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1. 发明授权

US4731409A Aqueous coating composition containing fine particles of water insoluble resin solution 失效
标题翻译：水性涂料组合物含有水不溶性树脂溶液的微粒
公开(公告)号：US4731409A
公开(公告)日：1988-03-15
申请号：US11211
申请日：1987-02-03
申请人： Hiroshi Miwa , Hideyoshi Noda , Sakuichi Konishi
发明人： Hiroshi Miwa , Hideyoshi Noda , Sakuichi Konishi
IPC分类号： C09D5/00 , C09D5/02 , C08L63/00 , C08L33/02
CPC分类号： C09D5/02
摘要： An aqueous coating composition comprising (A) an aqueous medium, (B) at least one water soluble or dilutable resin which has a water tolerance of 4 or more and whose 1% by weight aqueous solution shows a surface tension of 51 dyne/cm or less, and (C) fine particles of resinous solution of water insoluble resin in a hydrophobic solvent, the particles being uniformly dispersed in the combination of said aqueous medium (A) and the water soluble or dilutable resin (B) and having a mean diameter of 1.mu. or less, which is characterized in that the absolute value of difference in solubility parameter (.vertline..DELTA.Sp.vertline.) between said resinous solution and said water soluble or dilutable resin is within a range of .vertline..DELTA.Sp.vertline.
摘要翻译：一种水性涂料组合物，其包含（A）水性介质，（B）至少一种水溶性或可稀释的树脂，其耐水性为4以上，并且其1重量％的水溶液表现出51达因/厘米的表面张力或少量，（C）水不溶性树脂的树脂溶液在疏水性溶剂中的微细颗粒，均匀分散在所述水性介质（A）和水溶性或可稀释树脂（B）的组合中，其平均直径其特征在于，所述树脂溶液和所述水溶性或可稀释树脂之间的溶解度参数（| DELTA Sp|）的差异绝对值在| DELTA Sp| <2的范围内。本涂料组合物的储存稳定性和施加特性优异，得到具有优异光泽和表面光滑度的涂料。

2. 发明授权

US5037865A Resin dispersion type aqueous coating composition comprising microparticles of 1 .mu.m or less 失效
标题翻译：含有1μm以下的微粒的树脂分散型水性涂料组合物
公开(公告)号：US5037865A
公开(公告)日：1991-08-06
申请号：US339822
申请日：1989-01-23
申请人： Motoyoshi Yoshikawa , Hideyoshi Noda , Sakuichi Konishi
发明人： Motoyoshi Yoshikawa , Hideyoshi Noda , Sakuichi Konishi
IPC分类号： H01H23/02 , C08G18/08 , C09D5/00 , C09D5/02 , C09D163/00 , C09D175/00 , H01H9/16
CPC分类号： C09D5/02 , C08G18/0866 , C09D163/00
摘要： A resin dispersion type aqueous coating composition comprising a continuous phase of water medium and an aqueous resin and water insoluble resin microparticles uniformly dispersed, as a discontinuous phase, in said continuous phase, which is characterized in that said water insoluble resin is prepared by the reaction of a resin which is liquid at room temperatures and bears in its molecule functional groups capable of reacting with an epoxy or isocyanate group, and an epoxy compound or an isocyanate compound so as to give 10.about.100% reaction rate of the epoxy or isocyanate group contained in said compound. The present aqueous coating composition is excellent in its application characteristics and can give a coating with excellent gloss and smoothness.
摘要翻译：树脂分散水漆。包含（a）连续相，由aq。介质和水性树脂，（b）由水不溶性树脂制成的分散相。通过使环氧化物或异氰酸酯与cpd反应。对比功能性GPS。其与环氧树脂或异氰酸酯gps反应。使环氧或异氰酸酯gps的反应比例。是10-100％。水洗鞋树脂可以用有机溶剂配制。

3. 发明授权

US5023298A Curable composition 失效
公开(公告)号：US5023298A
公开(公告)日：1991-06-11
申请号：US457939
申请日：1989-12-27
申请人： Hiroshi Miwa , Yoshitaka Okude , Masakazu Watanabe , Sakuichi Konishi
发明人： Hiroshi Miwa , Yoshitaka Okude , Masakazu Watanabe , Sakuichi Konishi
IPC分类号： C09D5/00 , C08G59/00 , C08G59/18 , C08G59/40 , C08K5/35 , C08K5/5415 , C08L43/04 , C08L57/10 , C08L63/00 , C09D133/00 , C09D143/04 , C09D163/00 , C09D201/08
CPC分类号： C09D143/04 , C08K5/35 , C08K5/5415 , C08L43/04 , C08L57/10 , C09D133/00
摘要： Disclosed is a curable composition which is superior in chemical resistance and weather resistance and appearance by the use of oxazolidine compounds, comprising (A) a compound having a carboxylic anhydride group, (B) an oxazolidine compound and (C) a polymer containing an alkoxysilyl group. An epoxy compound (D) may be added to the composition.

4. 发明授权

US5043452A Titanium or silicon atom containing oxazolidine compound 失效
标题翻译：含有恶唑烷化合物的钛或硅原子
公开(公告)号：US5043452A
公开(公告)日：1991-08-27
申请号：US458372
申请日：1989-12-28
申请人： Hiroshi Miwa , Yoshitaka Okude , Masakazu Watanabe , Sakuichi Konishi
发明人： Hiroshi Miwa , Yoshitaka Okude , Masakazu Watanabe , Sakuichi Konishi
IPC分类号： C07F7/00 , C07F7/04 , C07F7/18 , C07F7/28
CPC分类号： C07F7/28 , C07F7/006 , C07F7/045 , C07F7/1824
摘要： Disclosed is a novel oxazolidine compound containing a titanium atom or a silicon atom. The ozazolidine compound is represented by the following formula [I]; ##STR1## wherein R represents a hydrogen atom, a C.sub.1 -C.sub.10 alkyl, an aryl group, a vinyl group, a C.sub.1 -C.sub.10 halogen substituted alkyl group or a C.sub.1 -C.sub.10 alkoxy group, M represents a silicon atom or a titanium atom, R.sup.1 represents a C.sub.2 -C.sub.5 alkylene group, R.sup.2 and R.sup.3 respectively represent a hydrogen atom, a C.sub.1 -C.sub.10 alkyl group or an aryl group, R.sup.4 represents a hydrogen atom or a methyl group and n is an integer of 0 to 3.

5. 发明授权

US5039343A Water borne metallic coating composition 失效
标题翻译：水性金属涂料组合物
公开(公告)号：US5039343A
公开(公告)日：1991-08-13
申请号：US509508
申请日：1990-04-16
申请人： Shinichiro Umeda , Yoshitaka Okude , Teruaki Kuwajima , Sakuichi Konishi , Satoru Nagahata , Masakazu Watanabe
发明人： Shinichiro Umeda , Yoshitaka Okude , Teruaki Kuwajima , Sakuichi Konishi , Satoru Nagahata , Masakazu Watanabe
IPC分类号： C08G18/62 , C08L61/20 , C08L63/02 , C09D5/38 , C09D133/06
CPC分类号： C09D5/38 , C08G18/6254 , C08G18/6266 , C09D133/066 , C08L61/20 , C08L63/00
摘要： The present invention provides a water borne metallic coating composition which stably disperses a metallic pigment and provides good metallic appearance independently of coating conditions. The water borne coating composition of the present invention comprises a specific film forming polymer (I), a specific fluorine containing compound (II), a metallic pigment (III), a crosslinking agent (IV), a compound (V) selected from the group consisting of a phosphorus containing titanate coupling agent and a phosphoric mono- or di-ester of a C.sub.11- C.sub.24 organic compound.

6. 发明授权

US5057156A Metallic pigment composition and water borne coating composition thereof 失效
标题翻译：金属颜料组合物及其水性涂料组合物
公开(公告)号：US5057156A
公开(公告)日：1991-10-15
申请号：US502771
申请日：1990-04-02
申请人： Teruaki Kuwajima , Satoru Nagahata , Sakuichi Konishi
发明人： Teruaki Kuwajima , Satoru Nagahata , Sakuichi Konishi
IPC分类号： C09C1/62 , C09C1/64 , C09C3/08 , C09D5/00 , C09D5/02 , C09D5/38 , C09D17/00
CPC分类号： C09C3/08 , C09C1/62 , C09C1/644 , C09D133/08 , C09D17/006 , C09D5/38 , C01P2004/84
摘要： Disclosed is a metallic pigment composition which is stably dispersed in a water borne coating composition and which also provides with smooth coatings having superior water resistance. The metallic pigment composition comprises a metallic pigment and a phosphorous compound represented by the following formula (I) or (II); ##STR1## wherein l and 0 or 1, m is an integer of 1 to 4, R.sub.1, R.sub.2 R.sub.7 and R.sub.8 represent aliphatic, alicyclic or aromatic hydrocarbon groups which are the same or different, selected from a hydrogen atom, a C.sub.1 -C.sub.24 aliphatic hydrocarbon group, a C.sub.3 -C.sub.24 alicyclic hydrocarbon group or a C.sub.6 -C.sub.24 aromatic hydrocarbon group, and R.sub.1 has a valence of m, R.sub.3, R.sub.4, R.sub.5 and R.sub.6, which are the same or different, represent C.sub.1 -C.sub.3 aliphatic hydrocarbon group or a C.sub.6 or C.sub.7 aromatic hydrocarbon group, ##STR2## wherein n is 0, 1 or 2, p is an integer of 1 to 3, n+P equals 3, q is 0 or 1, R.sub.9, R.sub.14 and R.sub.15, which are the same or different, represent a hydrogen atom, a C.sub.1 -C.sub.24 aliphatic hydrocarbon group, a C.sub.3 -C.sub.24 alicyclic hydrocarbon group or a C.sub.6 -C.sub.24 aromatic hydrocarbon group, R.sub.10, R.sub.11, R.sub.12 and R.sub.13, which are the same or different, represent a C.sub.1 -C.sub.3 aliphatic hydrocarbon group or a C.sub.6 or C.sub.7 aromatic hydrocarbon group;the phosphorus compound being present in an amount of 0.5 to 200 parts by weight based on 100 parts by weight of the metallic pigment.The present invention also provides a water borne coating composition which contains the metallic pigment composition.

7. 发明授权

US5183504A Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US5183504A
公开(公告)日：1993-02-02
申请号：US703805
申请日：1991-05-21
申请人： Teruaki Kuwajima , Shinichiro Umeda , Sakuichi Konishi
发明人： Teruaki Kuwajima , Shinichiro Umeda , Sakuichi Konishi
IPC分类号： C09D5/38 , C08G18/08 , C08L75/04 , C09D5/02 , C09D133/02 , C09D133/04 , C09D133/14 , C09D133/26 , C09D175/04 , C09J151/08
CPC分类号： C09J151/08 , C08G18/0823 , C09D133/14 , C09D133/26 , C09D175/04 , C08L75/04
摘要： Disclosed is an aqueous coating composition which keeps in high nonvolatile contents during coating operation and is capable of being effectively applied even under a relatively high humidity condition. The coating composition imparts high orientation of metallic pigment particles to the cured film. The aqueous coating composition of the present invention comprises a specific acryl polymer varnish (a) and a specific urethane oligomer dispersion.

8. 发明授权

US4528318A Aqueous coating composition, and its production 失效
标题翻译：水性涂料组合物及其制备
公开(公告)号：US4528318A
公开(公告)日：1985-07-09
申请号：US462235
申请日：1983-01-31
申请人： Sakuichi Konishi , Naohito Shingo , Mathuo Shibayama
发明人： Sakuichi Konishi , Naohito Shingo , Mathuo Shibayama
IPC分类号： C09D5/00 , C09D5/02 , C09D201/00 , C09D201/02 , C09D201/06 , C09D201/08 , C08L51/00
CPC分类号： C09D201/06
摘要： An aqueous coating composition which comprises an aqueous resin having a carboxyl group (I) and a water-insoluble resin powder (II), the aqueous resin (I) being the one dispersible or soluble into an aqueous medium by ionization when the carboxyl group is neutralized with a basic substance, and the water-insoluble resin powder (II) being the one of 5 to 100 in acid value obtained by reaction between a carboxyl group-containing resin of 20 to 300 in acid value in a solid state at room temperature and a monoepoxy compound or a monoisocyanate compound.
摘要翻译：一种水性涂料组合物，其包含具有羧基（I）和水不溶性树脂粉末（II）的水性树脂，所述水性树脂（I）是当所述羧基为羧基时，通过离子化可分散或溶解于水性介质中的水性树脂用碱性物质中和，水溶性树脂粉末（II）为酸值的5〜100的酸值，通过在室温下的固体状态的酸值为20〜300的羧基树脂反应而得到和单环氧化合物或单异氰酸酯化合物。

9. 发明授权

US4365043A Resinous particles for coating composition and its production 失效
标题翻译：用于涂料组合物的树脂颗粒及其生产
公开(公告)号：US4365043A
公开(公告)日：1982-12-21
申请号：US777548
申请日：1977-03-14
申请人： Sakuichi Konishi , Yukio Omori , Hiroyoshi Kataoka
发明人： Sakuichi Konishi , Yukio Omori , Hiroyoshi Kataoka
IPC分类号： C08J3/12 , C09D5/02 , C09D5/03 , C09D5/46 , C08L33/08 , C08L61/28 , C08L63/00 , C08L67/00
CPC分类号： C08J3/12 , C09D5/02 , C09D5/03 , C08J2300/10 , Y10S524/904
摘要： A process for preparing resinous particles for a coating composition, which comprises the steps of (1) subjecting an aqueous resin composition having an ionic group and no material solubility or dispersibility in water is dissolved or dispersed in an aqueous medium by at least partly neutralizing the ionic group to treatment with a powdering agent while applying thereto an operation for pulverization to deposit the resin in a particulate form and (2) recovering the deposited resinous particles from the aqueous medium.
摘要翻译：一种制备用于涂料组合物的树脂颗粒的方法，其包括以下步骤：（1）将具有离子性基团的水性树脂组合物在水中的溶解性或分散性不受物质溶解或分散在水性介质中，至少部分中和用粉末化剂处理，同时施加粉碎操作以将树脂沉积成颗粒形式，和（2）从水性介质中回收沉积的树脂颗粒。

10. 发明授权

US5151125A Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US5151125A
公开(公告)日：1992-09-29
申请号：US703804
申请日：1991-05-21
申请人： Teruaki Kuwajima , Shinichiro Umeda , Masakazu Watanabe , Sakuichi Konishi
发明人： Teruaki Kuwajima , Shinichiro Umeda , Masakazu Watanabe , Sakuichi Konishi
IPC分类号： C09D133/14 , C08F230/02 , C09D5/38 , C09D17/00 , C09D133/04 , C09D133/06 , C09D137/00 , C09D143/00 , C09D143/02
CPC分类号： C09D17/00 , C08F230/02 , C09D143/02 , C09D5/38
摘要： Disclosed is an aqueous metallic coating composition which significantly reduces the production of hydrogen gas and does not have the problems which are brought about from hydrophobic segments. The composition can be stored for a long period of time and provide a metallic coating having good appearance and film properties (e.g. water resistance and adhesive properties with substrates). The aqueous coating composition of the present invention comprises(a) an acryl resin having a number average molecular weight of 1,000 to 50,000, an acid value of 15 to 200 and a hydroxyl value of 20 to 200, prepared by copolymerizing an ethylenic monomer and a phosphate monomer represented by ##STR1## [wherein X represents a hydrogen atom or a methyl group, Y represents an alkylene group having 2 to 4 carbon atoms and n is an integer of 3 to 30.] and(b) a pigment;the acryl resin being present in an amount of 2 to 500 parts by weight, based on 100 parts by weight of the pigment.
摘要翻译：公开了一种显着降低氢气产生的水性金属涂料组合物，并且不具有从疏水链段引起的问题。该组合物可以长期储存并提供具有良好外观和膜性质（例如耐水性和与基材的粘合性）的金属涂层。本发明的水性涂料组合物包含（a）通过使乙烯类单体和乙烯类单体共聚制备的数均分子量为1,000〜50,000，酸值为15〜200，羟基值为20〜200的丙烯酸树脂由下式表示的磷酸酯单体（I）[式中，X表示氢原子或甲基，Y表示碳原子数2〜4的亚烷基，n表示3〜30的整数。]和（b）颜料 ; 基于100重量份的颜料，丙烯酸树脂以2至500重量份的量存在。

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