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    • 1. 发明授权
    • Process for producing thermoset resin
    • 生产热固性树脂的方法
    • US5189094A
    • 1993-02-23
    • US680005
    • 1991-04-01
    • Hiroyuki UmetaniHiroo InataShunichi MatsumuraHiroshi Mera
    • Hiroyuki UmetaniHiroo InataShunichi MatsumuraHiroshi Mera
    • C08F299/04C08L67/06
    • C08F299/0478C08L67/06
    • A process for producing a thermoset resin, which comprises reacting (A) a poly(cyclic iminoether), (B) an ethylenically unsaturated compound having a functional group reactive with the poly(cyclic iminoether), and (C) an ethylenically unsaturated monomer having no functional group reactive with the poly(cyclic iminoether), in the presence of an acid catalyst and a radical catalyst. Instead of the compound (B), there may be used the compound (D), i.e. a compound having at least two equivalents of at least one group selected from the class consisting of carboxyl, hydroxyl, amino, epoxy and carboxylic anhydride groups in the molecule and being free from an ethylenically unsaturated bond. The present application provides also a thermosetting composition and a thermoset resin.
    • 一种制备热固性树脂的方法,其包括使(A)聚(环亚胺基醚),(B)具有与聚(环亚胺醚)反应的官能团的烯键式不饱和化合物与(C)烯属不饱和单体 在酸催化剂和自由基催化剂的存在下,没有与聚(环亚胺醚)反应的官能团。 代替化合物(B),可以使用化合物(D),即具有至少两当量的选自羧基,羟基,氨基,环氧基和羧酸酐基团中的至少一个基团的化合物 分子并且不含烯属不饱和键。 本申请还提供了热固性组合物和热固性树脂。
    • 9. 发明授权
    • Plural liquid pack type, heat-curable polyisocyanate-polyol-polyepoxy
resin composition and process for producing a shaped resin article
therefrom
    • 多种液体包装型,可热固化的多异氰酸酯 - 多元醇 - 多环氧树脂组合物及其制备成型树脂制品的方法
    • US5223598A
    • 1993-06-29
    • US942104
    • 1992-09-08
    • Takeyoshi YamadaHiroyuki Umetani
    • Takeyoshi YamadaHiroyuki Umetani
    • C08G18/16C08G18/18C08G18/40
    • C08G18/1875C08G18/165C08G18/1816C08G18/4045C08G2120/00
    • A plural liquid pack type resin composition useful for producing a shaped resin article having an enhanced heat resistance, mechanical strength and machinability, comprises a first resinous individual component (A) comprising a polyisocyanate compound and a second resinous individual component (B) comprising a mixture of a polyol compound with a polyepoxy compound and a curing agent, or an individual sub-component (i) comprising a mixture of a polyol compound and a polyepoxy compounds and another individual sub-component (ii) comprising a mixture of the polyol compound with a curing agent, in which composition the polyol compound is contained in an amount of 10 to 40 equivalents of the hydroxyl group, the polyepoxy compound is contained in an amount of 5 to 20 equivalents of the epoxy group, and the total equivalent amount of the hydroxyl group and the epoxy groups is 15 to 45 equivalents per 100 equivalents of the isocyanate groups of the polyisocyanate compounds.
    • 可用于制造具有增强的耐热性,机械强度和机械加工性的成型树脂制品的多液体包装型树脂组合物包括包含多异氰酸酯化合物的第一树脂单独组分(A)和包含混合物的第二树脂单独组分(B) 多元醇化合物与多环氧化合物和固化剂的多元醇化合物,或包含多元醇化合物和聚环氧化合物的混合物的单独的副组分(i)和包含多元醇化合物与 固化剂,其中含有10〜40当量羟基的多元醇化合物的组合物,所述聚环氧化合物的含量为环氧基的5〜20当量, 羟基和环氧基相对于多异氰酸酯化合物的每100当量异氰酸酯基为15〜45当量。