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    • 6. 发明授权
    • Poly etch without separate oxide decap
    • 聚蚀刻无单独的氧化物剥落
    • US07442319B2
    • 2008-10-28
    • US11168023
    • 2005-06-28
    • Kevin Shea
    • Kevin Shea
    • C03C25/68
    • H01L21/32134B81C1/00595H01L21/76838H01L27/1052
    • The use of an ammonium hydroxide spike to a hot tetra methyl ammonium hydroxide (TMAH) solution to form an insitu poly oxide decapping step in a polysilicon (poly) etch process, results in a single step rapid poly etch process having uniform etch initiation and a high etch selectivity, that may be used in manufacturing a variety of electronic devices such as integrated circuits (ICs) and micro electro-mechanical (MEM) devices. The etching solution is formed by adding 35% ammonium hydroxide solution to a hot 12.5% TMAH solution at about 70° C. at a rate of 1% by volume, every hour. Such an etch solution and method provides a simple, inexpensive, single step self initiating poly etch that has etch stop ratios of over 200 to 1 over underlying insulator layers and TiN layers.
    • 将氢氧化铵尖峰用于热四甲基氢氧化铵(TMAH)溶液以在多晶硅(多晶)蚀刻工艺中形成原位聚氧化物去贴图步骤,导致具有均匀蚀刻开始的单步骤快速多晶刻蚀工艺和 高蚀刻选择性,其可用于制造各种电子器件,例如集成电路(IC)和微机电(MEM)器件。 蚀刻溶液通过在约70℃以每小时1体积%的速率将35%氢氧化铵溶液加入到热的12.5%TMAH溶液中形成。 这种蚀刻溶液和方法提供了一种简单,便宜的单步自发聚合蚀刻,其在下面的绝缘体层和TiN层上具有超过200比1的蚀刻停止比。
    • 9. 发明申请
    • Method of etching nitrides
    • 蚀刻氮化物的方法
    • US20060011586A1
    • 2006-01-19
    • US10892332
    • 2004-07-14
    • Kevin Shea
    • Kevin Shea
    • B44C1/22H01L21/461
    • H01L21/31111H01L27/10855
    • Etching chemistries for etching nitride materials selective to oxide materials and selective to resist patterning materials are disclosed along with methods of etching nitride materials, such as dielectric nitride materials and metal nitride materials. The etching chemistries and methods incorporate using an ultra-dilute (approximately 1500:1 to 2500:1) 49% hydrofluoric (HF) acid and optionally adding ozone (O3) to the etching mixture that etches nitride materials selective to oxide materials, such as oxides doped with impurities or non-doped oxides, and resist patterning materials. The dilution of the HF acid will affect the selectivity of the etching solution (nitride material to the oxide or resist materials) and can be tailored to obtain a desired etching result.
    • 蚀刻用于蚀刻对氧化物材料选择性并且抗蚀剂图案化材料选择性的氮化物材料的蚀刻化学品与氮化物材料如介电氮化物材料和金属氮化物材料的蚀刻方法一起公开。 蚀刻化学和方法使用超稀释(约1500:1至2500:1)49%氢氟酸(HF)酸和任选地向蚀刻氮化物的蚀刻混合物中加入臭氧(O 3 3 N) 对氧化物材料(例如掺杂有杂质或非掺杂氧化物的氧化物)和抗蚀剂图案化材料选择性材料。 HF酸的稀释将影响蚀刻溶液(氮化物材料对氧化物或抗蚀剂材料)的选择性,并且可以被调整以获得所需的蚀刻结果。