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1. 发明授权

US4025579A Process for the production of sheet-like structures 失效
标题翻译：生产片状结构的方法
公开(公告)号：US4025579A
公开(公告)日：1977-05-24
申请号：US616102
申请日：1975-09-23
申请人： Hermann Gruber , Alois Fehlbier , Hans-Dieter Ruprecht
发明人： Hermann Gruber , Alois Fehlbier , Hans-Dieter Ruprecht
IPC分类号： B29B11/00 , B29B7/00 , B29B15/00 , B29B17/00 , B29B17/04 , B29C35/00 , B29C39/00 , B29C39/02 , B29C39/24 , B29C67/00 , B29D7/00 , B32B25/00 , C08G18/00 , C08G18/10 , C08G18/76 , C08J11/00 , C08L7/00 , C08L21/00 , C08L23/00 , C08L75/00 , C08L75/08 , C08L101/00 , C09J175/00 , E01C13/00 , E04B1/84 , E04B1/98 , E04F13/02
CPC分类号： C08G18/7671 , C08G18/10 , C08L75/08
摘要： The present invention relates to a process for preparing elastic laminates by admixing elastomeric granules with a moisture hardenable polyurethane binder and hardening the binder. The binder is formulated to have a workable viscosity at room temperature and to avoid crystallization at temperatures above about 0.degree. C. The binder is the reaction product of polyisocyanates of the diphenyl methane series having at least 20 wt. % of 2,4'-diisocyanatodiphenyl methane and di- and/or trihydroxy polyethers.The invention also relates to the binder composition itself and a process for preparing it. The binder has a viscosity of about 1000 to 15,000 cP at 20.degree. C and an NCO content of about 5 to 15 wt. %. It is prepared at an NCO to OH ratio of about 2:1 to 15:1 and at about 15.degree. to 100.degree. C.
摘要翻译：本发明涉及一种制备弹性层压材料的方法，该弹性层压材料通过将弹性体颗粒与湿润可硬化的聚氨酯粘合剂混合并使粘结剂硬化。将粘合剂配制成在室温下具有可工作的粘度并避免在高于约0℃的温度下结晶。粘合剂是二苯基甲烷系列的多异氰酸酯的反应产物，其具有至少20wt。％的2,4'-二异氰酸根合二苯甲烷和二 - 和/或三羟基聚醚。

2. 发明授权

US06977290B2 Process for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and prepolymers thereof 失效
标题翻译：用于制备低聚脂族二醇，基于其的聚碳酸酯醇及其预聚物的方法
公开(公告)号：US06977290B2
公开(公告)日：2005-12-20
申请号：US10763003
申请日：2004-01-22
申请人： Hartmut Nefzger , Erika Bauer , Manfred Schmidt , Hans-Dieter Ruprecht , James-Michael Barnes
发明人： Hartmut Nefzger , Erika Bauer , Manfred Schmidt , Hans-Dieter Ruprecht , James-Michael Barnes
IPC分类号： C07C41/09 , C08G18/10 , C08G18/44 , C08G64/02 , C08G64/30 , C08G65/34
CPC分类号： C08G64/0208 , C07C41/09 , C08G18/10 , C08G18/44 , C08G64/305 , C08G65/34 , C07C43/135
摘要： The present invention relates to a method for preparing oligomeric aliphatic diols, polycarbonatediols based thereon and NCO-terminated prepolymers obtainable therefrom. The inventive compounds may find use in the preparation of polyurethanes.
摘要翻译：本发明涉及一种制备低聚脂族二醇，其上的聚碳酸酯醇和由其获得的NCO封端的预聚物的方法。本发明化合物可用于制备聚氨酯。

3. 发明授权

US4294934A Process for the production of elastic, optionally cellular, polyurethane ureas 失效
标题翻译：用于生产弹性，任选细胞的聚氨酯脲的方法
公开(公告)号：US4294934A
公开(公告)日：1981-10-13
申请号：US164752
申请日：1980-06-30
申请人： Gerhard Grogler , Jurgen Schwindt , Otto Ganster , Hans-Joachim Meiners , Hans-Dieter Ruprecht
发明人： Gerhard Grogler , Jurgen Schwindt , Otto Ganster , Hans-Joachim Meiners , Hans-Dieter Ruprecht
IPC分类号： C08G18/00 , C08G18/10 , C08G18/72 , C08G18/76 , C08G18/18 , C08G18/22
CPC分类号： C08G18/7671 , C08G18/10 , C08G2101/0008 , C08G2350/00 , C08G2380/00 , C08G2410/00 , Y10S528/906
摘要： The instant invention is directed to a process for the production of polyurethane urea elastomers having a gross density of more than 200 kg/m.sup.3 comprising: casting a reaction mixture of(A) an isocyanate prepolymer produced from(a) 1 mole of a compound containing at least 2 Zerewitinoff-active hydrogen atoms and having a molecular weight of from 400 to 10,000 and(b) 2 to 10 moles of diisocyanatodiphenylmethane,(B) an aromatic diamine, and(C) 0 to 50 mole percent, based on component (B), of a polyol containing primary hydroxyl groups and having a molecular weight of from 62 to 6000, the equivalent ratio between component (A) and components (B) + (C) amounting to between 0.9:1 and 1.3:1,into a mold, hardening the reaction mixture in the mold and subsequently removing it from the mold, the improvement wherein said isocyanate prepolymer (A) has been produced using an isomer mixture comprising:from 15 to 80 mole percent of 2,4'-diisocyanatodiphenylmethane,from 20 to 85 mole percent of 4,4'-diisocyanatodiphenylmethane, andfrom 0 to 20 mole percent of 2,2'-diisocyanatodiphenylmethane.
摘要翻译：本发明涉及生产总密度大于200kg / m 3的聚氨酯脲弹性体的方法，包括：浇铸（A）异氰酸酯预聚物的反应混合物，该异氰酸酯预聚物由（a）1摩尔含有至少2个Zerewitinoff活性氢原子，分子量为400至10,000，和（b）2至10摩尔二异氰酸二苯基甲烷，（B）芳族二胺和（C）0至50摩尔％，基于组分（ B），含有伯羟基并且分子量为62至6000的多元醇，组分（A）和组分（B）+（C）之间的当量比为0.9:1至1.3:1，转化为模具，使模具中的反应混合物硬化，随后将其从模具中除去，改进之处在于所述异氰酸酯预聚物（A）已经使用异构体混合物制备，所述异构体混合物包含：15至80摩尔％的2,4'-二异氰酸根合二苯基甲烷， 20至85摩尔％o f 4,4'-二异氰酸二苯基甲烷和0至20摩尔％的2,2'-二异氰酸二苯基甲烷。

4. 发明授权

US5601881A Method and device for coating a body rotating about an axis 失效
标题翻译：用于涂覆绕轴旋转的身体的方法和装置
公开(公告)号：US5601881A
公开(公告)日：1997-02-11
申请号：US436940
申请日：1995-05-08
申请人： Wolfgang Grimm , Dirk Bruning , Klaus Recker , Hans-Dieter Ruprecht , Heinz Muller
发明人： Wolfgang Grimm , Dirk Bruning , Klaus Recker , Hans-Dieter Ruprecht , Heinz Muller
IPC分类号： B29C47/02 , B05D5/00 , B29C53/62
CPC分类号： B29C47/021 , B29C47/0019 , B29C47/025
摘要： The coating of bodies rotating about an axis with a reaction mixture forming a polyurethane can be improved by making use of a sheet die disposed parallel to the axis of rotation of the body at an angle .alpha., whereby the rate of reaction of the reaction mixture and the relative movement are synchronized with the circumferential speed of the rotating body in such a way that the successive convolutions overlap in the form of scales and connect together seamlessly.
摘要翻译：利用形成聚氨酯的反应混合物绕轴线旋转的体的涂层可以通过使用以α角与主体的旋转轴线平行设置的片模提高，由此反应混合物的反应速率和相对运动与旋转体的圆周速度同步，使得连续的卷积以刻度的形式重叠并且无缝地连接在一起。

5. 发明授权

US5470515A Rotational molding process for insulating pipes 失效
标题翻译：绝缘管旋转成型工艺
公开(公告)号：US5470515A
公开(公告)日：1995-11-28
申请号：US157063
申请日：1993-12-03
申请人： Wolfgang Grimm , Norbert Eisen , Hans-Dieter Ruprecht
发明人： Wolfgang Grimm , Norbert Eisen , Hans-Dieter Ruprecht
IPC分类号： C08G18/48 , B29C44/00 , B29C44/32 , C08G18/50 , C08G18/65 , C08G18/66 , C08G101/00 , C08J9/02 , F16L59/14 , B29C44/20
CPC分类号： F16L59/141 , B29C44/324 , B29K2075/00 , B29L2023/225
摘要： For insulating pipes by application of at least one insulating layer and at least one outer surface layer by rotational molding, a rigid polyurethane foam is used as the insulating layer while a solid polyurethane is used as the surface layer.
摘要翻译： PCT No.PCT / EP92 / 01183第 371日期1993年12月3日第 102（e）日期1993年12月3日PCT提交1992年5月26日PCT公布。出版物WO92 / 21910 日期为1992年12月10日。对于通过旋转成型施加至少一个绝缘层和至少一个外表面层的绝缘管，使用硬质聚氨酯泡沫作为绝缘层，而使用固体聚氨酯作为表面层。

6. 发明授权

US06177494B1 N,N′-disubstituted N-(2-hydroxyalkyl)-ureas 失效
标题翻译： N，N'-二取代的N-（2-羟基烷基） - 脲
公开(公告)号：US06177494B1
公开(公告)日：2001-01-23
申请号：US09366527
申请日：1999-08-02
申请人： Richard Kopp , James-Michael Barnes , Hans-Dieter Ruprecht , Hans-Georg Wussow
发明人： Richard Kopp , James-Michael Barnes , Hans-Dieter Ruprecht , Hans-Georg Wussow
IPC分类号： C08J300
CPC分类号： C07D251/34 , C08K5/34924 , C08L75/06
摘要： Non-crystallizing N,N′-disubstituted N-(2-hydroxyalkyl)-ureas are used as hydrolysis protection agents in plastics containing ester groups. These disubstituted hydroxy-alkylureas impart excellent protection from hydrolysis to plastics containing ester groups and can be added directly to the plastics to be stabilized without the addition of special solvents.
摘要翻译：不结晶的N，N'-二取代的N-（2-羟基烷基） - 脲用作含有酯基的塑料中的水解保护剂。这些二取代的羟基烷基脲具有优异的水解保护性，可以防止水解成含有酯基的塑料，并且可以直接添加到待稳定的塑料中，而无需加入特殊的溶剂。

7. 发明授权

US4758601A Process for the production of polysiloxane ionomers, polysiloxane ionomers and their use for the production of cellular polyurethane elastomers 失效
标题翻译：制备聚硅氧烷离聚物，聚硅氧烷离聚物及其用于生产细胞聚氨酯弹性体的方法
公开(公告)号：US4758601A
公开(公告)日：1988-07-19
申请号：US57472
申请日：1987-06-03
申请人： Peter Haas , Hans-Dieter Ruprecht , Paul T. Henrichs
发明人： Peter Haas , Hans-Dieter Ruprecht , Paul T. Henrichs
IPC分类号： C08G18/42 , C08G18/08 , C08G18/61 , C08G18/73 , C08G18/74 , C08G77/38 , C08G77/48 , C08J9/00 , C08J9/02 , C08L75/00 , C08L75/04 , C08G18/14
CPC分类号： C08J9/0061 , C08G18/0819 , C08G18/61 , C08J9/02 , C08G2101/0008 , C08G2101/0066 , C08G2101/0083 , C08J2375/04 , C08J2483/00
摘要： The present invention is directed to a process for the production of waterproof, fine-cell polyurethane elastomers having a density of about 300 to 800 kg/m.sup.3 by reacting(a) organic polyisocyanates,(b) polyhydroxyl compounds having a molecular weight of about 400 to about 8000,(c) water and, optionally,(d) organic chain-extending agents containing at least two isocyanate-reactive hydrogen atoms and having a molecular weight of 32 to 399,the equivalent ratio of isocyanate groups to NCO-reactive groups in the overall formulation being about 0.90:1 to 1.20:1, characterized in that polysiloxane ionomers are added to the water/crosslinker component in concentrations of about 0.1 to 5% by weight, based on the reaction mixture as a whole.
摘要翻译：本发明涉及通过使（a）有机多异氰酸酯，（b）分子量为约400的多羟基化合物反应生产密度为约300至800kg / m 3的防水细孔聚氨酯弹性体的方法至约8000，（c）水和任选地（d）含有至少两个异氰酸酯反应性氢原子并且具有32至399的分子量的有机扩链剂，异氰酸酯基团与NCO反应性基团的当量比在总配方中为约0.90:1至1.20:1，其特征在于基于整个反应混合物，聚硅氧烷离聚物以约0.1至5重量％的浓度加入到水/交联剂组分中。

8. 发明授权

US4716210A Use of liquid, cold-hardening polyurethane-urea-forming components for corrosion-inhibiting, wear-resistant coatings on metal and plastics surfaces and moldings and on stone and concrete 失效
标题翻译：使用液体，冷硬化聚氨酯 - 尿素形成组件用于金属和塑料表面和模制品以及石材和混凝土上的腐蚀抑制，耐磨涂层
公开(公告)号：US4716210A
公开(公告)日：1987-12-29
申请号：US446082
申请日：1982-12-01
申请人： Gerhard Trummelmeyer , Hans-Dieter Ruprecht
发明人： Gerhard Trummelmeyer , Hans-Dieter Ruprecht
IPC分类号： C08G18/00 , C08G18/10 , C08G18/40 , C08G18/63 , C08G18/65 , C08G18/66 , C08G18/72 , C08G18/76 , C09D175/04 , C08G18/67
CPC分类号： C08G18/10 , C08G18/409 , C08G18/632 , C08G18/6529 , C08G18/657 , C08G18/7664 , C09D175/04 , C08G2150/90 , Y10S528/906 , Y10T428/31551
摘要： This invention relates to special combinations of polyurethane-urea-forming starting components which are suitable for corrosion-inhibiting wear prevention by casting, centrifugal casting or spraying. Said components are liquid, relatively low viscosity mixtures of polymer-containing or polyadduct-containing polypropylene oxide polyols and/or ethylene oxide-containing polypropylene oxide polyols having a small content of special, low-melting, readily soluble aromatic diamines and tertiary amine catalysts as component (A) which are reacted at room temperature with liquid polyisocyanates based on diphenyl methane diisocyanate or their NCO-prepolymers with polyether polyols as components (B).
摘要翻译：本发明涉及聚氨酯 - 尿素形成起始组分的特殊组合，其适用于通过铸造，离心铸造或喷涂防止腐蚀的磨损。所述组分是具有少量特殊的，低熔点，易溶的芳族二胺和叔胺催化剂的含有聚合物或含聚合物的聚环氧丙烷多元醇和/或环氧乙烷的聚环氧丙烷多元醇的液体，相对低粘度的混合物，在室温下与基于二苯基甲烷二异氰酸酯或其具有聚醚多元醇作为组分（B）的NCO预聚物的液体多异氰酸酯反应的组分（A）。

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