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1. 发明公开

US20240151683A1 REDOX-RESPONSIVE HALOGEN BONDING POLYMERS FOR SELECTIVE ELECTROCHEMICAL SEPARATION 审中-公开
公开(公告)号：US20240151683A1
公开(公告)日：2024-05-09
申请号：US18382796
申请日：2023-10-23
申请人： THE BOARD OF TRUSTEES OF THE UNIVERSITY OF ILLINOIS
发明人： Xiao SU , Nayeong KIM , Johannes ELBERT
IPC分类号： G01N27/333 , C08F130/04
CPC分类号： G01N27/333 , C08F130/04
摘要： The design of electrochemically responsive halogen donors in redox-active polymer for switchable electrosorption and release of anions. A redox-active group such as ferrocene acts as an electron-withdrawing group, facilitating the delocalization of the electrons on the halogen atom. Upon the oxidation of the ferrocene moiety, the halogen atom forms a partial-positive charge (σ-hole) on the elongation of the C—I bond, resulting in strong binding with anions in cooperation with the hydrogen bonds on the cyclopentadienyl ring on the oxidized ferrocene. During reduction of ferrocene, halogen bonding is deactivated, releasing the bound anions reversibly.

2. 发明授权

US08552129B2 Low melt flow branched ionomers 有权
标题翻译：低熔体流动分支离聚物
公开(公告)号：US08552129B2
公开(公告)日：2013-10-08
申请号：US13296692
申请日：2011-11-15
申请人： John Gaustad , Juan J. Aguirre , Joe Shuler
发明人： John Gaustad , Juan J. Aguirre , Joe Shuler
IPC分类号： C08F30/04 , C08F130/04 , C08F20/06 , C08L33/06 , B60C1/00
CPC分类号： C08F30/04 , C08F212/08 , C08F220/06 , C08F230/04 , C08J5/18 , C08J9/00 , C08J9/04 , C08J2325/14 , C08K5/0091 , C08L35/06 , C08L35/00 , C08F220/14 , C08F222/10
摘要： Embodiments of the present invention include a branched aromatic ionomer, and a process of making it, by co-polymerizing a first monomer comprising an aromatic moiety and an unsaturated alkyl moiety and a second monomer represented by the general formula: [R-AZ]y-MX wherein R is a hydrocarbon chain having from 2 to 40 carbons and at least one polymerizable unsaturation; A is an anionic group; M is a cationic group; Z is −1 or −2; X is +1, +2, +3, +4, or +5; and y is an integer having a value of from 1 to 4. The branched aromatic ionomer has a melt flow index ranging from 1.0 g/10 min. to 13 g/10 min. Optionally the melt flow index ranges from 1.3 g/10 min. to 1.9 g/10 min.
摘要翻译：本发明的实施方案包括支链芳族离聚物及其制备方法，通过共聚合包含芳族部分和不饱和烷基部分的第一单体和由通式[R-AZ] y表示的第二单体 -MX，其中R是具有2至40个碳的烃链和至少一个可聚合不饱和度; A是阴离子基团; M是阳离子基团; Z为-1或-2; X是+1，+2，+3，+4或+5; y为1〜4的整数。支链芳族离聚物的熔体流动指数为1.0g / 10min。至13g / 10min。任选地，熔体流动指数为1.3g / 10min。至1.9g / 10分钟。

3. 发明申请

US20130184421A1 Supramolecular Functional Materials 审中-公开
标题翻译：超分子功能材料
公开(公告)号：US20130184421A1
公开(公告)日：2013-07-18
申请号：US13789193
申请日：2013-03-07
申请人： University of the Witwatersrand
发明人： Manuel Antonio Fernandes
IPC分类号： C08F130/04 , C07F3/06 , C07F15/06 , C08G79/00
CPC分类号： C08F130/04 , C07F3/06 , C07F15/065 , C08G79/00 , C08G83/008
摘要： The field of this invention relates to supramolecular functional materials, particularly to coordination networks, more particularly to coordination polymers, more particularly to metal based one-dimensional coordination polymers. The metal based one-dimensional coordination polymers comprises a repeat unit [L1-M-L2]n where L1 and L2 are one of a plurality of carboxylate ligands and L1 can be the same as L2, M is a metal, particularly a transition metal, and n is an integer from 1 to infinity. The metal based one-dimensional coordination polymers display one or more physico-chemical properties giving at least one functionality to the supramolecular material. Furthermore, a method of forming the metal based one-dimensional coordination polymers is provided by a chemical reaction between said organic ligand and said metal where said method comprises at least one selectable chemical reaction condition from the group comprising: volume of reaction vessel, material composition of reaction vessel, temperature, pressure, humidity and gas defining an atmosphere inside reaction vessel.
摘要翻译：本发明的领域涉及超分子功能材料，特别涉及配位网络，更具体地涉及配位聚合物，更特别涉及基于金属的一维配位聚合物。基于金属的一维配位聚合物包括重复单元[L1-M-L2] n，其中L1和L2是多个羧酸盐配体之一，L1可以与L2相同，M是金属，特别是过渡金属，n是从1到无穷大的整数。基于金属的一维配位聚合物显示出一种或多种给予超分子材料至少一种官能团的物理化学性质。此外，通过所述有机配体和所述金属之间的化学反应提供形成金属的一维配位聚合物的方法，其中所述方法包括至少一种可选择的化学反应条件，其包括：反应容器的体积，材料组成的反应容器，温度，压力，湿度和气体，限定反应容器内的气氛。

4. 发明申请

US20110197969A1 METHODS AND INTERMEDIATES FOR THE SYNTHESIS OF DIPYRRIN-SUBSTITUTED PORPHYRINIC MACROCYCLES 失效
标题翻译：二吡啶取代的磷杂环化合物的合成方法及其中间体
公开(公告)号：US20110197969A1
公开(公告)日：2011-08-18
申请号：US13086751
申请日：2011-04-14
申请人： Lianhe Yu , Kannan Muthukumaran , Prathapan Sreedharan , Jonathan S. Lindsey
发明人： Lianhe Yu , Kannan Muthukumaran , Prathapan Sreedharan , Jonathan S. Lindsey
IPC分类号： H01L51/44 , C07D403/06 , C07D487/22 , C08F130/04 , G11C11/00
CPC分类号： H01L51/0077 , C07D403/06 , C07D403/14 , C07D487/22 , Y02E10/549 , Y02P70/521
摘要： The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.
摘要翻译：本发明提供二吡咯取代的卟啉大环化合物，可用于制备其的中间体及其制备方法。这些化合物可用于包括制备分子记忆装置，太阳能电池和光收集阵列的目的。

5. 发明申请

US20030078416A1 SUBSTITUTED PHENANTHROLINES 无效
标题翻译：取代的苯乙烯
公开(公告)号：US20030078416A1
公开(公告)日：2003-04-24
申请号：US08648270
申请日：1996-05-15
发明人： YITZHAK TOR , DIMITRIOS TZALIS
IPC分类号： C07H019/00 , C07H021/00 , C07D471/04 , C08F030/04 , C07H019/04 , C07H019/06 , C07H019/067 , C07H019/073 , C07H019/09 , C08F130/04
CPC分类号： C07D471/04 , C07F15/0053 , C07H21/00
摘要： The invention relates to 1,10 phenanthroline derivatives substituted at the 3-,8-positions.
摘要翻译：本发明涉及在3-，8-位取代的1,10个菲咯啉衍生物

6. 发明申请

US20020007028A1 Bioadhesive composition 有权
标题翻译：生物粘合剂组合物
公开(公告)号：US20020007028A1
公开(公告)日：2002-01-17
申请号：US09777266
申请日：2001-02-05
发明人： Hsing-Yeh Parker , Allan Sachs Hoffman
IPC分类号： C08F030/04 , C08F130/04 , C08F012/30 , C08F122/38
CPC分类号： C08F265/04 , A61L24/043 , C08F283/01 , C08F290/046 , C08F290/06 , C08F291/00 , C08L2666/02 , C09J151/003 , Y10S526/909 , C08L33/00
摘要： A bioadhesive composition is disclosed which includes copolymer particles containing as polymerized units, terminally unsaturated acid-containing oligomers and ethylenically unsaturated nonionic monomers. A method of preparing the bioadhesive composition and a method of using the bioadhesive composition are also disclosed.
摘要翻译：公开了一种生物粘合剂组合物，其包括含有聚合单元的共聚物颗粒，含末端不饱和酸的低聚物和烯属不饱和非离子单体。还公开了制备生物粘合剂组合物的方法和使用生物粘合剂组合物的方法。

7. 发明授权

US4529782A High molecular weight water soluble polymers 失效
标题翻译：高分子量水溶性聚合物
公开(公告)号：US4529782A
公开(公告)日：1985-07-16
申请号：US552735
申请日：1983-11-17
申请人： You-Ling Fan , Nan S. Chu , George L. Brode , Meyer R. Rosen
发明人： You-Ling Fan , Nan S. Chu , George L. Brode , Meyer R. Rosen
IPC分类号： C02F1/54 , C08F220/06 , C08F220/56 , C08F30/04 , C08F130/04 , C08F230/04
CPC分类号： C08F220/06 , C02F1/54 , C08F220/56
摘要： Described herein are water soluble acrylamide containing polymers having an intrinsic viscosity of at least about 15 dl/g. These polymers are suitable for use in water purification.
摘要翻译：本文描述的是具有至少约15dl / g的特性粘度的含水溶性丙烯酰胺的聚合物。这些聚合物适用于水净化。

8. 发明授权

US11512158B2 Self-polishing zwitterionic anti-fouling resin having main chain degradability and preparation therefor and use thereof 有权
公开(公告)号：US11512158B2
公开(公告)日：2022-11-29
申请号：US16605112
申请日：2018-03-29
申请人： South China University of Technology
发明人： Guangzhao Zhang , Chunfeng Ma , Qianni Xie
IPC分类号： C08F220/36 , C08F212/08 , C08F220/38 , C08F220/14 , C08F220/28 , C08F226/06 , C08L53/00 , C08F220/18 , C08F130/04
摘要： The present invention belongs to the technical field of marine anti-fouling materials, and discloses a self-polishing zwitterionic anti-fouling resin having a main chain degradability and the preparation therefor and the use thereof. The self-polishing zwitterionic anti-fouling resin is formed by copolymerizing the following three monomers (in the total mass of the monomers): 1% to 80% of an olefinic reactive monomer, 1% to 80% of a cycloketene acetal monomer, and 1% to 80% of a betaine type precursor. The anti-fouling resin has a main chain degradability and a side chain hydrolyzability, and the transition of a coating from being hydrophobic to being hydrophilic is achieved by the hydrolysis of a surface to produce a super-hydrophilic zwitterionic surface, in order to further enhance the anti-fouling ability of the system. The material not only overcomes the disadvantages of poor mechanical properties and poor solubility in an organic solvent of a zwitterionic material, but can also effectively control the long-term stable release of an anti-fouling agent, so as to achieve a synergistic anti-fouling effect of the anti-fouling agent and an anti-protein. The method of the present invention is simple, has a relatively low cost, and is suitable for industrial production. The material is used in the field of marine anti-fouling coatings.

9. 发明授权

US09745190B2 Passivated metal nanoparticles having an epoxide-based oligomer coating 有权
公开(公告)号：US09745190B2
公开(公告)日：2017-08-29
申请号：US13178398
申请日：2011-07-07
申请人： Paul Jelliss , Steven Buckner , Stephen W. Chung , Brandon J. Thomas
发明人： Paul Jelliss , Steven Buckner , Stephen W. Chung , Brandon J. Thomas
IPC分类号： B32B5/16 , B82Y30/00 , B82Y40/00 , B01J13/14 , B22F1/00 , C07F19/00 , C08F130/04 , B82B1/00 , B82B3/00
CPC分类号： B82Y30/00 , B01J13/14 , B22F1/0018 , B22F1/0062 , B22F2999/00 , B82Y40/00 , Y10T428/2991 , B22F2301/052 , B22F2301/058 , B22F2301/35 , B22F2304/054 , B22F2304/056 , B22F2304/058
摘要： This invention provides metal nanoparticles (e.g., aluminum, chromium, iron and magnesium) having an epoxide-based oligomer coating, compositions thereof, method of making the same, and methods of use thereof, including for energy related applications.

10. 发明授权

US08759413B2 Lanthanum containing novel polyacrylate for optical lenses 失效
标题翻译：含镧的新型聚丙烯酸酯用于光学透镜
公开(公告)号：US08759413B2
公开(公告)日：2014-06-24
申请号：US12303659
申请日：2007-03-09
申请人： Rakesh Kumar Khandal , Amita Malik , Geetha Seshadri , Mukti Tyagi
发明人： Rakesh Kumar Khandal , Amita Malik , Geetha Seshadri , Mukti Tyagi
IPC分类号： C08F290/06 , C08F30/04 , C08F130/04 , C08F230/04 , C08L63/00
CPC分类号： C08F230/04 , C08F212/08 , C08K3/22 , G02B1/041
摘要： A process for the preparation of lanthanum containing polyacrylates for optical applications. The process consists in dispersing lanthanum oxide in acrylic acid to form a monomer mixture. An aromatic carboxylic acid is added to the monomer mixture and then a cross linking agent is added thereto. Such a monomer mixture is subjected to the step of polymerization by gamma radiation.
摘要翻译：一种用于光学应用的含镧聚丙烯酸酯的制备方法。该方法在于将氧化镧在丙烯酸中分散以形成单体混合物。将芳族羧酸加入到单体混合物中，然后加入交联剂。这样的单体混合物经受γ辐射聚合的步骤。

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