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1. 发明授权

US4400408A Method for forming an anticorrosive coating on a metal substrate 失效
标题翻译：在金属基材上形成防腐涂层的方法
公开(公告)号：US4400408A
公开(公告)日：1983-08-23
申请号：US263542
申请日：1981-05-14
申请人： Hiroshi Asano , Takayuki Shimamune , Toshiki Goto , Hideo Nitta , Masashi Hosonuma
发明人： Hiroshi Asano , Takayuki Shimamune , Toshiki Goto , Hideo Nitta , Masashi Hosonuma
IPC分类号： C25B11/06 , B22F7/04 , C23C18/14 , C23C24/08 , C23C24/10 , C23C26/00 , C25B11/10 , B05D3/02 , B05D3/12
CPC分类号： C23C24/106 , B22F7/04 , C23C18/14 , C23C24/08
摘要： A method for forming an anticorrosive coating on the surface of a metal substrate, which comprises, in one embodiment, (1) coating the surface of the metal substrate with an anticorrosive metal capable of forming an alloy with the substrate metal and/or a hydride of the anticorrosive metal; (2) heating the coated surface, and then; (3) heating the coated surface in a vacuum or in an atmosphere substantially inert to the metal coating and the metal substrate by irradiating the coated surface with electron beams, laser beams or a plasma arc to sinter the coated metal and form an alloy layer in the interface between the metal substrate and the metal coating and, in another embodiment, subsequent to Step (2) and prior Step (3) above, coating the coated surface with a solution of a thermally decomposable platinum-group metal compound and then heating the resulting coated surface at about 40.degree. C. to about 600.degree. C.
摘要翻译：一种在金属基材的表面上形成防腐涂层的方法，在一个实施方案中包括（1）用能够与基底金属和/或氢化物形成合金的防腐金属涂覆金属基材的表面的防腐金属; （2）加热涂层表面，然后; （3）通过用电子束，激光束或等离子体电弧照射涂覆的表面，在真空中或在基本上对金属涂层和金属基板惰性的气氛中加热涂覆的表面，以烧结涂覆的金属并形成合金层金属基材和金属涂层之间的界面，在另一个实施方案中，在上述步骤（2）和先前步骤（3）之后，用可热分解的铂族金属化合物的溶液涂覆涂布表面，然后加热得到的涂覆表面在约40℃至约600℃

2. 发明授权

US4349581A Method for forming an anticorrosive coating on a metal substrate 失效
标题翻译：在金属基材上形成防腐涂层的方法
公开(公告)号：US4349581A
公开(公告)日：1982-09-14
申请号：US233704
申请日：1981-02-12
申请人： Hiroshi Asano , Takayuki Shimamune , Toshiki Goto , Hideo Nitta , Masashi Hosonuma
发明人： Hiroshi Asano , Takayuki Shimamune , Toshiki Goto , Hideo Nitta , Masashi Hosonuma
IPC分类号： C23C4/18 , C23C10/28 , C23C18/14 , C23C26/02 , C25B11/00 , B05D1/08
CPC分类号： C23C26/02 , C23C18/14 , C23C4/18 , C25B11/00
摘要： A method for forming an anticorrosive coating on the surface of a metal substrate, which comprises, in one embodiment, (1) coating the surface of the metal substrate with an anticorrosive metal capable of forming an alloy with the substrate metal using a spraying procedure, and (2) then heating the coated surface in a vacuum or in an atmosphere substantially inert to the metal coating and metal substrate by irradiating electron beams or a plasma arc thereonto to form an alloy layer in the interface between the metal substrate and the metal coating and, in a second embodiment, subsequent to step (1) and prior to step (2) above coating a solution of a thermally decomposable platinum-group metal compound on the surface of the resulting coating, and heat-treating the coated product at about 50.degree. to about 300.degree. C.
摘要翻译：一种在金属基材表面上形成防腐蚀涂层的方法，其特征在于，在一个实施方案中，（1）使用喷涂方法用能够与基材金属形成合金的防腐蚀金属涂覆金属基材的表面，和（2）然后在真空中或在基本上对金属涂层和金属基底呈惰性的气氛中通过在其上照射电子束或等离子弧来加热涂覆表面，以在金属基底和金属涂层之间的界面中形成合金层在第二实施方案中，在步骤（1）之后并且在上述步骤（2）之前，在所得涂层的表面上涂覆可热分解的铂族金属化合物溶液，并将涂覆产物在约 50〜300℃

3. 发明申请

US20130032491A1 MEMBRANE-ELECTRODE ASSEMBLY, ELECTROLYTIC CELL USING THE SAME, METHOD AND APPARATUS FOR PRODUCING OZONE WATER, METHOD FOR DISINFECTION AND METHOD FOR WASTEWATER OR WASTE FLUID TREATMENT 审中-公开
标题翻译：膜电极组件，使用其的电解槽，生产臭氧水的方法和装置，消毒方法和废水或废水处理方法
公开(公告)号：US20130032491A1
公开(公告)日：2013-02-07
申请号：US13641436
申请日：2010-11-29
申请人： Hideo Nitta , Masashi Hosonuma
发明人： Hideo Nitta , Masashi Hosonuma
IPC分类号： C25B11/03 , C02F1/467 , C25B15/00
CPC分类号： C02F1/46109 , C02F1/4672 , C02F1/78 , C02F2001/46138 , C02F2001/46157 , C02F2201/46115 , C02F2201/46145 , C02F2201/46195 , C02F2307/06 , C25B9/10 , Y02W10/37
摘要： This invention is to provide a membrane-electrode assembly, an electrolytic cell using the same, a method and an apparatus for producing ozone water, a method for disinfection and a method for wastewater or waste fluid treatment, by using which allow electrolysis reaction products or decomposition products to be produced at a high efficiency, channel pressure drop to be minimized, and the apparatus to be designed compact in size without sacrificing the production capacity.This invention relates to a membrane-electrode assembly, comprising an anode having a plurality of through-holes of 0.1 mm or more in diameter; a cathode having a plurality of through-holes of 0.1 mm or more in diameter at the same sites as in the anode; and a solid polymer electrolyte membrane coated on one face or the entire face of at least one of the anode and the cathode with the through-holes being maintained, wherein the anode, the solid polymer electrolyte membrane and the cathode are tightly adhered.
摘要翻译：本发明提供一种膜 - 电极组件，使用该电极组件的电解槽，臭氧水生产方法和装置，消毒方法和废水或废液处理方法，通过使用这种方法和装置，电解反应产物或以高效率生产的分解产物，通道压降最小化，并且设计尺寸紧凑的装置，而不牺牲生产能力。本发明涉及一种膜 - 电极组件，其包括具有多个直径为0.1mm以上的通孔的阳极; 阴极，其在与阳极相同的位置处具有直径为0.1mm以上的多个通孔; 以及固体聚合物电解质膜，其被覆在阳极和阴极中的至少一个的一个面或整个面上，并且保持通孔，其中阳极，固体聚合物电解质膜和阴极被紧密地粘合。

4. 发明申请

US20130026096A1 MEMBRANE-ELECTRODE ASSEMBLY, ELECTROLYTIC CELL USING THE SAME, METHOD AND APPARATUS FOR PRODUCING OZONE WATER, METHOD FOR DISINFECTION AND METHOD FOR WASTEWATER OR WASTE FLUID TREATMENT 审中-公开
标题翻译：膜电极组件，使用其的电解槽，生产臭氧水的方法和装置，消毒方法和废水或废水处理方法
公开(公告)号：US20130026096A1
公开(公告)日：2013-01-31
申请号：US13641032
申请日：2010-11-29
申请人： Hideo Nitta , Masashi Hosonuma
发明人： Hideo Nitta , Masashi Hosonuma
IPC分类号： C02F1/467 , C25B1/13 , C25B11/08 , C25B9/08 , C25B11/06 , C25B11/03 , C02F1/78
CPC分类号： C02F1/4672 , C02F1/006 , C02F1/46114 , C02F1/78 , C02F2001/46142 , C02F2001/46157 , C02F2201/46115 , C02F2201/46145 , C02F2201/46195 , C02F2307/06 , C25B9/10
摘要： This invention is to provide a membrane-electrode assembly, an electrolytic cell using the same, a method and an apparatus for producing ozone water, a method for disinfection and a method for wastewater or waste fluid treatment, by using which electrolysis reaction products or decomposition products obtained at the anode are produced at a high efficiency; channel pressure drop is minimized; and the apparatus is designed in compact size without sacrificing the production capacity.This invention relates to a membrane-electrode assembly comprising a solid polymer electrolyte membrane having a cation exchange membrane, an anode and a cathode tightly adhered to the respective surfaces of the solid polymer electrolyte membrane, with a plurality of through-holes with 0.1 mm or more in diameter over the entire surfaces of the anode, the solid polymer electrolyte membrane and the cathode, passing through these elements; an electrolytic cell using the membrane-electrode assembly; a method and an apparatus for producing ozone water; a method for disinfection; and a method for wastewater or waste fluid treatment.
摘要翻译：本发明是提供一种膜 - 电极组件，使用其的电解槽，臭氧水生产方法和设备，消毒方法和废水或废液处理方法，通过使用哪一种电解反应产物或分解以高效率生产在阳极获得的产物; 通道压降最小; 并且该设备被设计成紧凑的尺寸而不牺牲生产能力。本发明涉及一种膜 - 电极组件，其包括固体聚合物电解质膜，其具有阳离子交换膜，阳极和阴极，牢固地粘附到固体聚合物电解质膜的各个表面上，具有多个0.1mm的通孔或在整个阳极，固体聚合物电解质膜和阴极的整个表面上的直径更大，穿过这些元件; 使用该膜 - 电极组件的电解槽; 用于生产臭氧水的方法和设备; 一种消毒方法; 以及废水或废液处理方法。

5. 发明授权

US08337958B2 Manufacturing process of electrodes for electrolysis 有权
标题翻译：电解电极的制造工艺
公开(公告)号：US08337958B2
公开(公告)日：2012-12-25
申请号：US12381962
申请日：2009-03-18
申请人： Yi Cao , Masashi Hosonuma
发明人： Yi Cao , Masashi Hosonuma
IPC分类号： C23C14/30 , C23C14/58 , B05D3/02 , B05D5/12
CPC分类号： C25B11/0426 , C23C14/16 , C23C14/325 , C23C14/5806 , C23C14/5853 , C25C7/02
摘要： A process for manufacturing electrodes for electrolysis, including the steps of forming an arc ion plating undercoating layer comprising valve metal or valve metal alloy including a crystalline tantalum component and a crystalline titanium component on the surface of the electrode substrate comprising valve metal or valve metal alloy, by an arc ion plating method; heat sintering the electrode substrate to transform only the tantalum component of the arc ion plating undercoating layer into an amorphous substance; and forming an electrode catalyst layer on the surface of the arc ion plating undercoating layer including the valve metal or valve metal alloy including the tantalum component transformed to the amorphous substance and the crystalline titanium component.
摘要翻译：一种制造电解电极的方法，包括以下步骤：在电极基材的表面上形成包括结晶钽组分和结晶钛组分的阀金属或阀金属合金的电弧离子镀底涂层，其包括阀金属或阀金属合金，通过电弧离子镀法; 对电极基板进行加热烧结，仅将电弧离子电镀底涂层的钽成分变形为无定形物质; 以及在包括转换成非晶体的钽成分和结晶钛成分的阀金属或阀金属合金的电弧离子电镀底涂层的表面上形成电极催化剂层。

6. 发明授权

US07438790B2 Electrode for electrolysis and process for producing the same 有权
标题翻译：电解用电极及其制造方法
公开(公告)号：US07438790B2
公开(公告)日：2008-10-21
申请号：US11491917
申请日：2006-07-25
申请人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
发明人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25B11/12
CPC分类号： C23C16/278 , B82Y30/00 , C02F1/46104 , C02F2001/46138 , C02F2001/46152 , C02F2101/30 , C02F2101/303 , C02F2101/34 , C02F2305/08 , C23C16/0254 , C23C16/271 , C25B11/0478
摘要： The present invention provides an electrode for electrolysis including: a conductive substrate; and a conductive diamond formed on a surface of the conductive substrate, the conductive substrate having at least one surface shape selected from the group consisting of: (a) a surface shape of a combination of an Ra of 100-1,000-μm and an RSm of 50-10,000 μm; (b) a surface shape of a combination of an Ra of 2.5-100 μm and an RSm of 1.5-800 μm, and (c) a surface shape of a combination of an Ra of 0.01-2 μm and an RSm of 0.005-250 μm, and a process for producing the electrode.
摘要翻译：本发明提供一种电解用电极，包括：导电性基板; 以及形成在所述导电基板的表面上的导电金刚石，所述导电基板具有选自以下的至少一种表面形状：（a）Ra为100-1,000μm的组合的表面形状和RSm 50-10,000 mum; （b）Ra为2.5〜100μm，RSm为1.5〜800μm的组合的表面形状，（c）Ra为0.01〜2μm，RSm为0.005〜 250μm，以及电极的制造方法。

7. 发明授权

US07232508B2 Electrolytic electrode and process of producing the same 有权
标题翻译：电解电极及其制造方法
公开(公告)号：US07232508B2
公开(公告)日：2007-06-19
申请号：US10839246
申请日：2004-05-06
申请人： Masashi Hosonuma
发明人： Masashi Hosonuma
IPC分类号： C25B11/10
CPC分类号： C25B11/041 , C23C18/1216 , C23C18/1241 , C23C18/1279 , C23C18/1295 , C25B11/0405 , C25B11/0442 , C25D17/10
摘要： An electrolytic electrode having an interlayer having more excellent peeling resistance and corrosion resistance and longer electrolytic life than conventional electrolytic electrodes and capable of flowing a large amount of current at the industrial level and a process of producing the same are provided. The electrolytic electrode includes a valve metal or valve metal alloy electrode substrate on the surface of which is formed a high-temperature oxidation film by oxidation, and which is coated with an electrode catalyst. The high-temperature oxidation film is integrated with the electrode substrate, whereby peeling resistance is enhanced. Further, by heating the high-temperature oxidation film together with the electrode catalyst, non-electron conductivity of the interlayer is modified, thereby making it possible to flow a large amount of current.
摘要翻译：提供一种具有中间层的电解电极，其具有比常规电解电极更好的耐剥离性，耐腐蚀性和更长的电解寿命，并且能够在工业级流动大量电流及其制造方法。电解电极包括阀金属或阀金属合金电极基板，其表面通过氧化形成高温氧化膜，并且涂覆有电极催化剂。高温氧化膜与电极基板一体化，从而提高耐剥离性。此外，通过与电极催化剂一起加热高温氧化膜，改变了中间层的非电子传导性，从而可以流过大量的电流。

8. 发明申请

US20070029190A1 Electrode for electrolysis and process for producing the same 有权
标题翻译：电解用电极及其制造方法
公开(公告)号：US20070029190A1
公开(公告)日：2007-02-08
申请号：US11491917
申请日：2006-07-25
申请人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
发明人： Masashi Hosonuma , Masaharu Uno , Tomoyasu Shibata , Yoshinori Nishiki , Tsuneto Furuta
IPC分类号： C25C7/02
CPC分类号： C23C16/278 , B82Y30/00 , C02F1/46104 , C02F2001/46138 , C02F2001/46152 , C02F2101/30 , C02F2101/303 , C02F2101/34 , C02F2305/08 , C23C16/0254 , C23C16/271 , C25B11/0478
摘要： The present invention provides an electrode for electrolysis including: a conductive substrate; and a conductive diamond formed on a surface of the conductive substrate, the conductive substrate having at least one surface shape selected from the group consisting of: (a) a surface shape of a combination of an Ra of 100-1,000-μm and an RSm of 50-10,000 μm; (b) a surface shape of a combination of an Ra of 2.5-100 μm and an RSm of 1.5-800 μm, and (c) a surface shape of a combination of an Ra of 0.01-2 μm and an RSm of 0.005-250 μm, and a process for producing the electrode.
摘要翻译：本发明提供一种电解用电极，包括：导电性基板; 以及形成在所述导电基板的表面上的导电金刚石，所述导电基板具有选自以下的至少一种表面形状：（a）Ra为100-1,000μm的组合的表面形状和RSm 50-10,000 mum; （b）Ra为2.5〜100μm，RSm为1.5〜800μm的组合的表面形状，（c）Ra为0.01〜2μm，RSm为0.005〜 250μm，以及电极的制造方法。

9. 发明授权

US5034186A Process for providing titanium composite having a porous surface 失效
标题翻译：提供具有多孔表面的钛复合材料的方法
公开(公告)号：US5034186A
公开(公告)日：1991-07-23
申请号：US932551
申请日：1986-11-20
申请人： Takayuki Shimamune , Hideo Sato , Masashi Hosonuma
发明人： Takayuki Shimamune , Hideo Sato , Masashi Hosonuma
IPC分类号： B22F7/04 , A61F2/00 , A61F2/30 , A61L27/30 , A61L27/56 , B22F3/11 , B22F5/00 , B22F7/00 , C22C1/04 , C22C1/08 , C25B11/04
CPC分类号： C22C1/0458 , A61F2/30767 , A61L27/306 , A61L27/56 , B22F7/004 , C25B11/041 , A61F2002/30011 , A61F2002/30968 , A61F2250/0023 , A61F2310/00023 , A61F2310/00407 , B22F2998/00 , Y10T428/12042 , Y10T428/12063
摘要： A titanium or titanium alloy composite having a porous surface layer, which comprises a titanium or titanium alloy substrate and a porous titanium or titanium alloy layer that adheres strongly to said substrate, said porous layer being formed by first providing said substrate with a firmly adhering sinter of a mixture of a titanium or titanium alloy powder and a magnesium powder, and then removing magnesium from the sinter. A process for producing a titanium or titanium alloy composite having a porous surface layer, comprising: providing a coating composition comprising a binder added to a mixture of a titanium or titanium alloy powder and a magnesium powder; applying said composition to the surface of a titanium or titanium alloy substrate; heating the substrate at a temperature of from 650.degree. to 800.degree. C. in vacuo or an inert atmosphere so as to form a sinter of the powders of titanium or titanium alloy and magnesium which firmly adheres to said substrate; and removing magnesium from said sinter.
摘要翻译：一种具有多孔表面层的钛或钛合金复合体，其包括钛或钛合金基底和与所述基底强烈粘附的多孔钛或钛合金层，所述多孔层通过首先为所述基底提供牢固粘附的烧结体的钛或钛合金粉末和镁粉末的混合物，然后从烧结体中除去镁。一种制备具有多孔表面层的钛或钛合金复合材料的方法，包括：提供包含添加到钛或钛合金粉末和镁粉末的混合物中的粘合剂的涂料组合物; 将所述组合物施加到钛或钛合金基材的表面; 在真空或惰性气氛中，在650〜800℃的温度下加热基材，形成钛或钛合金和镁的粉末的烧结体，其牢固地附着在所述基材上; 并从所述烧结矿中除去镁。

10. 发明授权

US4847163A Metal-metal oxide composites and a coating layer of calcium phosphate on the oxide layer 失效
标题翻译：金属 - 金属氧化物复合物和氧化物层上的磷酸钙涂层
公开(公告)号：US4847163A
公开(公告)日：1989-07-11
申请号：US109887
申请日：1987-10-19
申请人： Takayuki Shimamune , Masashi Hosonuma
发明人： Takayuki Shimamune , Masashi Hosonuma
IPC分类号： A61C13/00 , A61C13/083 , A61C13/087 , A61F2/00 , A61K6/04 , A61L27/00 , A61L27/32 , C23C28/00
CPC分类号： C23C28/04 , A61L27/32 , C23C28/044 , A61F2310/00796 , Y10T428/12583 , Y10T428/1259 , Y10T428/12736 , Y10T428/12771 , Y10T428/12806
摘要： A calcium phosphate-coated composite material is disclosed, comprising a metallic substrate, an oxide layer on the metallic substrate, said oxide layer consisting essentially of the oxide of one or more metals selected from the group consisting of titanium, zirconium, hafnium, niobium, tantalum, tin, cobalt, aluminum, chromium, molybdenum and tungsten, and a coating layer of calcium phosphate provided on the oxide layer. A process for production of the calcium phosphate-coated composite material is also disclosed.
摘要翻译：公开了一种磷酸钙涂覆的复合材料，其包括金属基底，金属基底上的氧化物层，所述氧化物层主要由选自钛，锆，铪，铌等的一种或多种金属的氧化物组成，钽，锡，钴，铝，铬，钼和钨，以及设置在氧化物层上的磷酸钙涂层。还公开了一种生产磷酸钙复合材料的方法。

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