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    • 3. 发明授权
    • Method of regenerating adsorbents
    • 再生吸附剂的方法
    • US4179399A
    • 1979-12-18
    • US775982
    • 1977-03-09
    • Horst LichtenbergerKarl KnoblauchHorst GrochowskiHarald JuntgenJurgen Schwarte
    • Horst LichtenbergerKarl KnoblauchHorst GrochowskiHarald JuntgenJurgen Schwarte
    • B01J20/34C01B31/08B01J21/20
    • C01B31/086Y10S502/517
    • A charged adsorbent is accommodated in a desorbing vessel and in an intermediate container which communicates with the desorbing vessel. The charged adsorbent is desorbed in the desorbing vessel by contacting the same with a heat carrier, such as with hot sand, and a desorption gas which develops during the desorption of the charged adsorbent in the desorbing vessel is passed through the charged adsorbent accommodated in the intermediate container to capture at least one component of the desorption gas in the charged adsorbent present in the intermediate container. The purified desorption gas is withdrawn from the intermediate container, and the regenerated adsorbent is gradually discharged from the desorbing vessel and the supply of the adsorbent in the desorbing vessel is replenished by charged adsorbent from the intermediate container. The desorption gas is cooled during the passage thereof through the charged adsorbent present in the intermediate container. The magnitude of the temperature reduction of the desorption gas may be controlled by controlling the rate at which the desorption gas is discharged from the intermediate container, such as by resorting to the use of an adjustable vane. The adsorbent in the intermediate container may be confined by gas-permeable walls through which the desorption gas enters and leaves the adsorbent present in the intermediate container.
    • 带电的吸附剂容纳在解吸容器中和与解吸容器连通的中间容器中。 带电的吸附剂通过使其与热载体(例如用热砂)接触而在解吸容器中解吸,并且在解吸容器中的带电吸附剂的解吸附期间产生的解吸气体通过容纳在 中间容器以捕获存在于中间容器中的带电吸附剂中的解吸气体的至少一个组分。 从中间容器中取出纯化的解吸气体,从解吸容器中逐渐排出再生吸附剂,通过中间容器的带电吸附剂补充解吸容器中的吸附剂的供给。 解吸气体在其通过中间容器中存在的带电吸附剂的过程中被冷却。 解吸气体的温度降低的大小可以通过控制解吸气体从中间容器排出的速度来控制,例如通过使用可调叶片。 中间容器中的吸附剂可以被气体可渗透的壁限制,解吸气体通过其进入并离开存在于中间容器中的吸附剂。
    • 4. 发明授权
    • Method and arrangement for purifying gases
    • US4023939A
    • 1977-05-17
    • US663262
    • 1976-03-03
    • Harald JuntgenKarl KnoblauchHorst GrochowskiJurgen Schwarte
    • Harald JuntgenKarl KnoblauchHorst GrochowskiJurgen Schwarte
    • B01D53/08B01D53/06B01D53/50B01D53/81C01B17/60
    • B01D53/08B01D2253/102B01D2257/302B01D2258/0283
    • A gaseous substance such as a flue gas or a combustion gas contains an adsorbable impurity which is capable of undergoing an exothermic reaction in the presence of oxygen. The gaseous substance is passed into an adsorber via an inlet conduit. In the adsorber, the impurity in the gaseous substance is adsorbed therefrom. The purified gaseous substance is withdrawn from the adsorber therefrom. The purified gaseous substance is withdrawn from the adsorber via an outlet conduit and conveyed to an exhaust stack. The adsorption of the impurity, as well as the reaction thereof with oxygen in the adsorber, liberate heat. The liberated heat is conveyed from the adsorber by the gaseous substance which is being purified and, accordingly, no undue temperature increase, which may harm or even cause combustion of the adsorbent, occurs in the adsorber. The operation of purifying the gaseous substance is carried out at an underpressure so that, when passage of the gaseous substance through the adsorber is interrupted for some reason, currents of air tend to be drawn through the adsorber due to the suction effects generated in the inlet and outlet conduits. The currents of air constitute sources of fresh oxygen and, as a result, reaction of the adsorbed impurity can continue. The liberated heat is no longer removed, however, so that a drastic temperature increase will then occur in the adsorber. To avoid this, a pair of spaced butterfly valves is provided in both the inlet and outlet conduits. The butterfly valves close, although not with absolute gastightness, when the passage of the gaseous substance through the adsorber is interrupted. This reduces the suction effects. Air or an inert gas is admitted into the regions between the respective pairs of butterfly valves until a pressure on the order of atmospheric pressure has been reached in these regions. The air or inert gas serves as a sort of buffer which prevents the suction effects generated by the source of the gaseous substance and the exhaust stack from acting on the adsorber. Although the air or inert gas may leak into the adsorber until atmospheric pressure has been reached in the latter, any oxygen introduced in this manner is quickly used up so that only minimal temperature increases occur in the adsorber.
    • 5. 发明授权
    • Arrangement for regenerating particulate adsorbents
    • 再生颗粒状吸附剂的布置
    • US4201695A
    • 1980-05-06
    • US854528
    • 1977-11-25
    • Harald JuntgenKarl KnoblauchHorst GrochowskiJurgen Schwarte
    • Harald JuntgenKarl KnoblauchHorst GrochowskiJurgen Schwarte
    • B01J8/12B01J20/34C01B31/08B01J21/20B01D15/06B01J37/00
    • C01B31/088B01J20/3416B01J20/3483B01J8/12B01J2220/56
    • A reaction vessel for regenerating particulate adsorbents has a bottom outlet and top inlets for admission of the adsorbent to be regenerated by being heated to a regeneration temperature, and for a particulate regenerating material at a temperature above the regeneration temperature. The mixture of the adsorbent with the regenerating material forms a bed in the reaction vessel and is continuously withdrawn through the outlet so that the bed descends toward the latter and is replenished from above under the formation of a cone at the upper region of the bed. A plurality of tubular baffles coaxially surrounds the inlets which are also coaxial with one another, each of the tubular baffles penetrating into the bed in the region of the cone and retards the flow of the particles of the mixture down the slope of the cone in that the particles must pass underneath the baffle to flow to the next baffle. The bed may be confined between a plurality of axially overlapping spaced tubular guide baffles located in the interior of the reaction vessel with a spacing therefrom. At least one partition may be provided between one of the guide baffles and the vessel, subdividing the chamber between the vessel and the guide baffles into two compartments from which gases which develop during the regeneration of the adsorbent are separately exhausted.
    • 用于再生颗粒吸附剂的反应容器具有底部出口和顶部入口,用于通过加热到再生温度进入待再生的吸附剂,并且在高于再生温度的温度下具有颗粒再生材料。 吸附剂与再生材料的混合物在反应容器中形成床,并通过出口连续排出,使得床向下降并且在床的上部区域处形成锥体,从上方补充。 多个管状挡板同时围绕彼此同轴的入口,每个管状挡板在锥体的区域内渗透入床中,并使混合物颗粒的流动沿锥体的斜面延伸,因此在那 颗粒必须通过挡板下方流到下一个挡板。 床可以限制在位于反应容器内部的多个轴向重叠的间隔开的管状引导挡板之间,其间隔开。 可以在导流挡板和容器之一之间设置至少一个隔板,将容器和引导挡板之间的室细分成两个隔室,在该隔室中吸附剂再生过程中产生的气体分开排出。
    • 9. 发明授权
    • Method and apparatus for regenerating absorption particles
    • 用于再生吸收颗粒的方法和装置
    • US4017422A
    • 1977-04-12
    • US657406
    • 1976-02-12
    • Gunther GappaHarald JuntgenJurgen Klein
    • Gunther GappaHarald JuntgenJurgen Klein
    • B01J8/36B01J20/34C01B31/08B01D53/34B01D15/06
    • B01J8/36B01J20/20B01J20/3416B01J20/3458B01J20/3483C01B31/088B01J2220/56
    • A housing has a foraminous floor adapted to support a bed of adsorption particles. A plurality of baffles spaced above this floor subdivide the bed into a plurality of compartments. Impurity-carrying particles are fed to the compartment at one end of the elongated chamber and the particles overflow a weir at the compartment at the other end of the chamber. A hot gas is passed up through the bed in all of the chambers to deadsorb the particles and the baffles are spaced so that in the direction of flow each baffle projects more deeply into the bed to flow the flow toward the outlet end. A gas above the furthest upstream compartment is collected and condensed to recover useful constituents, and the gas from the other compartments is burned. It is possible to provide an upstream and a downstream compartment at an upper level and below them several downstream compartments, with the gas from the downstream compartments flowing up through the two upper compartments. The chamber has a length equal to at least twice its width and preferably equal to approximately the same multiple of its width as number of compartments it is divided into.
    • 壳体具有适于支撑吸附颗粒床的多孔地板。 在该地板之间间隔开的多个挡板将床分成多个隔间。 杂质携带颗粒在细长室的一端被供给到隔室,并且颗粒在室的另一端处的隔室溢出堰。 热气体在所有室中通过床,以阻止颗粒并且隔板间隔开,使得在流动方向上,每个挡板更深地突入床中以使流动朝向出口端流动。 收集并浓缩最上游隔室上方的气体以回收有用的成分,并且来自其他隔室的气体被燃烧。 可以在上一级和下游隔室设置上游和下游隔室,其中下游隔室中的气体向上流过两个上隔室。 腔室的长度至少等于其宽度的两倍,并且优选地等于其宽度与其被分成的间隔的数量的大致相同的倍数。
    • 10. 发明授权
    • Method of regenerating particulate adsorption agents
    • 再生颗粒吸附剂的方法
    • US4058374A
    • 1977-11-15
    • US694521
    • 1976-06-10
    • Harald JuntgenJurgen KleinGunther Gappa
    • Harald JuntgenJurgen KleinGunther Gappa
    • B01J8/36B01J20/34C01B31/08C02F1/28B01D53/08B01D53/12
    • C01B31/088B01J20/08B01J20/20B01J20/3416B01J20/3433B01J20/3458B01J8/36C02F1/28B01J2220/56
    • An apparatus for performing the method of the invention for the thermal regeneration of contaminated particulate adsorption agents in a fluidized state includes a regeneration chamber which has separate first and second zones for the thermal treatment of the adsorption agents in a fluidized state. A first inlet is provided for admitting contaminated adsorption agents into the first zone and a separate second inlet is provided for admitting contaminated adsorption agents into the second zone. A first outlet is provided for removing regenerated adsorption agents from the first zone whereas a separate second outlet is provided for removing regenerated adsorption agents from the second zone. Means for fluidizing and thermally treating the contaminated adsorption agents so as to regenerate the same includes a combustion chamber arranged to supply hot fluidizing gases to both of the treatment zones. A gas outlet in the regeneration chamber serves to exhaust the fluidizing gases from both of the treatment zones.
    • 用于进行流化状态的污染颗粒吸附剂的热再生的本发明方法的装置包括具有分离的第一和第二区的再生室,用于在流化状态下热处理吸附剂。 提供第一入口用于将污染的吸附剂引入第一区域,并且提供单独的第二入口用于将污染的吸附剂引入第二区域。 提供第一出口用于从第一区域除去再生的吸附剂,而提供单独的第二出口用于从第二区域除去再生的吸附剂。 用于流化和热处理污染的吸附剂以再生污染的吸附剂的装置包括布置成向两个处理区域供应热流化气体的燃烧室。 再生室中的气体出口用于从两个处理区域排出流化气体。