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    • 5. 发明授权
    • Plasma enhanced chemical vapor deposition method of forming titanium silicide comprising layers
    • 等离子体增强化学气相沉积法形成含硅化钛的层
    • US06586285B1
    • 2003-07-01
    • US10094017
    • 2002-03-06
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • H01L2184
    • C23C16/4407C23C16/14C23C16/42C23C16/4404
    • A first cleaning is conducted on a plasma enhanced chemical vapor deposition chamber at room ambient pressure. After the first cleaning, elemental titanium comprising layers are chemical vapor deposited on a first plurality of substrates within the chamber using at least TiCl4. Thereafter, titanium silicide comprising layers are plasma enhanced chemical vapor deposited on a second plurality of substrates within the chamber using at least TiCl4 and a silane. Thereafter, a second cleaning is conducted on the chamber at ambient room pressure. In one implementation after the first cleaning, an elemental titanium comprising layer is chemical vapor deposited over internal surfaces of the chamber while no semiconductor substrate is received within the chamber. In another implementation, a titanium silicide comprising layer is chemical vapor deposited over internal surfaces of the chamber while no semiconductor substrate is received within the chamber.
    • 在室内环境压力下,在等离子体增强化学气相沉积室上进行第一次清洗。 在第一次清洁之后,使用至少TiCl 4,在室内的第一组多个衬底上化学气相沉积包含层的元素钛。 此后,包含层的硅化钛是使用至少TiCl 4和硅烷沉积在室内的第二多个基板上的等离子体增强化学气相。 此后,在室内在室内进行第二清洗。 在第一次清洁之后的一个实施方案中,元素钛包含层在室的内表面上化学气相沉积,而在室内没有接收半导体衬底。 在另一个实施方案中,包含硅化钛的层在室的内表面上化学气相沉积,而在腔室内不接收半导体衬底。
    • 7. 发明申请
    • Plasma enhanced chemical vapor deposition method of forming titanium silicide comprising layers
    • 等离子体增强化学气相沉积法形成含硅化钛的层
    • US20060172087A1
    • 2006-08-03
    • US11394988
    • 2006-03-30
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip CampbellGurtej Sandhu
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip CampbellGurtej Sandhu
    • C23C16/14
    • H01L21/28518C23C16/42H01L21/28556
    • Chemical vapor deposition methods of forming titanium silicide including layers on substrates are disclosed. TiCl4 and at least one silane are first fed to the chamber at or above a first volumetric ratio of TiCl4 to silane for a first period of time. The ratio is sufficiently high to avoid measurable deposition of titanium silicide on the substrate. Alternately, no measurable silane is fed to the chamber for a first period of time. Regardless, after the first period, TiCl4 and at least one silane are fed to the chamber at or below a second volumetric ratio of TiCl4 to silane for a second period of time. If at least one silane was fed during the first period of time, the second volumetric ratio is lower than the first volumetric ratio. Regardless, the second feeding is effective to plasma enhance chemical vapor deposit a titanium silicide including layer on the substrate.
    • 公开了在衬底上形成包括层的硅化钛的化学气相沉积方法。 TiCl 4 S和至少一种硅烷首先以等于或高于TiCl 4的第一体积比与硅烷一起进料到室中,持续第一段时间。 该比例足够高以避免钛硅化物在衬底上的可测量沉积。 或者,在第一时间段内没有可测量的硅烷进料到室中。 无论如何,在第一阶段之后,将TiCl 4 S和至少一种硅烷以等于或低于TiCl 4的第二体积比与硅烷一起进料到室中,持续第二阶段 时间。 如果在第一时间段内进料至少一种硅烷,则第二体积比率低于第一体积比。 无论如何,第二次进料对于等离子体有效地提高了化学气相沉积在基底上的包含硅的硅化钛。
    • 9. 发明授权
    • Plasma enhanced chemical vapor deposition method of forming titanium silicide comprising layers
    • 等离子体增强化学气相沉积法形成含硅化钛的层
    • US07393563B2
    • 2008-07-01
    • US11394989
    • 2006-03-30
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • C23C16/14C23C16/24
    • H01L21/28518C23C16/42H01L21/28556
    • Chemical vapor deposition methods of forming titanium suicide including layers on substrates are disclosed. TiCl4 and at least one silane are first fed to the chamber at or above a first volumetric ratio of TiCl4 to silane for a first period of time. The ratio is sufficiently high to avoid measurable deposition of titanium silicide on the substrate. Alternately, no measurable silane is fed to the chamber for a first period of time. Regardless, after the first period, TiCl4 and at least one silane are fed to the chamber at or below a second volumetric ratio of TiCl4 to silane for a second period of time. If at least one silane was fed during the first period of time, the second volumetric ratio is lower than the first volumetric ratio. Regardless, the second feeding is effective to plasma enhance chemical vapor deposit a titanium silicide including layer on the substrate.
    • 公开了在衬底上形成包括层的硅化钛的化学气相沉积方法。 TiCl 4 S和至少一种硅烷首先以等于或高于TiCl 4的第一体积比与硅烷一起进料到室中,持续第一段时间。 该比例足够高以避免钛硅化物在衬底上的可测量沉积。 或者,在第一时间段内没有可测量的硅烷进料到室中。 无论如何,在第一阶段之后,将TiCl 4 S和至少一种硅烷以等于或低于TiCl 4的第二体积比与硅烷一起进料到室中,持续第二阶段 时间。 如果在第一时间段内进料至少一种硅烷,则第二体积比率低于第一体积比。 无论如何,第二次进料对于等离子体有效地提高了化学气相沉积在基底上的包含硅的硅化钛。
    • 10. 发明授权
    • Plasma enhanced chemical vapor deposition method of forming titanium silicide comprising layers
    • 等离子体增强化学气相沉积法形成含硅化钛的层
    • US06767823B2
    • 2004-07-27
    • US10094580
    • 2002-03-06
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • Cem BasceriIrina VasilyevaAmmar DerraaPhilip H. CampbellGurtej S. Sandhu
    • H01L214763
    • H01L21/28518C23C16/42H01L21/28556
    • Chemical vapor deposition methods of forming titanium silicide comprising layers on substrates are disclosed. TiCl4 and at least one silane are first fed to the chamber at or above a first volumetric ratio of TiCl4 to silane for a first period of time. The ratio is sufficiently high to avoid measurable deposition of titanium silicide on the substrate. Alternately, no measurable silane is fed to the chamber for a first period of time. Regardless, after the first period, TiCl4 and at least one silane are fed to the chamber at or below a second volumetric ratio of TiCl4 to silane for a second period of time. If at least one silane was fed during the first period of time, the second volumetric ratio is lower than the first volumetric ratio. Regardless, the second feeding is effective to plasma enhance chemical vapor deposit a titanium silicide comprising layer on the substrate.
    • 公开了在衬底上形成包含层的硅化钛的化学气相沉积方法。 首先将TiCl 4和至少一种硅烷以等于或高于TiCl 4与硅烷的第一体积比率进料到室中。 该比例足够高以避免钛硅化物在衬底上的可测量沉积。 或者,在第一时间段内没有可测量的硅烷进料到室中。 无论如何,在第一阶段之后,将TiCl 4和至少一种硅烷以等于或低于第二体积比的TiCl 4与硅烷进料至室中第二时间段。 如果在第一时间段内进料至少一种硅烷,则第二体积比率低于第一体积比。 无论如何,第二次进料对于等离子体有效地增强化学气相沉积在基底上的包含硅化钛的层。