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1. 发明申请

US20050143540A1 Ion exchange polymer dispersion, process for its production and its use 有权
标题翻译：离子交换聚合物分散体，其生产工艺及其应用
公开(公告)号：US20050143540A1
公开(公告)日：2005-06-30
申请号：US11030295
申请日：2005-01-07
申请人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
发明人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
IPC分类号： C08F30/04 , C08F130/04 , C08F230/04 , C08J3/03 , C08J5/20 , H01M4/86 , H01M4/88 , H01M4/92 , H01M4/96
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25° C. at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译：通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声波振动或剪切力，使得分散体在25℃下的粘度在10（1 / s）的剪切速率下，在增稠步骤中增加2-2000次。当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上形成的层来制备作为催化剂层的膜 - 电极组件通过相对于离子交换膜提供催化剂层，阴极和阳极中的至少一个。由于催化剂层强度高，缺点少，光滑性好，因此可以得到固体高分子电解质燃料电池用高性能膜 - 电极组件。

2. 发明授权

US07582713B2 Ion exchange polymer dispersion, process for its production and its use 有权
标题翻译：离子交换聚合物分散体，其生产工艺及其应用
公开(公告)号：US07582713B2
公开(公告)日：2009-09-01
申请号：US11030295
申请日：2005-01-07
申请人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
发明人： Ichiro Terada , Satoru Hommura , Nobuyuki Kasahara , Katsuya Ueno
IPC分类号： C08F12/30
CPC分类号： C08J5/2293 , C08F30/04 , C08F130/04 , C08F230/04 , C08J3/05 , C08J5/20 , C08J2327/12 , C08J2327/18 , H01M4/8605 , H01M4/8803 , H01M4/8828 , H01M4/921 , H01M4/96 , H01M8/1004 , H01M8/1023 , H01M8/1039 , H01M8/1051 , H01M8/1081 , Y02P70/56 , Y10T428/24802
摘要： A thickened ion exchange polymer dispersion is obtained by applying ultrasonic vibration or a shearing force to an ion exchange polymer dispersion having a fluorinated polymer having sulfonic acid groups as an ion exchange polymer uniformly dispersed in a dispersion medium so that the viscosity of the dispersion at 25° C. at a shear rate of 10 (1/s) increases 2-2000 times in a thickening step. When formed into a membrane, the dispersion can forms an ion exchange membrane having a uniform and small thickness, high strength, which is free from cracking and shows constant swelling in water and steam. Further, a layer formed by applying a coating solution containing this dispersion and a catalyst powder comprising catalyst metal particles and a carbon support loaded with the catalyst metal particles to a substrate can be used to prepare a membrane-electrode assembly as a catalyst layer for at least one of the cathode and the anode by providing the catalyst layer adjacently to an ion exchange membrane. Because the catalyst layer is highly strong, has few defects and is excellently smooth, a high-performance membrane-electrode assembly for solid polymer electrolyte fuel cells can be obtained.
摘要翻译：通过对具有磺酸基的氟化聚合物作为离子交换聚合物均匀分散在分散介质中的离子交换聚合物分散体施加超声波振动或剪切力，使得分散体在25℃下的粘度在10（1 / s）的剪切速率下，在增稠步骤中增加2-2000次。当形成膜时，分散体可以形成具有均匀且小的厚度，高强度的离子交换膜，其没有破裂并且在水和蒸汽中显示恒定的溶胀。此外，可以使用通过将含有该分散体的涂布溶液和包含催化剂金属颗粒的催化剂粉末和负载有催化剂金属颗粒的碳载体的催化剂粉末涂布到基板上而形成的层，以制备作为催化剂层的膜 - 电极组件通过相对于离子交换膜提供催化剂层，阴极和阳极中的至少一个。由于催化剂层强度高，缺点少，光滑性好，因此可以得到固体高分子电解质燃料电池用高性能膜 - 电极组件。

3. 发明授权

US08658746B2 Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权
标题翻译：用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装
公开(公告)号：US08658746B2
公开(公告)日：2014-02-25
申请号：US12976446
申请日：2010-12-22
申请人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
发明人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译：提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

4. 发明申请

US20060063903A1 Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权
公开(公告)号：US20060063903A1
公开(公告)日：2006-03-23
申请号：US11271915
申请日：2005-11-14
申请人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
发明人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.

5. 发明授权

US07902311B2 Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权
标题翻译：用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装
公开(公告)号：US07902311B2
公开(公告)日：2011-03-08
申请号：US12329119
申请日：2008-12-05
申请人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
发明人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译：提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

6. 发明授权

US07488788B2 Electrolyte polymer for polymer electrolyte fuel cells, process for its production and membrane-electrode assembly 有权
标题翻译：用于聚合物电解质燃料电池的电解质聚合物，其生产方法和膜 - 电极组装
公开(公告)号：US07488788B2
公开(公告)日：2009-02-10
申请号：US11271915
申请日：2005-11-14
申请人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
发明人： Nobuyuki Kasahara , Atsushi Watakabe , Tetsuji Shimohira , Hisao Kawazoe , Ichiro Terada
IPC分类号： C08F16/24
CPC分类号： C08J5/2243 , C08J2327/12 , H01B1/122 , H01M4/8668 , H01M8/1023 , H01M8/1039 , Y02P70/56
摘要： To provide an electrolyte polymer for polymer electrolyte fuel cells, made of a perfluorinated polymer having sulfonic groups, characterized in that in a test of immersing 0.1 g of the polymer in 50 g of a fenton reagent solution containing 3% of an aqueous hydrogen peroxide solution and 200 ppm of bivalent iron ions at 40° C. for 16 hours, the amount of eluted fluorine ions detected in the solution is not more than 0.002% of the total amount of fluorine in the polymer immersed. The electrolyte polymer of the present invention has very few unstable terminal groups and has an excellent durability, and therefore, is suitable as a polymer constituting an electrolyte membrane for polymer electrolyte fuel cells and a polymer contained in a catalyst layer.
摘要翻译：提供一种由具有磺酸基团的全氟化聚合物制成的聚合物电解质燃料电池用电解质聚合物，其特征在于，将0.1g聚合物浸入50g含3％过氧化氢水溶液的芬顿试剂溶液和200ppm二价铁离子在40℃下反应16小时，溶液中检出的洗脱氟离子的量不超过浸渍聚合物中氟的总量的0.002％。本发明的电解质聚合物具有非常少的不稳定的端基并且具有优异的耐久性，因此适合作为构成聚合物电解质燃料电池的电解质膜的聚合物和包含在催化剂层中的聚合物。

7. 发明申请

US20120148818A1 NOVEL FLUORINE-CONTAINING COPOLYMER AND MEMBRANE 审中-公开
标题翻译：新型含氟聚合物和膜
公开(公告)号：US20120148818A1
公开(公告)日：2012-06-14
申请号：US13362630
申请日：2012-01-31
申请人： Safir L. ADAM , Song Li , Shinji Okada , Nobuyuki Kasahara , Katsuya Ueno , Yoshitomi Morizawa , Takashi Okazoe
发明人： Safir L. ADAM , Song Li , Shinji Okada , Nobuyuki Kasahara , Katsuya Ueno , Yoshitomi Morizawa , Takashi Okazoe
IPC分类号： C08F214/24 , B32B27/28 , C09D127/12
CPC分类号： C08F214/24 , C08F214/242
摘要： A fluorine-containing copolymer, containing: chlorotrifluoroethylene monomer units (A); and monomer units (B), which are obtained by polymerizing a monomer selected from the group consisting of (i) a monomer having a formula: CH2═CHCOON(R0)2, wherein each R0 is independently a hydrogen or an alkyl group; (ii) N-vinylcaprolactam; (iii) a monomer having a formula: CH2═CR1CH2OCH2CR2═CH2, wherein R1 and R2 are each independently a hydrogen, a fluorine, or a methyl group; (iv) a monomer having a formula: CH2═CHCH2CH(CH3)—R3, wherein R3 is a linear alkyl group comprising 1 to 7 carbons; and (v) a monomer of methyl 2-fluoroacrylate, wherein a ratio, (A)/((A)+(B)), is from 3 to 99 mol %, a fluorine content of the copolymer is from 15 to 75 mol %, and a molecular weight of the copolymer is from 1,000 to 1,000,000.
摘要翻译：含有三氟氯乙烯单体单元（A）的含氟共聚物; 和单体单元（B），其通过聚合选自（i）具有式：CH 2 = CHCOON（R 0）2的单体的单体而获得的单体单元（B），其中每个R 10独立地为氢或烷基; （ii）N-乙烯基己内酰胺; （iii）具有式：CH 2 = CR 1 CH 2 OCH 2 CR 2 = CH 2的单体，其中R 1和R 2各自独立地为氢，氟或甲基; （iv）具有式：CH 2 = CHCH 2 CH（CH 3）-R 3的单体，其中R 3是包含1至7个碳的直链烷基; 和（v）2-氟丙烯酸甲酯的单体，其中（A）/（（A）+（B））的比例为3〜99摩尔％，共聚物的氟含量为15〜75摩尔％，共聚物的分子量为1,000〜1,000,000。

8. 发明授权

US08026316B2 Process for producing fluorination-treated perfluoropolymer 有权
标题翻译：生产氟化处理过的全氟聚合物的方法
公开(公告)号：US08026316B2
公开(公告)日：2011-09-27
申请号：US12616873
申请日：2009-11-12
申请人： Nobuyuki Kasahara , Noriaki Miyake
发明人： Nobuyuki Kasahara , Noriaki Miyake
IPC分类号： C08F8/22
CPC分类号： C08F8/22 , B01J19/0013 , B01J19/2415 , B01J2219/00087 , B29C47/0014 , C08F14/18 , C08F14/26 , C08F214/18 , C08F214/262 , C08F2/00
摘要： To provide a process for efficiently producing a perfluoropolymer having unstable terminal groups reduced. A process for producing a fluorination-treated perfluoropolymer, which comprises melting a thermoplastic perfluoropolymer to form strands and contacting the polymer strands with a fluorine gas. For fluorination-treatment of the perfluoropolymer, an apparatus 10 is used, which comprises a melt extruder 11 for melting and extruding the perfluoropolymer, a die 12 for forming the melt extruded polymer into continuous strands 1 and a fluorination tank 13 for contacting the continuous strands 1 with a fluorine gas.
摘要翻译：提供一种有效生产具有不稳定末端基团的全氟聚合物降低的方法。一种氟化处理的全氟聚合物的制造方法，其包括熔融热塑性全氟聚合物以形成股线并使聚合物链与氟气接触。对于全氟聚合物的氟化处理，使用装置10，其包括用于熔融和挤出全氟聚合物的熔体挤出机11，用于将熔融挤出的聚合物形成为连续的链1的模具12和用于使连续的链条接触的氟化槽13 1与氟气。

9. 发明授权

US06410808B1 Method for producing a fluoroalcohol 有权
标题翻译：氟代醇的制造方法
公开(公告)号：US06410808B1
公开(公告)日：2002-06-25
申请号：US09840072
申请日：2001-04-24
申请人： Yutaka Furukawa , Nobuyuki Kasahara , Kazuya Oharu , Shin Tatematsu
发明人： Yutaka Furukawa , Nobuyuki Kasahara , Kazuya Oharu , Shin Tatematsu
IPC分类号： C07C3134
CPC分类号： C07C41/26 , C07C29/124 , C07C43/137 , C07C31/38
摘要： A method for producing a fluoroalcohol of the following formula 1a, which comprises reacting a compound of the following formula 1 with water in a liquid phase at a temperature of 150° C. or higher under a gauge pressure of 0.4 MPa or higher: wherein n is an integer of from 1 to 5, X is a chlorine atom, a bromine atom or an iodine atom, p is an integer of at least 1, and R is a p-valent organic group, provided that when p is 1, R may be a hydrogen atom or a halogen atom.
摘要翻译：一种下式1a的氟代醇的制造方法，其特征在于，在表压为0.4MPa以上的条件下，使下式1的化合物与液相中的水在150℃以上的温度下反应：其中n 为1〜5的整数，X为氯原子，溴原子或碘原子，p为1以上的整数，R为p价有机基团，条件是当p为1时，R 可以是氢原子或卤素原子。

10. 发明授权

US07012164B2 Method for continuously producing a polyether 失效
标题翻译：连续生产聚醚的方法
公开(公告)号：US07012164B2
公开(公告)日：2006-03-14
申请号：US10895063
申请日：2004-07-21
申请人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
发明人： Kazuhiko Yamada , Nobuyuki Kasahara , Yoshinori Toyota , Chitoshi Suzuki , Shigeru Ikai , Hiroshi Hatano
IPC分类号： C08G65/28
CPC分类号： C08G65/2696 , C08G65/2663
摘要： A method for precisely producing a polyether having a relatively high molecular weight by means of a double metal cyanide complex catalyst is provided. A method for continuously producing a polyether, which comprises ring opening addition polymerization of an alkylene oxide in the presence of a double metal cyanide complex catalyst, wherein substantially no vapor phase part is present in a reactor.
摘要翻译：提供了一种通过双金属氰化物配合物催化剂精确生产具有较高分子量的聚醚的方法。一种连续生产聚醚的方法，其包括在双金属氰化物配位催化剂存在下环氧烷的开环加成聚合反应，其中在反应器中基本上不存在气相部分。

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