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1. 发明申请

US20110034713A1 Ortho-metalated, chelate-stabilized benzylamines of the rare-earth metals (RE) Ar3RE 审中-公开
标题翻译：稀土金属（RE）Ar3RE的正金属化，螯合稳定的苄胺
公开(公告)号：US20110034713A1
公开(公告)日：2011-02-10
申请号：US12745057
申请日：2008-11-25
申请人： Jörg Sundermeyer , Alexander Petrov , Oliver Thomas
发明人： Jörg Sundermeyer , Alexander Petrov , Oliver Thomas
IPC分类号： C07F5/00
CPC分类号： C07D207/06 , C07F3/00
摘要： The present invention describes homoleptic, ortho-metalated, chelate-stabilized benzylamine complexes of the rare-earth metals. The rare-earth metals are selected from Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. In the complexes according to the present invention, at least one benzylic proton of the benzylamine ligand is replaced by an alkyl or aryl group. Such complexes are preferred in which both benzylic protons of the benzylamine ligand are replaced by an alkyl- or aryl group. The complexes according to the present invention are produced by reaction of chelate-stabilized rare-earth metal halides with ortho-lithiated aryl ligands at room temperature under inert gas atmosphere. The complexes according to the present invention are thermally stable and suitable for being used as catalysts for the hydroamination of olefins.
摘要翻译：本发明描述了稀土金属的均聚，邻位金属化，螯合稳定的苄胺络合物。稀土金属选自Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy，Ho，Er，Tm，Yb，Lu。在根据本发明的络合物中，苄胺配体的至少一个苄基质子被烷基或芳基取代。这种络合物是优选的，其中苄胺配体的两个苄基质子都被烷基或芳基取代。根据本发明的络合物通过螯合稳定的稀土金属卤化物与邻位锂化的芳基配体在室温下在惰性气体气氛下反应来制备。根据本发明的络合物是热稳定的并且适用于用作烯烃的水解的催化剂。

2. 发明申请

US20140155562A1 HOMOLEPTIC RARE EARTH TRIARYL COMPLEXES 审中-公开
标题翻译： HOMOLEPTIC RARE EARTH TRIARYL复合材料
公开(公告)号：US20140155562A1
公开(公告)日：2014-06-05
申请号：US14235285
申请日：2012-08-02
申请人： Oliver Thomas , Jörg Sundermeyer
发明人： Oliver Thomas , Jörg Sundermeyer
IPC分类号： C07F9/53 , C08F136/08 , C07F9/535 , C08G63/84
CPC分类号： C07F9/5345 , C07F9/5352 , C08F4/52 , C08F4/545 , C08F36/08 , C08F136/08 , C08G63/00 , C08G63/823 , C08G63/84 , C08G69/00 , C08G69/14
摘要： The invention relates to chelate-stabilized homleptic triaryl compounds based on phenylphosphoranes, to methods for preparing same and to the use thereof as catalysts. According to the invention, the object is achieved by homleptic rare earth triaryl complexes of the general formula (I), where SE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu; X=O, CRR′; R1, R2=phenyl; R, R′=mutually independently H, alkyl with n=10 C atoms, phenyl or trimethylsilyl.
摘要翻译：本发明涉及基于苯基磷烷的螯合稳定的亲和三芳基化合物，其制备方法及其作为催化剂的用途。根据本发明，该目的通过通式（I）的亲水性稀土三芳基络合物实现，其中SE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy， Ho，Er，Tm，Yb或Lu; X = O，CRR'; R1，R2 =苯基; R，R'=相互独立地为H，具有n = 10个C原子的烷基，苯基或三甲基甲硅烷基。

3. 发明授权

US09187505B2 Homoleptic rare earth triaryl complexes 有权
标题翻译：同位素稀土三芳基络合物
公开(公告)号：US09187505B2
公开(公告)日：2015-11-17
申请号：US14235285
申请日：2012-08-02
申请人： Oliver Thomas , Jörg Sundermeyer
发明人： Oliver Thomas , Jörg Sundermeyer
IPC分类号： C07F9/53 , C07F9/535 , C08G69/00 , C08G69/14 , C08G63/00 , C08G63/84 , C08F4/52 , C08F36/08 , C08F136/08 , C08F4/54 , C08G63/82
CPC分类号： C07F9/5345 , C07F9/5352 , C08F4/52 , C08F4/545 , C08F36/08 , C08F136/08 , C08G63/00 , C08G63/823 , C08G63/84 , C08G69/00 , C08G69/14
摘要： The invention relates to chelate-stabilized homleptic triaryl compounds based on phenylphosphoranes, to methods for preparing same and to the use thereof as catalysts. According to the invention, the object is achieved by homleptic rare earth triaryl complexes of the general formula (I), where SE=Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb or Lu; X═O, CRR′; R1, R2=phenyl; R, R′=mutually independently H, alkyl with n=10 C atoms, phenyl or trimethylsilyl.
摘要翻译：本发明涉及基于苯基磷烷的螯合稳定的亲和三芳基化合物，其制备方法及其作为催化剂的用途。根据本发明，通过通式（I）的亲水性稀土三芳基络合物，其中SE = Sc，Y，La，Ce，Pr，Nd，Pm，Sm，Eu，Gd，Tb，Dy， Ho，Er，Tm，Yb或Lu; X = O，CRR'; R1，R2 =苯基; R，R'=相互独立地为H，具有n = 10个C原子的烷基，苯基或三甲基甲硅烷基。

4. 发明申请

US20080291605A1 NIOBIUM SUBOXIDE POWDER 有权
标题翻译：氮氧化物粉末
公开(公告)号：US20080291605A1
公开(公告)日：2008-11-27
申请号：US12131536
申请日：2008-06-02
申请人： Oliver Thomas , Christoph Schnitter
发明人： Oliver Thomas , Christoph Schnitter
IPC分类号： C01G33/00 , H01G9/15
CPC分类号： H01B3/12 , C01G33/00 , C01P2004/03 , C01P2004/50 , C01P2004/53 , C01P2004/61 , C01P2006/12 , C01P2006/17 , C01P2006/40 , C01P2006/80 , C04B35/495 , C04B35/6265 , C04B35/6268 , C04B2235/3206 , C04B2235/3251 , C04B2235/3253 , C04B2235/3256 , C04B2235/3258 , C04B2235/5409 , C04B2235/5427 , C04B2235/5445 , C04B2235/5463 , C04B2235/549 , C04B2235/608 , C04B2235/6581 , C04B2235/72 , C04B2235/721 , C04B2235/724 , H01G9/0525
摘要： A niobium suboxide powder comprising 100 to 600 ppm of magnesium is described. The niobium suboxide powder may (alternatively or in addition to 100 to 600 ppm of magnesium) further include 50 to 400 ppm of molybdenum and/or tungsten. The niobium suboxide powder is suitable for the production of: capacitors having an insulator layer of niobium pentoxide; capacitor anodes produced from the niobium suboxide powder; and corresponding capacitors.
摘要翻译：描述了包含100至600ppm的镁的低氧化铌粉末。低氧化铌粉末（或者除了100〜600ppm的镁之外）还包括50〜400ppm的钼和/或钨。低氧化铌粉末适用于生产具有五氧化二铌绝缘体层的电容器; 由低氧铌粉制成的电容器阳极; 和相应的电容器。

5. 发明授权

US07381396B2 Niobium suboxide powder 有权
标题翻译：低氧铌粉
公开(公告)号：US07381396B2
公开(公告)日：2008-06-03
申请号：US10889719
申请日：2004-07-13
申请人： Oliver Thomas , Christoph Schnitter
发明人： Oliver Thomas , Christoph Schnitter
IPC分类号： C01G33/00 , H01G9/00 , H01G9/04 , H01G9/042
CPC分类号： H01B3/12 , C01G33/00 , C01P2004/03 , C01P2004/50 , C01P2004/53 , C01P2004/61 , C01P2006/12 , C01P2006/17 , C01P2006/40 , C01P2006/80 , C04B35/495 , C04B35/6265 , C04B35/6268 , C04B2235/3206 , C04B2235/3251 , C04B2235/3253 , C04B2235/3256 , C04B2235/3258 , C04B2235/5409 , C04B2235/5427 , C04B2235/5445 , C04B2235/5463 , C04B2235/549 , C04B2235/608 , C04B2235/6581 , C04B2235/72 , C04B2235/721 , C04B2235/724 , H01G9/0525
摘要： A niobium suboxide powder comprising 100 to 600 ppm of magnesium is described. The niobium suboxide powder may (alternatively or in addition to 100 to 600 ppm of magnesium) further include 50 to 400 ppm of molybdenum and/or tungsten. The niobium suboxide powder is suitable for the production of: capacitors having an insulator layer of niobium pentoxide; capacitor anodes produced from the niobium suboxide powder; and corresponding capacitors.
摘要翻译：描述了包含100至600ppm的镁的低氧化铌粉末。低氧化铌粉末（或者除了100〜600ppm的镁之外）还包括50〜400ppm的钼和/或钨。低氧化铌粉末适用于生产具有五氧化二铌绝缘体层的电容器; 由低氧铌粉制成的电容器阳极; 和相应的电容器。

6. 发明授权

US06558447B1 Metal powders produced by the reduction of the oxides with gaseous magnesium 有权
标题翻译：通过用气态镁还原氧化物产生的金属粉末
公开(公告)号：US06558447B1
公开(公告)日：2003-05-06
申请号：US09445331
申请日：2001-03-16
申请人： Leonid N. Shekhter , Terrance B. Tripp , Leonid L. Lanin , Karlheinz Reichert , Oliver Thomas , Joachim Vieregge
发明人： Leonid N. Shekhter , Terrance B. Tripp , Leonid L. Lanin , Karlheinz Reichert , Oliver Thomas , Joachim Vieregge
IPC分类号： B22F100
CPC分类号： H01G9/0525 , B22F9/023 , B22F9/20 , B22F9/22 , B22F2998/00 , B22F2998/10 , C22B5/04 , C22B26/22 , C22B34/24 , C22C1/045 , B22F1/0007 , B22F1/0088 , B22F1/0055 , B22F1/0011
摘要： Metal powder Ta and/or Nb, with or without one or metals from the group Ta, Nb, Ti, Mo, W, V, Zr and Hf, is made in a fine powder form by reduction of metal oxide by contact with a gaseous reducing agent, preferably an alkaline earth metal, to near complete reduction, leaching, further deoxidation and agglomeration, the powder so produced being sinterable to capacitor anode form and processable to other usages.
摘要翻译：金属粉末Ta和/或Nb，具有或不具有一种或来自Ta，Nb，Ti，Mo，W，V，Zr和Hf的金属，通过与气体接触而还原金属氧化物而制成细粉末形式还原剂，优选碱土金属，以接近完全还原，浸出，进一步脱氧和附聚，所生产的粉末可与电容器阳极形式烧结并可加工成其他用途。

7. 发明授权

US07618610B2 Niobium suboxide powder 有权
标题翻译：低氧铌粉
公开(公告)号：US07618610B2
公开(公告)日：2009-11-17
申请号：US12131536
申请日：2008-06-02
申请人： Oliver Thomas , Christoph Schnitter
发明人： Oliver Thomas , Christoph Schnitter
IPC分类号： C01G33/00 , H01G9/00 , H01G9/04 , H01G9/042
CPC分类号： H01B3/12 , C01G33/00 , C01P2004/03 , C01P2004/50 , C01P2004/53 , C01P2004/61 , C01P2006/12 , C01P2006/17 , C01P2006/40 , C01P2006/80 , C04B35/495 , C04B35/6265 , C04B35/6268 , C04B2235/3206 , C04B2235/3251 , C04B2235/3253 , C04B2235/3256 , C04B2235/3258 , C04B2235/5409 , C04B2235/5427 , C04B2235/5445 , C04B2235/5463 , C04B2235/549 , C04B2235/608 , C04B2235/6581 , C04B2235/72 , C04B2235/721 , C04B2235/724 , H01G9/0525
摘要： A niobium suboxide powder comprising 100 to 600 ppm of magnesium is described. The niobium suboxide powder may (alternatively or in addition to 100 to 600 ppm of magnesium) further include 50 to 400 ppm of molybdenum and/or tungsten. The niobium suboxide powder is suitable for the production of: capacitors having an insulator layer of niobium pentoxide; capacitor anodes produced from the niobium suboxide powder; and corresponding capacitors.
摘要翻译：描述了包含100至600ppm的镁的低氧化铌粉末。低氧化铌粉末（替代地或除了100至600ppm的镁之外）还包括50至400ppm的钼和/或钨。低氧化铌粉末适用于生产具有五氧化二铌绝缘体层的电容器; 由低氧铌粉制成的电容器阳极; 和相应的电容器。

8. 发明申请

US20050013765A1 Niobium suboxide powder 有权
标题翻译：低氧铌粉
公开(公告)号：US20050013765A1
公开(公告)日：2005-01-20
申请号：US10889719
申请日：2004-07-13
申请人： Oliver Thomas , Christoph Schnitter
发明人： Oliver Thomas , Christoph Schnitter
IPC分类号： C01F5/02 , C01G20060101 , C01G33/00 , C04B35/00 , C04B35/495 , C22C1/05 , C22C29/12 , H01B3/02 , H01B3/12 , H01G20060101 , H01G4/10 , H01G9/042 , H01G9/052
CPC分类号： H01B3/12 , C01G33/00 , C01P2004/03 , C01P2004/50 , C01P2004/53 , C01P2004/61 , C01P2006/12 , C01P2006/17 , C01P2006/40 , C01P2006/80 , C04B35/495 , C04B35/6265 , C04B35/6268 , C04B2235/3206 , C04B2235/3251 , C04B2235/3253 , C04B2235/3256 , C04B2235/3258 , C04B2235/5409 , C04B2235/5427 , C04B2235/5445 , C04B2235/5463 , C04B2235/549 , C04B2235/608 , C04B2235/6581 , C04B2235/72 , C04B2235/721 , C04B2235/724 , H01G9/0525
摘要： A niobium suboxide powder comprising 100 to 600 ppm of magnesium is described. The niobium suboxide powder may (alternatively or in addition to 100 to 600 ppm of magnesium) further include 50 to 400 ppm of molybdenum and/or tungsten. The niobium suboxide powder is suitable for the production of: capacitors having an insulator layer of niobium pentoxide; capacitor anodes produced from the niobium suboxide powder; and corresponding capacitors.
摘要翻译：描述了包含100至600ppm的镁的低氧化铌粉末。低氧化铌粉末（或者除了100〜600ppm的镁之外）还包括50〜400ppm的钼和/或钨。低氧化铌粉末适用于生产具有五氧化二铌绝缘体层的电容器; 由低氧铌粉制成的电容器阳极; 和相应的电容器。

9. 发明授权

US06821314B1 Capacitor powder 有权
标题翻译：电容粉
公开(公告)号：US06821314B1
公开(公告)日：2004-11-23
申请号：US10129536
申请日：2002-05-07
申请人： Karlheinz Reichert , Oliver Thomas , Christoph Schnitter
发明人： Karlheinz Reichert , Oliver Thomas , Christoph Schnitter
IPC分类号： B22F100
CPC分类号： H01G9/042 , H01G9/0525 , Y10T428/12181
摘要： An electrolyte capacitor containing a niobium anode, a niobium oxide barrier layer, a semiconducting cathode and an electrolyte is described, where the niobium oxide barrier comprises a least one metal from the group consisting of Al, Si, Ti, Zr, Mo, W, Y and Ta.
摘要翻译：描述了含有铌阳极，铌氧化物阻挡层，半导体阴极和电解质的电解质电容器，其中铌氧化物阻挡层包括由Al，Si，Ti，Zr，Mo，W等组成的组中的至少一种金属， Y和Ta。

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