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1. 发明授权

US3954702A S-triazine derivatives containing naphthylamino groups as polymer stabilizers 失效
标题翻译：含有萘基氨基的S-三嗪衍生物作为聚合物稳定剂
公开(公告)号：US3954702A
公开(公告)日：1976-05-04
申请号：US527825
申请日：1974-11-27
申请人： Hermann Westlinning , Werner Schwarze , Horst Fleischhauer
发明人： Hermann Westlinning , Werner Schwarze , Horst Fleischhauer
IPC分类号： C08K5/3492 , C08J3/20
CPC分类号： C08K5/3492 , Y10S524/925
摘要： Triazine derivatives ##EQU1## use as light and heat stabilizers and for improving fatigue properties in rubber vulcanizates have the following composition: A 1,3,5-triazine derivative of the formula whereinX is ##EQU2## --SR.sup.6 or chlorine, and Y isOr --SR.sup.7,R.sup.1, r.sup.2, r.sup.3 and R.sup.4 being hydrogen, alkyl of 1 to 18 carbon atoms, phenyl, allyl, or methallyl and wherein alkyl may be substituted by --OH, --OR.sup.5 (R.sup.5 being lower alkyl) or --CN and wherein R.sup.1 and R.sup.3 may also be .alpha.-naphthyl or .beta.-naphthyl with the provision that the R.sup.2 or R.sup.4 group which is attached to the same N must then be hydrogen; and whereinR.sup.6 and R.sup.7 are alkyl or 1 to 18 carbon atoms or a thioether group of the formulaC.sub.n H.sub.2n.sub.+1 -- S -- CH.sub.2 -- CH.sub.2 --,n being 1 to 18.The invention also embraces a vulcanizing process, a vulcanizable composition and a rubber vulcanizate including or using the above triazine derivatives.
摘要翻译：三嗪衍生物R3-ANGLE R4用作轻热稳定剂并用于改善橡胶硫化胶中的疲劳性能具有以下组成：式Y | C（I）的1,3,5-三嗪衍生物ANGLE NN PARALLEL | X - CC-ANGLE N其中X为R 1 -N ANGLE，R 2 -SR 6或氯，Y为OR -SR 7，R 1，R 2，R 3和R 4为氢，1至18个碳原子的烷基，苯基，烯丙基或甲代烯丙基，其中烷基可以被-OH，-OR5（R5是低级烷基）或-CN取代，其中R1和R3也可以是α-萘基或β-萘基，其条件是连接到相同的R2或R4基团 N必须是氢; 并且其中R 6和R 7为烷基或1至18个碳原子或式C n H 2n + 1 -S-CH 2 -CH 2 - 的硫醚基，n为1至18。

2. 发明授权

US3947436A Sulfur containing organo-organooxysilane 失效
标题翻译：含硫有机氧化硅烷
公开(公告)号：US3947436A
公开(公告)日：1976-03-30
申请号：US451290
申请日：1974-03-14
申请人： Gottfried Rocktaschel , Friedrich Thurn , Horst Fleischhauer , Werner Schwarze , Hermann Westlinning
发明人： Gottfried Rocktaschel , Friedrich Thurn , Horst Fleischhauer , Werner Schwarze , Hermann Westlinning
IPC分类号： C07F7/08 , C07F7/18 , C08K5/548 , C08K9/06 , C07D251/46 , C07D251/38
CPC分类号： C08K9/06 , C07F7/0859 , C07F7/1804 , C08K5/54 , C08K5/548
摘要： There are prepared sulfur containing organoorganooxysilanes of the formula A-X-Z where A is R-S--, where R is a triazine or thiodiazole residue, X is a divalent organic residue, Z is -SiR" (OR').sub.2 ; -Si(OR').sub.3 ; -Si(OR').sub.2 -O-Si(OR').sub.3 ; -Si(OR').sub.2 -O-Si(OR').sub.2 -X-A; where R' and R" are alkyl groups of 1 to 12 carbon atoms. The compounds are useful as additives to cross-linkable mixtures containing organic polymers.
摘要翻译：制备式为A-X-Z的含硫有机有机氧代硅烷，其中A为R-S-，其中R为三嗪或硫代噻唑残基，X为二价有机残基，Z为-SiR“（OR'）2; -Si（OR'）3; -Si（OR'）2-O-Si（OR'）3; -Si（OR'）2-O-Si（OR'）2-X-A; 其中R'和R“是1至12个碳原子的烷基。该化合物可用作含有机聚合物的可交联混合物的添加剂。

3. 发明授权

US07871047B2 Fixture for spatial positioning of a device 失效
标题翻译：装置的空间定位装置
公开(公告)号：US07871047B2
公开(公告)日：2011-01-18
申请号：US11924398
申请日：2007-10-25
申请人： Werner Schwarze , Hugo Stephan , Andreas Martin
发明人： Werner Schwarze , Hugo Stephan , Andreas Martin
IPC分类号： F16M11/00
CPC分类号： A61B17/2255 , A61B90/50 , A61B2017/0069 , A61B2090/508
摘要： In a fixture for spatial positioning of a device, in particular a device for a medical application, that is supported in a pivoting arrangement on a holding device or the like by means of an arm, quick and easy alignment of the device in relation to a person's treatment area is provided. This alignment is achieved in that a ring-shaped holding body is attached to the free end of the arm, that a spherical outer jacket surface is provided on the device with the surface enclosed wholly or in part by the holding body, and that the outer jacket surface of the device is held in the holding body and can be pivoted relative to the holding body.
摘要翻译：在用于设备的空间定位的固定装置中，特别是用于医疗应用的装置，其通过臂支撑在保持装置等上的枢转装置中，能够快速且容易地对准装置相对于提供人的治疗区。这种对准是通过将环形保持体附接到臂的自由端来实现的，该球形外护套表面设置在该装置上，该表面全部或部分地被保持体封闭，并且外壳装置的护套表面被保持在保持体中并且可以相对于保持体枢转。

4. 发明授权

US4520209A Process for cyclizing upsilon-chlorocarboxylic acids 失效
标题翻译：使上 - 次氯羧酸环化的方法
公开(公告)号：US4520209A
公开(公告)日：1985-05-28
申请号：US625188
申请日：1984-06-28
申请人： Werner Schwarze , Axel Kleemann , Hans Remmel , Wolfgang Hohn
发明人： Werner Schwarze , Axel Kleemann , Hans Remmel , Wolfgang Hohn
IPC分类号： C07C69/74 , B01J31/00 , B01J31/02 , C07B20060101 , C07C20060101 , C07C67/00 , C07C67/30 , C07C67/317
CPC分类号： C07C67/317 , C07C2101/02
摘要： .gamma.-chlorocarboxylic acid methyl or ethyl esters are cyclized to the corresponding cyclopropane carboxylic acid esters by employing the sodium or potassium alcoholate of methanol or ethanol in the presence of the same alcohol at a temperature above the boiling point of the alcohol employed.
摘要翻译：在高于所用醇沸点的温度下，使用甲醇或乙醇钠或钾醇在相同的醇存在下将γ-氯羧酸甲酯或乙酯环化成相应的环丙烷羧酸酯。

5. 发明授权

US4402733A Herbicidally active 1,2,4-triazin-5-one derivatives 失效
标题翻译：除草活性的1,2,4-三嗪-5-酮衍生物
公开(公告)号：US4402733A
公开(公告)日：1983-09-06
申请号：US255517
申请日：1981-04-20
申请人： Georg Pissiotas , Willy Meyer , Werner Schwarze , Herbert Klenk , Wolfgang Leuchtenberg
发明人： Georg Pissiotas , Willy Meyer , Werner Schwarze , Herbert Klenk , Wolfgang Leuchtenberg
IPC分类号： A01N43/707 , A01P13/00 , C07D253/075 , A01N43/64 , C07D253/06
CPC分类号： C07D253/075 , A01N43/707
摘要： Herbicidally active derivatives of the formula ##STR1## in which R represents methyl, ethyl or n-propyl.
摘要翻译：式“IMAGE”的除草活性衍生物，其中R代表甲基，乙基或正丙基。

6. 发明授权

US4189550A Antistatic agents for thermoplastic synthetic resins 失效
标题翻译：热塑性合成树脂的防静电剂
公开(公告)号：US4189550A
公开(公告)日：1980-02-19
申请号：US819342
申请日：1977-07-27
申请人： Werner Schwarze , Wolfgang Merk , Volker Binder
发明人： Werner Schwarze , Wolfgang Merk , Volker Binder
IPC分类号： C08K5/17 , C08K5/19
CPC分类号： C08K5/17 , C08K5/19
摘要： There are used as antistatic agents for thermoplastic synthetic resins compounds of the formulae ##STR1## where R and R' are saturated alkyl groups in which the sum of the carbon atoms in the two alkyl groups is 4 to 30 carbon atoms and wherein one of R and R' can be hydrogen,R.sup.2 is hydrogen, lower alkyl with one to 5 carbon atoms, 2-hydroxyethyl, 2-hydroxypropyl, 2,3-dihydroxypropyl, benzyl o-,m- and/or p-methylbenzyl, o-,m- and/or p-chlorobenzyl, o-,m- and/or p-bromobenzyl, aminoalkyl (C.sub.2 to C.sub.6), preferably aminoalkyl (C.sub.2 and C.sub.3), alkyl (C.sub.1 to C.sub.6)-amino-alkyl (C.sub.2 to C.sub.6), 2-hydroxyethyl-aminoalkyl (C.sub.2 to C.sub.6), 2-hydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6) or 2,3-dihydroxypropyl-aminoalkyl (C.sub.2 to C.sub.6),R.sup.3 in case the compound is present as the ammonium salt is hydrogen or a lower alkyl group with 1 to 5 carbon atoms,R.sup.4 is hydrogen or hydroxyl, andX.sup.- is a monovalent, inorganic or organic acid group or one equivalent of a polybasic inorganic or organic acid group.The antistatic compounds can be premixed with silica to give enhanced antistatic activity.
摘要翻译：作为式（Ⅰ）的热塑性合成树脂化合物的抗静电剂，其中R和R'是饱和的烷基，其中两个烷基中的碳原子的总和是4至30个碳原子并且其中R和R'中的一个可以是氢，R 2是氢，具有1至5个碳原子的低级烷基，2-羟乙基，2-羟丙基，2,3-二羟丙基，邻 - ，间 - 和/ 甲基苄基，邻 - ，间 - 和/或对氯苄基，邻 - ，间 - 和/或对 - 溴苄基，氨基烷基（C2至C6），优选氨基烷基（C2和C3），烷基（C1至C6）烷基（C2至C6），2-羟乙基 - 氨基烷基（C2至C6），2-羟丙基 - 氨基烷基（C2至C6）或2,3-二羟丙基 - 氨基烷基（C2至C6），R3表示化合物以铵盐是氢或具有1至5个碳原子的低级烷基，R4是氢或羟基，X是一价无机或有机酸基团或一当量的多元无机或有机酸基团。抗静电化合物可以与二氧化硅预混合以提高抗静电活性。

7. 发明授权

US4161491A Process for the production of alpha-ketocarboxylic acid amides and cycloaliphatic products 失效
标题翻译：制备α-酮羧酸酰胺和脂环族产物的方法
公开(公告)号：US4161491A
公开(公告)日：1979-07-17
申请号：US802903
申请日：1977-06-02
申请人： Axel Kleemann , Herbert Klenk , Werner Schwarze
发明人： Axel Kleemann , Herbert Klenk , Werner Schwarze
IPC分类号： C07C231/06 , C07C20060101 , C07C67/00 , C07C231/00 , C07C235/72 , C07C235/80 , C07C102/02 , C07C102/08 , C07C103/127 , C07C103/19
CPC分类号： C07C231/06
摘要： There are prepared .alpha.-ketocarboxylic acid amides of the formula ##STR1## where R is hydrogen, R.sub.1 and R.sub.2 are the same or different, R.sub.1 is alkyl of 1 to 18 carbon atoms or haloalkyl, preferably chloroalkyl, of 1 to 18 carbon atoms, and R.sub.2 is hydrogen, alkyl of 1 to 18 carbon atoms or haloalkyl, preferably chloroalkyl, of 1 to 18 carbon atoms or ##STR2## together is a cycloalkyl group of 3 to 8 carbon atoms which can be substituted by one or more 1 to 5 carbon atom alkyl groups or by one or more halogen atoms, preferably chlorine atoms, with the proviso that when ##STR3## form a cycloalkyl group then R can also be alkyl of 1 to 5 carbon atoms. The process comprises saponifying an acyl cyanide of the formula ##STR4## in which R, R.sub.1 and R.sub.2 are as defined above in an organic solvent or mixture of such solvents which is liquid and inert under the reaction conditions, first with gaseous hydrogen chloride and then treating with water at a temperature of about -70.degree. C. to about +70.degree. C. and then isolating the .alpha.-ketocarboxylic acid amide in conventional manner. Several of the cyclic .alpha.-ketocarboxylic acid amides are new compounds.
摘要翻译：制备式（I）的α-酮羧酸酰胺，其中R是氢，R 1和R 2相同或不同，R 1是1至18个碳原子的烷基或卤代烷基，优选氯代烷基，其为1至18 碳原子，R 2是氢，1至18个碳原子的烷基或具有1至18个碳原子的卤代烷基，优选氯代烷基，或者“IMAGE”是3-8个碳原子的环烷基，其可以被一个或多个 1至5个碳原子的烷基或一个或多个卤素原子，优选氯原子，条件是当形成环烷基时，则R也可以是1至5个碳原子的烷基。该方法包括在其中R 1，R 2和R 2如上所定义的式（Ⅶ）的酰基氰在有机溶剂或这种在反应条件下为液体和惰性的溶剂的混合物中，首先用气态氢然后在约-70℃至约+70℃的温度下用水处理，然后以常规方式分离α-酮羧酸酰胺。几种环状α-酮羧酸酰胺是新的化合物。

8. 发明授权

US4108875A Process for the production of acyl cyanides (B) 失效
标题翻译：酰基氰生产工艺（二）
公开(公告)号：US4108875A
公开(公告)日：1978-08-22
申请号：US802942
申请日：1977-06-02
申请人： Herbert Klenk , Heribert Offermanns , Werner Schwarze
发明人： Herbert Klenk , Heribert Offermanns , Werner Schwarze
IPC分类号： C07C253/14 , B01J23/00 , B01J27/00 , C07B61/00 , C07C67/00 , C07C253/00 , C07C255/17 , C07C255/18 , C07C255/31 , C07C255/40 , C07C255/45 , C07C255/53 , C07C255/56 , C07D307/06 , C07D307/54 , C07D307/56 , C07D333/04 , C07D333/22 , C07D333/24 , C07D307/36 , C07C57/00 , C07C63/06
CPC分类号： C07C255/00 , C07C253/14 , C07D307/54 , C07D333/24
摘要： There are prepared acyl cyanides of the formula ##STR1## where R is a straight or branched chain alkyl group having 1 to 18 carbon atoms, preferably 1 to 10 carbon atoms, and which also can be substituted by one or more phenyl groups or halogen atoms, preferably chlorine, or R is preferably a cycloalkyl group having 3 to 8 carbon atoms, preferably cyclopropyl, which can have one or more 1 to 3 carbon atom alkyl or halogen, preferably chlorine, substituents wherein in all of the above set forth substitutions the halogen atoms and the phenyl groups are not on the carbon atom adjacent to the carbonyl group or R is a substituted phenyl group, a naphthyl group, a substituted naphthyl group or a five membered heterocyclic group, e.g., furyl, thienyl or alkyl substituted thienyl, wherein the substituents on the phenyl or naphthyl are halogen atoms, nitro groups or alkyl or alkoxy groups having 1 to 5 carbon atoms. The process comprises reacting an acyl halide of the formulaR--CO--Hal (II)in which R is as defined above and Hal is a chlorine or bromine atom, with a mixture consisting of about 0.1 to 5 equivalents of the alkali metal cyanide and about 0.05 to 2 equivalents of the copper (I) salt at a temperature of about 50.degree. to 180.degree. C in the presence of a carboxylic acid nitrile inert under the reaction conditions employed. Certain of the compounds are novel per se.
摘要翻译：制备式（I）的酰基氰化物，其中R是具有1至18个碳原子，优选1至10个碳原子的直链或支链烷基，并且也可被一个或多个苯基取代或卤素原子，优选氯，或R优选为具有3至8个碳原子的环烷基，优选环丙基，其可以具有一个或多个1至3个碳原子的烷基或卤素，优选氯，取代基，其中在上述所有卤素原子和苯基不在与羰基相邻的碳原子上，或者R是取代的苯基，萘基，取代的萘基或五元杂环基，例如呋喃基，噻吩基或烷基取代的噻吩基，其中苯基或萘基上的取代基是卤素原子，硝基或具有1-5个碳原子的烷基或烷氧基。该方法包括使式R-CO-Hal（II）的酰卤，其中R如上定义，Hal是氯或溴原子，与由约0.1至5当量的碱金属氰化物和在约50至180℃的温度下，在所用反应条件下在惰性的羧酸腈存在下，约0.05-2当量的铜（I）盐。某些化合物本身是新颖的。

9. 发明授权

US4061869A Antistatic agent for thermoplastic synthetic resin 失效
标题翻译：热塑性合成树脂的防静电剂
公开(公告)号：US4061869A
公开(公告)日：1977-12-06
申请号：US687632
申请日：1976-05-18
申请人： Werner Schwarze , Wolfgang Merk , Volker Binder
发明人： Werner Schwarze , Wolfgang Merk , Volker Binder
IPC分类号： C08L23/00 , C07D303/04 , C08K5/00 , C08K5/06 , C08L1/00 , C08L7/00 , C08L21/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C09K3/16 , C08L23/06 , C08L23/12 , C08L25/06 , C08L27/06
CPC分类号： C09K3/16 , C07D303/04 , C08K5/06 , Y10S524/91 , Y10T428/31649
摘要： There are prepared compounds of the formula ##STR1## where R and R.sup.1 are saturated and preferably linear alkyl groups in which the sum of carbon atoms in the two alkyl groups is 4 to 30,One of R and R.sup.1 can also be hydrogen,R.sup.2 is hydrogen or if R.sup.3 is hydrogen, thenR.sup.2 is the group ##STR2## where n is 1 to 10, R.sup.3 is hydrogen or, if R.sup.2 is hydrogen, thenR.sup.3 is the group ##STR3## and R.sup.4 is hydrogen or methyl.The compounds are useful as antistatic agents for thermoplastic resins.
摘要翻译：制备式“IMAGE”的化合物，其中R和R 1是饱和的，优选直链烷基，其中两个烷基中的碳原子总数为4至30，一个R和R 1也可以是氢，R 2是氢或如果R 3为氢，则R 2为基团，其中n为1至10，R 3为氢，或者如果R 2为氢，则R 3为基团，且R 4为氢或甲基。

10. 发明授权

US3978103A Sulfur containing organosilicon compounds 失效
标题翻译：含硫的有机硅化合物
公开(公告)号：US3978103A
公开(公告)日：1976-08-31
申请号：US467583
申请日：1974-05-06
申请人： Eugen Meyer-Simon , Werner Schwarze , Friedrich Thurn , Rudolf Michel
发明人： Eugen Meyer-Simon , Werner Schwarze , Friedrich Thurn , Rudolf Michel
IPC分类号： C07F7/18 , C08K5/548 , C09C1/30 , C23F11/16
CPC分类号： B82Y30/00 , C07F7/1804 , C08K5/548 , C09C1/3081 , C23F11/16 , C01P2004/62 , C01P2004/64 , C01P2004/80 , C01P2006/12 , Y10T152/10495
摘要： Sulfur containing organosilicon compounds are prepared having the formula:Z -- Alk -- S.sub.n -- Alk -- Zin which Z is: ##EQU1## where R.sub.1 and R.sub.alkyl of 1 to 4 carbon atoms or phenyl andR.sub.2 is alkoxy of 1 to 8 carbon atoms, cycloalkoxy of 5 to 8 carbon atoms or alkylmercapto of 1 to 8 carbon atoms, alk is a divalent aliphatic hydrocarbon or unsaturated aliphatic hydrocarbon or a cyclic hydrocarbon containing 1 to 18 carbon atoms and n is a whole number from 2 to 6.

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