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1. 发明申请

US20180287162A1 HIGH SURFACE AREA POROUS CARBON MATERIALS AS ELECTRODES 审中-公开
公开(公告)号：US20180287162A1
公开(公告)日：2018-10-04
申请号：US15766261
申请日：2016-10-10
申请人： James M. Tour , Wang Tuo , Rodrigo Villegas Salvatierra , Almaz S. Jalilov
发明人： James M. Tour , Wang Tuo , Rodrigo Villegas Salvatierra , Almaz S. Jalilov
IPC分类号： H01M4/66 , H01M4/04 , H01M4/133 , H01M4/134 , H01M4/1393 , H01M4/1395 , H01M4/62 , H01M10/0525
摘要： Embodiments of the present disclosure pertain to an electrode that includes: a porous carbon material; a metal (e.g., Li) associated with the porous carbon material; and a conductive additive (e.g., graphene nanoribbons) associated with the porous carbon material. The metal may be in the form of a non-dendritic or non-mossy coating on a surface of the porous carbon material. The electrodes may also be associated with a substrate, such as a copper foil. The electrodes may be utilized as anodes or cathodes in energy storage devices, such as lithium ion batteries. Additional embodiments pertain to energy storage devices that contain the electrodes of the present disclosure. Further embodiments pertain to methods of making the electrodes by associating porous carbon materials with a conductive additive, a metal, and optionally a substrate. The electrode may then be incorporated as a component of an energy storage device.

2. 发明申请

US20180008957A1 HYDRATED POROUS MATERIALS FOR SELECTIVE CO2 CAPTURE 审中-公开
公开(公告)号：US20180008957A1
公开(公告)日：2018-01-11
申请号：US15640765
申请日：2017-07-03
申请人： James M. Tour , Almaz S. Jalilov
发明人： James M. Tour , Almaz S. Jalilov
IPC分类号： B01J20/20 , C10L3/10 , B01J20/30 , B01J20/28 , B01D53/02
CPC分类号： B01J20/20 , B01D53/025 , B01D53/62 , B01D2253/102 , B01D2253/306 , B01D2253/311 , B01D2256/24 , B01D2256/245 , B01D2257/504 , B01J20/28073 , B01J20/28076 , B01J20/3085 , C10L3/104 , C10L2290/542 , Y02A50/2342 , Y02C10/04 , Y02C10/08
摘要： In some embodiments, the present disclosure pertains to methods of capturing CO2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO2 associated environment; and capturing CO2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO2 in the CO2 associated environment. In some embodiments, the step of capturing includes forming CO2-hydrates within the pores of the porous material, where the CO2·n/H2O ratio is n

3. 发明授权

US09776165B2 Porous carbon materials for CO2 separation in natural gas 有权
公开(公告)号：US09776165B2
公开(公告)日：2017-10-03
申请号：US15001835
申请日：2016-01-20
申请人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan , Yilun Li
发明人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan , Yilun Li
IPC分类号： C01B31/08 , B01J20/20 , B01D53/02 , B01J20/28 , C01B31/00 , B01J20/30 , B01J20/34
CPC分类号： B01J20/20 , B01D53/02 , B01D2253/102 , B01D2257/304 , B01D2257/504 , B01J20/28011 , B01J20/28066 , B01J20/2808 , B01J20/28083 , B01J20/3078 , B01J20/3416 , B01J20/3483 , B01J20/3491 , B01J2220/4825 , B01J2220/4837 , B01J2220/485 , B01J2220/4893 , C01B32/00 , C01B32/30 , C01B32/50 , C01P2004/80 , Y02C10/08 , Y02C20/20 , Y02P20/152
摘要： In some embodiments, the present disclosure pertains to materials for use in CO2 capture in high pressure environments. In some embodiments, the materials include a porous carbon material containing a plurality of pores for use in a high pressure environment. Additional embodiments pertain to methods of utilizing the materials of the present disclosure to capture CO2 from various environments. In some embodiments, the materials of the present disclosure selectively capture CO2 over hydrocarbon species in the environment.

4. 发明授权

US10232343B2 Hydrated porous materials for selective CO2 capture 有权
公开(公告)号：US10232343B2
公开(公告)日：2019-03-19
申请号：US15640765
申请日：2017-07-03
申请人： James M. Tour , Almaz S. Jalilov
发明人： James M. Tour , Almaz S. Jalilov
IPC分类号： B01D53/02 , B01J20/20 , B01D53/62 , B01J20/28 , B01J20/30 , C10L3/10
摘要： In some embodiments, the present disclosure pertains to methods of capturing CO2 from an environment by hydrating a porous material with water molecules to the extent thereby to define a preselected region of a plurality of hydrated pores and yet to the extent to allow the preselected region of a plurality of pores of the porous material to uptake gas molecules; positioning the porous material within a CO2 associated environment; and capturing CO2 by the hydrated porous material. In some embodiments, the pore volume of the hydrated porous material includes between 90% and 20% of the pre-hydrated pore volume to provide unhydrated pore volume within the porous material for enhanced selective uptake of CO2 in the CO2 associated environment. In some embodiments, the step of capturing includes forming CO2-hydrates within the pores of the porous material, where the CO2.nH2O ratio is n

5. 发明申请

US20160001260A1 POROUS CARBON MATERIALS FOR CO2 SEPARATION IN NATURAL GAS 有权
标题翻译：用于天然气中二氧化碳分离的多孔碳材料
公开(公告)号：US20160001260A1
公开(公告)日：2016-01-07
申请号：US14833248
申请日：2015-08-24
申请人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan , Yilun Li
发明人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan , Yilun Li
IPC分类号： B01J20/20 , B01J20/28 , B01D53/02
CPC分类号： B01J20/20 , B01D53/02 , B01D2253/102 , B01D2257/304 , B01D2257/504 , B01J20/28011 , B01J20/28066 , B01J20/2808 , B01J20/28083 , B01J20/3078 , B01J20/3416 , B01J20/3483 , B01J20/3491 , B01J2220/4825 , B01J2220/4837 , B01J2220/485 , B01J2220/4893 , C01B32/00 , C01B32/30 , C01B32/50 , C01P2004/80 , Y02C10/08 , Y02C20/20 , Y02P20/152
摘要： In some embodiments, the present disclosure pertains to materials for use in CO2 capture in high pressure environments. In some embodiments, the materials include a porous carbon material containing a plurality of pores for use in a high pressure environment. Additional embodiments pertain to methods of utilizing the materials of the present disclosure to capture CO2 from various environments. In some embodiments, the materials of the present disclosure selectively capture CO2 over hydrocarbon species in the environment.
摘要翻译：在一些实施方案中，本公开涉及用于在高压环境中进行二氧化碳捕获的材料。在一些实施例中，材料包括含有用于高压环境的多个孔的多孔碳材料。另外的实施例涉及利用本公开的材料从各种环境捕获CO 2的方法。在一些实施方案中，本公开的材料在环境中选择性地捕获在烃类上的CO 2。

6. 发明申请

US20150111018A1 LOW COST CARBON MATERIALS FOR THE CAPTURE OF CO2 AND H2S FROM VARIOUS ENVIRONMENTS 审中-公开
标题翻译：用于从各种环境中捕获二氧化碳和硫化氢的低成本碳材料
公开(公告)号：US20150111018A1
公开(公告)日：2015-04-23
申请号：US14458802
申请日：2014-08-13
申请人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan
发明人： James M. Tour , Desmond E. Schipper , Chih-Chau Hwang , Josiah Tour , Almaz S. Jalilov , Gedeng Ruan
IPC分类号： B01D53/04 , B01J20/30 , B01J20/20
CPC分类号： B01D53/04 , B01D53/02 , B01D2253/102 , B01D2257/304 , B01D2257/504 , B01J20/20 , B01J20/3078 , Y02C10/04 , Y02C10/08
摘要： In some embodiments, the present disclosure pertains to methods of capturing a gas from an environment by associating the environment with a porous carbon material that includes, without limitation, protein-derived porous carbon materials, carbohydrate-derived porous carbon materials, cotton-derived porous carbon materials, fat-derived porous carbon materials, waste-derived porous carbon materials, asphalt-derived porous carbon materials, coal-derived porous carbon materials, coke-derived porous carbon materials, asphaltene-derived porous carbon materials, oil product-derived porous carbon materials, bitumen-derived porous carbon materials, tar-derived porous carbon materials, pitch-derived porous carbon materials, anthracite-derived porous carbon materials, melamine-derived porous carbon materials, and combinations thereof. In some embodiments, the associating results in sorption of gas components (e.g., CO2, H2S, and combinations thereof) to the porous carbon material. Additional embodiments of the present disclosure pertain to the porous carbon materials and methods of making the same.
摘要翻译：在一些实施方案中，本公开涉及通过将环境与多孔碳材料缔合而捕获气体的方法，所述多孔碳材料包括但不限于蛋白质衍生的多孔碳材料，来自碳水化合物的多孔碳材料，来自棉花的多孔碳材料碳材料，脂肪衍生的多孔碳材料，废物衍生的多孔碳材料，沥青衍生的多孔碳材料，煤衍生的多孔碳材料，焦炭衍生的多孔碳材料，沥青质衍生的多孔碳材料，油产品多孔碳材料碳材料，沥青衍生的多孔碳材料，焦油衍生的多孔碳材料，沥青衍生的多孔碳材料，无烟煤衍生的多孔碳材料，三聚氰胺衍生的多孔碳材料及其组合。在一些实施方案中，缔合导致气体组分（例如，CO 2，H 2 S及其组合）吸附至多孔碳材料。本公开的另外的实施方案涉及多孔碳材料及其制备方法。

7. 发明授权

US09493355B2 Solvent-based methods for production of graphene nanoribbons 有权
标题翻译：用于生产石墨烯纳米带的基于溶剂的方法
公开(公告)号：US09493355B2
公开(公告)日：2016-11-15
申请号：US14345016
申请日：2012-09-14
申请人： James M. Tour , Wei Lu , Bostjan Genorio
发明人： James M. Tour , Wei Lu , Bostjan Genorio
IPC分类号： C01B31/02 , C07C29/32 , C08F112/08 , C01B31/04
CPC分类号： C08F112/08 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B32/178 , C01B32/18 , C01B32/184 , C01B32/194 , C01B2202/06 , C01B2204/06 , C07C2/76 , C07C15/56 , C07C29/32 , C07C67/035 , C07C69/76 , D01F9/12 , Y10S977/734 , Y10S977/846 , Y10S977/961
摘要： The present invention provides methods of preparing functionalized graphene nanoribbons. Such methods include: (1) exposing a plurality of carbon nanotubes (CNTs) to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to an electrophile to form functionalized graphene nanoribbons (GNRs). The methods may also include a step of exposing the opened CNTs to a protic solvent to quench any reactive species on them. Additional methods include preparing unfunctionalized GNRs by: (1) exposing a plurality of CNTs to an alkali metal source in the presence of an aprotic solvent to open them; and (2) exposing the opened CNTs to a protic solvent to form unfunctionalized GNRs.
摘要翻译：本发明提供了制备官能化石墨烯纳米带的方法。这些方法包括：（1）在非质子溶剂的存在下将多个碳纳米管（CNT）暴露于碱金属源以将其打开; 和（2）将开放的CNT暴露于亲电子试剂以形成官能化的石墨烯纳米带（GNR）。所述方法还可以包括将开放的CNT暴露于质子溶剂以淬灭其上的任何反应性物质的步骤。另外的方法包括：通过以下步骤制备未官能化的GNR：（1）在非质子溶剂存在下将多个CNT暴露于碱金属源以打开它们; 和（2）将开放的CNT暴露于质子溶剂以形成未官能化的GNR。

8. 发明授权

US09356151B2 Fabrication of graphene nanoribbons and nanowires using a meniscus as an etch mask 有权
标题翻译：使用弯月面作为蚀刻掩模制造石墨烯纳米带和纳米线
公开(公告)号：US09356151B2
公开(公告)日：2016-05-31
申请号：US14171642
申请日：2014-02-03
申请人： James M. Tour , Vera Abramova , Alexander Slesarev
发明人： James M. Tour , Vera Abramova , Alexander Slesarev
IPC分类号： H01L21/44 , H01L29/786 , C01B31/04 , H01L21/3065 , H01L21/311 , H01L21/3213 , H01L29/66 , B82Y40/00
CPC分类号： H01L29/78684 , B82Y40/00 , C01B32/182 , C01B32/194 , H01L21/3065 , H01L21/31116 , H01L21/32131 , H01L29/66742 , H01L29/78606 , H01L29/78696
摘要： In some embodiments, the present disclosure pertains to methods of preparing graphene nanoribbons from a graphene film associated with a meniscus, where the method comprises patterning the graphene film while the meniscus acts as a mask above a region of the graphene film, and where the patterning results in formation of graphene nanoribbons from the meniscus-masked region of the graphene film. Additional embodiments of the present disclosure pertain to methods of preparing wires from a film associated with a meniscus, where the method comprises patterning the film while the meniscus acts as a mask above a region of the film, and where the patterning results in formation of a wire from the meniscus-masked region of the film. Additional embodiments of the present disclosure pertain to chemical methods of preparing wires from water-reactive materials.
摘要翻译：在一些实施方案中，本公开涉及从与弯液面相关联的石墨烯膜制备石墨烯纳米带的方法，其中所述方法包括图案化所述石墨烯膜，同时所述弯液面用作所述石墨烯膜的区域上方的掩模，并且其中所述图案化导致从石墨烯膜的弯液面掩蔽区域形成石墨烯纳米带。本公开的另外的实施例涉及从与弯液面相关联的膜制备线的方法，其中所述方法包括图案化所述膜，同时所述弯月面用作所述膜的区域上方的掩模，并且其中所述图案化导致形成电线从弯月面掩盖的区域。本公开的另外的实施方案涉及从水反应性材料制备电线的化学方法。

9. 发明申请

US20150162381A1 ADDRESSABLE SIOX MEMORY ARRAY WITH INCORPORATED DIODES 有权
标题翻译：可寻址的存储器阵列与入射二极管
公开(公告)号：US20150162381A1
公开(公告)日：2015-06-11
申请号：US14240973
申请日：2012-08-27
申请人： James M. Tour , Jun Yao , Jian Lin , Gunuk Wang , Krishna Palem
发明人： James M. Tour , Jun Yao , Jian Lin , Gunuk Wang , Krishna Palem
IPC分类号： H01L27/24 , H01L29/66 , H01L45/00
CPC分类号： H01L27/2463 , H01L27/2409 , H01L29/66136 , H01L29/66143 , H01L29/8611 , H01L29/8613 , H01L29/872 , H01L45/04 , H01L45/1233 , H01L45/1253 , H01L45/145 , H01L45/1608 , H01L45/1616 , H01L45/1625 , H01L45/1675
摘要： Various embodiments of the resistive memory cells and arrays discussed herein comprise: (1) a first electrode; (2) a second electrode; (3) resistive memory material; and (4) a diode. The resistive memory material is selected from the group consisting of SiOx, SiOxH, SiOxNy, SiOxNyH, SiOxCz, SiOxCzH, and combinations thereof, wherein each of x, y and z are equal or greater than 1 or equal or less than 2. The diode may be any suitable diode, such as n-p diodes, p-n diodes, and Schottky diodes.
摘要翻译：本文讨论的电阻式存储器单元和阵列的各种实施例包括：（1）第一电极; （2）第二电极; （3）电阻记忆材料; 和（4）二极管。电阻性存储材料选自SiOx，SiOxH，SiOxNy，SiOxNyH，SiOxCz，SiOxCzH及其组合，其中x，y和z各自等于或大于1或等于或小于2.二极管可以是任何合适的二极管，例如np二极管，pn二极管和肖特基二极管。

10. 发明申请

US20150023858A1 REBAR HYBRID MATERIALS AND METHODS OF MAKING THE SAME 有权
标题翻译： REBAR混合材料及其制备方法
公开(公告)号：US20150023858A1
公开(公告)日：2015-01-22
申请号：US14335566
申请日：2014-07-18
申请人： James M. Tour , Zheng Yan , Zhiwei Peng , Robert H. Hauge , Yilun Li
发明人： James M. Tour , Zheng Yan , Zhiwei Peng , Robert H. Hauge , Yilun Li
IPC分类号： C01B31/36 , B29C39/00 , H01B1/04 , C01B31/04 , C01B31/02
CPC分类号： C01B32/956 , B29C39/003 , B29K2105/124 , B29K2995/0005 , B29L2007/00 , C01B21/064 , C01B32/178 , C01B32/18 , C01B32/184 , C01B32/186 , C01P2004/13
摘要： In some embodiments, the present disclosure pertains to methods of forming a reinforcing material by: (1) depositing a first material onto a catalyst surface; and (2) forming a second material on the catalyst surface, where the second material is derived from and associated with the first material. In some embodiments, the first material includes, without limitation, carbon nanotubes, graphene nanoribbons, boron nitride nanotubes, chalcogenide nanotubes, carbon onions, and combinations thereof. In some embodiments, the formed second material includes, without limitation, graphene, hexagonal boron nitride, chalcogenides, and combinations thereof. In additional embodiments, the methods of the present disclosure also include a step of separating the formed reinforcing material from the catalyst surface, and transferring the separated reinforcing material onto a substrate without the use of polymers. Additional embodiments of the present disclosure pertain to reinforcing materials formed by the aforementioned methods.
摘要翻译：在一些实施方案中，本公开涉及通过以下步骤形成增强材料的方法：（1）将第一材料沉积到催化剂表面上; 和（2）在所述催化剂表面上形成第二材料，其中所述第二材料衍生并与所述第一材料相关联。在一些实施方案中，第一材料包括但不限于碳纳米管，石墨烯纳米带，氮化硼纳米管，硫族化物纳米管，碳鎓和它们的组合。在一些实施例中，所形成的第二材料包括但不限于石墨烯，六方氮化硼，硫族化合物及其组合。在另外的实施方案中，本公开的方法还包括将形成的增强材料从催化剂表面分离并将分离的增强材料转移到基材上而不使用聚合物的步骤。本公开的另外的实施方案涉及通过上述方法形成的增强材料。

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