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1. 发明授权

US4195973A Process for printing with developing dyes which employs having ether substituents derived from glycols, polyglycols, or alkoxy derivatives thereof 失效
标题翻译：使用具有衍生自乙二醇，聚二醇或其烷氧基衍生物的醚取代基的显影染料进行印刷的方法
公开(公告)号：US4195973A
公开(公告)日：1980-04-01
申请号：US958134
申请日：1978-11-06
申请人： Hasso Hertel , Horst Curtius , Erich Feess , Paul Karacsonyi
发明人： Hasso Hertel , Horst Curtius , Erich Feess , Paul Karacsonyi
IPC分类号： D06P1/607 , C09B67/36 , D06P3/68 , C09B27/00 , D06P1/12
CPC分类号： D06P3/68 , C09B67/0079
摘要： o-Aminophenol ethers deriving from lower alkylene glycols, lower alkylene polyglycols and the corresponding mono-lower alkyl ethers which may be substituted in the phenyl nucleus by halogen or nitro, are useful as diazo components in the "all-in" printing process for preparing developing dyes on cellulose. In this process the printing paste contains the alkaline solution of the coupling component, a dispersion of the amine, sodium nitrite and a thickening composition and developing of the dye is brought about with acidic means, followed by or combined with a heat treatment.
摘要翻译：衍生自低级亚烷基二醇的邻氨基苯酚醚，低级亚烷基聚二醇和可以在苯基核中被卤素或硝基取代的相应的单低级烷基醚可用作“全进”印刷方法中的重氮组分，用于制备在纤维素上发展染料。在该方法中，印刷浆料含有偶联组分的碱性溶液，胺，亚硝酸钠和增稠组合物的分散体和染料的显影以酸性方式进行，随后进行热处理或与热处理组合。

2. 发明授权

US4094637A Process for the printing with developing dyes 失效
标题翻译：用显影染料印刷的方法
公开(公告)号：US4094637A
公开(公告)日：1978-06-13
申请号：US623338
申请日：1975-10-17
申请人： Erich Feess , Willy Gronen , Hasso Hertel
发明人： Erich Feess , Willy Gronen , Hasso Hertel
IPC分类号： D06P1/28 , D06P1/653 , D06P3/68 , C09B27/00 , D06P1/02
CPC分类号： D06P3/68 , D06P1/28 , D06P1/6533 , Y10S534/01 , Y10S8/907
摘要： Cellulosic material is printed with a paste containing the alkaline solution of a coupler, the dispersion of a diazotable aromatic amine, a nitrite and a thickener and the dyestuff is developed on the fiber by acidic steaming or by adding solutions of organic acids and steaming or drying.
摘要翻译：纤维素材料印有含有偶合剂碱溶液，可重氮芳香胺，亚硝酸盐和增稠剂的分散体的浆料，并且该染料通过酸性蒸汽或通过加入有机酸溶液和蒸或干燥而在纤维上显影。

3. 发明授权

US4696675A Process for preparing water-insoluble blue azo dyes on the fiber: hydroxynaphthoic amide and diazotized di-alkoxy-benzidine 失效
标题翻译：在纤维上制备水不溶性蓝色偶氮染料的方法：羟基萘甲酰胺和重氮化的二烷氧基联苯胺
公开(公告)号：US4696675A
公开(公告)日：1987-09-29
申请号：US845623
申请日：1986-03-27
申请人： Hasso Hertel , Klaus Hunger , Heinrich Frolich
发明人： Hasso Hertel , Klaus Hunger , Heinrich Frolich
IPC分类号： D06P1/12 , C09B35/14 , D06P3/68 , C09B35/02
CPC分类号： D06P3/68 , C09B35/14 , Y10S8/918
摘要： Using the method of azoic dyeing, fast blue dyeings are obtained when the bis-diazotable diazo component used is a compound of the general formula (1) ##STR1## in which R is a straight-chain or branched alkyl group of 3 to 5 carbon atoms or a (C.sub.1 -C.sub.3)-alkoxy-(C.sub.2 -C.sub.4)-alkyl group having straight-chain and/or branched alkyl groups of in total 3 to 5 carbon atoms, and the coupling component used is a compound conforming to the general formula (2) ##STR2## in which Z stands for a hydrogen atom or a halogen atom or an alkoxy group of 1 to 4 carbon atoms and Aryl denotes a phenyl radical or a 1-naphthyl radical which can be substituted by 1, 2 or 3 substituents from the group consisting of halogen, nitro, alkyl of 1 to 4 carbon atoms and alkoxy of 1 to 4 carbon atoms, and the coupling reaction and dye formation on the fiber are carried out at a pH value between 4 and 10.
摘要翻译：使用偶氮染色方法，当所用的双重氮偶氮重氮组分是通式（1）的化合物时，得到了快速的蓝色染色，其中R是3或3的直链或支链烷基至5个碳原子或具有总共3至5个碳原子的具有直链和/或支链烷基的（C1-C3） - 烷氧基 - （C2-C4） - 烷基，所用的偶合组分是符合化合物（2）其中Z表示氢原子或卤素原子或1〜4个碳原子的烷氧基，通式（2）表示苯基或1-萘基，可以是被1,2或3个由卤素，硝基，1至4个碳原子的烷基和1至4个碳原子的烷氧基取代的取代基取代，纤维上的偶联反应和染料形成在pH值在4到10之间。

4. 发明授权

US4078887A Concentrated stable solutions of coupling components for the ice color dyeing, their preparation and use 失效
标题翻译：浓缩稳定的偶联组分溶液用于冰染色，其制备和使用
公开(公告)号：US4078887A
公开(公告)日：1978-03-14
申请号：US744141
申请日：1976-11-22
申请人： Rudolf Kostka , Hasso Hertel
发明人： Rudolf Kostka , Hasso Hertel
IPC分类号： C09B41/00 , C09B67/36 , D06P1/12 , C09B27/00 , D06P1/02
CPC分类号： C09B67/0079 , D06P1/12
摘要： Highly concentrated solutions of coupling components of the ice-color dyeing technique had been found which possess a very good stability to storage and can readily be used for the preparation of diluted aqueous bottoming baths of the ice-color technique; these novel solutions contain the coupling component, water, sodium-or potassium hydroxide, and are characterized by the imperative content of diethylene-glycol or a content of a mixture of diethylene-glycol and ethylene-glycol or propylene-glycol or both.
摘要翻译：已经发现了具有非常好的储存稳定性的冰色染色技术的高浓度偶联组分溶液，并且可以容易地用于制备冰色技术的稀释含水底层浴; 这些新型溶液含有偶联组分，水，氢氧化钠或氢氧化钾，其特征在于二甘醇的必需含量或二甘醇和乙二醇或丙二醇或两者的混合物的含量。

5. 发明授权

US4035144A Dyeing preparations containing boric acid for preparing water-insoluble azo dyestuffs on fiber 失效
标题翻译：含有硼酸的染色剂在纤维上制备水不溶性偶氮染料
公开(公告)号：US4035144A
公开(公告)日：1977-07-12
申请号：US594112
申请日：1975-07-08
申请人： Hasso Hertel
发明人： Hasso Hertel
IPC分类号： C09B67/42 , D06P1/12 , C07C113/00 , D06P1/74 , D06P3/68
CPC分类号： C09B67/0071 , D06P1/12
摘要： New improved dyeing preparations (formulations) have been found for preparing water-soluble azo dyestuffs on fiber according to ice-color dyeing which contain a diazonium or tetrazonium compound of an aromatic mono- or diamine having a pKa-value of more than 2.5 as well as boric acid instead of the usual aluminum sulfate or chromium (III)-acetate. These new dyeing compositions have the same good properties as comparable known dyeing preparations but avoid the severe disadvantages of the known preparations in respect to requirements in industrial medicine and ecology.
摘要翻译：已经发现新的改进的染色制剂（制剂）用于根据冰色染色在纤维上制备水溶性偶氮染料，其中含有pKa值大于2.5的芳族单胺或二胺的重氮或四唑化合物作为硼酸代替通常的硫酸铝或醋酸铬（III）。这些新染色组合物与可比较的已知染色制剂具有相同的良好性能，但避免了已知制剂在工业医学和生态学方面的要求的严重缺点。

6. 发明授权

US3961887A Process for the printing of cellulose containing textile material 失效
标题翻译：用于印刷含纤维素的纺织材料的方法
公开(公告)号：US3961887A
公开(公告)日：1976-06-08
申请号：US404729
申请日：1973-10-09
申请人： Willy Gronen , Hasso Hertel
发明人： Willy Gronen , Hasso Hertel
IPC分类号： D06P1/44 , D06P3/66 , D06P3/68 , C09B27/00
CPC分类号： D06P3/68 , D06P3/66 , Y10S8/907 , Y10S8/908 , Y10S8/911 , Y10S8/912 , Y10S8/93
摘要： A process for the printing of cellulose containing textiles or textiles consisting completely of cellulose with water-insoluble azo dyestuffs produced on the fiber, which comprises printing the material previously impregnated with alkaline liquors of .beta.-hydroxy-naphthoic acid arylamides or acetoacetic acid arylamides and sodium nitrite with a printing paste containing an aqueous dispersion of an amine suitable for ice color dyeing having a maximum grain size of 0.03 mm or less, acidifiers and a thickening, and finishing the prints after drying in usual manner by washing, soaping and rinsing.
摘要翻译：一种用于在纤维上印刷完全由纤维素组成的纤维素与纤维素的水不溶性偶氮染料的纺织品或纺织品的印刷方法，该方法包括印刷预先浸渍有β-羟基 - 萘甲酸芳基酰胺或乙酰乙酸芳基酰胺的碱性液体的物质亚硝酸盐，其含有适用于最大粒度为0.03mm以下的冰染色剂的胺的水性分散体，酸化剂和增稠剂的印刷浆料，并且通过洗涤，皂洗和漂洗以通常的方式干燥后的印刷品。

7. 发明授权

US4987221A Bisdiazonium salts of 4,4'-diamino-3,3'-dialkoxybiphenyls and a process for their preparation 失效
标题翻译： 4,4'-二氨基-3,3'-二烷氧基联苯的双重重氮盐及其制备方法
公开(公告)号：US4987221A
公开(公告)日：1991-01-22
申请号：US844858
申请日：1986-03-27
申请人： Hasso Hertel , Klaus Hunger , Heinrich Frolich
发明人： Hasso Hertel , Klaus Hunger , Heinrich Frolich
IPC分类号： C09B35/02 , C07C67/00 , C07C241/00 , C07C245/20 , C09B35/08 , D06P1/12
CPC分类号： C09B35/08 , D06P1/12
摘要： Bisdiazonium salts of the formula (1) ##STR1## in which R denotes a linear or branched alkyl or alkoxyalkyl radical having 3-5 carbon atoms and X.sup.- represents the radical of a strong acid or of a zinc chloride double salt, and a process for their preparation by diazotizing a 4,4'-diamino-3,3'-dialkoxybiphenyl of the formula (2) ##STR2## in which R has the meaning mentioned, in an aqueous, strong, non-oxidizing inorganic or organic acid at temperatures from about -10.degree. C. to about +40.degree. C. by means of an alkali metal nitrite, and precipitating the resulting bisdiazonium salts by adding an alkali metal chloride, bisulfate, monosulfonate of 1,5-naphthalenedisulfonic acid or tetrafluoroborate or zinc chloride.These salts are useful in dyeing and printing textile fiber materials by the methods of the ice color technique, using suitable coupling components; they are also useful for preparing photographic tracings by the methods of reprography.
摘要翻译：式（1）的Biaziazonium盐其中R表示具有3-5个碳原子的直链或支链烷基或烷氧基烷基，X表示强酸或氯化锌双盐的自由基，（2）的4,4'-二氨基-3,3'-二烷氧基联苯的制备方法，其中R具有上述含义，在水，强，非 - 通过碱金属亚硝酸盐在约-10℃至约+ 40℃的温度下氧化无机或有机酸，并通过加入1,5-二甲基苯磺酸的碱金属氯化物，硫酸氢盐，单磺酸盐沉淀所得的双重氮盐，萘二磺酸或四氟硼酸盐或氯化锌。这些盐可用于通过使用合适的偶联组分的冰色技术的方法对纺织纤维材料进行染色和印花; 它们也可用于通过复制方法制备照相追踪。

8. 发明授权

US4906250A Process for the preparation of water-insoluble azo dyes on the fiber: impregnating with coupling component and treating with diazonium salt of 4-chloro-2,5-dialkoxy aniline 失效
标题翻译：在纤维上制备水不溶性偶氮染料的方法：用偶联组分浸渍并用4-氯-2,5-二烷氧基苯胺的重氮盐处理
公开(公告)号：US4906250A
公开(公告)日：1990-03-06
申请号：US256693
申请日：1988-10-12
申请人： Hasso Hertel
发明人： Hasso Hertel
IPC分类号： D06P1/12 , C09B29/01 , D06P3/68
CPC分类号： D06P3/68 , C09B29/0003 , Y10S8/918
摘要： According to the procedures of the ice color dyeing technique, fiber materials, such as, for example, cellulose fiber materials, are dyed by coupling the fiber material bottomed with a coupling component in an aqueous medium with the diazonium compound of an aniline compound of the general formula (1) mentioned and defined below, the coupling reaction and dye formation on the fiber being carried out at a pH between 3 and 10 ##STR1## in which R stands for a straight-chain or branched alkyl group of 3 or 4 carbon atoms.
摘要翻译：根据冰染色技术的步骤，将纤维材料，例如纤维素纤维材料，通过将水性介质中的偶联组分的底部纤维材料与苯乙烯化合物的重氮化合物在下文提及和定义的通式（1）中，纤维上的偶联反应和染料形成在3和10（1）之间的pH下进行，其中R代表3的直链或支链烷基或4个碳原子。

9. 发明授权

US4331443A Concentrated solutions of water-insoluble coupling components 失效
标题翻译：水不溶性偶联组分的浓缩溶液
公开(公告)号：US4331443A
公开(公告)日：1982-05-25
申请号：US122451
申请日：1980-02-19
申请人： Rudolf Kostka , Hasso Hertel
发明人： Rudolf Kostka , Hasso Hertel
IPC分类号： C09B41/00 , C09B67/36 , D06P1/12 , C09B27/00 , D06P1/02
CPC分类号： D06P1/12 , C09B67/0079
摘要： Concentrated solutions of water-insoluble bis-acetoacetic acid-diphenylamides as coupling components; these solutions contain in addition to one or more of these coupling components water and sodium and/or potassium hydroxide and as aliphatic solvent one or more mono- or di- to hexa-ethyleneglycol monoalkyl ethers having lower alkyl radicals, and optionally ethyleneglycol, diethyleneglycol and/or propyleneglycol. The coupling components are contained in the solutions in a concentration of up to about 50% by weight without deteriorating the storage stability of the solutions. The solutions may be used for preparing water-insoluble azo dyestuffs on the fiber according to "ice-color" dyeing. On pouring into water containing a small amount of sodium hydroxide they give immediately ready-to-use impregnation baths.
摘要翻译：水不溶性双乙酰乙酸 - 二苯胺作为偶联组分的浓缩溶液; 这些溶液除了一种或多种这些偶联组分外还含有水和钠和/或氢氧化钾和作为脂族溶剂，一种或多种具有低级烷基的单 - 或二 - 至六 - 乙二醇单烷基醚，以及任选的乙二醇，二甘醇和 /或丙二醇。偶联组分以高达约50重量％的浓度包含在溶液中，而不会降低溶液的储存稳定性。该溶液可用于根据“冰色”染色在纤维上制备水不溶性偶氮染料。在倒入含有少量氢氧化钠的水中时，立即即刻使用浸渍浴。

10. 发明授权

US4183727A Process for the production of water-insoluble azo dyestuffs on the fiber 失效
标题翻译：在纤维上生产水不溶性偶氮染料的方法
公开(公告)号：US4183727A
公开(公告)日：1980-01-15
申请号：US914924
申请日：1978-06-12
申请人： Hasso Hertel , Peter Frey
发明人： Hasso Hertel , Peter Frey
IPC分类号： D06P3/68 , C09B27/00
CPC分类号： D06P3/68
摘要： An improved process for the preparation of water-insoluble azo dyestuffs on vegetable fibers according to the method of the ice-color technique had been found, impregnating first the fibrous material with an azo component and then developing it with a diazo solution of an aromatic amino compound in the neutral or slightly alkaline range, wherein an alkali metal borate is used to neutralize the diazo solution.The dyeings prepared in this improved dyeing process for ice color dyeing have very good fastness properties and are obtained with high color yields. The improvement of the dyeing process is seen in the use of alkali metal borate as a neutralizing agent, which avoids the creation of foam in the surfactant-containing diazo solution.
摘要翻译：已经发现根据冰色技术的方法在植物纤维上制备水不溶性偶氮染料的改进方法，首先用偶氮组分浸渍纤维材料，然后用芳族氨基的重氮溶液化合物在中性或轻微碱性范围内，其中使用碱金属硼酸盐中和重氮溶液。在这种改进的染色染色工艺中制备的染色具有非常好的牢度性能，并且以高的色彩产率获得。在使用碱金属硼酸盐作为中和剂时可以看出染色过程的改善，这避免了在含表面活性剂的重氮溶液中产生泡沫。

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