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1. 发明授权

US4495174A Anesthetic polyorganophosphazenes 失效
标题翻译：麻醉聚有机膦腈
公开(公告)号：US4495174A
公开(公告)日：1985-01-22
申请号：US390345
申请日：1982-06-21
申请人： Harry R. Allcock , Paul E. Austin , Thomas X. Neenan
发明人： Harry R. Allcock , Paul E. Austin , Thomas X. Neenan
IPC分类号： A61K31/80 , A61K47/48 , C08G79/02 , A61K9/58 , C08G79/04
CPC分类号： A61K47/48223 , A61K31/80 , C08G79/025
摘要： A long-acting, local anesthetic, comprising a polymeric phosphazene backbone, and 2-amino-4-picoline radical having local anesthetic activity and an amino functional group on the ring of said radical through which said radical is covalently attached to the phosphazene backbone by a phosphorous-nitrogen single bond is disclosed along with medicaments containing such anesthetics.
摘要翻译：包含聚合磷腈骨架的长效局部麻醉剂和具有局部麻醉活性的2-氨基-4-甲基吡啶基和所述基团的环上的氨基官能团，所述基团通过其将所述基团共价连接到磷腈骨架上公开了含有这种麻醉剂的药物的磷 - 氮单键。

2. 发明授权

US4880622A Water-soluble phosphazene polymers having pharmacological applications 失效
标题翻译：具有药理应用的水溶性磷腈聚合物
公开(公告)号：US4880622A
公开(公告)日：1989-11-14
申请号：US865504
申请日：1986-05-20
申请人： Harry R. Allcock , Paul E. Austin , Sukky Kwon
发明人： Harry R. Allcock , Paul E. Austin , Sukky Kwon
IPC分类号： A01N25/10 , A61K9/20 , C08G79/02
CPC分类号： C08G79/025 , A01N25/10 , A61K9/2031
摘要： Novel poly(organophosphazene) polymers are used for the controlled release of pharmaceuticals, pesticides, herbicides, plant growth regulators and fertilizers. These polymers also act as foam control agents.
摘要翻译：新型聚（有机膦腈）聚合物用于控制药物，农药，除草剂，植物生长调节剂和肥料的释放。这些聚合物也用作泡沫控制剂。

3. 发明授权

US4412066A Polymer bound dyes prepared by diazo coupling reactions with poly(organophosphazenes) 失效
标题翻译：通过与聚（有机膦腈）重氮偶合反应制备的聚合物结合染料
公开(公告)号：US4412066A
公开(公告)日：1983-10-25
申请号：US389118
申请日：1982-06-16
申请人： Harry R. Allcock , Paul E. Austin
发明人： Harry R. Allcock , Paul E. Austin
IPC分类号： C08G79/02 , C09B41/00 , C09B69/10 , G03C1/835 , C08G79/04
CPC分类号： C09B69/106 , C08G79/025 , C09B41/00 , G03C1/835
摘要： Polymer-bound dyes have been prepared by the diazotization of high polymeric [NP(OC.sub.6 H.sub.5).sub.x - (OC.sub.6 H.sub.4 NH.sub.2 -p).sub.y ]n, followed by coupling to phenol, .beta.-naphthol, 6'-NaO.sub.3 S-.beta.-naphthol, and p-aminophenylnaphthalene. These reactions were preceded by model compound studies with the cyclic trimer [NP(OC.sub.6 H.sub.4 NH.sub.2 -p-).sub.2 ].sub.3. In both cases, the aminophenoxy units were generated by reduction of 4-nitrophenoxy groups with the use of PtO.sub.2 and hydrogen. The phosphazene skeleton was unaffected by the reduction, diazotization, and diazo coupling processes. The physical characteristics of the trimers and high polymers are described.
摘要翻译：聚合物结合的染料已经通过高聚物[NP（OC6H5）x-（OC6H4NH2-p）y] n的重氮化制备，然后与苯酚，β-萘酚，6'-NaO 3 S-β-萘酚和p - 氨基苯基萘。之前，用环状三聚体[NP（OC6H4NH2-p-）2] 3进行模型化合物研究。在这两种情况下，通过使用PtO 2和氢还原4-硝基苯氧基来产生氨基苯氧基单元。磷腈骨架不受还原，重氮化和重氮偶合过程的影响。描述了三聚体和高聚物的物理特性。

4. 发明授权

US4636387A Anesthetic polyorganophosphazenes 失效
标题翻译：麻醉聚有机膦腈
公开(公告)号：US4636387A
公开(公告)日：1987-01-13
申请号：US708907
申请日：1984-09-21
申请人： Harry R. Allcock , Paul E. Austin , Thomas X. Neenan
发明人： Harry R. Allcock , Paul E. Austin , Thomas X. Neenan
IPC分类号： A61K31/80 , A61K47/48 , C08G79/02 , A61K9/58 , C08G79/04
CPC分类号： A61K47/48223 , A61K31/80 , C08G79/025
摘要： A long-acting, local anesthetic, comprising a polymeric phosphazene backbone, and certain radicals having local anesthetic activity and an amino functional group on the ring of said radical through which said radical is covalently attached to the phosphazene backbone by a phosphorous-nitrogen single bond is disclosed along with medicaments containing such anesthetics. The radicals employed are 2-amino-4-picoline, benoxinate, naepaine and phenacaine.
摘要翻译：一种长效局部麻醉剂，其包含聚合磷腈骨架，以及某些具有局部麻醉活性的基团和所述基团的环上的氨基官能团，所述基团通过磷 - 氮单键共价连接到磷腈骨架上与包含这种麻醉剂的药物一起被公开。所用的基团是2-氨基-4-甲基吡啶，苯草胺，奈帕因和吩非那韦。

5. 发明授权

US5986022A Continuous manufacture of silicone coploymers 失效
标题翻译：连续生产硅酮共聚物
公开(公告)号：US5986022A
公开(公告)日：1999-11-16
申请号：US53291
申请日：1998-04-01
申请人： Paul E. Austin , James S. Ritscher , Robert A. Kayser , William E. Crane , David D. Farris
发明人： Paul E. Austin , James S. Ritscher , Robert A. Kayser , William E. Crane , David D. Farris
IPC分类号： C08L83/05 , B01J19/18 , C08F2/06 , C08G77/06 , C08G77/12 , C08G77/34 , C08G77/38 , C08G77/46
CPC分类号： B01J19/1862 , C08G77/38 , B01J2219/00094
摘要： Disclosed is a continuous process for producing silicone copolymers using a series of at least one stirred-tank reactor, the last of which reactors in said series has crude product stream feeding into at least one plug flow reactor, wherein this crude product stream is sufficiently homogeneous that this stream which undergoes further reaction in the plug flow reactor does not undergo phase separation.
摘要翻译：公开了使用一系列至少一个搅拌釜反应器生产硅氧烷共聚物的连续方法，其中最后一个反应器中的所述系列中的反应器具有进料至至少一个活塞流反应器的粗产物流，其中该粗产物流足够均匀在活塞流反应器中经历进一步反应的该流不经历相分离。

6. 发明授权

US4857583A Process for the preparation of organopolysiloxane surfactants 失效
标题翻译：制备有机聚硅氧烷表面活性剂的方法
公开(公告)号：US4857583A
公开(公告)日：1989-08-15
申请号：US69527
申请日：1987-07-02
申请人： Paul E. Austin , David D. Farris , James D. Reedy , Charles Blevins , Philbert E. Ramdatt
发明人： Paul E. Austin , David D. Farris , James D. Reedy , Charles Blevins , Philbert E. Ramdatt
IPC分类号： B01F17/54 , C08G18/00 , C08G18/08 , C08G77/42 , C08G77/46 , C08G81/00 , C08J9/00 , C08L75/00 , C08L83/04 , C08L83/05
CPC分类号： C08J9/0061 , C08G77/46 , C08J2375/04 , C08J2483/00
摘要： An improved process is provided for the preparation of siloxane-oxyalkylene block copolymer surfactant compositions which utilized a hydrosilation reaction with high boiling point polar polyols as the reaction solvent. The reaction solvent need not be removed from the block copolymer, particularly when the block copolymer is used as a surfactant for polyurethane foam formulations. Dipropylene glycol is the preferred polar solvent and when used in the preparation of the surfactants need not be removed when the surfactants are employed in the preparation of urethane foams.

7. 发明授权

US5648444A Hydrosilation in esters without hydroxyl moieties 失效
标题翻译：在没有羟基部分的酯中的氢解
公开(公告)号：US5648444A
公开(公告)日：1997-07-15
申请号：US559341
申请日：1995-11-15
申请人： Paul E. Austin , Kenrick M. Lewis , William E. Crane , Rudolph A. Cameron
发明人： Paul E. Austin , Kenrick M. Lewis , William E. Crane , Rudolph A. Cameron
IPC分类号： C08L83/12 , C08G77/46 , C08G81/00 , C08L87/00 , C08G77/06
CPC分类号： C08G77/46
摘要： The present invention encompasses manufacturing polysiloxane polyether copolymers using esters without any hydroxyl groups thereon, organohydrogen silanes and unsaturated polyoxyalkylene polyethers. Said esters are of low volatility and high boiling point and have at least eight carbons. The process yields clear copolymer solutions and do not need to have the ester solvent stripped. Also taught are novel compositions incorporating the ester solvent to make the copolymer and the copolymer and the ester solvent.
摘要翻译：本发明包括使用其上没有任何羟基的酯制备聚硅氧烷聚醚共聚物，有机氢硅烷和不饱和聚氧化烯聚醚。所述酯具有低挥发性和高沸点并且具有至少8个碳。该方法产生透明的共聚物溶液，并且不需要使酯溶剂剥离。还教导了结合酯溶剂以制备共聚物和共聚物和酯溶剂的新型组合物。

8. 发明授权

US5159096A Process for the preparation of siloxane-oxyalkylene copolymers 失效
标题翻译：制备硅氧烷 - 氧化烯共聚物的方法
公开(公告)号：US5159096A
公开(公告)日：1992-10-27
申请号：US767825
申请日：1991-09-30
申请人： Paul E. Austin , Harold D. Furbee , Anne K. McMullen
发明人： Paul E. Austin , Harold D. Furbee , Anne K. McMullen
IPC分类号： C08G77/46
CPC分类号： C08G77/46
摘要： The invention provides an improved solventless hydrosilation process for preparing a siloxane-oxyalkylene copolymers, the improvement comprising conducting the reaction in the presence of at least one sodium metal phosphate.

9. 发明授权

US06448361B1 Continuous manufacture of silicone copolymers 有权
标题翻译：连续制造硅酮共聚物
公开(公告)号：US06448361B1
公开(公告)日：2002-09-10
申请号：US09398749
申请日：1999-09-17
申请人： Paul E. Austin , James S. Ritscher , Robert A. Kayser , William E. Crane , David D. Farris
发明人： Paul E. Austin , James S. Ritscher , Robert A. Kayser , William E. Crane , David D. Farris
IPC分类号： C08G7704
CPC分类号： B01J19/1862 , B01J2219/00094 , C08G77/38
摘要： Disclosed is a continuous process for producing silicone copolymer using a series of at least one stirred-tank reactor the last of which feeds into at least one plug flow reactor, wherein the crude product stream exiting the last of said stirred-tank reactors is sufficiently homogeneous that the stream which undergoes further reaction in the plug flow reactor does not undergo phase separation.
摘要翻译：公开了使用一系列至少一个搅拌釜反应器来生产硅氧烷共聚物的连续方法，其中最后一个反应器进料至少一个活塞流反应器，其中离开最后的所述搅拌釜反应器的粗产物流是足够均匀的在活塞流反应器中经历进一步反应的料流不经历相分离。

10. 发明授权

US06897280B2 Continuous manufacture of silicone copolymers via multi-stage blade-mixed plug flow tubular reactor 有权
标题翻译：通过多级叶片混合塞流式管式反应器连续制造硅氧烷共聚物
公开(公告)号：US06897280B2
公开(公告)日：2005-05-24
申请号：US10253263
申请日：2002-09-23
申请人： Ladislau Heisler , David D. Farris , David B. Davis , Paul E. Austin
发明人： Ladislau Heisler , David D. Farris , David B. Davis , Paul E. Austin
IPC分类号： C10J3/50 , C08G77/08
CPC分类号： C08G77/06 , C08G77/46 , C10J3/50 , C10J2200/09 , C10J2200/152
摘要： A process is disclosed for producing silicone copolymers, wherein the process comprises the steps of: (a) providing at least one multi-stage blade-mixed plug flow reactor having an entry and an exit; (b) continuously feeding (i) hydrogen siloxane, (ii) olefinically substituted polyether or olefin capable of reacting with said hydrogen siloxane, and (iii) catalyst for the reaction to the entry of the multi-stage blade-mixed plug flow reactor, and (c) continuously withdrawing from the exit of the multi-stage blade-mixed plug flow reactor a stream that comprises silicone copolymer and is substantially free of unreacted hydrogen siloxane, provided that said hydrogen siloxane and said polyether or olefin have a residence time at reaction temperature in the multi-stage blade-mixed plug flow reactor sufficient to effect substantially complete hydrosilation.
摘要翻译：公开了一种用于生产硅氧烷共聚物的方法，其中该方法包括以下步骤：（a）提供具有入口和出口的至少一个多级叶片混合活塞式流动反应器; （b）连续进料（i）氢硅氧烷，（ii）能够与所述氢硅氧烷反应的烯属取代的聚醚或烯烃，和（iii）用于与多级叶片混合活塞式流动反应器进入的反应的催化剂，并且（c）从多级叶片混合活塞式流动反应器的出口连续地抽出包含硅氧烷共聚物并且基本上不含未反应的氢硅氧烷的流，条件是所述氢硅氧烷和所述聚醚或烯烃在多级叶片混合活塞式流动反应器中的反应温度足以实现基本上完全的硅氢化。

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