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    • 1. 发明授权
    • Apparatus for determining wall thickness of microcapsule
    • 用于测定微胶囊壁厚的装置
    • US07280231B2
    • 2007-10-09
    • US10792869
    • 2004-03-05
    • Hidekazu YoshizawaMasaki Hayashi
    • Hidekazu YoshizawaMasaki Hayashi
    • G01B11/28
    • G01B11/0625G01N15/1456G01N2015/025G01N2015/1493
    • A thickness-determining apparatus for determining a wall thickness of a microcapsule having a refractive index n1 comprises a sensor 1 for detecting a light scattering intensity data I1 with respect to the microcapsule dispersed in a medium having a refractive index n1, and a light scattering intensity data I2 with respect to the microcapsule dispersed in a medium having a refractive index n2; a memory circuit 3 for storing a theoretical equation correlating a light scattering intensity characteristic with a particle size; and an arithmetic circuit 5 for calculating an inner diameter r1 and an outer diameter r2 from the theoretical equation based on the light scattering intensity data I1 and I2, and calculating the wall thickness.
    • 用于确定折射率n 1的微胶囊的壁厚的厚度测定装置包括用于检测相对于分散在折射率为n 1的介质中的微胶囊的光散射强度数据I 1的传感器1,以及 相对于分散在折射率n 2的介质中的微胶囊的光散射强度数据I 2; 存储电路3,用于存储将光散射强度特性与粒度相关的理论方程; 以及用于基于光散射强度数据I 1和I 2从理论方程计算内径r 1和外径r 2并计算壁厚的算术电路5。
    • 2. 发明申请
    • Processes for producing microcapsules
    • 生产微胶囊的方法
    • US20060210711A1
    • 2006-09-21
    • US11369059
    • 2006-03-07
    • Masaki HayashiHidekazu Yoshizawa
    • Masaki HayashiHidekazu Yoshizawa
    • B01J13/02
    • C09D11/03B01J13/02
    • A process for producing a microcapsule comprises adding water to an liquid organic dispersion at a room temperature, wherein the liquid organic dispersion comprises a colorant particle, a hydrophobic organic solvent, and an aqueous solution containing a water-soluble resin having an acid value of 20 to 400 mgKOH/g and having been neutralized to a neutralization degree of 5 to 50 mol %, and emulsifying the resin through phase inversion to produce a capsule particle in an aqueous phase, wherein the capsule particle comprises a dispersion system containing the colorant particle and the organic solvent, and a wall comprising the resin and encapsulating the dispersion system. In the process, when the amount to be added of water at which a mixture of the resin solution and water becomes clouded by addition of water to the resin solution is given as Y parts by weight, the phase inversion emulsification step is conducted by adding 0.75Y to 1.25Y parts by weight of water relative to 1 part by weight of the solid content of the neutralized resin to the liquid organic dispersion. Thus obtained microcapsule has a small dispersivity of the particle size, a large thickness of the wall, and a high strength.
    • 微胶囊的制造方法包括在室温下将水加入到液体有机分散体中,其中液体有机分散体包含着色剂颗粒,疏水性有机溶剂和含有酸值为20的水溶性树脂的水溶液 至400mgKOH / g,并被中和至中和度为5〜50mol%,并通过相转化乳化树脂以在水相中产生胶囊颗粒,其中胶囊颗粒包含含有着色剂颗粒的分散体系和 有机溶剂和包含树脂的壁并封装分散体系。 在该过程中,当通过向树脂溶液中加入水而使树脂溶液和水的混合物变得混浊的水的添加量为Y重量份时,相转化乳化步骤通过将0.75 Y至相对于1重量份中和的树脂与液体有机分散体的固体含量的1.25Y重量份的水。 由此得到的微胶囊的粒径分布小,壁厚大,强度高。