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    • 2. 发明授权
    • Polyoxymethylene molding materials having improved thermal stability,
their preparation and their use
    • 聚甲醛成型材料具有改进的热稳定性,其制备及其用途
    • US4837400A
    • 1989-06-06
    • US152389
    • 1988-02-04
    • Manfred WalterWilhelm SchuetteHeiner Goerrissen
    • Manfred WalterWilhelm SchuetteHeiner Goerrissen
    • C08L59/00C08K3/32C08K3/34C08K5/13C08K5/521C08K13/02
    • C08K5/521C08K13/02C08K3/34
    • Polyoxymethylene molding materials having improved heat stability and consisting of(A) one or more polyoxymethylene homopolymers and/or copolymers and(B) one or more antioxidants having a sterically hindered phenolic structure,(C) with or without additives, contain(D) as an additive, one or more alkaline earth metal silicates and/or alkaline earth metal glycerophosphates, advantageously in an amount of from 0.002 to 2.0% by weight, based on the weight of component (A),for improving the heat stability, reducing the tendency to discoloration and minimizing the free formaldehyde content.To prepare the novel polyoxymethylene molding materials, the components are advantageously melted in an extruder at from 150.degree. to 260.degree. C.The polyoxymethylene molding materials are useful for the production of films or, preferably, moldings, which are used, for example, in the automotive, electrical appliances and electronics industries.
    • 具有改进的热稳定性并由(A)一种或多种聚甲醛均聚物和/或共聚物组成的聚甲醛成型材料和(B)一种或多种具有空间位阻酚结构的抗氧化剂,(C)含或不含添加剂,含有(D)为 添加剂,一种或多种碱土金属硅酸盐和/或碱土金属甘油磷酸盐,其用量以组分(A)的重量计为0.002至2.0重量%,用于改善热稳定性,降低趋势 使变色和使游离甲醛含量最小化。 为了制备新颖的聚甲醛成型材料,有利的是在150至260℃的挤出机中熔融组分。聚氧化亚甲基成型材料可用于生产薄膜或模制品,例如用于 汽车,电器和电子行业。