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1. 发明授权

US4278660A Complex or salt of a platinum (II) compound and a nitrogen containing polymer 失效
标题翻译：铂（II）化合物和含氮聚合物的络合物或盐
公开(公告)号：US4278660A
公开(公告)日：1981-07-14
申请号：US958976
申请日：1978-11-09
申请人： Harry R. Allcock , Robert W. Allen , John P. O'Brien
发明人： Harry R. Allcock , Robert W. Allen , John P. O'Brien
IPC分类号： C07F15/00 , A61K31/74 , A61K31/28 , A61K31/555
CPC分类号： C07F15/0093
摘要： A cis- complex or -salt of a square planar platinum compound and a nitrogen containing oligomer or polymer prepared by reacting a platinum (II) compound with a nitrogen containing oligomer or polymer in an organic solvent or an acidic aqueous medium, said complex or salt being useful for treating animal malignant tumor cells sensitive to cis-square planar platinum compounds.
摘要翻译：通过在有机溶剂或酸性水性介质中使铂（II）化合物与含氮低聚物或聚合物反应而制备的正方形平面铂化合物和含氮低聚物或聚合物的顺 - 络合物或盐，所述络合物或盐可用于治疗对顺式平面铂化合物敏感的动物恶性肿瘤细胞。

2. 发明授权

US4151185A Complex or salt of a platinum (II) compound and a nitrogen containing polymer 失效
标题翻译：铂（II）化合物和含氮聚合物的络合物或盐
公开(公告)号：US4151185A
公开(公告)日：1979-04-24
申请号：US792608
申请日：1977-05-02
申请人： Harry R. Allcock , Robert W. Allen , John P. O'Brien
发明人： Harry R. Allcock , Robert W. Allen , John P. O'Brien
IPC分类号： C07F15/00
CPC分类号： C07F15/0093
摘要： A cis- complex or -salt of a square planar platinum compound and a nitrogen containing oligomer or polymer prepared by reacting a platinum (II) compound with a nitrogen containing oligomer or polymer in an organic solvent or an acidic aqueous medium, said complex or salt being useful as an anti-cancer agent.
摘要翻译：通过在有机溶剂或酸性水性介质中使铂（II）化合物与含氮低聚物或聚合物反应而制备的正方形平面铂化合物和含氮低聚物或聚合物的顺 - 络合物或盐，所述络合物或盐作为抗癌剂有用。

3. 发明授权

US4288585A Carboranylcyclotriphosphazenes and their polymers 失效
标题翻译：碳硼烷基环三磷腈及其聚合物
公开(公告)号：US4288585A
公开(公告)日：1981-09-08
申请号：US129799
申请日：1980-03-12
申请人： Robert A. Administrator of the National Aeronatuics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
发明人： Robert A. Administrator of the National Aeronatuics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
IPC分类号： C08G79/02 , C08G73/00
CPC分类号： C08G79/025
摘要： Carboranyl-substituted polyphosphazenes are prepared by heat polymerizing a carboranyl halocyclophosphazene at 250.degree. C. for about 120 hours in the absence of oxygen and moisture. The cyclophosphazene is obtained by allowing a lithium carborane, e.g. the reaction product of methyl-o-carborane with n-butyllithium in ethyl ether, to react with e.g. hexachlorocyclotriphosphazene at ambient temperatures and in anhydrous conditions. For greater stability in the presence of moisture, the chlorine substituents of the polymer are then replaced by aryloxy or alkoxy groups, such as CF.sub.3 CH.sub.2 O--.The new substantially inorganic polymers are thermally stable materials which produce a high char yield when exposed to extreme temperatures, and can thus serve to insulate less heat and fire resistant substances.
摘要翻译：碳硼烷基取代的聚磷腈通过在250℃下在不存在氧和水分的情况下将碳硼烷基卤代环磷腈加热聚合约120小时来制备。环磷腈是通过使碳二亚硼酸锂，甲基邻碳硼烷与正丁基锂在乙醚中的反应产物，六氯环三磷腈在环境温度和无水条件下。为了在存在水分的情况下获得更大的稳定性，聚合物的氯取代基然后被芳氧基或烷氧基取代，例如CF 3 CH 2 O-。新的基本上无机的聚合物是热稳定的材料，当暴露在极端温度下时产生高的焦炭产率，并且因此可以用来绝热较少的耐热和耐火物质。

4. 发明授权

US4276403A Process for the preparation of polycarboranylphosphazenes 失效
标题翻译：制备聚碳硼烷基磷腈的方法
公开(公告)号：US4276403A
公开(公告)日：1981-06-30
申请号：US129798
申请日：1980-03-12
申请人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
发明人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch , Harry R. Allcock , John P. O'Brien , Angelo G. Scopelianos , Larry L. Fewell
IPC分类号： C08G79/02 , C08G73/00
CPC分类号： C08G79/025
摘要： Polydihalophosphazenes, e.g. --N.dbd.P(Cl).sub.2 ].sub.n, are allowed to react at ambient temperatures for at least one hour with a lithium carborane in a suitable inert solvent. The remaining chlorine substituents of the carboranyl polyphosphazene are then replaced with aryloxy or alkoxy groups to enhance moisture resistance. The polymers give a high char yield when exposed to extreme heat and flame and can be used as insulation.
摘要翻译：聚二卤代磷腈，例如 -N = P（Cl）2] n在环境温度下与碳化硼锂在合适的惰性溶剂中反应至少1小时。然后用芳氧基或烷氧基代替碳硼烷基聚磷腈的剩余氯取代基，以增强耐湿性。当暴露于极热和火焰时，聚合物具有高的焦炭产率，可用作绝缘体。

5. 发明授权

US06759157B1 Proton conducting polymer membranes 失效
标题翻译：质子导电聚合物膜
公开(公告)号：US06759157B1
公开(公告)日：2004-07-06
申请号：US09590985
申请日：2000-06-09
申请人： Harry R. Allcock , Michael A. Hofmann , Serguei N. Lvov , Xiang Y. Zhou , Digby McDonald
发明人： Harry R. Allcock , Michael A. Hofmann , Serguei N. Lvov , Xiang Y. Zhou , Digby McDonald
IPC分类号： H01M810
CPC分类号： B01D67/0011 , B01D2325/20 , B01D2325/26 , C08J5/22 , H01M8/04197 , H01M8/1034 , H01M8/1067 , Y02P70/56
摘要： Proton conducting membranes having improved resistance to methanol crossover are provided, along with methods for their manufacture. In a preferred embodiment, the polymeric membranes are formed by (a) dissolving a polymer, preferably a polyphosphazene, in an organic solvent to form a polymer solution; (b) adding an oxyacid to the polymer solution; (c) optionally, adding water to the polymer solution, preferably in a molar ratio equivalent to the oxyacid; (d) optionally, concentrating the polymer solution; (e) casting the polymer solution on a casting surface, such as one formed of or coated with TEFLON™; and (f) removing the organic solvent, so as to form the polymeric membrane. A particularly useful application for these polymeric membranes is in fuel cells, such as those wherein methanol and oxygen are converted into electrical energy.
摘要翻译：提供了具有改进的抗甲醇交联性的质子导电膜及其制造方法。在优选的实施方案中，聚合物膜通过（a）将聚合物，优选聚磷腈溶解在有机溶剂中形成聚合物溶液而形成; （b）向聚合物溶液中加入含氧酸; （c）任选地，向聚合物溶液中加入水，优选以相对于含氧酸的摩尔比加入; （d）任选地，浓缩聚合物溶液; （e）将聚合物溶液浇铸在诸如由TEFLON TM形成或涂覆的铸造表面上; 和（f）除去有机溶剂，以便形成聚合物膜。这些聚合物膜的特别有用的应用是在燃料电池中，例如其中甲醇和氧被转化为电能的那些。

6. 发明授权

US06482910B1 Polynorbornenes with pendant cyclotriphosphazenes 失效
标题翻译：聚降冰片烯与侧链环三磷腈
公开(公告)号：US06482910B1
公开(公告)日：2002-11-19
申请号：US09644592
申请日：2000-08-23
申请人： Harry R. Allcock , Walter R. Laredo
发明人： Harry R. Allcock , Walter R. Laredo
IPC分类号： C08F23620
CPC分类号： C08G61/02 , C08F132/08 , C08G61/06 , C08G61/08
摘要： A polymer composition comprising a polynorbonene backbone and pendant cyclotriphosphazene groups has been developed. The pendant cyclotriphosphazene group can have various substituents such as C1-C10 alkyl, C1-C10 haloalkyl, C3-C6 cycloalkyl, phenyl, substituted phenyl, aryl, —(CH2CH2OCH2CH2)nOCH3 in which n is a positive integer, aminoalkyl, alkoxyalkyl, phenoxyalkyl, aryloxyalkyl and amidoalkyl. The polynorbonene backbone can have substituents such as H, CH3, X which is a halo group, and C2-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkoxy, phenoxy, and aryloxy. In a preferred embodiment, the pendant triphosphazene group can have either —CH2CF3, phenyl, 4-ethylcarboxylatophenyl, —CH2CH3, or —CH2CH2OCH2CH2OCH3 while the polynorbonene backbone can have H and low alkyl groups. The polyphosphazene compositions can be prepared readily via ring-opening-metathesis-polymerization of an olefin having norbornene structure with pendant cyclotriphosphazene groups. The polyphosphazene compositions disclosed are useful as elastomers, optical materials, electrically conductive materials, biomedical materials, compatibilizing agents, surfactants, additives for coatings, and as flame retardants.
摘要翻译：已经开发了包含聚碳链烷骨架和侧链三磷腈基团的聚合物组合物。侧环三膦腈基可以具有各种取代基，例如C1-C10烷基，C1-C10卤代烷基，C3-C6环烷基，苯基，取代的苯基，芳基， - （CH2CH2OCH2CH2）nOCH3，其中n是正整数，氨基烷基，烷氧基烷基，苯氧基烷基，芳氧基烷基和酰氨基烷基。多亚碳烯骨架可以具有取代基，例如H，CH 3，X是卤素基团，和C 2 -C 6烷基，C 3 -C 6环烷基，C 2 -C 6烷氧基，苯氧基和芳氧基。在一个优选的实施方案中，三膦酰基侧基可以具有-CH 2 CF 3，苯基，4-乙基羧基苯基，-CH 2 CH 3或-CH 2 CH 2 OCH 2 CH 2 OCH 3，而多亚氮烷骨架可具有H和低级烷基。聚磷腈组合物可以通过具有降冰片烯结构的烯烃与侧链三环磷腈基团的开环 - 复分解聚合来容易地制备。所公开的聚磷腈组合物可用作弹性体，光学材料，导电材料，生物医学材料，相容剂，表面活性剂，涂料用添加剂和阻燃剂。

7. 发明授权

US5965627A Blends of polyurethane and polyphosphazene and their use as flame-retardant foamed compositions 失效
标题翻译：聚氨酯和聚磷腈的共混物及其作为阻燃发泡组合物的用途
公开(公告)号：US5965627A
公开(公告)日：1999-10-12
申请号：US852769
申请日：1997-05-07
申请人： Harry R. Allcock , Michael M. Coleman , Carey S. Reed , Kevin S. Guigley
发明人： Harry R. Allcock , Michael M. Coleman , Carey S. Reed , Kevin S. Guigley
IPC分类号： C08G18/64 , C08L85/02 , C08L75/00
CPC分类号： C08G18/6461 , C08L85/02 , C08G2101/00
摘要： Flame-retardant polymer blends of a polyurethane polymer or prepolymer and a poly(organophosphazene) are disclosed. Preferred poly(organophosphazenes) contain functional groups capable of reacting with isocyanate groups present during the curing of the polyurethane. The blends are preferably formulated by reacting the poly(organophosphazene) containing functional groups under conditions where some of the functional groups of the poly(organophosphazene) can react with the isocyanate groups present during the polymerization and curing of the polyurethane. These polymer blends are useful for making flame-retardant foamed articles of manufacture.
摘要翻译：公开了聚氨酯聚合物或预聚物和聚（有机膦腈）的阻燃聚合物共混物。优选的聚（有机膦腈）含有能够在聚氨酯固化期间与异氰酸酯基反应的官能团。混合物优选通过在聚（有机膦腈）的一些官能团可以与在聚氨酯的聚合和固化期间存在的异氰酸酯基团反应的条件下使含有聚（有机膦腈）的官能团的反应来配制。这些聚合物共混物可用于制造阻燃发泡制品。

8. 发明授权

US5747604A Polyphosphazenes with unsaturated side groups useful as reaction intermediates, cross-linkable polymers, and as components of interpenetrating polymer networks 失效
标题翻译：具有不饱和侧基的聚磷腈可用作反应中间体，可交联聚合物，以及互穿聚合物网络的组分
公开(公告)号：US5747604A
公开(公告)日：1998-05-05
申请号：US589747
申请日：1996-04-01
申请人： Harry R. Allcock , Karyn Visscher , Young Baek Kim
发明人： Harry R. Allcock , Karyn Visscher , Young Baek Kim
IPC分类号： C08G79/02 , C08L85/02 , C08L101/00
CPC分类号： C08G79/025 , C08L85/02 , C08L101/00 , Y10S525/903
摘要： A number of new poly(organophosphazenes) have been synthesized which bear 2-butenoxy or 4-allyloxyphenylphenoxy side groups. Co-substituent groups included trifluoroethoxy, phenoxy, or benzyloxyphenoxy groups. Species with 4-allyloxyphenylphenoxy units underwent Si--H coupling to linear silanes or siloxanes to extend the side groups and form hybrid phosphazene/organosilicon polymers. A number of these polymers are rubbery elastomers which are readily cross-linked by heat or light. Seven of the mixed-substituent, cross-linked polymers were incorporated into interpenetrating polymer networks (IPN's) with polystyrene, poly(methyl methacrylate), polyacrylonitrile, poly(acrylic acid) and poly(dimethylsiloxane). The phase compatibility characteristics of the IPN's were assessed by DSC, TEM, FT-IR spectroscopy, and 1H and 31P NMR spectroscopy data.
摘要翻译：已经合成了许多具有2-丁烯氧基或4-烯丙氧基苯基苯氧基侧基的新的聚（有机膦腈）。共取代基包括三氟乙氧基，苯氧基或苄氧基苯氧基。具有4-烯丙氧基苯基苯氧基单元的物质经历与线性硅烷或硅氧烷的Si-H偶联以延伸侧基并形成杂化磷腈/有机硅聚合物。许多这些聚合物是通过热或轻易交联的橡胶状弹性体。混合取代的交联聚合物中的7个与聚苯乙烯，聚（甲基丙烯酸甲酯），聚丙烯腈，聚（丙烯酸）和聚（二甲基硅氧烷）掺入互穿聚合物网络（IPN）中。通过DSC，TEM，FT-IR光谱和1H和31P NMR光谱数据评估IPN的相位相容性。

9. 发明授权

US5562909A Phosphazene polyelectrolytes as immunoadjuvants 失效
标题翻译：磷腈聚电解质作为免疫佐剂
公开(公告)号：US5562909A
公开(公告)日：1996-10-08
申请号：US090841
申请日：1993-07-12
申请人： Harry R. Allcock , Alexander K. Andrianov , Robert S. Langer , Karyn B. Visscher
发明人： Harry R. Allcock , Alexander K. Andrianov , Robert S. Langer , Karyn B. Visscher
IPC分类号： A61K39/385 , A61K9/16 , A61K39/39 , C08G79/02
CPC分类号： C08G79/025 , A61K39/39 , A61K9/1641 , A61K2039/541 , A61K2039/55555
摘要： A immunoadjuvant soluble phosphazene polyelectrolyte is disclosed. In one embodiment, the polymeric adjuvant is an poly(organophosphazene) with (i) ionized or ionizable pendant groups that contain, for example, carboxylic acid, sulfonic acid, or hydroxyl moieties, and (ii) pendant groups that are susceptible to hydrolysis under the conditions of use, to impart biodegradability to the polymer.
摘要翻译：公开了一种免疫佐剂可溶性磷腈聚电解质。在一个实施方案中，聚合物助剂是具有（i）含有例如羧酸，磺酸或羟基部分的离子化或可离子化侧基的聚（有机膦腈），和（ii）易于水解的侧基使用条件，赋予聚合物生物降解性。

10. 发明授权

US5457160A Polyphosphazene blends 失效
标题翻译：聚磷腈混合物
公开(公告)号：US5457160A
公开(公告)日：1995-10-10
申请号：US157951
申请日：1993-11-24
申请人： Harry R. Allcock , Karyn B. Visscher
发明人： Harry R. Allcock , Karyn B. Visscher
IPC分类号： C08L25/06 , C08L27/06 , C08L29/04 , C08L33/02 , C08L33/12 , C08L71/00 , C08L85/02
CPC分类号： C08L33/02 , C08L25/06 , C08L27/06 , C08L29/04 , C08L33/12 , C08L85/02 , C08L71/00
摘要： Polymer blends of the following:(i) poly[bis(methylamino)phosphazene] and poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene;(ii) poly[bis(methylamino)phosphazene] with poly(vinyl chloride), poly(methyl methacrylate), poly(ethylene oxide), or polystyrene;(iii) poly[bis(2-(2-methoxyethoxy)ethoxy)phosphazene with poly(vinyl alcohol) or poly(acrylic acid); and(iv) poly[bis(phenoxy)phosphazene] with polystyrene or poly(methyl methacrylate).
摘要翻译：以下聚合物共混物：（i）聚[双（甲基氨基）磷腈]和聚[双（2-（2-（2-甲氧基乙氧基）乙氧基）磷腈）（ii）与聚（氯乙烯），聚（甲基丙烯酸甲酯），聚（环氧乙烷）或聚苯乙烯的聚[双（甲基氨基）磷腈] （iii）聚[二（2-（2-甲氧基乙氧基）乙氧基）磷腈与聚（乙烯醇）或聚（丙烯酸）; 和（iv）聚[双（苯氧基）磷腈]与聚苯乙烯或聚（甲基丙烯酸甲酯）。

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