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    • 1. 发明申请
    • Fluorinated divinyl ethers
    • 氟化二乙烯基醚
    • US20060122301A1
    • 2006-06-08
    • US11006879
    • 2004-12-08
    • Haridasan NairDavid Nalewajek
    • Haridasan NairDavid Nalewajek
    • C08K3/26
    • C08F216/125C07C41/06C07C43/17C07C43/172C07C2601/14
    • Fluorinated divinyl ethers having structures according to Formula I or II: RfCX═CY—O—Z—O—CH═CH2  (I) RfCX═CY—O—M—O—CY═CXRf  (II) wherein Rf is fluorine or a C1-C20 fluorinated alkyl; X and Y are independently hydrogen, a halogen, or a C1-C20 fluorinated alkylene; Z is a C1-C20 alkylene, C3-C10 cycloalkylene, four to ten ring member aromatic and non-aromatic heterocycloalkylene, C6-C15 arylene, or C7-C20 arylalkylene; and M is a C1-C20 alkylene, C3-C18 fluorinated alkylene provided that the chain does not terminate with -CHF- or -CF2-, or a C3-C18 diol having the formula —HO—CH2—(CF2)n—CH2—OH— wherein n is an integer from 1 to 16. Curable compositions, polymers, films, coatings, and optical devices comprising fluorinated divinyl ether compounds are also disclosed as well as processes for producing optical devices from the fluorinated divinyl ether compounds and processes for producing the fluorinated divinyl ethers.
    • 具有根据式I或II的结构的氟化二乙烯基醚:<?in-line-formula description =“In-line Formulas”end =“lead”?> R CX-CY-OZO-CH -CH 2(I)<?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas” end =“lead”?> R CX-CY-OMO-CY-CXR (II)<?in-line-formula description =“In-Line Formulas “end =”tail“?>其中R 1是氟或C 1 -C 20氟代烷基; X和Y独立地是氢,卤素或C 1 -C 20氟代亚烷基; Z是C 1 -C 20亚烷基,C 3 -C 10亚环烷基,4至10个环成员 芳族和非芳族杂环亚烷基,C 6 -C 15亚芳基或C 7 -C 20芳基亚烷基; 并且M是C 1 -C 20亚烷基,C 3 -C 18氟化亚烷基,条件是链 不用-CHF-或-CF 2 - 或具有式-HO-CH 2的C 3 -C 18二醇终止, 其中n是1至16的整数。(2)其中n是1至16的整数。 还公开了包含氟化二乙烯基醚化合物的可固化组合物,聚合物,膜,涂料和光学装置,以及从氟化二乙烯基醚化合物生产光学器件的方法和用于生产氟化二乙烯基醚的方法。