reaction zone TSB(1st zone), which is calculated as the mean of the inflow temperature and the outflow temperature of the heat transfer medium, is in accordance with the formulae (I) and (II) TSB(1st zone)≦TR(1st zone)−TSafety(1st zone) (I) TSB, Ymax(1st zone)−TA(1st zone)≦TSB(1st zone)≦TSB, Ymax(1st zone)+TB(1st zone), (II) where TR(1st zone) is the runaway temperature of the first reaction zone; TSafety(1st zone) is the safety temperature of the first reaction zone and has a value of 1° C.; TSB, Ymax(1st zone) is the mean temperature of the heat transfer medium in the first reaction zone at which the maximum maleic anhydride yield is achieved in the range TSB(1st zone)≦TR(1st zone); TA(1st zone) is 20° C.; and TB(1st zone) is 10° C.

2. 发明申请

US20050256319A1 Method for producing maleic anhydride 有权
公开(公告)号：US20050256319A1
公开(公告)日：2005-11-17
申请号：US10522993
申请日：2003-07-22
申请人： Jens Weiguny , Wilhelm Ruppel , Mark Duda
发明人： Jens Weiguny , Wilhelm Ruppel , Mark Duda
IPC分类号： C07B61/00 , C07D307/60 , C07D307/36
CPC分类号： C07D307/60
摘要： Process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of hydrocarbons having at least four carbon atoms by means of oxygen-containing gases at from 350 to 500° C. in the presence of a volatile phosphorus compound over a vanadium-, phosphorus- and oxygen-containing catalyst in a shell-and-tube reactor unit having at least one reaction zone cooled by means of a heat transfer medium, in which the temperature and/or the amount of the heat transfer medium flowing into the first (relative to the feed direction) reaction zone are set so that the mean temperature of the heat transfer medium in the first reaction zone TSB(1st zone), which is calculated as the mean of the inflow temperature and the outflow temperature of the heat transfer medium, is in accordance with the formulae (I) and (II) TSB(1st zone)≦TR(1st zone)−TSafety(1st zone) (I) TSB, Ymax(1st zone)−TA(1st zone)≦TSB(1st zone)≦TSB, Ymax(1st zone)+TB(1st zone) (II), where TR(1st zone) is the runaway temperature of the first reaction zone; TSafety(1st zone) is the safety temperature of the first reaction zone and has a value of 1° C.; TSB, Ymax(1st zone) is the mean temperature of the heat transfer medium in the first reaction zone at which the maximum maleic anhydride yield is achieved in the range TSB(1st zone)≦TR(1st zone); TA(1st zone) is 20° C.; and TB(1st zone) is 10° C.

3. 发明授权

US06803473B2 Method for producing maleic acid anhydride 有权
标题翻译：马来酸酐生产方法
公开(公告)号：US06803473B2
公开(公告)日：2004-10-12
申请号：US10220746
申请日：2002-09-05
申请人： Jens Weiguny , Sebastian Storck , Andreas Tenten , Wilhelm Ruppel
发明人： Jens Weiguny , Sebastian Storck , Andreas Tenten , Wilhelm Ruppel
IPC分类号： C07D30760
CPC分类号： B01J8/067 , B01J2208/00212 , B01J2208/0053 , C07C51/215 , C07C57/145
摘要： In a process for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of hydrocarbons having at least four carbon atoms using oxygen-containing gases in the presence of a volatile phosphorus compound over a catalyst comprising vanadium, phosphorus and oxygen in a shell-and-tube reactor unit having at least two successive cooled reaction zones, the temperature of the first reaction zone is from 350 to 450° C. and the temperature of the second and further reaction zones is from 350 to 480° C. and the temperature difference between the hottest reaction zone and the coolest reaction zone is at least 2° C.
摘要翻译：在使用含氧气体的挥发性磷化合物存在下，在包含钒，磷和氧的催化剂存在下，通过异构催化气相氧化具有至少四个碳原子的烃来制备马来酸酐的方法，管式反应器单元具有至少两个连续冷却的反应区，第一反应区的温度为350-450℃，第二反应区和其它反应区的温度为350-480℃，温度差为最热的反应区和最冷的反应区为至少2℃

4. 发明授权

US08721997B2 Reactor for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated 有权
标题翻译：用于连续非均相催化的至少一种待脱氢烃的部分脱氢反应器
公开(公告)号：US08721997B2
公开(公告)日：2014-05-13
申请号：US12912127
申请日：2010-10-26
申请人： Claus Hechler , Wilhelm Ruppel , Goetz-Peter Schindler , Catharina Klanner , Hans-Juergen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Joachim Mueller-Engel
发明人： Claus Hechler , Wilhelm Ruppel , Goetz-Peter Schindler , Catharina Klanner , Hans-Juergen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Joachim Mueller-Engel
IPC分类号： B01J8/00
CPC分类号： C07C5/333 , B01J8/067 , B01J19/02 , B01J2219/0236 , C07C51/215 , C22C30/00 , C22C38/40 , Y02P20/52 , C07C11/06 , C07C11/02 , C07C57/04
摘要： A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a composite material which consists, on its side in contact with the reaction chamber, of a steel B with specific elemental composition which, on its side facing away from the reaction chamber, either directly or via an intermediate layer of copper, or of nickel, or of copper and nickel, is plated onto a steel A with specific elemental composition, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.
摘要翻译：在反应器中连续不均匀催化的待脱氢烃的部分脱氢的方法，该反应器由复合材料制成，该复合材料在其与反应室接触的一侧由具有特定元素组成的钢B组成，其直接或经由铜或镍或铜和镍的中间层离开反应室的一侧被镀在具有特定元素组成的钢A上，并且还将脱氢烃和反应堆本身。

5. 发明授权

US07790942B2 Process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated 有权
标题翻译：至少一种待脱氢烃的连续不均匀催化部分脱氢的方法
公开(公告)号：US07790942B2
公开(公告)日：2010-09-07
申请号：US11614425
申请日：2006-12-21
申请人： Claus Hechler , Wilhelm Ruppel , Goetz-Peter Schindler , Catharina Klanner , Hans-Juergen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Joachim Mueller-Engel
发明人： Claus Hechler , Wilhelm Ruppel , Goetz-Peter Schindler , Catharina Klanner , Hans-Juergen Bassler , Martin Dieterle , Karl-Heinrich Klappert , Klaus Joachim Mueller-Engel
IPC分类号： C07C5/327 , C07C5/333 , B01J8/00
CPC分类号： C07C5/3335 , B01J8/008 , B01J8/02 , B01J8/18 , B01J19/02 , B01J2219/00033 , B01J2219/0236 , B01J2219/0286 , C07C5/321 , C07C5/333 , C07C5/48 , C07C45/33 , C07C45/35 , C07C51/215 , C07C51/252 , C07C51/43 , C07C67/08 , C22C38/001 , C22C38/005 , C22C38/02 , C22C38/04 , C22C38/34 , C22C38/40 , C23C10/08 , C23C10/50 , Y02P20/52 , Y02T50/67 , C07C11/06 , C07C57/04 , C07C69/54 , C07C11/04 , C07C47/22
摘要： A process for continuous heterogeneously catalyzed partial dehydrogenation of at least one hydrocarbon to be dehydrogenated in a reactor which is manufactured from a steel with specific elemental composition on its side in contact with the reaction gas, and also partial oxidations of the dehydrogenated hydrocarbon and the reactor itself.
摘要翻译：在反应器中连续不均匀地催化部分脱氢至少一种待脱氢烃的方法，该反应器由与反应气体接触的一侧具有特定元素组成的钢制成，以及脱氢烃和反应器的部分氧化本身。

6. 发明授权

US07186395B2 Iron oxides with a higher degree of refining 有权
标题翻译：具有较高精炼度的氧化铁
公开(公告)号：US07186395B2
公开(公告)日：2007-03-06
申请号：US10473214
申请日：2002-04-03
申请人： Christian Walsdorff , Michael Bajer , Reinhard Körner , Klaus Harth , Gerald Vorberg , Wilhelm Ruppel
发明人： Christian Walsdorff , Michael Bajer , Reinhard Körner , Klaus Harth , Gerald Vorberg , Wilhelm Ruppel
IPC分类号： B10J23/745 , C07C5/32 , C01G49/00
CPC分类号： C01G49/06 , B01J23/745 , B01J23/78 , B01J23/881 , B01J23/8872 , B01J35/023 , B01J37/08 , B01J37/088 , C01G49/02 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/12 , C01P2006/14 , C01P2006/16 , C01P2006/80 , C07C5/3332 , C07C2523/745 , Y10S423/01 , C07C15/46
摘要： Iron oxides are upgraded by calcining at from 700 to 1200° C.
摘要翻译：铁氧化物通过700至1200℃的煅烧升级。

7. 发明授权

US07164039B2 Heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid 有权
标题翻译：将丙烯非均相催化部分气相氧化成丙烯酸
公开(公告)号：US07164039B2
公开(公告)日：2007-01-16
申请号：US10808282
申请日：2004-03-25
申请人： Jochen Petzoldt , Martin Dieterle , Heiko Arnold , Wilhelm Ruppel , Klaus Joachim Mueller-Engel
发明人： Jochen Petzoldt , Martin Dieterle , Heiko Arnold , Wilhelm Ruppel , Klaus Joachim Mueller-Engel
IPC分类号： C07C51/16
CPC分类号： C07C51/252 , C07C57/04
摘要： In a process for heterogeneously catalyzed partial gas phase oxidation of propene to acrylic acid, the propene-containing starting reaction gas mixture is oxidized in a first reaction stage using a fixed catalyst bed 1 which consists of a plurality of fixed catalyst bed zones and is accommodated in two successive temperature zones A, B, and the acrolein-containing product gas mixture of the first reaction stage is then oxidized in a second reaction stage using a fixed catalyst bed 2 which consists of a plurality of fixed catalyst bed zones and is accommodated in two successive temperature zones C, D, and the transition from one temperature zone to another temperature zone within one reaction stage does not spatially coincide with a transition from one fixed catalyst bed zone to another fixed catalyst bed zone.
摘要翻译：在将丙烯非均相催化的部分气相氧化成丙烯酸的方法中，含丙烯的起始反应气体混合物在第一反应阶段中使用由多个固定催化剂床区组成的固定催化剂床1被氧化，在两个连续的温度区A，B和第一反应阶段的含丙烯醛的产物气体混合物然后在第二反应阶段中使用由多个固定催化剂床区组成的固定催化剂床2进行氧化，两个连续的温度区域C，D以及在一个反应阶段内从一个温度区域到另一个温度区域的过渡在空间上与从一个固定催化剂床区域到另一个固定催化剂床区域的过渡不一致。

8. 发明申请

US20060183627A1 Method for regenerating re2o7 doped catalyst supports 审中-公开
标题翻译：再生Re2o7掺杂催化剂载体的方法
公开(公告)号：US20060183627A1
公开(公告)日：2006-08-17
申请号：US10547293
申请日：2004-02-16
申请人： Jurgen Stephan , Markus Schubert , Christian Weichert , Wilhelm Ruppel , Peter Resch , Soeren Zimdahl , Frank Mrzena , Andreas Molitor , Stefan Berg , Mathias Fohrmann
发明人： Jurgen Stephan , Markus Schubert , Christian Weichert , Wilhelm Ruppel , Peter Resch , Soeren Zimdahl , Frank Mrzena , Andreas Molitor , Stefan Berg , Mathias Fohrmann
IPC分类号： B01J38/12
CPC分类号： B01J23/92 , B01J23/36 , B01J38/12 , B01J38/14 , C07C6/04 , Y02P20/584
摘要： Method of regenerating an Re2O7-doped supported catalyst which has been deactivated by use in the metathesis of a hydrocarbon mixture comprising C2-C6-olefins (C2-6= feed) (deactivated catalyst), which comprises treating the deactivated catalyst with an inert gas (regeneration gas K1) at from 400 to 800° C. and subsequently treating the deactivated catalyst which has been pretreated with regeneration gas K1 with an oxygen-containing gas (regeneration gas K2).
摘要翻译：通过在包含C 2 -C 6烷基的烃混合物的复分解中使用已经失活的Re 2 O 2 O 7重掺合载体催化剂的再生方法， C 6 - 6 - 烯烃（C 2-6）进料）（失活催化剂），其包括用惰性气体处理失活的催化剂（再生气体K 1），然后用含氧气体（再生气体K 2）处理已经用再生气体K 1预处理的失活催化剂。

9. 发明申请

US20110130607A1 REACTOR FOR CARRYING OUT AUTOTHERMAL GAS-PHASE DEHYDROGENATIONS 有权
标题翻译：用于实施自动气相脱氢反应的反应器
公开(公告)号：US20110130607A1
公开(公告)日：2011-06-02
申请号：US12957618
申请日：2010-12-01
申请人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
发明人： Grigorios Kolios , Wilhelm Ruppel , Ulrike Wegerle , Jasmina Kessel , Wolfgang Gerlinger , Godwind Tafara Peter Mabande , Goetz-Peter Schindler , Albena Kostova , Gerhard Olbert , Peter Pfab
IPC分类号： C07C5/333 , B01J8/02
CPC分类号： B01J19/2485 , B01J2219/182
摘要： A reactor (1) in the form of an essentially horizontal cylinder for carrying out an autothermal gas-phase dehydrogenation of a hydrocarbon-comprising gas stream (2) by means of an oxygen-comprising gas stream (3) to give a reaction gas mixture over a heterogeneous catalyst configured as monolith (4), wherein the interior of the reactor (1) is divided by a detachable, cylindrical or prismatic housing G which is arranged in the longitudinal direction of the reactor (1) and is gastight in the circumferential direction and open at two end faces of the housing into an inner region A having one or more catalytically active zones (5), in which in each case a packing composed of monoliths (4) stacked on top of one another, next to one another and above one another and before each catalytically active zone (5) in each case a mixing zone (6) having solid internals are provided, and an outer region B arranged coaxially to the inner region A, is proposed.
摘要翻译：一种基本上水平的圆筒形式的反应器（1），用于通过含氧气流（3）进行含烃气流（2）的自热气相脱氢，得到反应气体混合物在构造为整料（4）的非均相催化剂上，其中反应器（1）的内部被沿着反应器（1）的纵向布置的可拆卸的圆柱形或棱柱形的壳体G分开，并且在圆周方向并且在壳体的两个端面处打开到具有一个或多个催化活性区域（5）的内部区域A中，其中在每个情况下由堆叠在彼此顶部的整料（4）彼此相邻的填料构成并且在每种情况下，在每个催化活性区（5）之前和之前提供具有固体内部的混合区（6），并且提供与内部区域A同轴布置的外部区域B.

10. 发明申请

US20110009627A1 REACTOR FOR CARRYING OUT HIGH PRESSURE REACTIONS, METHOD FOR STARTING AND METHOD FOR CARRYING OUT A REACTION 审中-公开
标题翻译：实施高压反应的反应器，起动方法和进行反应的方法
公开(公告)号：US20110009627A1
公开(公告)日：2011-01-13
申请号：US12864540
申请日：2009-01-21
申请人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
发明人： Helmut Schmidtke , Wilhelm Ruppel , Helmut Berrsche , Johann-Peter Melder , Udo Rheude , Petr Kubanek , Gerhard Ruf , Wolfgang Gunkel , Wolfgang Mägerlein , Karl-Heinz Ross
IPC分类号： B01J19/00 , C07D265/30 , C07C209/04
CPC分类号： B01J8/067 , B01J8/008 , B01J2208/00539 , B01J2208/00796
摘要： The invention relates to a reactor for performing high-pressure reactions, comprising at least one tube (31) whose ends are each conducted through a tube plate (33) and which is bonded to the tube plate (33). The tube plates (33) and the at least one tube (31) are surrounded by an outer jacket, such that an outer space (39) is formed between the tube (31) and the outer jacket. The tube plates (33) each have at least one surface composed of a nickel-base alloy and the at least one tube (31) is in each case welded on to the surface composed of the nickel-base alloy. The surface composed of the nickel-base alloy points in each case in the direction of the particular reactor end. The outer jacket has a thickness which is sufficient to absorb tensile forces which occur between tube (31) and outer jacket owing to a temperature difference in the event of different expansion. The invention further relates to a process for starting up the reactor and for performing an exothermic reaction in the reactor.
摘要翻译：本发明涉及一种用于进行高压反应的反应器，包括至少一个管（31），其端部各自通过管板（33）导通，并连接到管板（33）。管板（33）和至少一个管（31）被外护套围绕，使得在管（31）和外护套之间形成外部空间（39）。管板（33）各自具有由镍基合金构成的至少一个表面，并且至少一个管（31）各自焊接在由镍基合金构成的表面上。由镍基合金组成的表面在每种情况下都指向特定反应器端的方向。外护套的厚度足以吸收由于在不同膨胀的情况下的温度差而在管（31）和外护套之间发生的张力。本发明还涉及一种启动反应器并在反应器中进行放热反应的方法。

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