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    • 3. 发明授权
    • Process for the processing of organic textile materials
    • 有机纺织材料加工工艺
    • US4102640A
    • 1978-07-25
    • US741274
    • 1976-11-12
    • Jacques ZurbuchenPaul Dussy
    • Jacques ZurbuchenPaul Dussy
    • D06B19/00D06P1/00D06P1/96D06P5/20D06P5/02B08B3/00
    • D06P1/96D06B19/0029D06B19/0088D06P1/0004D06P5/2066Y02P70/643Y10S8/932
    • Described is a process for the processing of organic textile materials by application of an aqueous dispersion or solution of a processing agent having affinity for the fibres, with a ratio of goods to liquor of at most 1:2, and subsequent fixing of the processing agent by means of a steam treatment, characterized in that the ratio of goods to liquor of the applied liquor is increased, below the absorption temperature of the processing agent, by the admission of saturated steam in such a manner that the processing agent is uniformly dispersed on the material before commencement of the fixing process.The advantages of this process are that there are used practically no products contaminating the waste liquors, particularly no surface-active substances tending to form foam, and that there are nevertheless obtained perfectly satisfactory processing effects. Surprisingly, moreover, irregularities caused by the material are levelled out during dyeing.
    • 描述了一种通过使用对纤维具有亲和性的加工剂的水性分散体或溶液来处理有机纺织材料的方法,其中商品与液体的比例至多为1:2,随后固定加工剂 通过蒸汽处理,其特征在于,通过进入饱和蒸汽使处理剂均匀分散在上述方式下,所施加的液体的商品与液体的比例增加到低于加工剂的吸收温度 材料在开始修理过程之前。
    • 4. 发明授权
    • Water-insoluble reactive dyestuffs which are soluble in aprotic solvents
    • 可溶于非质子溶剂的水不溶性活性染料
    • US3974160A
    • 1976-08-10
    • US412242
    • 1973-11-02
    • Herbert SeilerPaul Dussy
    • Herbert SeilerPaul Dussy
    • C09B62/02D06P1/38D06P1/90D06P1/92D06P3/10C07D251/50
    • C09B62/02D06P1/38D06P1/908D06P1/924D06P1/928D06P3/10
    • Valuable reactive dyestuffs containing no acid, salt-forming, water-solubilizing groups and which, among others, can be applied from organic solvents, especially aprotic solvents correspond to the formula ##EQU1## wherein D represents the radical of an organic dyestuff,Q represents the bridging member --NX.sub.3 --, --O--, --S-- or --NX.sub.3 CO--, whereby X.sub.3 denotes hydrogen or a lower alkyl group,R represents the radical of a nitrogen heterocycle containing at least one substituent which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom,X.sub.1 represents hydrogen, an alkyl or an alkoxyalkyl group andX.sub.2 represents an alkyl or an alkoxyalkyl group having in all at least 4 carbon atoms, whereby X.sub.1 and X.sub.2 must together contain, when X.sub.1 denotes an alkyl or an alkoxyalkyl group, at least 8 carbon atoms,OrX.sub.1 represents a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms, andX.sub.2 represents an unsubstituted or substituted alkyl group having at most 18 carbon atoms, a lower alkenyl group having preferably 1 to 4 carbon atoms or a cyclohexyl radical, unsubstituted or substituted by lower alkyl groups having preferably 1 to 4 carbon atoms. Fiber materials dyed with these dyestuffs exhibit very good fastness properties, especially fastness to wet processing, rubbing and dry-cleaning.
    • 不含酸,盐形成,水溶性基团的有价值的活性染料,其中尤其可以由有机溶剂施用,特别是非质子传递溶剂对应于式X1 DQRN ANGLE X2,其中D表示有机染料的基团Q 表示桥连基团-NX 3 - , - O - , - S-或-NX 3 CO-,其中X 3表示氢或低级烷基,R表示含有至少一个可被分离为阴离子的取代基的氮杂环基团 并且其结合于与叔氮原子相邻的环碳原子,X1表示氢,烷基或烷氧基烷基,X2表示具有全部至少4个碳原子的烷基或烷氧基烷基,由此X1和X2必须一起 含有,当X1表示烷基或烷氧基烷基时,至少有8个碳原子,OR X1代表环己基,未取代或被具有优选1-4个碳原子的低级烷基取代,X2代表 具有至多18个碳原子的未取代或取代的烷基,具有优选1至4个碳原子的低级烯基或未被取代或被具有优选1至4个碳原子的低级烷基取代的环己基。 用这些染料染色的纤维材料表现出非常好的牢度性能,特别是湿法加工,摩擦和干洗牢度。
    • 7. 发明授权
    • Metallized bis-formazans
    • 金属化双甲烷
    • US4158003A
    • 1979-06-12
    • US741017
    • 1976-11-11
    • Otto BitterlinPaul Dussy
    • Otto BitterlinPaul Dussy
    • C09B50/06C09B45/48
    • C09B50/06
    • Heavy-metal-containing bisformazan dyestuffs of the formula ##STR1## WHEREIN A.sub.1, A.sub.2, B.sub.1 and B.sub.2 are the same or different and each represents an unsubstituted or substituted o-phenylene radical or an o-naphthylene radical,R.sub.1 and R.sub.2 are the same or different and each represent a monovalent organic radical,Me.sub.1 and Me.sub.2 each represent nickel or copper,X.sub.1 and X.sub.2 are the same or different and each represents a metal-binding substituent connected to A.sub.1, B.sub.1, A.sub.2 or B.sub.2 in a position ortho to that to which the nitrogen is linked,Y represents the radical of a dibasic carboxylic acid or a radical which is derived from an, at least, bifunctional heterocyclic compound,Z represents a salt-forming water-solubilizing group, dissociating acid in water, selected from --SO.sub.3.sup..crclbar. M.sym. and --COO.sup..crclbar. M.sup..sym.wherein M.sup..sym. represents a cation,N represents a number from 2 to 6, andWherein aromatic radicals present may contain further substituents known per se for use in azo dyestuffs, and wherein the grouping --NH--Y--HN-- is bound directly or via a bridging member to a ring carbon atom of A.sub.1, A.sub.2, B.sub.1, B.sub.2, R.sub.1 or R.sub.2 ,which bis-formazans are substantive dyestuffs suitable for the dyeing or printing of textile material made from natural or regenerated cellulose. The aforesaid bis-formazan dyestuffs are distinguished by high coloring strength and substantivity to cellulose textile material. The dyeings obtained therewith are of a pure shade of color and have good fastness properties, especially to light and wet.
    • 具有下式的重金属的双甲缩醛染料,其中A1,A2,B1和B2相同或不同,并且各自表示未取代或取代的邻亚苯基或邻亚萘基, R1和R2相同或不同,各自表示一价有机基团,Me1和Me2各自表示镍或铜,X1和X2相同或不同,表示与A1,B1,A2或B2连接的金属结合取代基 在与氮连接的位置的邻位,Y表示二元羧酸或至少由双官能的杂环化合物衍生的基团的基团,Z表示形成盐的水溶性基团,离解的 其中M(+)表示阳离子,N代表从2到6的数目,以及存在于本文中的AROMATIC RADICALS可能含有的 在AZO DYESTUFFS和本集团所使用的更多替代品 ING -NH-Y-HN-直接键合或通过桥连构件结合到A1,A2,B1,B2,R1或R2的环碳原子上,双甲烷是适合纺织材料的染色或印花的实质性染料 由天然或再生纤维素制成。 上述双甲an染料的特征在于高着色强度和对纤维素纺织材料的亲和性。 由此获得的染色具有纯色的色泽,并且具有良好的牢度性能,特别是对于光和湿。
    • 9. 发明授权
    • Water-insoluble anthraquinone dyestuffs containing a halodiazinyl group
which are soluble in aprotic solvents
    • 含有可溶于非质子传递溶剂的卤代二乙烯基的水不溶性蒽醌染料
    • US4049661A
    • 1977-09-20
    • US660403
    • 1976-02-23
    • Herbert SeilerPaul Dussy
    • Herbert SeilerPaul Dussy
    • C09B62/00C09B62/02D06P1/38D06P1/90D06P1/92D06P3/10C07D239/00C09B5/16C09B5/44
    • D06P1/924C09B62/00C09B62/02D06P1/38D06P1/908D06P1/928D06P3/10
    • New reactive dyestuffs free from acid, salt-forming, water-solubilizing groups, and having the formula ##STR1## wherein D represents the radical of an anthraquinone dyestuff,Q represents NX.sub.3, O, S or NX.sub.3 CO wherein X.sub.3 represents hydrogen or lower alkyl,R represents diazinyl containing only chlorine, bromine or fluorine substituents, each of which can be split off as anion and which is bound to a ring carbon atom adjacent to a tertiary nitrogen atom,X.sub.1 represents hydrogen andX.sub.2 represents alkyl having from 8 to 18 carbon atoms, orX.sub.1 and X.sub.2 represents the same or different alkyl or alkoxyalkyl wherein X.sub.1 and X.sub.2 must together contain from 8 to 36 carbon atoms, orX.sub.1 represents cyclohexyl or cyclohexyl substituted by lower alkyl, andX.sub.2 represents alkyl of 1 to 18 carbon atoms, alkyl of 1 to 18 carbon atoms substituted by a member selected from the group consisting of hydroxyl, lower alkoxy, lower alkenyloxy and cyano, lower alkenyl, cyclohexyl or cyclohexyl substituted by lower alkyl, said dyestuffs being suitable for the dyeing and printing of hydrophobic organic fibre material, especially fibre material from synthetic polyamide, and being characterized by their good to excellent solubility in aprotic solvents or mixture of solvents.
    • 新的活性染料不含酸,盐形成,水溶性基团,并具有下式:其中D表示蒽醌染料的基团,Q表示NX3,O,S或NX3CO,其中X3表示氢或低级烷基, R表示仅含有氯,溴或氟取代基的二嗪基,其各自可以作为阴离子分离,并且与邻近叔氮原子的环碳原子结合,X1表示氢,X2表示具有8至18个碳原子的烷基 或X 1和X 2表示相同或不同的烷基或烷氧基烷基,其中X 1和X 2必须一起含有8至36个碳原子,或X 1表示被低级烷基取代的环己基或环己基,X 2表示1至18个碳原子的烷基, 被选自羟基,低级烷氧基,低级烯氧基和氰基的低级烯基,环己基或被低级烷基取代的环己基取代的1至18个碳原子的烷基, 所述染料适用于疏水性有机纤维材料的染色和印花,特别是合成聚酰胺的纤维材料,其特征在于其在非质子溶剂或溶剂混合物中的良好至优异的溶解性。